* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
5520 DIELECTRIC/ENCAPSULANT COMPOSITION
ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Product Use
adhesives
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: blue
Change in color: Not available
Physical Form: liquid
Odor: pine odor
Health Hazards: respiratory tract burns, skin burns, eye burns, mucous membrane burns, central nervous system depression, allergic reactions, cancer
Potential Health Effects
Inhalation
Short Term: cough, irritation (possibly severe), allergic reactions, metal fume fever, vomiting, diarrhea, chest pain, difficulty breathing, irregular heartbeat, symptoms of drunkenness, emotional disturbances, loss of coordination, lung damage, paralysis, convulsions
Long Term: same as effects reported in short term exposure, irritation, cough, lack of sense of smell, metal fume fever, digestive disorders, weight loss, chest pain, difficulty breathing, wheezing, asthma, headache, bluish skin color, lung damage, blood disorders, reproductive effects, cancer
Skin Contact
Short Term: irritation (possibly severe), allergic reactions
Long Term: same as effects reported in short term exposure, irritation (possibly severe), allergic reactions, skin disorders, rash, lung congestion, kidney damage
Eye Contact
Short Term: irritation (possibly severe), eye damage
Long Term: same as effects reported in short term exposure, irritation, eye damage
Ingestion
Short Term: irritation (possibly severe), rash, changes in body temperature, fever, changes in blood pressure, ringing in the ears, nausea, vomiting, digestive disorders, diarrhea, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, symptoms of drunkenness, dizziness, emotional disturbances, tremors, loss of coordination, hearing loss, internal bleeding, kidney damage, paralysis, convulsions, unconsciousness, coma
Long Term: same as effects reported in short term exposure, cough, rash, changes in blood pressure, ringing in the ears, nausea, vomiting, digestive disorders, diarrhea, stomach pain, loss of appetite, weight loss, difficulty breathing, headache, drowsiness, dizziness, pain in extremities, loss of coordination, hearing loss, bluish skin color, blood disorders
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No |
Component Name Synonyms |
1272/2008 (CLP) |
Percent |
7429-90-5 231-072-3 -- |
ALUMINUM, METALLIC, POWDER |
Flam. Sol. 1 - H228 Water-react. 2 - H261 Note(s): T |
<60 |
7440-21-3 231-130-8 -- |
SILICON |
-- |
<60 |
7440-24-6 231-133-4 -- |
STRONTIUM, POWDER |
-- |
<60 |
7440-67-7 231-176-9 -- |
ZIRCONIUM METAL, DRY |
Pyr. Sol. 1 - H250 Water-react. 1 - H260 Note(s): T |
<60 |
7631-86-9 231-545-4 -- |
SILICON DIOXIDE |
-- |
<60 |
7440-66-6 231-175-3 -- |
ZINC |
-- |
10 - 30 |
25265-77-4 246-771-9 -- |
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE |
-- |
5 - 10 |
7440-39-3 231-149-1 -- |
BARIUM |
-- |
5 - 10 |
112-73-2 204-001-9 -- |
DIETHYLENE GLYCOL DIBUTYL ETHER |
-- |
5 - 10 |
131-11-3 205-011-6 -- |
DIMETHYL PHTHALATE |
-- |
5 - 10 |
1345-16-0 310-193-6 -- |
COBALT ALUMINATE BLUE SPINEL |
-- |
1 - 5 |
770-35-4 212-222-7 -- |
PHENOXYISOPROPANOL |
-- |
1 - 5 |
9004-57-3 618-384-9 -- |
ETHYLCELLULOSE |
-- |
1 - 5 |
Not Available -- -- |
PROPRIETARY COMPONENT |
-- |
0.1 - 1 |
Not Available -- -- |
AMINE SALT |
-- |
0.1 - 1 |
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Aluminium compounds, Aluminum, welding fumes, Strontium compounds, Zirconium compounds, n.o.s., Zinc compounds, Barium compounds, inorganic, Barium compounds, n.o.s., Cobalt compounds, Cobalt, inorganic compounds.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Never make an unconscious person vomit or drink fluids. Give large amounts of water. DO NOT induce vomiting. If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
Note to Physicians
For inhalation, consider oxygen.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Slight fire hazard.
Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.
Occupational spill/release
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
ACGIH: |
1 mg/m3 TWA respirable particulate matter |
NIOSH: |
10 mg/m3 TWA total dust; 5 mg/m3 TWA respirable dust |
OSHA (US): |
15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction |
Mexico: |
10 mg/m3 TWA VLE-PPT dust |
SILICON |
7440-21-3 |
NIOSH: |
10 mg/m3 TWA total dust; 5 mg/m3 TWA respirable dust |
OSHA (US): |
15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction |
Mexico: |
10 mg/m3 TWA VLE-PPT inhalable fraction |
|
20 mg/m3 STEL [PPT-CT] |
ZIRCONIUM METAL, DRY |
7440-67-7 |
ACGIH: |
5 mg/m3 TWA |
|
10 mg/m3 STEL |
NIOSH: |
5 mg/m3 TWA |
|
10 mg/m3 STEL |
|
50 mg/m3 IDLH |
OSHA (US): |
5 mg/m3 TWA as Zr (related to Zirconium compounds) |
Mexico: |
5 mg/m3 TWA VLE-PPT as Zr (related to Zirconium compounds) |
|
10 mg/m3 STEL [PPT-CT] as Zr (related to Zirconium compounds) |
SILICON DIOXIDE |
7631-86-9 |
NIOSH: |
6 mg/m3 TWA |
|
3000 mg/m3 IDLH |
OSHA (US): |
20 mppcf TWA; ((80)/(% SiO2) mg/m3 TWA) |
BARIUM |
7440-39-3 |
ACGIH: |
0.5 mg/m3 TWA |
DIMETHYL PHTHALATE |
131-11-3 |
ACGIH: |
5 mg/m3 TWA |
NIOSH: |
5 mg/m3 TWA |
|
2000 mg/m3 IDLH |
OSHA (US): |
5 mg/m3 TWA |
Mexico: |
5 mg/m3 TWA VLE-PPT |
|
10 mg/m3 STEL [PPT-CT] |
COBALT ALUMINATE BLUE SPINEL |
1345-16-0 |
ACGIH: |
0.02 mg/m3 TWA as Co (related to Cobalt inorganic compounds) |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Protective Materials
nitrile butadiene rubber (NBR), polyethylene, vinyl
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying half-mask respirator equipped with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece, organic vapor cartridge(s) and high-efficiency particulate filter(s). Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance
|
Not available |
Physical State
|
Liquid |
Odor
|
pine odor |
Color
|
blue |
Odor Threshold
|
Not available |
pH
|
Not available |
Melting Point
|
Not available |
Boiling Point
|
Not available |
Freezing point
|
Not available |
Evaporation Rate
|
Not available |
Boiling Point Range
|
Not available |
Flammability (solid, gas)
|
Not available |
Autoignition
|
Not available |
Flash Point
|
120 °C (calculated) |
Lower Explosive Limit
|
Not available |
Decomposition
|
Not available |
Upper Explosive Limit
|
Not available |
Vapor Pressure
|
Not available |
Vapor Density (air=1)
|
Not available |
Specific Gravity (water=1)
|
Not available |
Water Solubility
|
(slightly soluble) |
Partition coefficient: n-octanol/water
|
Not available |
Viscosity
|
Not available |
Solubility (Other)
|
Not available |
Density
|
Not available |
Physical Form
|
liquid |
Texture
|
viscous |
OSHA Flammability Class
|
IIIB |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.
Incompatible Materials
acids, bases, halo carbons, halogens, combustible materials, metals, oxidizing materials, metal salts, metal oxides, reducing agents, peroxides, metal carbide, amines
5520 DIELECTRIC/ENCAPSULANT COMPOSITION ACIDS: Incompatible. BASES: Incompatible. CHLORINATED RUBBER: Incomaptible. CHLORINE TRIFLUORIDE: Incompatible. ETHYLENE OXIDE: Incompatible. MAGNESIUM: Incompatible. OXIDIZING AGENTS: Incompatible. ZIRCONIUM ACID SOLUTIONS: Violent reaction. ALKALI HYDROXIDES: Explosion on heating. ALKALI METAL CARBONATES: Explosive reaction. ALKALI METAL SALTS (CHROMATES, DICHROMATES, MOLYBDATES, SULFATES, TUNGSTATES) Violent or explosive reaction. AQUA REGIA: Reacts. BORAX: Explosion on heating. CARBON DIOXIDE: Fire and explosion hazard. CARBON DIOXIDE AND NITROGEN: Ignites on heating. CARBON TETRACHLORIDE: Explosion. CUPRIC OXIDE: Explosion. FLAMMABLE GASES: Violent or explosive reaction. FLAMMABLE LIQUIDS: Violent or explosive reaction. HYDROGEN FLUORIDE: Reacts. IRON OXIDE (DUST): Exothermic reaction. LEAD: 10-70% zirconium alloy ignites on impact with hammer. LEAD OXIDE: Explosion. NITROGEN: Fire and explosion hazard. NITRYL FLUORIDE: Incandescent reaction. MAGNESIUM CHLORIDE: Fire and explosion hazard. ORGANIC PEROXIDES: Violent or explosive reaction. OXIDIZERS: Violent or explosive reaction. PHOSPHORIC ACID (HOT): Reacts. PHOSPHORUS: Incandescent reaction when heated in a vacuum. POTASSIUM BISULFATE: Fire and explosion hazard. POTASSIUM CHLORATE: Explosion on heating and ignition on impacts. POTASSIUM HYDROXIDE: Attacks metals. POTASSIUM NITRATE: Explosion on heating. SODIUM TETRABORATE (HYDRATED): Explosive reaction. SULFURIC ACID (HOT, CONCENTRATED): Attacks. ZIRCONIUM HYDROXIDE: Explosion reaction. SILICON ALUMINUM + LEAD OXIDE: Mixture may explode on heating. BROMINE TRIFLUORIDE: Ignition reaction. CESIUM ACETYLIDE: Vigorous reaction on heating. CALCIUM: Violently incandescent reaction above 1050 C, after a short delay. CHLORINE (GASEOUS): Ignition on contact at ambient temperatures. CHLORINE TRIFLUORIDE: Ignition reaction. COBALT TRIFLUORIDE: Exothermic reaction, attaining red heat on warming. FLUORINE: Ignites at room temperature; attains temperatures above 1400 C. HYDROFLUORIC ACID: Attacks silicon. HYDROFLUORIC ACID + NITRIC ACID MIXTURE: Attacks silicon. IODINE PENTAFLUORIDE: Incandescent reaction. IRIDIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. LEAD OXIDE: An initiating mixture of silicon and lead dioxide (2: 1) attains a temperature around 1100 C after ignition by small flame. MANGANESE TRIFLUORIDE: Violent reaction. METAL CARBONATES (ALKALI): Exothermic reaction on heating, attaining incandescence and evolving carbon monoxide. MOLYBDENUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. NITROSYL FLUORIDE: Reacts with incandescence. OSMIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN DIFLUORIDE: Generates sparks on heating. PEROXYFORMIC ACID: Traces of manganese dioxide may promote oxidation with ignition. RHENIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. RUBIDIUM ACETYLIDE: Reacts vigorously on warming. SILVER FLUORIDE: Violent reaction. SODIUM-POTASSIUM ALLOY: The reaction forms sodium silicide, which is spontaneously flammable in air. URANIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. WATER: Combustible or explosive reaction at sufficiently high temperatures and pressures. SILICON DIOXIDE CHLORINE TRIFLUORIDE: Fire hazard. FLUORINE: Fire hazard. HYDROCHLORIC ACID + WATER: Explosion hazard with gel form. HYDROFLUORIC ACID: Dissolves, releasing silicon tetrafluoride. HYDROGEN FLUORIDE: Incompatible. HYDROGENATED VEGETABLE OILS: Incompatible. MAGNESIUM (POWDERED): Explosion hazard on heating in the presence of moisture. MANGANESE TRIFLUORIDE: May react violently on heating, releasing silicon tetrafluoride. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN DIFLUORIDE: Explosion hazard under certain conditions and in the presence of moisture. OZONE: Potential explosion hazard at low temperatures if organic material is present. PHOSPHORIC ACID (CONCENTRATED): Attacks on heating. SODIUM (BURNING): Reacts with finely divided silica. VINYL ACETATE (VAPOR): May react vigorously with gel form. XENON HEXAFLUORIDE: May react explosively by forming xenon trioxide. STRONTIUM ACETOACETIC ACID: May react with evolution of hydrogen. ACIDS (CONCENTRATED): Violent reaction. ALCOHOLS: May react with evolution of hydrogen. ANILINE: May react with evolution of hydrogen. BROMINE: Ignites at 400 C. CHLORINE: Incandescent reaction at 300 C. ETHYL ALCOHOL: May react with the evolution of hydrogen. HALOGENS: May ignite. MERCURY OXIDE: Possible explosion. METAL SALTS: Possible explosion. OXIDIZERS (STRONG): Vigorous reaction. SILVER CHLORIDE: Possible explosion. SILVER OXIDE: Possible explosion. ZINC ACIDS: Evolves hydrogen gas which may be ignited by the heat of the reaction ALKALIES: Evolves hydrogen gas which may be ignited by the heat of the reaction. ALUMINUM (POWDER): Possible ignition. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL: May spark on impact. AMMONIUM NITRATE: Violent reaction or formation of explosive mixture. AMMONIUM SULFIDE: May explode in a closed container. ARSENIC: Incandescent reaction when heated. ARSENIC TRIOXIDE: Explosive reaction on heating. BROMOMETHANE: Forms flammable compounds. CADMIUM: Incandescent reaction. CALCIUM CHLORIDE: Evolves hydrogen gas which may be ignited by the heat of the reaction. CARBON DISULFIDE: Incandescent reaction. CARBON TETRACHLORIDE + METHANOL: Extremely vigorous reaction. CHLORATES: Forms shock-sensitive mixtures. CHLORINATED RUBBER: Violent or explosive reaction at elevated temperatures. CHROMIC ANHYDRIDE: Violent reaction and possible ignition. COBALT HALIDE (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. ETHYL ACETOACETATE + TRIBROMONEOPENTYL ALCOHOL: May react explosively. HALOCARBONS: Possible violent reaction with ignition. HALOGENS: Possible ignition. HYDRAZINE NITRATE: Ignites on warming. HYDROXYLAMINE: May ignite or explode when heated. INTERHALOGENS: Violent reaction and possible ignition. LEAD AZIDE: Increased sensitivity to explosive decomposition. MANGANESE DICHLORIDE: Explosive reaction when heated. METAL OXIDES: Possible ignition or incandescent reaction. NITRIC ACID: Incandescent reaction. 2-NITROANISOLE + SODIUM HYDROXIDE: Exothermic reaction. NITROBENZENE: May form pyrophoric residue. NITRYL FLUORIDE: Incandesces when warmed. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXYFORMIC ACID: Violent explosion on contact. POTASSIUM NITRATE: Explosive reaction on heating. POTASSIUM PEROXIDE: Incandescent reaction. RHODIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. RUTHENIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. SELENIUM: Incandescent reaction. SELENINYL BROMIDE: Ignition. SILVER + ELECTROLYTES (BATTERIES): May spontaneously combust. SODIUM PEROXIDE: Incandescent reaction. SULFUR: Violent reaction. TELLURIUM: Incandescent reaction. ZINC CHLORIDE: May increase flammability. BARIUM ACIDS: Violent reaction. AMMONIA: Incompatible. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. CARBON TETRACHLORIDE: Violent reaction or possible explosion. FLUOROTRICHLOROMETHANE: Forms an explosive mixture. IODINE HEPTAFLUORIDE: Exothermic reaction. OXIDIZERS (STRONG): Fire and explosion hazard. TETRACHLOROETHYLENE: Forms an explosive mixture. TRICHLOROETHYLENE: Forms an explosive mixture. TRICHLOROTRIFLUOROETHANE: Forms an explosive mixture. DIETHYLENE GLYCOL DIBUTYL ETHER OXIDIZERS (STRONG): Fire and explosion hazard. ETHERS BORON TRIIODIDE: Vigorous reaction. DIMETHYL PHTHALATE ACIDS (STRONG): Fire and explosion hazard. ALKALIES (STRONG): Fire and explosion hazard. NITRATES: Fire and explosion hazard. OXIDIZERS (STRONG): Fire and explosion hazard. 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE ACIDS: May react. OXIDIZERS (STRONG): Fire and explosion hazard. COBALT ALUMINATE BLUE SPINEL OXIDIZERS (STRONG): Incompatible. PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER) ACIDS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. ETHYLCELLULOSE OXIDIZERS (STRONG): Fire and explosion hazard. ALUMINUM ACIDS: Reacts to form flammable hydrogen gas. ALCOHOLS: Vigorous reaction, with increase in temperature and pressure. AMMONIUM NITRATE: Explosive mixture. AMMONIUM PEROXODISULFATE: Possible explosion. ANTIMONY: Violent reaction when heated. ANTIMONY TRICHLORIDE (VAPOR): Ignition. ARSENIC: Violent reaction when heated. BARIUM PEROXIDE: Ignition on contact. BASES: Reacts to form flammable hydrogen gas. BISMUTH (POWDERED): Pyrophoric mixture. BISMUTH TRIOXIDE: Explodes on heating. BROMINE: Vigorous reaction. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. CARBON DIOXIDE: Ignites when heated. CARBON DIOXIDE + ALUMINUM HALIDES: Incandescent reaction. CARBON DISULFIDE (VAPOR): Ignition. CARBON TETRACHLORIDE + METHANOL: Possible hazardous reaction. CHLORINE: Ignition. CHLORINE TRIFLUORIDE + CHARCOAL: Possible violent reaction. CHLOROFLUOROHYDROCARBONS: Forms shock-sensitive mixture. CHLOROFORMAMIDINIUM NITRATE: Explosive ignition. CHROMIC ANHYDRIDE: Violent reaction or ignition. DIBORANE: Forms spontaneously flammable hydrides. DISULFUR DIBROMIDE: Violent reaction. FLUORINE: Attacks. FORMIC ACID: Incandescent reaction. HALOCARBONS: Explodes on contact. HYDROCHLORIC ACID: Violent reaction. HYDROFLUORIC ACID: Violent reaction. HYDROGEN CHLORIDE: Vigorous exothermic reaction. INTERHALOGENS: Possible ignition or explosive reaction. IODINE + WATER: Violent reaction. IRON: Exothermic reaction with evolution of flammable hydrogen gas. MERCURY: Reacts violently. MERCURY(II) SALTS: Vigorous reaction. METAL BROMATES: Forms shock-sensitive mixture. METAL CHLORATES: Forms shock-sensitive mixture. METAL IODATES: Forms shock-sensitive mixture. METAL NITRATES: Forms explosive mixture. METAL OXIDES: Violent or explosive reaction if heated. METAL SULFATES: Violent explosive reaction. METHANOL: Forms a detonable mixture. NIOBIUM OXIDE + SULFUR: Dangerous fire hazard. NITRIC OXIDE (VAPOR): Ignition. NITROUS OXIDE (VAPOR): Ignition. NITRYL FLUORIDE: Incandesces when heated. NON-METALS: Violent reaction. NON-METAL HALIDES: Ignition. OXIDIZERS: Fire and explosion hazard. OXYGEN: Spontaneous ignition and possible explosion. PALLADIUM: Exothermic reaction at 600 C. PERFORMIC ACID: Violent reaction. PEROXIDES: Possible ignition or explosion. PHOSGENE: Spontaneous ignition. PICRIC ACID + WATER: Possible ignition. PLATINUM: Rapid exothermic reaction. SILICON + LEAD OXIDE: Explodes on heating. SILICON STEEL: Violent reaction. SILVER CHLORIDE: Possible explosive reaction. SODIUM CARBIDE: Violent reaction. SODIUM CARBONATE: Possible explosion on heating. SODIUM DIURANATE: Exothermic reaction. SODIUM HYDROXIDE: Reacts to form explosive hydrogen gas. SULFUR DIOXIDE: Spontaneous ignition. ZINC: Possible fire hazard.
Hazardous Decomposition Products
oxides of carbon, nitrogen, zinc, phenols, ammonia
Thermal decomposition products: oxides of carbon, nitrogen, zinc, phenolic compounds, ammonia.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
SILICON (7440-21-3)
Oral LD50 Rat 3160 mg/kg
SILICON DIOXIDE (7631-86-9)
Oral LD50 Rat >5000 mg/kg
Dermal LD50 Rabbit >2000 mg/kg
Inhalation LC50 Rat >2.2 mg/L 1 h
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE (25265-77-4)
Oral LD50 Rat 3200 mg/kg
Dermal LD50 Rat >15200 mg/kg
Inhalation LC50 Rat >3.55 mg/L 6 h (no deaths occurred)
BARIUM (7440-39-3)
Oral LD50 Rat 132 mg/kg
DIETHYLENE GLYCOL DIBUTYL ETHER (112-73-2)
Oral LD50 Rat 3900 mg/kg
DIMETHYL PHTHALATE (131-11-3)
Oral LD50 Rat 6800 mg/kg
PHENOXYISOPROPANOL (770-35-4)
Oral LD50 Rat 2830 mg/kg
ETHYLCELLULOSE (9004-57-3)
Oral LD50 Rat >5 g/kg
Component Carcinogenicity
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
ACGIH: |
A4 - Not Classifiable as a Human Carcinogen |
ZIRCONIUM METAL, DRY |
7440-67-7 |
ACGIH: |
A4 - Not Classifiable as a Human Carcinogen |
SILICON DIOXIDE |
7631-86-9 |
IARC: |
Monograph 68 [1997]; Supplement 7 [1987] (Group 3 (not classifiable)) |
BARIUM |
7440-39-3 |
ACGIH: |
A4 - Not Classifiable as a Human Carcinogen |
COBALT ALUMINATE BLUE SPINEL |
1345-16-0 |
ACGIH: |
A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (related to Cobalt inorganic compounds) |
IARC: |
Monograph 52 [1991] (related to Cobalt compounds) (Group 2B (possibly carcinogenic to humans)) |
DFG: |
Category 2 (considered to be carcinogenic for man) (related to Cobalt compounds) |
OSHA: |
Present (related to Cobalt compounds) |
Aluminum itself has not been evaluated by IARC However, aluminum production has been evaluated as IARC Group 1 (Human Sufficient Evidence) There is sufficient evidence that certain exposures occurring during aluminum production cause cancer Adenocarcinomas and squamous-cell carcinomas of the lung in rats were produced after inhalation or repeated intratracheal instillation of various forms of crystalline silica Malignant lymphomas developed in rats after intrapleural and intraperitoneal injections of quartz suspensions and intrapleural injection of cristobalite and tridymite Epidemiologic studies indicate lung cancer occurs more frequently among silicotics than in the general population Several epidemiological studies have been conducted addressing cancer risks among workers exposed to dusts containing cobalt in hard metal production facilities A significant increase in the risk for lung cancer was reported among workers in hard-metal facilities exposed to hard metal dusts containing cobalt and tungsten carbide in France The evidence for just cobalt dust in the absence of tungsten carbide was considered inadequate A study by inhalation of cobalt sulfate heptahydrate in male and female mice and rats showed increased incidences of alveolar/bronchiolar neoplasms in both sexes of mice and rats An increase in adrenal pheochromocytomas in female rats was also observed Sarcomas, at the injection site, were the result of cobalt metal powder being tested in two experiments in rats by intramuscular injection and intrathoracic injection Rabbits also developed sarcomas at the injection site in an experiment by intraosseous injection Intraperitoneal injection of a cobalt-chromium-aluminum spinel in rats produced local malignant tumors; intratracheal instillation produced pulmonary squamous-cell carcinomas.
Medical Conditions Aggravated by Exposure
Alzheimer's disease, respiratory disorders, respiratory disorders, respiratory disorders, skin disorders and allergies, kidney disorders, skin disorders and allergies, respiratory disorders,
Additional Data
Smoking may enhance the toxic effects May cross the placenta May be excreted in breast milk.
Nephrotoxicity has been demonstrated with excessive exposure to silicon Excessive zinc intake has been associated with a copper-deficiency anemia Elevated aluminum levels have been associated with Alzheimer's disease, neurofibrillary degeneration, and anemia.
Inhalation - Acute Exposure
METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours ZIRCONIUM: No data available SILICON: Dust may cause respiratory and mucous membrane irritation and cough Intratracheal administration of 25 mg in rabbits produced slight pulmonary lesions SILICON DIOXIDE: Dusts may cause irritation of the respiratory tract and coughing STRONTIUM, POWDER: On contact with moisture, strontium releases flammable hydrogen gas and strontium hydroxide which is an alkaline corrosive Inhalation of corrosive substances may cause symptoms of respiratory tract irritation possibly including coughing, choking, pain in the nose, mouth and throat and burns of the mucous membranes If sufficient quantities are inhaled, pulmonary edema may develop, often with a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include weak, rapid pulse, hypotension, hemoconcentration and moist rales ZINC: Inhalation of dust may cause irritation with difficulty in breathing and sneezing Neurological and psychiatric symptomology including irritability, upper extremity coarse intention tremor, incoordination, and ataxia have also been reported Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic, or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude, and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but it is quickly lost All symptoms usually subside within 24-36 hours BARIUM: May cause sore throat, coughing, shortness of breath, vomiting, diarrhea, trembling, faintness, and paralysis of the arms and legs Barium and its soluble compounds may also cause dyspnea, weakness, anxiety, cardiac irregularity and other muscle stimulation effects, and convulsions DIETHYLENE GLYCOL DIBUTYL ETHER: May cause irritation DIMETHYL PHTHALATE: Vapor or mist may cause irritation of the upper respiratory tract with coughing, sore throat and difficulty in breathing Central nervous system depression may also occur 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: No data available COBALT ALUMINATE BLUE SPINEL: May cause irritation, nausea, and metallic taste PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): Rats exposed to saturated vapor at room temperature showed no adverse effects However, vapors generated at 100 C, caused rats to experience significant nasal and respiratory irritation ETHYLCELLULOSE: Toxicological studies on animals and humans suggest that methylcellulose, a related compound, is innocuous when in contact with delicate membranes of the body.
Inhalation - Chronic Exposure
METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days ZIRCONIUM: Pulmonary granulomas have been observed in zirconium workers Exposure of animals to zirconium compound dusts caused interstitial pneumonitis, peribronchial abscesses, peribronchial granuloma, and lobular pneumonia Fibrous lung changes and liver necrosis was observed in animals dosed intratracheally with various zirconium compounds SILICON: Inert dust may cause excessive production of mucous, mucous gland hypertrophy, and increased airway resistance and may contribute to chronic bronchitis SILICON DIOXIDE: Exposure to dusts of crystalline or amorphous silica for 6 months to 30 years may result in silicosis with symptoms of cough, chest pain, dyspnea, tachypnea, marked weakness and weight loss This pulmonary insufficiency may be characterised by diffuse nodular fibrosis, distortion of bronchi, diminished chest expansion, decreased vital capacity and compensatory and bullous emphysema Although pulmonary fibrosis has been reported from workers exposed to amorphous silica, the crystalline form is the established cause of fibrotic response in the lung However, the amorphous form has been reported fibrogenic to a lesser extent As the disease progresses, cor pulmonale, cardiorespiratory failure, and death may occur Various forms and preparations of crystalline silica produced adenocarcinomas and squamous cell carcinomas of the lungs in rats STRONTIUM, POWDER: Depending on the concentration and duration of exposure, repeated or prolonged exposure to corrosive substances may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances ZINC: Severe gastrointestinal disturbances and hypochromic anemia have been reported, but other chemicals may have contributed to the effects BARIUM: No data available DIETHYLENE GLYCOL DIBUTYL ETHER: No data available DIMETHYL PHTHALATE: Prolonged exposure may result in irritation 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: No data available COBALT ALUMINATE BLUE SPINEL: Repeated exposure may cause pulmonary problems PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): No data available ETHYLCELLULOSE: No data available.
Inhalation - Other Toxicity Information
ALUMINUM, METALLIC, POWDER: May cause irritation with coughing and shortness of breath Exposure to freshly formed fumes of aluminum may result in metal fume fever See information on metal fume fever Prolonged or repeated exposure to large concentrations of fine dust may cause emphysema, bronchial asthma and pulmonary fibrosis characterized by coughing, sputum production, weakness, anorexia, basal crackles, dyspnea, pneumothorax, and cardiac failure Radiographic and pathological changes in the lungs may occur The lung disease may be rapidly progressive, irreversible, and fatal Bacterial infection may cause progression of the lung disease A few rare cases of encephalophathy have been reported from occupational exposure; symptoms included mental deterioration and seizures In sensitive individuals, aluminum may exacerbate asthma Epidemiological studies of aluminum production have reported increased incidences of lung, bladder, and other cancers among exposed workers However, the causative agents for these cancers have not been determined SILICON DIOXIDE: CARCINOGEN (CRYSTALLINE SILICA).
Skin Contact - Acute Exposure
ALUMINUM, METALLIC, POWDER: May cause irritation by abrasion ZIRCONIUM: Some zirconium compounds may cause sensitization reactions in previously exposed persons SILICON: May cause mechanical irritation SILICON DIOXIDE: Prolonged skin contact with dry particulate may cause drying of the skin STRONTIUM, POWDER: On contact with moisture, strontium releases flammable hydrogen gas and strontium hydroxide which is an alkaline corrosive Direct contact with alkaline substances may cause severe pain, burns and possibly brownish stains The corroded areas are soft, gelatinous and necrotic and the tissue destruction may be deep ZINC: Dust may cause mechanical irritation and mild dermatitis in intertriginous areas Reaction with moisture on skin may result in serious burns BARIUM: May cause irritation DIETHYLENE GLYCOL DIBUTYL ETHER: May cause irritation DIMETHYL PHTHALATE: Use in insect repellant formulations has resulted in very little irritancy for humans Animal studies indicate that absorption through the skin is not likely to result in acute toxic effects 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: Application to the skin of guinea pigs caused slight irritation COBALT ALUMINATE BLUE SPINEL: May cause irritation PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): Low in toxicity by absorption through the skin The LD50 was >2.0 gm/kg when applied to rabbit skin ETHYLCELLULOSE: Contact may cause mild irritation The LD50 for rabbits was >5000 mg/kg The cellulose gums have been considered nonirritating and nonsensitizing.
Skin Contact - Chronic Exposure
ALUMINUM, METALLIC, POWDER: May cause dermatitis with itching Rarely, sensitization reactions have been reported Vascular changes in the skin and congestive numbness of the fingers have been reported from occupational exposure ZIRCONIUM: Repeated contact with some zirconium compounds have produced hypersensitivity granulomas characterized by dusky red-brown papules The granulomas produced by insoluble zirconium salts may persist for years and are resistant to treatment where as those produced by soluble salts usually disappear within a few months SILICON: No data available SILICON DIOXIDE: No data available STRONTIUM, POWDER: Effects depend on the concentration and duration of exposure Repeated or prolonged contact with alkaline substances may cause dermatitis or effects similar to acute exposure ZINC: 300 ug applied to human skin intermittently for 3 days caused mild irritation Allergic reactions are rare, but have been reported BARIUM: Repeated or prolonged contact may cause dermatitis DIETHYLENE GLYCOL DIBUTYL ETHER: No data available DIMETHYL PHTHALATE: The 90 day LD50 by repeated skin application in rabbits was greater than 4 mL/kg Symptoms included pulmonary edema and slight renal damage There was no irritation or sensitization reported Administration to rats and mice produced inflammation and necrosis at the application site 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: Repeated application to guinea pigs resulted in slight irritation COBALT ALUMINATE BLUE SPINEL: No data available PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): Prolonged or repeated contact may cause irritation and possibly burns ETHYLCELLULOSE: No data available.
Skin Contact - Other Toxicity Information
COBALT ALUMINATE BLUE SPINEL: See information on cobalt compounds STRONTIUM: Pyrophoric solids may cause thermal burns On contact with moisture, strontium releases strontium hydroxide, an alkaline corrosive See information on alkaline corrosives.
Eye Contact - Acute Exposure
ALUMINUM, METALLIC, POWDER: May cause irritation due to abrasion and corneal necrosis Intraocular aluminum deposits in human eyes have been well tolerated for several years without injurous effect, except occasionally slight depigmentation of adjacent iris A low-grade uveal inflammation with posterior synechias, partial atrophy of the iris, and small opacities in the lenses and pigmentation of the fundus was reported in rabbits from intraocular deposits ZIRCONIUM: No data available SILICON: Silicon dust may cause irritation SILICON DIOXIDE: Dusts may cause irritation with redness and pain STRONTIUM, POWDER: On contact with moisture, strontium releases flammable hydrogen gas and strontium hydroxide which is an alkaline corrosive Direct contact with alkaline substances may cause pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact There may be edema, destruction of epithelium, corneal opacification, and iritis When damage is less than excessive, these symptoms tend to ameliorate In severe burns, the full extent of the injury may not be immediately apparent Late complications may include persistent edema, vascularization and scarring of the cornea, permanent opacity, staphyloma, cataract, and symblepharon ZINC: Dust may cause mechanical irritation or injury to the surface of the eye, with discomfort, reddening, and tearing Direct contact may cause serious corneal burns BARIUM: Direct contact may cause irritation, redness, and pain DIETHYLENE GLYCOL DIBUTYL ETHER: May cause irritation DIMETHYL PHTHALATE: Contact with the eyes may cause smarting and considerable pain, but no damage or only slight reversible disturbance of the epithelium 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: Application to rabbit eyes caused slight to moderate irritation COBALT ALUMINATE BLUE SPINEL: May cause irritation PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): Application of 2 drops of the liquid to rabbit eyes caused initial pain, irritation and corneal injury which healed within 1 week Vapors generated at 100 C also resulted in eye irritation ETHYLCELLULOSE: Contact may cause mechanical irritation.
Eye Contact - Chronic Exposure
ALUMINUM, METALLIC, POWDER: Capillary changes in the conjunctiva were observed in workers of one aluminum plant ZIRCONIUM: No data available SILICON: No data available SILICON DIOXIDE: No data available STRONTIUM, POWDER: Effects depend on concentration and duration of exposure Repeated or prolonged contact with alkaline substances may result in conjunctivitis or effects as in acute exposure ZINC: No data available BARIUM: Repeated or prolonged exposure may cause conjunctivitis DIETHYLENE GLYCOL DIBUTYL ETHER: No data available DIMETHYL PHTHALATE: Repeated or prolonged exposure may cause conjunctivitis 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: Repeated or prolonged exposure to irritants may cause conjunctivitis COBALT ALUMINATE BLUE SPINEL: No data available PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): Repeated or prolonged exposure to irritants may cause conjunctivitis ETHYLCELLULOSE: No data available.
Eye - Other Toxicity Information
STRONTIUM: Pyrophoric solids may cause thermal burns On contact with moisture, strontium releases strontium hydroxide, an alkaline corrosive See information on alkaline corrosives.
Ingestion - Acute Exposure
ALUMINUM, METALLIC, POWDER: Large doses may cause gastrointestinal irritation, vomiting and diarrhea Aluminum is poorly absorbed and may decrease absorption of other substances Neurotoxic effects may occur in persons with impaired kidney function or chronic renal failure ZIRCONIUM: Zirconium and its salts generally have low systemic toxicity Acutely poisoned animals showed progressive depression and decreased activity until death Pathologic observations included kidney and liver lesions SILICON: May cause digestive tract irritation SILICON DIOXIDE: The effects of ingestion are purely mechanical as the substance is inert chemically and biologically STRONTIUM, POWDER: Ingestion of strontium may cause gastrointestinal disorders, painful contractions in the limbs and possibly myocardial involvement On contact with moisture, strontium releases flammable hydrogen gas and strontium hydroxide which is an alkaline corrosive Alkaline substances may cause immediate pain and circumoral burns and corrosion of the mucous membranes which at first turn white and soapy and then become brown, edematous and ulcerated There may be profuse salivation Swallowing and speech may be difficult at first and then almost impossible Even when there is no evidence of oral burns, the esophagus and stomach may be involved with burning pain, vomiting and diarrhea The vomitus may be thick and slimy with mucus, and later contain blood and shreds of mucous membrane Epiglottal edema may result in respiratory distress and possibly asphyxia Shock with marked hypotension, weak and rapid pulse, shallow respiration, and clammy skin may occur Circulatory collapse may ensue and if uncorrected, lead to renal failure In severe cases, esophageal or gastric perforation are possible and may be accompanied by mediastinitis, substernal pain, peritonitis, abdominal rigidity, and fever Esophageal, and possibly gastric or pyloric stricture may occur within a few weeks, but may be delayed for months or even years Death may result within a short time from asphyxia, circulatory collapse, or aspiration of even minute amounts Later death may be due to the complications of perforation, pneumonia, or the effects of stricture formation ZINC: Large oral doses may cause gastrointestinal distress with stomach cramps, dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting, hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, tightness in the throat, shock, collapse, renal failure, and death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach BARIUM: Barium and soluble barium compounds may cause salivation, vomiting, severe diarrhea with watery and bloody stools, colic, gastroenteritis, weakness, giddiness, anxiety, tinnitis, vertigo, confusion, and increasing somnolence without coma, dyspnea, slow pulse, hypokalemia, delayed kidney damage, and at high levels, hemolysis and hemorrhages in the stomach, intestines and kidneys may occur Stimulation of all muscle types may result in hyperperistalsis, bladder contraction, lumbar pain, muscle twitching progressing to convulsions and/or paralysis, vasoconstriction, and irregular contraction of the heart followed by arrest in systole Death may occur from cardiac or respiratory failure DIETHYLENE GLYCOL DIBUTYL ETHER: The LD50 reported in rats was 3900 mg/kg DIMETHYL PHTHALATE: May cause a burning sensation of the lips, tongue and mouth, and abdominal pain with nausea, vomiting, and diarrhea Central nervous system depression may occur with dizziness, hypotension, unconsciousness, and coma 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: The lethal dose reported in rats was >3200 mg/kg The only symptoms reported were slight transient weakness and sialorrhea COBALT ALUMINATE BLUE SPINEL: No data available PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): 2.83 gm/kg produced central nervous system depression in rats and death within 48 hours Large doses of propylene glycols may produce renal injuries ETHYLCELLULOSE: The LD50 for rats was >5000 mg/kg.
Ingestion - Chronic Exposure
ALUMINUM, METALLIC, POWDER: Animals with a diet of 340 ppm showed decreased growth in 2nd and 3rd generations ZIRCONIUM: Subacute doses of zirconium compounds produced weight loss, weakness, diarrhea, liver damage, and death in animals SILICON: No data available SILICON DIOXIDE: No data available STRONTIUM, POWDER: On a diet high in strontium and low in calcium, young pigs developed severe bone deformities, incoordination, weakness and hindleg paralysis Depending on the concentration, repeated ingestion alkaline substances may result in inflammatory and ulcerative effects on the oral mucous membranes and other effects as with acute exposure ZINC: Patients taking zinc in amounts 10 times the RDA for months and years have not shown any adverse reactions Excessive absorption may cause copper-deficiency anemia Ingestion of approximately 85.7 mg/kg/day for 2 days caused lethargy, lightheadedness, staggering, and difficulty in writing clearly 2 people who ingested 40 ppm in drinking water for several months experienced lack of concentration, drowsiness, mental and physical fatigue, pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, nausea, weight loss, and lassitude 90 ppm in the diet for 5 weeks has resulted in a decrease in the HDL cholesterol level Pancreatic abnormalities have also been observed A diet of 0.25% in rats caused no injury; above 0.25% there was breakdown of the homeostatic mechanism, growth retardation, hypochromic anemia, and defective mineralization of the bones Mice fed 500 ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm for 13 weeks caused liver and kidney damage and some deaths Cows fed 2% for 2 days developed severe enteritis, with 7 of 40 dying Severe pulmonary emphysema and changes in the myocardium, kidneys, and liver were observed Pigs fed >1000 ppm had reduced food intake and weight gain; at >2000 ppm, death occurred after 2 weeks Bone changes were observed in foals fed 5400 ppm High dietary levels of zinc have been associated with reduced fetal weights, altered concentrations of fetal iron and copper, and alopecia and reduced growth of offspring in animals BARIUM: No effects have been reported in humans Animal studies have shown effects on the hemopoietic and central nervous systems DIETHYLENE GLYCOL DIBUTYL ETHER: No data available DIMETHYL PHTHALATE: Rats fed dietary levels of up to 8% for 2 years showed growth effects and chronic nephritic changes 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE: Repeated administration to animals caused a slight increase in liver weights COBALT ALUMINATE BLUE SPINEL: No data available PHENOXYISOPROPANOL (PROPYLENE GLYCOL PHENYL ETHER): No data available ETHYLCELLULOSE: No adverse effects were noted in a group of 80 rats maintained for 8 months on a diet of 1.2% ethylcellulose.
Ingestion - Other Toxicity Information
COBALT ALUMINATE BLUE SPINEL: See information on cobalt compounds STRONTIUM: Ingestion of strontium may cause gastrointestinal disorders, a decrease in serum calcium, painful contractions in the limbs and possibly myocardial involvement On a diet high in strontium and low in calcium, young pigs developed severe bone deformities, incoordination, weakness and hindleg paralysis When fed to dogs, 192 mg/kg body weight produced vomiting and diarrhea Pyrophoric solids may cause thermal burns On contact with moisture, strontium releases strontium hydroxide, an alkaline corrosive See information on alkaline corrosives.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
SILICON DIOXIDE |
7631-86-9 |
Fish: |
LC50 96 h Brachydanio rerio 5000 mg/L [static] |
Algae: |
EC50 72 h Pseudokirchneriella subcapitata 440 mg/L IUCLID |
Invertebrate: |
EC50 48 h Ceriodaphnia dubia 7600 mg/L IUCLID |
ZINC |
7440-66-6 |
Fish: |
LC50 96 h Pimephales promelas 2.16 - 3.05 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.211 - 0.269 mg/L [semi-static]; LC50 96 h Pimephales promelas 2.66 mg/L [static]; LC50 96 h Cyprinus carpio 30 mg/L; LC50 96 h Cyprinus carpio 0.45 mg/L [semi-static]; LC50 96 h Cyprinus carpio 7.8 mg/L [static]; LC50 96 h Lepomis macrochirus 3.5 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.59 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 0.41 mg/L [static] |
Algae: |
EC50 96 h Pseudokirchneriella subcapitata 0.11 - 0.271 mg/L [static] EPA; EC50 72 h Pseudokirchneriella subcapitata 0.09 - 0.125 mg/L [static] EPA |
Invertebrate: |
EC50 48 h Daphnia magna 0.139 - 0.908 mg/L [Static] EPA |
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE |
25265-77-4 |
Fish: |
LC50 96 h Pimephales promelas 30 mg/L |
Algae: |
EC50 72 h Pseudokirchneriella subcapitata 18.4 mg/L IUCLID |
DIMETHYL PHTHALATE |
131-11-3 |
Fish: |
LC50 96 h Lepomis macrochirus 49.5 mg/L; LC50 96 h Lepomis macrochirus 37 - 69 mg/L [static]; LC50 96 h Oncorhynchus mykiss 56 mg/L [flow-through]; LC50 96 h Pimephales promelas 39 mg/L [flow-through]; LC50 96 h Pimephales promelas 121 mg/L [static] |
Algae: |
EC50 72 h Pseudokirchneriella subcapitata 28.4 - 71 mg/L EPA; EC50 72 h Desmodesmus subspicatus 204 mg/L IUCLID; EC50 96 h Pseudokirchneriella subcapitata 20.6 - 45.8 mg/L EPA; EC50 96 h Pseudokirchneriella subcapitata 142 mg/L [static] EPA |
Invertebrate: |
EC50 48 h Daphnia magna 33 mg/L IUCLID |
Bioconcentration Factor
SILICON DIOXIDE |
7631-86-9 |
BCF |
(no bioaccumulation expected) |
DIMETHYL PHTHALATE |
131-11-3 |
BCF |
4.7 - 57 species: fish |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
BARIUM |
7440-39-3 |
RCRA: |
100 mg/L regulatory level |
DIMETHYL PHTHALATE |
131-11-3 |
RCRA: |
waste number U102 |
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
TDG Information:
No Classification assigned.
ADR Information:
No Classification assigned.
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
ALUMINUM, METALLIC, POWDER (7429-90-5)
Restriction(s): E [UN1309] (III, coated); E [UN1309] (II, coated); D/E [UN1396] (II, uncoated); E [UN1396] (III, uncoated)
SILICON (7440-21-3)
Restriction(s): E [UN1346] (III, amorphous)
ZIRCONIUM METAL, DRY (7440-67-7)
Restriction(s): D/E [UN1308] (I, suspended in a flammable liquid); D/E [UN1308] (II, suspended in a flammable liquid); E [UN1358] (II, powdered wetted); E [UN1932] (III, scrap); B/E [UN2008] (I, powder, dry); D/E [UN2008] (II, powder, dry); E [UN2008] (III, powder, dry); E [UN2009] (III, dry); E [UN2858] (III, dry); D/E [UN1308] (III, suspended in a flammable liquid)
ZINC (7440-66-6)
Restriction(s): E [UN1435] (III, ashes); E [UN1436] (I, dust or powder); D/E [UN1436] (II, dust or powder); E [UN1436] (III, dust or powder)
BARIUM (7440-39-3)
Restriction(s): D/E [UN1400] (II)
RID Information:
No Classification assigned.
IATA Information:
No Classification assigned.
ICAO Information:
No Classification assigned.
IMDG Information:
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
SARA 313: |
1 % de minimis concentration (dust or fume only) |
ZINC |
7440-66-6 |
SARA 313: |
1 % de minimis concentration (dust or fume only) |
CERCLA: |
454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm) |
BARIUM |
7440-39-3 |
SARA 313: |
1 % de minimis concentration |
DIETHYLENE GLYCOL DIBUTYL ETHER |
112-73-2 |
TSCA 12b: |
Section 5 , 1 % de minimus concentration |
DIMETHYL PHTHALATE |
131-11-3 |
SARA 313: |
1 % de minimis concentration |
CERCLA: |
5000 lb final RQ; 2270 kg final RQ |
COBALT ALUMINATE BLUE SPINEL |
1345-16-0 |
SARA 313: |
0.1 % de minimis concentration (related to Cobalt inorganic compounds) |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: No Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component |
CAS |
CA |
MA |
MN |
NJ |
PA |
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
Yes |
Yes |
Yes |
Yes |
Yes |
SILICON |
7440-21-3 |
No |
Yes |
Yes |
Yes |
Yes |
STRONTIUM, POWDER |
7440-24-6 |
Yes |
No |
No |
Yes |
No |
ZIRCONIUM METAL, DRY |
7440-67-7 |
Yes |
Yes |
Yes |
Yes |
Yes |
SILICON DIOXIDE |
7631-86-9 |
Yes |
Yes |
Yes |
Yes |
Yes |
ZINC |
7440-66-6 |
Yes |
Yes |
No |
Yes |
Yes |
BARIUM |
7440-39-3 |
No |
Yes |
Yes |
Yes |
Yes |
DIMETHYL PHTHALATE |
131-11-3 |
Yes |
Yes |
Yes |
Yes |
Yes |
COBALT ALUMINATE BLUE SPINEL |
1345-16-0 |
No |
No |
Yes |
Yes |
Yes |
Not listed under California Proposition 65
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
|
1 % |
ZIRCONIUM METAL, DRY |
7440-67-7 |
|
1 % |
SILICON DIOXIDE |
7631-86-9 |
|
1 % |
DIMETHYL PHTHALATE |
131-11-3 |
|
1 % |
Germany Water Classification
ALUMINUM, METALLIC, POWDER (7429-90-5)
ID Number 1443 , not considered hazardous to water
ZIRCONIUM METAL, DRY (7440-67-7)
ID Number 1443 , not considered hazardous to water
SILICON DIOXIDE (7631-86-9)
ID Number 849 , not considered hazardous to water
ID Number 849 , not considered hazardous to water
ZINC (7440-66-6)
ID Number 1349 , not considered hazardous to water (particle size >1mm)
ID Number 7325 , hazard class 2 - hazard to waters (particle size <=1 mm)
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE (25265-77-4)
ID Number 5230 , hazard class 1 - low hazard to waters
BARIUM (7440-39-3)
ID Number 9285 , hazard class 1 - low hazard to waters
DIETHYLENE GLYCOL DIBUTYL ETHER (112-73-2)
ID Number 2575 , hazard class 1 - low hazard to waters
DIMETHYL PHTHALATE (131-11-3)
ID Number 205 , hazard class 1 - low hazard to waters
PHENOXYISOPROPANOL (770-35-4)
ID Number 5043 , hazard class 1 - low hazard to waters
ETHYLCELLULOSE (9004-57-3)
ID Number 5291 , hazard class 1 - low hazard to waters
REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006
This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process
SILICON DIOXIDE (7631-86-9)
Assigned to Member State The Netherlands (Initial Grounds for Concern: Substance characterization/Nanoparticles, toxicity of different forms of the substance)
None needed according to classification criteria.
Component Analysis - Inventory
Component |
CAS# |
US |
CA |
EU |
AU |
PH |
JP |
KR |
CN |
NZ |
ALUMINUM, METALLIC, POWDER |
7429-90-5 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
SILICON |
7440-21-3 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
STRONTIUM, POWDER |
7440-24-6 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
ZIRCONIUM METAL, DRY |
7440-67-7 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
SILICON DIOXIDE |
7631-86-9 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
ZINC |
7440-66-6 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE |
25265-77-4 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
BARIUM |
7440-39-3 |
Yes |
DSL |
EIN |
Yes |
Yes |
No |
Yes |
Yes |
Yes |
DIETHYLENE GLYCOL DIBUTYL ETHER |
112-73-2 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
DIMETHYL PHTHALATE |
131-11-3 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
COBALT ALUMINATE BLUE SPINEL |
1345-16-0 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
PHENOXYISOPROPANOL |
770-35-4 |
Yes |
DSL |
EIN |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
ETHYLCELLULOSE |
9004-57-3 |
Yes |
DSL |
No |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Flammable Solids Category 1 H228 Flammable solid (powder; stabilised)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder; pyrophoric)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder; pyrophoric or stabilised)
ZIRCONIUM METAL, DRY (7440-67-7)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder; pyrophoric)
Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder; non-pyrophoric)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder; pyrophoric)
ZINC (7440-66-6)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (dust and powder; pyrophoric)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (dust and powder; pyrophoric)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (dust and powder; stabilised)
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (dust and powder, pyrophoric)
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H228 Flammable solid
H250 Catches fire spontaneously if exposed to air
H261 In contact with water releases flammable gases
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZIRCONIUM METAL, DRY (7440-67-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H251 Self-heating, may catch fire
H260 In contact with water releases flammable gases which may ignite spontaneously
Prevention
P235+P410 Keep cool. Protect from sunlight
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P407 Maintain air gap between stacks/pallets
P413 Store bulk masses at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H260 In contact with water releases flammable gases which may ignite spontaneously
H410 Very toxic to aquatic life with long lasting effects
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Flammable Solids Category 1 H228 Flammable solid
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases
ZIRCONIUM METAL, DRY (7440-67-7)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H228 Flammable solid
H261 In contact with water releases flammable gases
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZIRCONIUM METAL, DRY (7440-67-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H260 In contact with water releases flammable gases which may ignite spontaneously
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
ALUMINUM, METALLIC, POWDER (7429-90-5) Approval: H27-B-015/C-036B_P
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (Source Ambiguous - Also Cat. 3 H261)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 3 H261 In contact with water releases flammable gases (Source Ambiguous - Also Cat. 2 H261)
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system)
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system)
SILICON (7440-21-3)
Flammable Solids Category 2 H228 Flammable solid Approval: 21A3549
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 21A3549
STRONTIUM, POWDER (7440-24-6)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air Approval: 20A2237
ZIRCONIUM METAL, DRY (7440-67-7)
Flammable Solids Category 1 H228 Flammable solid (powder) Approval: H27-B-073/C-118B_P
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: H27-B-073/C-118B_P
SILICON DIOXIDE (7631-86-9)
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: H27-A-043/C-114A_P
Carcinogenicity Category 1A H350 May cause cancer Approval: H27-A-043/C-114A_P
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: H27-A-043/C-114A_P
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system,immune system,kidneys) Approval: H27-A-043/C-114A_P
ZINC (7440-66-6)
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 20A2067
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 20A2067
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 20A2067
BARIUM (7440-39-3)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases Approval: 175
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 175
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 175
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 175
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 175
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 175
DIMETHYL PHTHALATE (131-11-3)
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 25B0035
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25B0035
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 25B0035
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 25B0035
PHENOXYISOPROPANOL (770-35-4)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 25A0010
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25A0010
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 25A0010
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
SILICON (7440-21-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
H320 Causes eye irritation
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
STRONTIUM, POWDER (7440-24-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P422 Store contents under appropriate liquid or inert gas as specified
ZIRCONIUM METAL, DRY (7440-67-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H228 Flammable solid
H335 May cause respiratory irritation
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
SILICON DIOXIDE (7631-86-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H319 Causes serious eye irritation
H350 May cause cancer
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Warning
Hazard(s)
H320 Causes eye irritation
H410 Very toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BARIUM (7440-39-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H402 Harmful to aquatic life
H412 Harmful to aquatic life with long lasting effects
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIMETHYL PHTHALATE (131-11-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H320 Causes eye irritation
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H402 Harmful to aquatic life
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PHENOXYISOPROPANOL (770-35-4)
Symbol(s)
Signal Word Danger
Hazard(s)
H318 Causes serious eye damage
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
ALUMINUM, METALLIC, POWDER (7429-90-5)
MOEL: |
Carcinogenicity Category 1A H350 May cause cancer (metal powder)
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (metal powder) |
SILICON (7440-21-3)
NEMA: |
Flammable Solids Category 2 H228 Flammable solid |
STRONTIUM, POWDER (7440-24-6)
NEMA: |
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously |
ZIRCONIUM METAL, DRY (7440-67-7)
MOEL: |
Self-Reactive Substances and Mixtures Type C H242 Heating may cause a fire
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
NEMA: |
Flammable Solids Category 2 H228 Flammable solid |
ZINC (7440-66-6)
MOEL: |
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Carcinogenicity Category 1A H350 May cause cancer
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
NEMA: |
Flammable Solids Category 2 H228 Flammable solid |
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE (25265-77-4)
MOEL: |
Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled |
BARIUM (7440-39-3)
MOEL: |
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects |
NEMA: |
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air |
DIMETHYL PHTHALATE (131-11-3)
MOEL: |
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H350 May cause cancer
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Symbol(s)
Signal Word Danger
Hazard(s)
H260 In contact with water releases flammable gases which may ignite spontaneously
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H242 Heating may cause a fire
H315 Causes skin irritation
H319 Causes serious eye irritation
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P411 Store at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H350 May cause cancer
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Symbol(s)
Signal Word Danger
Hazard(s)
H330 Fatal if inhaled
Prevention
P271 Use only outdoors or in a well-ventilated area
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H412 Harmful to aquatic life with long lasting effects
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P422 Store contents under appropriate liquid or inert gas as specified
Symbol(s)
Signal Word Warning
Hazard(s)
H336 May cause drowsiness or dizziness
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
ALUMINUM, METALLIC, POWDER (7429-90-5) Approval: HSR001263
Flammable Solids Category 1 H228 Flammable solid (powder, coated PG II)
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (powder, coated PG II)
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish,crustacean,algal) (powder, coated PG II)
SILICON (7440-21-3) Approval: HSR001306
Flammable Solids Category 2 H228 Flammable solid
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
STRONTIUM, POWDER (7440-24-6) Approval: HSR006486
Pyrophoric Liquids Category 1 H250 Catches fire spontaneously if exposed to air
ZIRCONIUM METAL, DRY (7440-67-7) Approval: HSR007363
Flammable Solids Category 2 H228 Flammable solid (>1% in a non hazardous diluent)
ZINC (7440-66-6) Approval: HSR001301
Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder/dust, PG I)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder/dust, PG I)
Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled (powder/dust, PG I)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder/dust, PG I)
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE (25265-77-4) Approval: HSR003120
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,fish)
BARIUM (7440-39-3) Approval: HSR001265
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (blood,body weight,Cardiovascular system,kidneys,liver,lungs)
Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (Cardiovascular system,kidneys)
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates
DIMETHYL PHTHALATE (131-11-3) Approval: HSR002976
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (algal,crustacean,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
PHENOXYISOPROPANOL (770-35-4) Approval: HSR003522
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H228 Flammable solid
H373 May cause damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P273 Avoid release to the environment
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P314 Get medical advice/attention if you feel unwell
P370+P378 In case of fire: Use appropriate media for extinction
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
SILICON (7440-21-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
H303 May be harmful if swallowed
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P370+P378 In case of fire: Use appropriate media for extinction
STRONTIUM, POWDER (7440-24-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P422 Store contents under appropriate liquid or inert gas as specified
ZIRCONIUM METAL, DRY (7440-67-7)
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H251 Self-heating, may catch fire
H260 In contact with water releases flammable gases which may ignite spontaneously
H333 May be harmful if inhaled
H400 Very toxic to aquatic life
Prevention
P235+P410 Keep cool. Protect from sunlight
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P407 Maintain air gap between stacks/pallets
P413 Store bulk masses at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE (25265-77-4)
Signal Word Warning
Hazard(s)
H303 May be harmful if swallowed
H412 Harmful to aquatic life with long lasting effects
Prevention
P273 Avoid release to the environment
Response
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BARIUM (7440-39-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
H301 Toxic if swallowed
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H372 Causes damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects
H432 Toxic to terrestrial vertebrates
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P332+P313 If skin irritation occurs: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIMETHYL PHTHALATE (131-11-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H331 Toxic if inhaled
H319 Causes serious eye irritation
H402 Harmful to aquatic life
H433 Harmful to terrestrial vertebrates
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PHENOXYISOPROPANOL (770-35-4)
Symbol(s)
Signal Word Warning
Hazard(s)
H303 May be harmful if swallowed
H319 Causes serious eye irritation
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
ALUMINUM, METALLIC, POWDER (7429-90-5)
Listing: Present (coated powder stabilized)
ZIRCONIUM METAL, DRY (7440-67-7)
Listing: Present (powder dry)
Listing: Present (dry finished sheets strips or coiled wire)
ZINC (7440-66-6)
Listing: Present (powder)
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
ALUMINUM, METALLIC, POWDER (7429-90-5)
Taiwan: |
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases |
ZIRCONIUM METAL, DRY (7440-67-7)
Taiwan: |
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air |
|
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases |
ZINC (7440-66-6)
Taiwan: |
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder) |
|
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder) |
|
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation (powder) |
|
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (powder) |
BARIUM (7440-39-3)
Taiwan: |
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases |
|
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
DIMETHYL PHTHALATE (131-11-3)
Taiwan: |
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
PHENOXYISOPROPANOL (770-35-4)
Taiwan: |
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation (classified in accordance to European Union CLP Regulation, classification obtained from joint registration or through majority of the enterprises) |
ETHYLCELLULOSE (9004-57-3)
Taiwan: |
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation (suggested classification obtained through foreign chemical related database) |
|
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation (suggested classification obtained through foreign chemical related database) |
|
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation (suggested classification obtained through foreign chemical related database) |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
ALUMINUM, METALLIC, POWDER (7429-90-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZIRCONIUM METAL, DRY (7440-67-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H261 In contact with water releases flammable gases
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H261 In contact with water releases flammable gases
H316 Causes mild skin irritation
H410 Very toxic to aquatic life with long lasting effects
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P332+P313 If skin irritation occurs: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BARIUM (7440-39-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H261 In contact with water releases flammable gases
H335 May cause respiratory irritation
Prevention
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P402+P404 Store in a dry place. Store in a closed container
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
DIMETHYL PHTHALATE (131-11-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H335 May cause respiratory irritation
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PHENOXYISOPROPANOL (770-35-4)
Symbol(s)
Signal Word Warning
Hazard(s)
H319 Causes serious eye irritation
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
ETHYLCELLULOSE (9004-57-3)
Symbol(s)
Signal Word Warning
Hazard(s)
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved