* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
STYCAST UV-300
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Product Use
adhesives
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: red
Change in color: Not available
Physical Form: liquid
Health Hazards: potentially fatal on contact with the skin, harmful if swallowed, harmful if inhaled or on contact with the skin, harmful on contact with the skin or swallowed, respiratory tract irritation, skin irritation, eye irritation, central nervous system depression, allergic reactions, nerve damage
Physical Hazards: May polymerize. Containers may rupture or explode.
Potential Health Effects
Inhalation
Short Term: irritation, nausea, headache
Long Term: same as effects reported in short term exposure
Skin Contact
Short Term: irritation, allergic reactions, rash, itching
Long Term: same as effects reported in short term exposure
Eye Contact
Short Term: irritation
Long Term: same as effects reported in short term exposure
Ingestion
Short Term: no information on significant adverse effects
Long Term: same as effects reported in short term exposure
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
Not Available -- -- | ACRYLIC OLIGOMERS | -- | <74.57 |
27813-02-1 248-666-3 -- | HYDROXYPROPYL METHACRYLATE | -- | <14.5 |
88-12-0 201-800-4 -- | N-VINYL-2-PYRROLIDONE | Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Eye Dam. 1 - H318 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373 Note(s): D | <7.45 |
25584-83-2 247-118-0 -- | HYDROXYPROPYL ACRYLATE | Acute Tox. 3 (Oral) - H301 Acute Tox. 3 (Dermal) - H311 Acute Tox. 3 (Inh.) - H331 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Note(s): C, D | <3.75 |
67-56-1 200-659-6 -- | METHYL ALCOHOL | Flam. Liq. 2 - H225 Acute Tox. 3 (Oral) - H301 Acute Tox. 3 (Dermal) - H311 Acute Tox. 3 (Inh.) - H331 STOT SE 1 - H370 | <2 |
947-19-3 213-426-9 -- | (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE | -- | <1.86 |
2530-85-0 219-785-8 -- | 3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE | -- | <0.8 |
6731-36-8 229-782-3 -- | 1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE | -- | <0.6 |
Not Available -- -- | ESTERS | -- | <0.35 |
79-41-4 201-204-4 -- | METHACRYLIC ACID | Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Skin Corr. 1A - H314 Note(s): D | <0.2 |
84-74-2 201-557-4 -- | DIBUTYL PHTHALATE | Repr. 1B - H360Df Aquatic Acute 1 - H400 | <0.2 |
150-76-5 205-769-8 -- | 4-METHOXYPHENOL | Acute Tox. 4 (Oral) - H302 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 | <0.1 |
75-56-9 200-879-2 -- | PROPYLENE OXIDE | Flam. Liq. 1 - H224 Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Muta. 1B - H340 Carc. 1B - H350 STOT SE 3 - H335 | <0.001 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Never make an unconscious person vomit or drink fluids. Give large amounts of water. DO NOT induce vomiting. If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
Note to Physicians
For inhalation, consider oxygen.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 1 Reactivity: 2
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Slight fire hazard. Containers may rupture or explode if exposed to heat.
Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.
Occupational spill/release
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store in a tightly closed container. Avoid contact with light. Store in a cool, dry place. Store in original container.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
N-VINYL-2-PYRROLIDONE | 88-12-0 |
ACGIH: | 0.05 ppm TWA |
METHYL ALCOHOL | 67-56-1 |
ACGIH: | 200 ppm TWA |
| 250 ppm STEL |
| Skin - potential significant contribution to overall exposure by the cutaneous route |
NIOSH: | 200 ppm TWA; 260 mg/m3 TWA |
| 250 ppm STEL; 325 mg/m3 STEL |
| Potential for dermal absorption |
| 6000 ppm IDLH |
Europe: | 200 ppm TWA; 260 mg/m3 TWA |
| Possibility of significant uptake through the skin |
OSHA (US): | 200 ppm TWA; 260 mg/m3 TWA |
Mexico: | 200 ppm TWA VLE-PPT; 260 mg/m3 TWA VLE-PPT |
| 250 ppm STEL [PPT-CT]; 310 mg/m3 STEL [PPT-CT] |
| Skin - potential for cutaneous absorption |
METHACRYLIC ACID | 79-41-4 |
ACGIH: | 20 ppm TWA |
NIOSH: | 20 ppm TWA; 70 mg/m3 TWA |
| Potential for dermal absorption |
DIBUTYL PHTHALATE | 84-74-2 |
ACGIH: | 5 mg/m3 TWA |
NIOSH: | 5 mg/m3 TWA |
| 4000 mg/m3 IDLH |
OSHA (US): | 5 mg/m3 TWA |
Mexico: | 5 mg/m3 TWA VLE-PPT |
| 10 mg/m3 STEL [PPT-CT] |
4-METHOXYPHENOL | 150-76-5 |
ACGIH: | 5 mg/m3 TWA |
NIOSH: | 5 mg/m3 TWA |
PROPYLENE OXIDE | 75-56-9 |
ACGIH: | 2 ppm TWA |
NIOSH: | 400 ppm IDLH |
OSHA (US): | 100 ppm TWA; 240 mg/m3 TWA |
Mexico: | 20 ppm TWA VLE-PPT; 50 mg/m3 TWA VLE-PPT |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Liquid |
Odor | Not available | Color | red |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | Not available |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | >93.3 °C |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | (negligible) |
Vapor Density (air=1) | >1 | Specific Gravity (water=1) | 1.2 |
Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Volatility | (negligible) | OSHA Flammability Class | IIIB |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
May polymerize violently or explosively.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.
Incompatible Materials
acids, combustible materials, amines, metals, oxidizing materials, peroxides, bases, reducing agents, halo carbons, halogens, metal carbide
STYCAST UV-300 ACIDS (STRONG LEWIS OR MINERAL): Incompatible. AMIDES: Incompatible. AMINES: Incompatible. CARBON STEEL: Incompatible. COPPER: Incompatible. CURING AGENTS: Incompatible. IRON: Incompatible. OXIDIZERS (STRONG): Incompatible. PEROXIDES: Incompatible. N-VINYL-2-PYRROLIDONE ACIDS: May initiate polymerization. AZO COMPOUNDS: May initiate polymerization. OXIDIZERS: Vigorous reaction. PEROXIDES: May initiate polymerization. REDOX REAGENTS: May initiate polymerization. HYDROXYPROPYL ACRYLATE ACIDS: Incompatible. BASES: Incompatible. FREE RADICAL INITIATORS: Incompatible. ORGANIC PEROXIDES: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. REDUCING AGENTS: Incompatible. STEEL (MILD): Incompatible. METHYL ALCOHOL ACETYL BROMIDE: Violent reaction with formation of hydrogen bromide. ALKYLALUMINUM SOLUTIONS: Violent reaction. ALUMINUM: Corrodes. BARIUM PERCHLORATE: Distillation yields highly explosive alkyl perchlorate. BERYLLIUM HYDRIDE: Violent reaction, even at -196 C. BROMINE: Vigorously exothermic reaction. CALCIUM CARBIDE: Violent reaction. CHLORINE: Possible ignition and explosion hazard. CHLOROFORM AND SODIUM HYDROXIDE: Explosive reaction. CHROMIUM TRIOXIDE (CHROMIC ANHYDRIDE): Possible ignition. CYANURIC CHLORIDE: Violent reaction. DICHLOROMETHANE: Possible ignition and explosion. DIETHYL ZINC: Possible ignition and explosion. HYDROGEN PEROXIDE + WATER: Explosion hazard. IODINE + ETHANOL + MERCURIC OXIDE: Explosion hazard. LEAD: Corrodes. LEAD PERCHLORATE: Explosion hazard. MAGNESIUM: Violent reaction. MAGNESIUM (POWDERED): Mixtures are capable of detonation. METALS: Incompatible. NICKEL: Possible ignition in the presence of nickel catalyst. NITRIC ACID (CONCENTRATED): Mixtures of greater than 25% acid may decompose violently. OXIDIZERS (STRONG): Fire and explosion hazard. PERCHLORIC ACID: Explosion hazard. PHOSPHOROUS TRIOXIDE: Possible violent reaction and ignition. PLASTICS, RUBBER, COATINGS: May be attacked. POTASSIUM: Possible dangerous reaction. POTASSIUM HYDROXIDE + CHLOROFORM: Exothermic reaction. POTASSIUM TERT-BUTOXIDE: Fire and explosion hazard. SODIUM + CHLOROFORM: Possible explosion. SODIUM HYPOCHLORITE: Explosion hazard. SODIUM METHOXIDE + CHLOROFORM: Violent reaction. SULFURIC ACID: Fire and explosion hazard. ZINC: Explosion hazard. (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE OXIDIZERS (STRONG): Fire and explosion hazard. HYDROXYPROPYL METHACRYLATE ACIDS: Incompatible. BASES: Incompatible. FREE RADICAL INITIATORS: Incompatible. ORGANIC PEROXIDES: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. REDUCING AGENTS: Incompatible.
Hazardous Decomposition Products
aldehydes, organic acids, acrylic compounds, various organic fragments, oxides of carbon
Thermal decomposition products: aldehydes, organic acids, acrylic compounds, organic compounds, oxides of carbon.
Possibility of Hazardous Reactions
May polymerize. Avoid contact with incompatible materials.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Oral LD50 Rat 11200 mg/kg
Dermal LD50 Rabbit >3000 mg/kg
N-VINYL-2-PYRROLIDONE (88-12-0)
Oral LD50 Rat 830 mg/kg
Dermal LD50 Rabbit 560 mg/kg
Inhalation LC50 Rat 3.07 mg/L 4 h
METHYL ALCOHOL (67-56-1)
Oral LD50 Rat 6200 mg/kg
Inhalation LC50 Rat 22500 ppm 8 h
METHACRYLIC ACID (79-41-4)
Oral LD50 Rat 1060 mg/kg
Dermal LD50 Rabbit 500 - 1000 mg/kg
Inhalation LC50 Rat 7.1 mg/L 4 h
DIBUTYL PHTHALATE (84-74-2)
Oral LD50 Rat 7499 mg/kg
Dermal LD50 Rabbit >20 mL/kg
Inhalation LC50 Rat >15.68 mg/L 4 h
4-METHOXYPHENOL (150-76-5)
Oral LD50 Rat 1600 mg/kg
PROPYLENE OXIDE (75-56-9)
Oral LD50 Rat 520 mg/kg
Dermal LD50 Rabbit 1244 mg/kg
Inhalation LC50 Rat 0.948 mg/L 4 h
Component Carcinogenicity
N-VINYL-2-PYRROLIDONE | 88-12-0 |
ACGIH: | A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans |
IARC: | Monograph 71 [1999]; Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable)) |
DFG: | Category 4 (no significant contribution to human cancer) |
DIBUTYL PHTHALATE | 84-74-2 |
DFG: | Category 3B (could be carcinogenic for man) |
PROPYLENE OXIDE | 75-56-9 |
ACGIH: | A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans |
IARC: | Monograph 60 [1994]; Supplement 7 [1987] (Group 2B (possibly carcinogenic to humans)) |
NTP: | Reasonably Anticipated To Be A Human Carcinogen |
DFG: | Category 4 (no significant contribution to human cancer) |
OSHA: | Present |
Medical Conditions Aggravated by Exposure
eye disorders, kidney disorders, skin disorders and allergies,
Additional Data
May cross react with similar compounds May cause blindness.
May cause liver and kidney damage.
Inhalation - Acute Exposure
HYDROXYPROPYL METHACRYLATE: Vapors may cause irritation N-VINYL-2-PYRROLIDONE: May cause irritation and narcosis at high concentrations Exposure to 3200 mg/m3 was lethal to rats HYDROXYPROPYL ACRYLATE: May cause irritation to nose, throat and respiratory system Rats exposed for 7-8 hours of vapor at room temperature had no significant adverse effects Rats exposed to vapor generated at 100 C for 4.25 hours died either during the exposure or within 1 hour after exposure was terminated Rats exposed for 1 hour to vapors generated at 100 C survived but gross observation revelaed kidney and liver injury METHYL ALCOHOL: May cause irritation of the mucous membranes, coughing, oppression in the chest, tracheitis, bronchitis, tinnitus, unsteady gait, twitching, colic, constipation, nystagmus, and blepharospasm Symptoms from occupational exposure include paresthesias, numbness and shooting pains in the hands and forearms Metabolic acidosis, and effects on the eyes and central nervous system may occur as detailed in acute ingestion (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Inhalation - Chronic Exposure
HYDROXYPROPYL METHACRYLATE: No data available N-VINYL-2-PYRROLIDONE: No data available HYDROXYPROPYL ACRYLATE: No data available METHYL ALCOHOL: Repeated or prolonged exposure may cause effects as in acute ingestion Repeated exposure to 200-375 ppm caused recurrent headaches in workers Exposure for 4 years to 1200-8000 ppm resulted in marked diminution of vision and enlargement of the liver in a workman Reproductive effects have been reported in animals (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Inhalation - Other Toxicity Information
STYCAST UV-300 (Emerson and Cuming, Inc. has reported the following): Vapors from heating may cause respiratory irritation, nausea and headaches Inhalation hazard at room temperature is unlikely, due to the low volatility of this product.
Skin Contact - Acute Exposure
METHYL ALCOHOL: Contact with liquid may cause irritation Skin absorption may occur and cause metabolic acidosis and effects on the eyes and central nervous system as detailed in acute ingestion STYCAST UV-300 (Emerson and Cuming, Inc. has reported the following): Contains material which may cause moderate irritation This product may cause skin sensitization/allergic skin reactions which may be severe in certain individuals Symptoms include rash, itching, hives, and swelling of the extremities May be harmful if absorbed through the skin (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available N-VINYL-2-PYRROLIDONE: Direct contact may cause irritation Exposure to 560 mg/kg was lethal to rabbits HYDROXYPROPYL METHACRYLATE: May cause moderate irritation Caused contact dermatitis in human testing HYDROXYPROPYL ACRYLATE: May cause irritation One worker developed swelling and blisters on his foot 12 hours after initial exposure Six months later an erythematous papular eruption developed on his forearms, thighs, and groin after being exposed for a day Absorption may occur.
Skin Contact - Chronic Exposure
HYDROXYPROPYL METHACRYLATE: Repeated or prolonged contact may cause strong allergic reaction STYCAST UV-300 (Emerson and Cuming, Inc. has reported the following): Prolonged or repeated exposure to the liquid may exert a defatting or drying motion on the skin, possibly resulting in dermatitis (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available HYDROXYPROPYL ACRYLATE: Repeated or prolonged exposure may cause sensitization dermatitis METHYL ALCOHOL: Repeated or prolonged contact with the liquid may cause defatting of the skin resulting in erythema, scaling, and eczematoid dermatitis Chronic absorption may result in metabolic acidosis and effects as detailed in acute ingestion N-VINYL-2-PYRROLIDONE: No data available.
Eye Contact - Acute Exposure
HYDROXYPROPYL METHACRYLATE: May cause severe irritation and possible permanent injury METHYL ALCOHOL: Vapors may cause irritation High concentrations have been reported to cause violent inflammation of the conjunctiva and epithelial defects on the cornea Mild irritation may occur with dilute solutions; the undiluted liquid has produced moderate corneal opacity and conjunctival redness in rabbits Application of a drop of methanol in rabbit eyes caused a mild reversible reaction, graded 3 on a scale of 1-10 after 24 hours N-VINYL-2-PYRROLIDONE: Direct contact with 100 mg caused severe irritation in rabbits HYDROXYPROPYL ACRYLATE: The application of 0.1 ml to rabbits caused severe irritation and corneal injury sufficient to cause impairment of vision (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Eye Contact - Chronic Exposure
HYDROXYPROPYL METHACRYLATE: Repeated or prolonged contact with irritants may cause conjunctivitis METHYL ALCOHOL: Repeated or prolonged contact may cause conjunctivitis N-VINYL-2-PYRROLIDONE: No data available HYDROXYPROPYL ACRYLATE: Repeated or prolonged exposure to irritants may cause conjunctivitis (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Eye - Other Toxicity Information
STYCAST UV-300 (Emerson and Cuming, Inc. has reported the following) Contains material that may cause severe irritation to the eyes.
Ingestion - Acute Exposure
HYDROXYPROPYL METHACRYLATE: No data available N-VINYL-2-PYRROLIDONE: Ingestion of 1470 mg/kg was lethal to rats HYDROXYPROPYL ACRYLATE: The LD50 reported in rats ranged from 250 to 500 mg/kg METHYL ALCOHOL: May cause mild and transient inebriation and subsequent drowsiness followed by an asymptomatic period lasting 8-48 hours Following the delay, coughing, dyspnea, headache, dullness, weakness, vertigo or dizziness, nausea, vomiting, occasional diarrhea, anorexia, violent pain in the back, abdomen, and extremities, restlessness, apathy or delirium, and rarely, excitement and mania may occur Rapid, shallow respiration due to metabolic acidosis, cold and clammy skin, hypotension, cyanosis, opisthotonos, convulsions, mild tachycardia, cardiac depression, peripheral neuritis, cerebral and pulmonary edema, unconsciousness, and coma are possible Effects on the eye may include optic neuritis, blurred or dimmed vision, dilated, unresponsive pupils, ptosis, eye pain, concentric constriction of visual fields, diplopia, change in color perception, photophobia, and optic nerve atrophy Partial blindness or possibly delayed transient or permanent blindness may occur Bilateral sensorineural deafness has been reported in a single case Liver, kidney, heart, stomach, intestinal and pancreatic damage may also occur Death may be due to respiratory failure or rarely from circulatory collapse As little as 15 ml has caused blindness; the usual fatal dose is 60-240 ml Prolonged asthenia and irreversible effects on the nervous system including difficulty in speech, motor dysfunction with rigidity, spasticity, and hypokinesis have been reported (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Ingestion - Chronic Exposure
HYDROXYPROPYL METHACRYLATE: No data available N-VINYL-2-PYRROLIDONE: No data available HYDROXYPROPYL ACRYLATE: No data available METHYL ALCOHOL: Repeated ingestion may cause visual impairment and blindness and other systemic effects as detailed in acute ingestion Reproductive effects have been reported in animals (1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE: No data available.
Ingestion - Other Toxicity Information
STYCAST UV-300 (Emerson and Cuming, Inc. has reported the following) Harmful if swallowed.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
N-VINYL-2-PYRROLIDONE | 88-12-0 |
Algae: | EC50 72 h Desmodesmus subspicatus 780 mg/L IUCLID |
Invertebrate: | EC50 48 h Daphnia species 45 mg/L IUCLID |
HYDROXYPROPYL ACRYLATE | 25584-83-2 |
Fish: | LC50 96 h Pimephales promelas 1.9 mg/L [flow-through] |
METHYL ALCOHOL | 67-56-1 |
Fish: | LC50 96 h Pimephales promelas 28200 mg/L [flow-through]; LC50 96 h Pimephales promelas >100 mg/L [static]; LC50 96 h Oncorhynchus mykiss 19500 - 20700 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 18 - 20 mL/L [static]; LC50 96 h Lepomis macrochirus 13500 - 17600 mg/L [flow-through] |
DIBUTYL PHTHALATE | 84-74-2 |
Fish: | LC50 96 h Pimephales promelas 0.71 - 1.2 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.31 - 5.45 mg/L [static]; LC50 96 h Oncorhynchus mykiss >1.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 1.24 - 5.3 mg/L [static]; LC50 96 h Lepomis macrochirus 1.38 - 1.74 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 0.42 - 1.28 mg/L [static] |
Algae: | EC50 72 h Desmodesmus subspicatus 1.2 mg/L IUCLID; EC50 96 h Pseudokirchneriella subcapitata 0.4 mg/L [static] EPA |
Invertebrate: | EC50 48 h Daphnia magna 2.99 mg/L [Static] EPA; EC50 48 h Daphnia magna 3.4 mg/L IUCLID |
4-METHOXYPHENOL | 150-76-5 |
Fish: | LC50 96 h Pimephales promelas 84.3 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 28.5 mg/L [flow-through] |
PROPYLENE OXIDE | 75-56-9 |
Fish: | LC50 96 h Lepomis macrochirus 215 mg/L [static] |
Algae: | EC50 96 h Pseudokirchneriella subcapitata 240 mg/L IUCLID |
Invertebrate: | EC50 48 h Daphnia magna 350 mg/L IUCLID |
Bioconcentration Factor
METHYL ALCOHOL | 67-56-1 |
BCF | <10 species: fish |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
METHYL ALCOHOL | 67-56-1 |
RCRA: | waste number U154 (Ignitable waste) |
DIBUTYL PHTHALATE | 84-74-2 |
RCRA: | waste number U069 |
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
TDG Information:
No Classification assigned.
ADR Information:
No Classification assigned.
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
METHYL ALCOHOL (67-56-1)
Restriction(s): D/E [UN1230] (II)
METHACRYLIC ACID (79-41-4)
Restriction(s): E [UN2531] (II)
PROPYLENE OXIDE (75-56-9)
Restriction(s): D/E [UN1280] (I)
RID Information:
No Classification assigned.
IATA Information:
No Classification assigned.
ICAO Information:
No Classification assigned.
IMDG Information:
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
METHYL ALCOHOL | 67-56-1 |
SARA 313: | 1 % de minimis concentration |
CERCLA: | 5000 lb final RQ; 2270 kg final RQ |
DIBUTYL PHTHALATE | 84-74-2 |
SARA 313: | 1 % de minimis concentration |
CERCLA: | 10 lb final RQ; 4.54 kg final RQ |
PROPYLENE OXIDE | 75-56-9 |
SARA 302: | 10000 lb TPQ |
SARA 313: | 0.1 % de minimis concentration |
CERCLA: | 100 lb final RQ; 45.4 kg final RQ |
SARA 304: | 100 lb EPCRA RQ |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: Yes Pressure: No Reactivity: Yes
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
N-VINYL-2-PYRROLIDONE | 88-12-0 | No | No | No | Yes | No |
METHYL ALCOHOL | 67-56-1 | Yes | Yes | Yes | Yes | Yes |
METHACRYLIC ACID | 79-41-4 | Yes | Yes | Yes | Yes | Yes |
DIBUTYL PHTHALATE | 84-74-2 | Yes | Yes | Yes | Yes | Yes |
4-METHOXYPHENOL | 150-76-5 | Yes | Yes | Yes | Yes | Yes |
PROPYLENE OXIDE | 75-56-9 | Yes | Yes | Yes | Yes | Yes |
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects
Component Analysis
METHYL ALCOHOL | 67-56-1 |
Repro/Dev. Tox | developmental toxicity , 3/16/2012 |
DIBUTYL PHTHALATE | 84-74-2 |
Repro/Dev. Tox | developmental toxicity , 12/2/2005 |
| male reproductive toxicity , 12/2/05 |
| female reproductive toxicity , initial date 12/2/05 |
PROPYLENE OXIDE | 75-56-9 |
Carc: | carcinogen , 10/1/1988 |
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
N-VINYL-2-PYRROLIDONE | 88-12-0 |
| 1 % |
METHYL ALCOHOL | 67-56-1 |
| 1 % |
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE | 2530-85-0 |
| 1 % |
METHACRYLIC ACID | 79-41-4 |
| 1 % |
DIBUTYL PHTHALATE | 84-74-2 |
| 1 % |
4-METHOXYPHENOL | 150-76-5 |
| 1 % |
PROPYLENE OXIDE | 75-56-9 |
| 1 % |
Germany Water Classification
HYDROXYPROPYL METHACRYLATE (27813-02-1)
ID Number 1256 , hazard class 1 - low hazard to waters
N-VINYL-2-PYRROLIDONE (88-12-0)
ID Number 1141 , hazard class 1 - low hazard to waters
HYDROXYPROPYL ACRYLATE (25584-83-2)
ID Number 2087 , hazard class 1 - low hazard to waters
METHYL ALCOHOL (67-56-1)
ID Number 145 , hazard class 1 - low hazard to waters
ID Number 145 , hazard class 2 - hazard to waters
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE (2530-85-0)
ID Number 4427 , hazard class 1 - low hazard to waters
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
ID Number 1499 , hazard class 2 - hazard to waters
METHACRYLIC ACID (79-41-4)
ID Number 1252 , hazard class 1 - low hazard to waters
DIBUTYL PHTHALATE (84-74-2)
ID Number 186 , hazard class 2 - hazard to waters
ID Number 186 , hazard class 3 - severe hazard to waters
4-METHOXYPHENOL (150-76-5)
ID Number 129 , hazard class 1 - low hazard to waters
PROPYLENE OXIDE (75-56-9)
ID Number 3418 , hazard class 3 - severe hazard to waters
REACH Candidate List of Substances Subject to Authorization (Article 59(1)) - Reg. (EU) No. 1907/2006
This list includes substances listed on the candidate list of substances subject to Authorisation. Once listed on the candidate list, substances present in articles in concentrations meeting or exceeding 0.1 % w/w must be disclosed according to Article 33 of REACH
DIBUTYL PHTHALATE | 84-74-2 |
| Reason for inclusion: Toxic for reproduction, Article 57c |
PROPYLENE OXIDE | 75-56-9 |
| Reason for inclusion: Carcinogenic, Article 57a;Mutagenic, Article 57b |
REACH List of Substances Subject to Authorization (Annex XIV) - Reg. (EU) No. 1907/2006
This list includes substances subject to Authorisation. Under the Authorization requirement of REACH, manufacturers, importers, and downstream users will have to apply for the 'authorisation' to use certain substances
DIBUTYL PHTHALATE (84-74-2)
Intrisic properties: Toxic for reproduction Category 1B,Article 57 Application date: August 21, 2013 Sunset date: February 21, 2015 Exempted uses: Uses in the immediate packaging of medicinal products covered under Regulation (EC) No 726/2004,Directive 2001/82/EC,and/or Directive 2011/83/EC
REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006
This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
DIBUTYL PHTHALATE (84-74-2)
Use restricted. See item 30.; Use restricted. See item 51[b].
PROPYLENE OXIDE (75-56-9)
Use restricted. See item 28.; Use restricted. See item 29.
REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006
This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Assigned to Member State France (Initial Grounds for Concern: Human health/Suspected CMR, Sensitiser, Exposure/Wide dispersive use, Consumer use, High RCR, High aggregated tonnage)
HYDROXYPROPYL ACRYLATE (25584-83-2)
Assigned to Member state France (Initial grounds for concern: Suspected Carcinogenic, suspected Mutagenic, suspected Sensitiser, wide dispersive use, exposure of workers, high RCR, high (aggregated) tonnage, other exposure/risk based concern)
METHYL ALCOHOL (67-56-1)
Assigned to Member State Poland (Initial Grounds for Concern: Human health/Suspected CMR, Exposure/High exposure for workers and the environment, wide dispersive use, consumer use)
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE (2530-85-0)
Assigned to Member State Ireland (Initial Grounds for Concern: Human health/Suspected sensitiser;Exposure/Wide dispersive use, Worker exposure, Consumer use, High aggregated tonnage)
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
Assigned to Member State Germany (Initial Grounds for Concern: Environment/Suspected PBT/vPvB)
Symbol(s)
Xn Harmful
Xi Irritant
Risk Phrases
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
R41 Risk of serious damage to eyes.
R37/38 Irritating to respiratory system and skin.
R43 May cause sensitization by skin contact.
R40 Limited evidence of a carcinogenic effect.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
HYDROXYPROPYL METHACRYLATE | 27813-02-1 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
N-VINYL-2-PYRROLIDONE | 88-12-0 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
HYDROXYPROPYL ACRYLATE | 25584-83-2 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
METHYL ALCOHOL | 67-56-1 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
(1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE | 947-19-3 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE | 2530-85-0 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE | 6731-36-8 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
METHACRYLIC ACID | 79-41-4 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
DIBUTYL PHTHALATE | 84-74-2 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
4-METHOXYPHENOL | 150-76-5 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
PROPYLENE OXIDE | 75-56-9 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
Skin Sensitization Category 1 H317 May cause allergic skin reaction
HYDROXYPROPYL ACRYLATE (25584-83-2)
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
METHYL ALCOHOL (67-56-1)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs
METHACRYLIC ACID (79-41-4)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
DIBUTYL PHTHALATE (84-74-2)
Reproductive Toxicity Category 1B H360Df May damage the unborn child. Suspected of damaging fertility
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
4-METHOXYPHENOL (150-76-5)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Skin Sensitization Category 1 H317 May cause allergic skin reaction
PROPYLENE OXIDE (75-56-9)
Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation (containing <=5% H2SO4)
Germ Cell Mutagenicity Category 1B H340 May cause genetic defects
Carcinogenicity Category 1B H350 May cause cancer
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Symbol(s)
Signal Word Warning
Hazard(s)
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P321 Specific treatment (see label)
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
HYDROXYPROPYL ACRYLATE (25584-83-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause allergic skin reaction
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHYL ALCOHOL (67-56-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H370 Causes damage to organs
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHACRYLIC ACID (79-41-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIBUTYL PHTHALATE (84-74-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H360Df May damage the unborn child. Suspected of damaging fertility
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
4-METHOXYPHENOL (150-76-5)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPYLENE OXIDE (75-56-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H340 May cause genetic defects
H350 May cause cancer
H335 May cause respiratory irritation
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
N-VINYL-2-PYRROLIDONE (88-12-0)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Carcinogenicity Category 2 H351 Suspected of causing cancer
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure)
HYDROXYPROPYL ACRYLATE (25584-83-2)
Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (Minimum classification)
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification)
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
METHYL ALCOHOL (67-56-1)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (Minimum classification)
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification)
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (No information to prove exclusion of certain routes of exposure)
METHACRYLIC ACID (79-41-4)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
DIBUTYL PHTHALATE (84-74-2)
Reproductive Toxicity Category 1B H360Df May damage the unborn child. Suspected of damaging fertility
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
4-METHOXYPHENOL (150-76-5)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Skin Sensitization Category 1 H317 May cause allergic skin reaction
PROPYLENE OXIDE (75-56-9)
Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Germ Cell Mutagenicity Category 1B H340 May cause genetic defects
Carcinogenicity Category 1B H350 May cause cancer
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
N-VINYL-2-PYRROLIDONE (88-12-0)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H318 Causes serious eye damage
H351 Suspected of causing cancer
H335 May cause respiratory irritation
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician
P322 Specific measures (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
HYDROXYPROPYL ACRYLATE (25584-83-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause allergic skin reaction
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHYL ALCOHOL (67-56-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H370 Causes damage to organs
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHACRYLIC ACID (79-41-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIBUTYL PHTHALATE (84-74-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H360Df May damage the unborn child. Suspected of damaging fertility
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
4-METHOXYPHENOL (150-76-5)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPYLENE OXIDE (75-56-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H340 May cause genetic defects
H350 May cause cancer
H335 May cause respiratory irritation
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
N-VINYL-2-PYRROLIDONE (88-12-0) Approval: H27-B-023/C-044B_P
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Acute toxicity Inhalation - Dust and Mist Category 4 H332 Harmful if inhaled
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Carcinogenicity Category 2 H351 Suspected of causing cancer
Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (Central Nervous System,respiratory system,liver)
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system,liver,Hematopoietic System)
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects
HYDROXYPROPYL ACRYLATE (25584-83-2)
Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 25A0018
Acute toxicity Dermal Category 2 H310 Fatal in contact with skin Approval: 25A0018
Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Approval: 25A0018
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 25A0018
Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 25A0018
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25A0018
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 25A0018
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system) Approval: 25A0018
Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: 25A0018
METHYL ALCOHOL (67-56-1)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: 21B3012
Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 21B3012
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 21B3012
Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child Approval: 21B3012
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System,retina,systemic toxicity) Approval: 21B3012
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 21B3012
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 21B3012
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Central Nervous System,retina) Approval: 21B3012
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
Organic Peroxides Type B H241 Heating may cause a fire or explosion Approval: 23A5119
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (kidneys,liver) Approval: 23A5119
METHACRYLIC ACID (79-41-4)
Flammable Liquids Category 4 H227 Combustible liquid Approval: 70
Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 70
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Approval: 70
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage Approval: 70
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 70
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 70
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (adrenal gland,kidneys,liver,nervous system) Approval: 70
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (respiratory system) Approval: 70
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 70
DIBUTYL PHTHALATE (84-74-2)
Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 25B0015
Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child Approval: 25B0015
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25B0015
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system) Approval: 25B0015
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 25B0015
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects Approval: 25B0015
4-METHOXYPHENOL (150-76-5)
Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 897
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 897
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Approval: 897
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 897
PROPYLENE OXIDE (75-56-9)
Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour Approval: 22B4527
Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 99
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Approval: 22B4527
Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Approval: 22B4527
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 22B4527
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 99
Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 99
Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 99
Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 22B4527
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 22B4527
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 99
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 99
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 99
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
N-VINYL-2-PYRROLIDONE (88-12-0)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H311 Toxic in contact with skin
H332 Harmful if inhaled
H318 Causes serious eye damage
H351 Suspected of causing cancer
H371 May cause damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
H412 Harmful to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
HYDROXYPROPYL ACRYLATE (25584-83-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H372 Causes damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P262 Do not get in eyes, on skin, or on clothing
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHYL ALCOHOL (67-56-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H302 Harmful if swallowed
H319 Causes serious eye irritation
H360 May damage fertility or the unborn child
H370 Causes damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H241 Heating may cause a fire or explosion
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
Response
P314 Get medical advice/attention if you feel unwell
Storage
P410 Protect from sunlight
P411+P235 Store at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHACRYLIC ACID (79-41-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H227 Combustible liquid
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIBUTYL PHTHALATE (84-74-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H317 May cause allergic skin reaction
H360 May damage fertility or the unborn child
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
4-METHOXYPHENOL (150-76-5)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H402 Harmful to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPYLENE OXIDE (75-56-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H311 Toxic in contact with skin
H330 Fatal if inhaled
H315 Causes skin irritation
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H402 Harmful to aquatic life
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
HYDROXYPROPYL METHACRYLATE (27813-02-1)
MOEL: | Explosives Division 1.3 H203 Explosive; fire, blast or projection hazard |
METHYL ALCOHOL (67-56-1)
MOE: | Flammable liquids Category 2 H225 Highly flammable liquid and vapour. Acute toxicity Oral Category 3 H301 Toxic if swallowed. Acute toxicity Dermal Category 3 H311 Toxic in contact with skin. Acute toxicity Inhalation Category 3 H331 Toxic if inhaled. Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - Single exposure Category 1 H370 Causes damage to organs. |
MOEL: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs body,Central Nervous System,optic nerve Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure Central Nervous System,eyes |
NEMA: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE (2530-85-0)
MOEL: | Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
NEMA: | Organic Peroxides Type B H241 Heating may cause a fire or explosion |
METHACRYLIC ACID (79-41-4)
MOEL: | Corrosive to Metals Category 1 H290 May be corrosive to metals Acute toxicity Oral Category 4 H302 Harmful if swallowed Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure adrenal gland,kidneys,liver,nervous system Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure respiratory system |
DIBUTYL PHTHALATE (84-74-2)
MOE: | Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child. Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life. |
MOEL: | Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Skin Sensitization Category 1 H317 May cause allergic skin reaction Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs kidneys,nervous system Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure respiratory system Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure liver,testes Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
4-METHOXYPHENOL (150-76-5)
MOEL: | Acute toxicity Oral Category 4 H302 Harmful if swallowed Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
PROPYLENE OXIDE (75-56-9)
MOE: | Flammable liquids Category 1 H224 Extremely flammable liquid and vapour. Acute toxicity Oral Category 4 H302 Harmful if swallowed. Acute toxicity Dermal Category 4 H312 Harmful in contact with skin. Acute toxicity Inhalation Category 3 H331 Toxic if inhaled. Skin corrosion/irritation Category 2 H315 Causes skin irritation. Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation. Germ cell mutagenicity Category 1 H340 May cause genetic defects. Carcinogenicity Category 1 H350 May cause cancer. Specific target organ toxicity - Single exposure Category 3 H335 May cause respiratory irritation. |
MOEL: | Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour Acute toxicity Oral Category 4 H302 Harmful if swallowed Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Skin Sensitization Category 1 H317 May cause allergic skin reaction Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Carcinogenicity Category 1B H350 May cause cancer Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
NEMA: | Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H203 Explosive; fire, blast or projection hazard
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P230 Keep wetted
P240 Ground/Bond container and receiving equipment
P250 Do not subject to grinding/shock/friction
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P370+P380 In case of fire: Evacuate area
P372 Explosion risk in case of fire
P373 DO NOT fight fire when fire reaches explosives
Storage
P401 Store in accordance with local/regional/national/international regulations
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H319 Causes serious eye irritation
H370 Causes damage to organs
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H315 Causes skin irritation
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P321 Specific treatment (see label)
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H241 Heating may cause a fire or explosion
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
Storage
P410 Protect from sunlight
P411+P235 Store at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H290 May be corrosive to metals
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P234 Keep only in original container
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P390 Absorb spillage to prevent material-damage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H360 May damage fertility or the unborn child
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H331 Toxic if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H340 May cause genetic defects
H350 May cause cancer
H335 May cause respiratory irritation
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H341 Suspected of causing genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H335 May cause respiratory irritation
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
HYDROXYPROPYL METHACRYLATE (27813-02-1) Approval: HSR003915
Skin Sensitization Category 1 H317 May cause allergic skin reaction
N-VINYL-2-PYRROLIDONE (88-12-0) Approval: HSR002737
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (blood,liver,upper respiratory system)
Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (digestive system,liver)
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (crustacean)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
HYDROXYPROPYL ACRYLATE (25584-83-2) Approval: HSR004664
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Skin Corrosion/Irritation Category 1C H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates
METHYL ALCOHOL (67-56-1) Approval: HSR001186
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Single Exposure Inhalation Category 1 H370 Causes damage to organs if inhaled (eyes,Nervous System)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
(1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE (947-19-3) Approval: HSR003643
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish)
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE (2530-85-0) Approval: HSR006272
Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8) Approval: HSR001371
Organic Peroxides Type E H242 Heating may cause a fire (>43% Dibutyl phthalate)
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation (>43% Dibutyl phthalate)
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation (>43% Dibutyl phthalate)
Skin Sensitization Category 1 H317 May cause allergic skin reaction (>43% Dibutyl phthalate)
Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child (>43% Dibutyl phthalate)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (fish) (>43% Dibutyl phthalate)
METHACRYLIC ACID (79-41-4) Approval: HSR001539
Flammable Liquids Category 4 H227 Combustible liquid (stabilised)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (stabilised)
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (stabilised)
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage (stabilised)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage (stabilised)
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (kidneys,liver,nose) (stabilised)
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (algal,fish) (stabilised)
Hazardous to the Terrestrial Environment - Soil Category 2 H422 Toxic to the soil environment (stabilised)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates (stabilised)
DIBUTYL PHTHALATE (84-74-2) Approval: HSR002713
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,fish,crustacean)
4-METHOXYPHENOL (150-76-5) Approval: HSR003017
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (crustacean,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
PROPYLENE OXIDE (75-56-9) Approval: HSR001220
Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Germ Cell Mutagenicity Category 1 H340 May cause genetic defects
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (nose)
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
HYDROXYPROPYL METHACRYLATE (27813-02-1)
Symbol(s)
Signal Word Warning
Hazard(s)
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P321 Specific treatment (see label)
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
N-VINYL-2-PYRROLIDONE (88-12-0)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H318 Causes serious eye damage
H372 Causes damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
H433 Harmful to terrestrial vertebrates
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician
P322 Specific measures (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
HYDROXYPROPYL ACRYLATE (25584-83-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H432 Toxic to terrestrial vertebrates
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHYL ALCOHOL (67-56-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H433 Harmful to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
(1-HYDROXYCYCLOHEXYL)PHENYLMETHANONE (947-19-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H303 May be harmful if swallowed
H319 Causes serious eye irritation
H402 Harmful to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
3-(METHACRYLOXYPROPYL)TRIMETHOXYSILANE (2530-85-0)
Symbol(s)
Signal Word Warning
Hazard(s)
H333 May be harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P321 Specific treatment (see label)
1,1-BIS(TERT-BUTYL)-3,3,5-TRIMETHYLCYCLOHEXANE PEROXIDE (6731-36-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H242 Heating may cause a fire
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
H360 May damage fertility or the unborn child
H400 Very toxic to aquatic life
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P405 Store locked up
P410 Protect from sunlight
P411+P235 Store at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHACRYLIC ACID (79-41-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H227 Combustible liquid
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H373 May cause damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
H422 Toxic to the soil environment
H433 Harmful to terrestrial vertebrates
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIBUTYL PHTHALATE (84-74-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H303 May be harmful if swallowed
H319 Causes serious eye irritation
H360 May damage fertility or the unborn child
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
4-METHOXYPHENOL (150-76-5)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
H400 Very toxic to aquatic life
H433 Harmful to terrestrial vertebrates
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPYLENE OXIDE (75-56-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H331 Toxic if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H340 May cause genetic defects
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects
H432 Toxic to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
METHYL ALCOHOL (67-56-1)
Listing: Present
Listing: Present (>=3% and <10% by mass)
PROPYLENE OXIDE (75-56-9)
Listing: Present
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
N-VINYL-2-PYRROLIDONE (88-12-0)
Taiwan: | Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Acute toxicity Dermal Category 3 H311 Toxic in contact with skin |
| Acute toxicity Inhalation Category 3 H331 Toxic if inhaled |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
| Carcinogenicity Category 2 H351 Suspected of causing cancer |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
| Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness |
| Aspiration Hazard Category 2 H305 May be harmful if swallowed and enters airways |
METHYL ALCOHOL (67-56-1)
Taiwan: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child |
| Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (eyes) |
METHACRYLIC ACID (79-41-4)
Taiwan: | Flammable Liquids Category 4 H227 Combustible liquid |
| Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Acute toxicity Dermal Category 3 H311 Toxic in contact with skin |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
DIBUTYL PHTHALATE (84-74-2)
Taiwan: | Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child |
| Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
4-METHOXYPHENOL (150-76-5)
Taiwan: | Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Skin Sensitization Category 1 H317 May cause allergic skin reaction |
PROPYLENE OXIDE (75-56-9)
Taiwan: | Flammable Liquids Category 1 H224 Extremely flammable liquid and vapour |
| Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Acute toxicity Dermal Category 4 H312 Harmful in contact with skin |
| Acute toxicity Inhalation Category 3 H331 Toxic if inhaled |
| Skin Corrosion/Irritation Category 2 H315 Causes skin irritation |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Germ Cell Mutagenicity Category 1 H340 May cause genetic defects |
| Carcinogenicity Category 2 H351 Suspected of causing cancer |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
N-VINYL-2-PYRROLIDONE (88-12-0)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H318 Causes serious eye damage
H351 Suspected of causing cancer
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H305 May be harmful if swallowed and enters airways
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P331 Do NOT induce vomiting
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHYL ALCOHOL (67-56-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
METHACRYLIC ACID (79-41-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H227 Combustible liquid
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIBUTYL PHTHALATE (84-74-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H360 May damage fertility or the unborn child
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
4-METHOXYPHENOL (150-76-5)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPYLENE OXIDE (75-56-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H224 Extremely flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H331 Toxic if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H340 May cause genetic defects
H351 Suspected of causing cancer
H335 May cause respiratory irritation
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved