VANADIUM OXYTRICHLORIDE

inorganic, salt 

VANADYL TRICHLORIDE; TRICHLOROOXOVANADIUM; VANADYL CHLORIDE; VANADIUM TRICHLORIDE MONOXIDE; VANADIUM OXYCHLORIDE; VANADIUM CHLORIDE OXIDE; VANADIUM TRICHLORIDE OXIDE; VANADIUM MONOXIDE TRICHLORIDE; VANADIUM TRICHLORIDE MONOOXIDE; TRICHLOROVANADIUM OXIDE; VANADIUM OXIDE TRICHLORIDE; VANADIUM(V) OXYTRICHLORIDE; STCC 4932388; UN 2443

Emergency Overview 

Color:  yellow 

Change in color: hygroscopic

Physical Form: fuming liquid

Odor:  pungent odor 

Health Hazards:  harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  Contact with water or moist air may generate flammable and/or toxic gases. 

Short Term:  irritation (possibly severe), difficulty breathing 

Long Term:  tooth decay, digestive disorders 

Short Term:  irritation (possibly severe), blisters 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 

Short Term:  burns, diarrhea, stomach pain 

Long Term:  same as effects reported in short term exposure 

This product may be regulated, have exposure limits or other information identified as the following: Vanadium-oxides, Vanadium compounds.

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 

For inhalation, consider oxygen. For ingestion, consider gastric lavage. 

calcium disodium edetate/dextrose, intravenous; calcium disodium edetate/procaine, intramuscular. Get medical attention immediately. 

See Section 9 for Flammability Properties 

Negligible fire hazard. 

carbon dioxide, regular dry chemical Large fires: Flood with water. Apply water from a protected location or from a safe distance. 

Do not get water inside container. Do not scatter spilled material with high-pressure water streams. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. 

Avoid contact with combustible materials. Do not touch spilled material. Do not get water inside container. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water directly on material. Only personnel trained for the hazards of this material should perform clean up and disposal. Dike for later disposal. Do not use water. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. 

Store and handle in accordance with all current regulations and standards. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: Vanadium (V) 0.5 mg/m3 Any air-purifying respirator equipped with an N100, R100, or P100 filter (including N100, R100, and P100 filtering facepieces) except quarter-mask respirators. Any supplied-air respirator. 1.25 mg/m3 Any supplied-air respirator operated in a continuous-flow mode. Any powered, air-purifying respirator with a high-efficiency particulate filter. 2.5 mg/m3 Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 35 mg/m3 Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. 

alcohol, ether, acetic acid 

Contact with water or moist air may form flammable and/or toxic gases or vapors. 

Avoid contact with combustible materials. Keep dry. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. 

combustible materials, metals, 

VANADIUM OXYTRICHLORIDE: ALCOHOLS: Incompatible. ALDEHYDES: Incompatible. ANTIMONY: Incompatible. ARSENIC: Incompatible. CALCIUM: Incompatible. CESIUM: Incompatible. ETHYLENE + PROPYLENE: Catalyzes polymerization. GALLIUM: Incompatible. INDIUM: Incompatible. MANY ORGANIC COMPOUNDS: Reacts. METALS: Corrosive to most metals in the presence of moisture. PHOSPHORUS: Explosive reaction below 100 C with more than small amounts. POTASSIUM: Incompatible. RUBIDIUM: Violent reaction at 60 C. SODIUM: Violent reaction possible.

acid halides, acid halides, oxides of vanadium 

Thermal decomposition products: hydrogen chloride. Thermal decomposition products: hydrogen chloride, oxides of vanadium.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

VANADIUM OXYTRICHLORIDE: Vapors may cause irritation of the nose and throat On contact with moisture this chemical releases hydrochloric acid which is a corrosive material, and severe irritation of the respiratory tract may occur The chemical may be absorbed via inhalation Sore throat, coughing, and shortness of breath may occur.

VANADIUM OXYTRICHLORIDE: Releases hydrochloric acid, an acidic corrosive, on contact with moisture Depending on the concentration and duration of exposure, repeated or prolonged exposure to an acidic substance may cause erosion of the teeth, inflammatory and ulcerative changes in the mouth, and possibly jaw necrosis Bronchial irritation with cough and frequent attacks of bronchial pneumonia may occur Gastrointestinal disturbances are possible.

VANADIUM OXYTRICHLORIDE May cause severe irritation with burns and blisters of the skin.

VANADIUM OXYTRICHLORIDE No data available.

VANADIUM OXYTRICHLORIDE May cause severe irritation.

VANADIUM OXYTRICHLORIDE No data available.

VANADIUM OXYTRICHLORIDE: Releases hydrochloric acid, an acid corrosive, on contact with moisture Severe irritation to tissues may occur Vanadium oxytrichloride may be absorbed via ingestion, and abdominal pain and diarrhea may occur Low levels were lethal to animals.

VANADIUM OXYTRICHLORIDE Depending on the concentration, repeated ingestion of acidic substances may result in inflammatory and ulcerative changes in the mucous membranes of the mouth and other effects as in acute ingestion.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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