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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *

Material Name:

VOC MIX-3, 1ML

ChemADVISOR, Inc.

Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237

E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.

Synonyms

INV# 00701; INV# 00707

* * * Section 2 - HAZARDS IDENTIFICATION * * *

Emergency Overview

Color: colorless

Change in color: Not available

Physical Form: liquid

Health Hazards: skin irritation, eye irritation, central nervous system depression, nerve damage, cancer

Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire.

Potential Health Effects

Inhalation

Short Term: irritation, cough, ringing in the ears, constipation, headache, drowsiness, dizziness, tingling sensation, pain in extremities, tremors, loss of coordination, blood disorders, nerve damage

Long Term: irritation, sensitivity to light, changes in blood pressure, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, pain in extremities, loss of coordination, visual disturbances, dilated pupils or pin-point pupils, blindness, bluish skin color, lung congestion, heart damage, kidney damage, liver damage, nerve damage, reproductive effects, effects on the brain, convulsions, unconsciousness, coma, cancer

Skin Contact

Short Term: irritation, absorption may occur, headache, drowsiness, dizziness, loss of coordination, blood disorders

Long Term: irritation, headache, drowsiness, dizziness, loss of coordination, blood disorders, nerve damage, cancer

Eye Contact

Short Term: irritation, eye damage

Long Term: irritation

Ingestion

Short Term: irritation, sensitivity to light, changes in blood pressure, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, pain in extremities, loss of coordination, visual disturbances, dilated pupils or pin-point pupils, blindness, bluish skin color, lung congestion, heart damage, kidney damage, liver damage, nerve damage, effects on the brain, convulsions, unconsciousness, coma

Long Term: changes in blood pressure, headache, drowsiness, dizziness, loss of coordination, visual disturbances, blindness, bluish skin color, blood disorders, heart damage, kidney damage, liver damage, nerve damage, reproductive effects, cancer

* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *

CAS EC No Registration No	Component Name Synonyms	1272/2008 (CLP)	Percent
67-56-1 200-659-6 --	METHYL ALCOHOL	Flam. Liq. 2 - H225 Acute Tox. 3 (Oral) - H301 Acute Tox. 3 (Dermal) - H311 Acute Tox. 3 (Inh.) - H331 STOT SE 1 - H370	97.4
78-87-5 201-152-2 --	PROPYLENE DICHLORIDE	Flam. Liq. 2 - H225 Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332	0.2
79-00-5 201-166-9 --	1,1,2-TRICHLOROETHANE	Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Carc. 2 - H351	0.2
79-01-6 201-167-4 --	TRICHLOROETHYLENE	Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Muta. 2 - H341 Carc. 1B - H350 STOT SE 3 - H336 Aquatic Chronic 3 - H412	0.2
79-34-5 201-197-8 --	1,1,2,2-TETRACHLOROETHANE	Acute Tox. 1 (Dermal) - H310 Acute Tox. 2 (Inh.) - H330 Aquatic Chronic 2 - H411	0.2
87-68-3 201-765-5 --	HEXACHLOROBUTADIENE	--	0.2
96-12-8 202-479-3 --	1,2-DIBROMO-3-CHLOROPROPANE	Acute Tox. 3 (Oral) - H301 Muta. 1B - H340 Carc. 1B - H350 Repr. 1A - H360F STOT RE 2 - H373 Aquatic Chronic 3 - H412	0.2
96-18-4 202-486-1 --	1,2,3-TRICHLOROPROPANE	Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Carc. 1B - H350 Repr. 1B - H360F Note(s): D	0.2
106-93-4 203-444-5 --	ETHYLENE DIBROMIDE	Acute Tox. 3 (Oral) - H301 Acute Tox. 3 (Dermal) - H311 Acute Tox. 3 (Inh.) - H331 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Carc. 1B - H350 STOT SE 3 - H335 Aquatic Chronic 2 - H411	0.2
107-06-2 203-458-1 --	ETHYLENE DICHLORIDE	Flam. Liq. 2 - H225 Acute Tox. 4 (Oral) - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Carc. 1B - H350 STOT SE 3 - H335	0.2
142-28-9 205-531-3 --	1,3-DICHLOROPROPANE	--	0.2
542-75-6 208-826-5 --	1,3-DICHLOROPROPENE	Flam. Liq. 3 - H226 Acute Tox. 3 (Oral) - H301 Acute Tox. 3 (Dermal) - H311 Acute Tox. 4 (Inh.) - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 STOT SE 3 - H335 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Note(s): C, D	0.2
563-58-6 209-253-3 --	1,1-DICHLOROPROPENE	Flam. Liq. 2 - H225 Acute Tox. 3 (Oral) - H301 Aquatic Chronic 3 - H412	0.2
630-20-6 211-135-1 --	1,1,1,2-TETRACHLOROETHANE	--	0.2

Component Related Regulatory Information

This product may be regulated, have exposure limits or other information identified as the following: Ethane dichloride (1300-21-6), Trichloroethane (25323-89-1).

* * * Section 4 - FIRST AID MEASURES * * *

Inhalation

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.

Skin

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

Ingestion

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.

Note to Physicians

For inhalation, consider oxygen. For ingestion, consider gastric lavage.

* * * Section 5 - FIRE FIGHTING MEASURES * * *

See Section 9 for Flammability Properties

NFPA Ratings:

Health: 1 Fire: 3 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

Flammable Properties

Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive.

Extinguishing Media

alcohol-resistant foam, carbon dioxide, regular dry chemical, water

Large fires: Use alcohol-resistant foam or flood with fine water spray.

Fire Fighting Measures

Move container from fire area if it can be done without risk. Dike for later disposal. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *

Water Release

Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.

Occupational spill/release

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).

* * * Section 7 - HANDLING AND STORAGE * * *

Storage Procedures

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Refrigerate. Store in a tightly closed container. Keep separated from incompatible substances.

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *

Component Exposure Limits

METHYL ALCOHOL	67-56-1
ACGIH:	200 ppm TWA
	250 ppm STEL
	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	200 ppm TWA; 260 mg/m3 TWA
	250 ppm STEL; 325 mg/m3 STEL
	Potential for dermal absorption
	6000 ppm IDLH
Europe:	200 ppm TWA; 260 mg/m3 TWA
	Possibility of significant uptake through the skin
OSHA (US):	200 ppm TWA; 260 mg/m3 TWA
Mexico:	200 ppm TWA VLE-PPT; 260 mg/m3 TWA VLE-PPT
	250 ppm STEL [PPT-CT]; 310 mg/m3 STEL [PPT-CT]
	Skin - potential for cutaneous absorption
PROPYLENE DICHLORIDE	78-87-5
ACGIH:	10 ppm TWA
NIOSH:	400 ppm IDLH
OSHA (US):	75 ppm TWA; 350 mg/m3 TWA
Mexico:	75 ppm TWA VLE-PPT; 350 mg/m3 TWA VLE-PPT
	110 ppm STEL [PPT-CT]; 510 mg/m3 STEL [PPT-CT]
1,1,2-TRICHLOROETHANE	79-00-5
ACGIH:	10 ppm TWA
	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	10 ppm TWA; 45 mg/m3 TWA
	Potential for dermal absorption
	100 ppm IDLH
OSHA (US):	10 ppm TWA; 45 mg/m3 TWA
	prevent or reduce skin absorption
Mexico:	10 ppm TWA VLE-PPT; 45 mg/m3 TWA VLE-PPT
	20 ppm STEL [PPT-CT]; 30 mg/m3 STEL [PPT-CT]
	Skin - potential for cutaneous absorption
TRICHLOROETHYLENE	79-01-6
ACGIH:	10 ppm TWA
	25 ppm STEL
NIOSH:	1000 ppm IDLH
OSHA (US):	100 ppm TWA
	200 ppm Ceiling
Mexico:	100 ppm TWA VLE-PPT; 535 mg/m3 TWA VLE-PPT
	200 ppm STEL [PPT-CT]; 1080 mg/m3 STEL [PPT-CT]
1,1,2,2-TETRACHLOROETHANE	79-34-5
ACGIH:	1 ppm TWA
	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	1 ppm TWA; 7 mg/m3 TWA
	Potential for dermal absorption
	100 ppm IDLH
OSHA (US):	5 ppm TWA; 35 mg/m3 TWA
	prevent or reduce skin absorption
Mexico:	5 ppm TWA VLE-PPT; 35 mg/m3 TWA VLE-PPT
	10 ppm STEL [PPT-CT]; 70 mg/m3 STEL [PPT-CT]
	Skin - potential for cutaneous absorption
HEXACHLOROBUTADIENE	87-68-3
ACGIH:	0.02 ppm TWA
	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	0.02 ppm TWA; 0.24 mg/m3 TWA
	Potential for dermal absorption
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
OSHA (US):	1 ppb TWA
	1 ppb TWA (See 29 CFR 1910.1044)
1,2,3-TRICHLOROPROPANE	96-18-4
ACGIH:	0.005 ppm TWA
NIOSH:	10 ppm TWA; 60 mg/m3 TWA
	Potential for dermal absorption
	100 ppm IDLH
OSHA (US):	50 ppm TWA; 300 mg/m3 TWA
Mexico:	50 ppm TWA VLE-PPT; 300 mg/m3 TWA VLE-PPT
	75 ppm STEL [PPT-CT]; 450 mg/m3 STEL [PPT-CT]
	Skin - potential for cutaneous absorption
ETHYLENE DIBROMIDE	106-93-4
ACGIH:	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	0.045 ppm TWA
	0.13 ppm Ceiling 15 min
	100 ppm IDLH
OSHA (US):	20 ppm TWA
	30 ppm Ceiling
Mexico:	Skin - potential for cutaneous absorption
ETHYLENE DICHLORIDE	107-06-2
ACGIH:	10 ppm TWA
NIOSH:	1 ppm TWA; 4 mg/m3 TWA
	2 ppm STEL; 8 mg/m3 STEL
	50 ppm IDLH
OSHA (US):	50 ppm TWA
	100 ppm Ceiling
Mexico:	10 ppm TWA VLE-PPT; 40 mg/m3 TWA VLE-PPT
1,3-DICHLOROPROPENE	542-75-6
ACGIH:	1 ppm TWA
	Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH:	1 ppm TWA; 5 mg/m3 TWA
	Potential for dermal absorption

Component Analysis

Biological limit value

There are no biological limit values for any of this product's components.

Ventilation

Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

Protective Clothing

Wear appropriate chemical resistant clothing. Remove any chemical soaked clothing immediately.

Glove Recommendations

Wear appropriate chemical resistant gloves. OSHA REGULATED SUBSTANCES: U.S. OSHA 29 CFR 1910.1044.

Respiratory Protection

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 2000 ppm Any supplied-air respirator. 5000 ppm Any supplied-air respirator operated in a continuous-flow mode. 6000 ppm Any supplied-air respirator with a tight-fitting facepiece that is operated in a continuous-flow mode. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *

Appearance	clear	Physical State	Liquid
Odor	Not available	Color	colorless
Odor Threshold	Not available	pH	Not available
Melting Point	-14 °C	Boiling Point	156 °C
Freezing point	Not available	Evaporation Rate	Not available
Boiling Point Range	Not available	Flammability (solid, gas)	Not available
Autoignition	Not available	Flash Point	Not available
Lower Explosive Limit	Not available	Decomposition	Not available
Upper Explosive Limit	Not available	Vapor Pressure	Not available
Vapor Density (air=1)	Not available	Specific Gravity (water=1)	1.387
Water Solubility	Not available	Partition coefficient: n-octanol/water	Not available
Viscosity	Not available	Solubility (Other)	Not available
Density	Not available	Physical Form	liquid

* * * Section 10 - STABILITY AND REACTIVITY * * *

Chemical Stability

Stable at normal temperatures and pressure.

Incompatible Materials

halo carbons, combustible materials, metals, oxidizing materials, halogens, metal carbide, bases, acids

METHYL ALCOHOL ACETYL BROMIDE: Violent reaction with formation of hydrogen bromide. ALKYLALUMINUM SOLUTIONS: Violent reaction. ALUMINUM: Corrodes. BARIUM PERCHLORATE: Distillation yields highly explosive alkyl perchlorate. BERYLLIUM HYDRIDE: Violent reaction, even at -196 C. BROMINE: Vigorously exothermic reaction. CALCIUM CARBIDE: Violent reaction. CHLORINE: Possible ignition and explosion hazard. CHLOROFORM AND SODIUM HYDROXIDE: Explosive reaction. CHROMIUM TRIOXIDE (CHROMIC ANHYDRIDE): Possible ignition. CYANURIC CHLORIDE: Violent reaction. DICHLOROMETHANE: Possible ignition and explosion. DIETHYL ZINC: Possible ignition and explosion. HYDROGEN PEROXIDE + WATER: Explosion hazard. IODINE + ETHANOL + MERCURIC OXIDE: Explosion hazard. LEAD: Corrodes. LEAD PERCHLORATE: Explosion hazard. MAGNESIUM: Violent reaction. MAGNESIUM (POWDERED): Mixtures are capable of detonation. METALS: Incompatible. NICKEL: Possible ignition in the presence of nickel catalyst. NITRIC ACID (CONCENTRATED): Mixtures of greater than 25% acid may decompose violently. OXIDIZERS (STRONG): Fire and explosion hazard. PERCHLORIC ACID: Explosion hazard. PHOSPHOROUS TRIOXIDE: Possible violent reaction and ignition. PLASTICS, RUBBER, COATINGS: May be attacked. POTASSIUM: Possible dangerous reaction. POTASSIUM HYDROXIDE + CHLOROFORM: Exothermic reaction. POTASSIUM TERT-BUTOXIDE: Fire and explosion hazard. SODIUM + CHLOROFORM: Possible explosion. SODIUM HYPOCHLORITE: Explosion hazard. SODIUM METHOXIDE + CHLOROFORM: Violent reaction. SULFURIC ACID: Fire and explosion hazard. ZINC: Explosion hazard.

Hazardous Decomposition Products

oxides of carbon

Thermal decomposition products: oxides of carbon.

Possibility of Hazardous Reactions

Will not polymerize.

* * * Section 11 - TOXICOLOGICAL INFORMATION * * *

Component Analysis - LD50/LC50

The components of this material have been reviewed in various sources and the following selected endpoints are published:

METHYL ALCOHOL (67-56-1)

Oral LD50 Rat 6200 mg/kg

Inhalation LC50 Rat 22500 ppm 8 h

PROPYLENE DICHLORIDE (78-87-5)

Oral LD50 Rat 1900 mg/kg

Dermal LD50 Rabbit 8750 µL/kg

Inhalation LC50 Rat 14 mg/L 10 h

1,1,2-TRICHLOROETHANE (79-00-5)

Oral LD50 Rat 836 mg/kg

Rabbit 3730 uL/kg Skin LD50 1969 AIHAAP KJ3150000

Inhalation LC50 Rat 2.78 mg/L 8 h

TRICHLOROETHYLENE (79-01-6)

Mouse 2400 mg/kg Oral LD50 1990 VCVGH* KX4550000

Rabbit >20 gm/kg Skin LD50 NTIS** KX4550000

Inhalation LC50 Rat 26 mg/L 4 h

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Oral LD50 Rat 200 mg/kg

Dermal LD50 Rabbit 3990 mg/kg

Inhalation LC50 Rat 8.6 mg/L 4 h

HEXACHLOROBUTADIENE (87-68-3)

Cat 187 mg/kg Oral LD50 1990 VCVGH* EJ0700000

Mouse 150 mg/kg Skin LD50 1990 VCVGH* EJ0700000

Mouse 370 mg/m3/2 hour Inhalation LC50 1990 VCVGH* EJ0700000

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Guinea pig 150 mg/kg Oral LD50 1966 PCOC** TX8750000

Rabbit 1400 mg/kg Skin LD50 1961 TXAPA9 TX8750000

Inhalation LC50 Rat 103 ppm 8 h

1,2,3-TRICHLOROPROPANE (96-18-4)

Oral LD50 Rat 150 mg/kg

Dermal LD50 Rabbit 250 mg/kg

Mouse 3400 mg/m3/2 hour Inhalation LC50 1990 VCVGH* TZ9275000

ETHYLENE DIBROMIDE (106-93-4)

Oral LD50 Rat 117 mg/kg

Dermal LD50 Rabbit 300 mg/kg

ETHYLENE DICHLORIDE (107-06-2)

Oral LD50 Rat 680 mg/kg

Dermal LD50 Rabbit 4890 mg/kg

Inhalation LC50 Rat 4 mg/L 6 h

1,3-DICHLOROPROPANE (142-28-9)

Oral LD50 Rat 1250 mg/kg

1,3-DICHLOROPROPENE (542-75-6)

Oral LD50 Rat 224 mg/kg

Dermal LD50 Rabbit 333 mg/kg

Inhalation LC50 Rat 2.7 - 3.07 mg/L 4 h

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Oral LD50 Rat 670 mg/kg

Inhalation LC50 Rat 2100 ppm 4 h

Component Carcinogenicity

PROPYLENE DICHLORIDE	78-87-5
ACGIH:	A4 - Not Classifiable as a Human Carcinogen
IARC:	Monograph 110 [in preparation]; Monograph 71 [1999]; Monograph 41 [1986] (Group 1 (carcinogenic to humans))
DFG:	Category 3B (could be carcinogenic for man)
OSHA:	Present
1,1,2-TRICHLOROETHANE	79-00-5
ACGIH:	A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:	Monograph 71 [1999]; Monograph 52 [1991]; Supplement 7 [1987] (Group 3 (not classifiable))
DFG:	Category 3B (could be carcinogenic for man)
TRICHLOROETHYLENE	79-01-6
ACGIH:	A2 - Suspected Human Carcinogen
IARC:	Monograph 106 [2014]; Monograph 63 [1995] (Group 1 (carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen
DFG:	Category 1 (causes cancer in man)
OSHA:	Present
1,1,2,2-TETRACHLOROETHANE	79-34-5
ACGIH:	A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:	Monograph 106 [2014]; Monograph 71 [1999]; Supplement 7 [1987]; Monograph 20 [1979] (Group 2B (possibly carcinogenic to humans))
DFG:	Category 3B (could be carcinogenic for man)
OSHA:	Present
HEXACHLOROBUTADIENE	87-68-3
ACGIH:	A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:	Monograph 73 [1999]; Supplement 7 [1987] (Group 3 (not classifiable))
DFG:	Category 3B (could be carcinogenic for man)
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
IARC:	Monograph 71 [1999]; Supplement 7 [1987]; Monograph 20 [1979] (Group 2B (possibly carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen
DFG:	Category 2 (considered to be carcinogenic for man)
OSHA:	Present
OSHA:	see 29 CFR 1910.1044
1,2,3-TRICHLOROPROPANE	96-18-4
ACGIH:	A2 - Suspected Human Carcinogen
IARC:	Monograph 63 [1995] (Group 2A (probably carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen
DFG:	Category 2 (considered to be carcinogenic for man)
OSHA:	Present
ETHYLENE DIBROMIDE	106-93-4
ACGIH:	A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:	Monograph 71 [1999]; Supplement 7 [1987]; Monograph 15 [1977] (overall evaluation upgraded from 2B to 2A with supporting evidence from other relevant data) (Group 2A (probably carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen
DFG:	Category 2 (considered to be carcinogenic for man)
OSHA:	Present
ETHYLENE DICHLORIDE	107-06-2
ACGIH:	A4 - Not Classifiable as a Human Carcinogen
IARC:	Monograph 71 [1999]; Supplement 7 [1987]; Monograph 20 [1979] (Group 2B (possibly carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen
DFG:	Category 2 (considered to be carcinogenic for man)
OSHA:	Present
1,3-DICHLOROPROPENE	542-75-6
ACGIH:	A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:	Monograph 71 [1999] (technical grade); Supplement 7 [1987]; Monograph 41 [1986] (Group 2B (possibly carcinogenic to humans))
NTP:	Reasonably Anticipated To Be A Human Carcinogen (technical grade)
DFG:	Category 2 (considered to be carcinogenic for man, cis- and trans-isomers)
OSHA:	Present
1,1,1,2-TETRACHLOROETHANE	630-20-6
IARC:	Monograph 106 [2014]; Monograph 71 [1999]; Supplement 7 [1987]; Monograph 41 [1986] (Group 2B (possibly carcinogenic to humans))
OSHA:	Present

Ethylene dibromide is carcinogenic to rats producing squamous-cell carcinomas of the forestomach, hepatocellular carcinomas in females, and hemangiosarcomas in males and to mice producing squamous-cell carcinomas of the forestomach and alveolar/bronchiolar adenomas When inhaled, ethylene dibromide increased the incidence of nasal cavity tumors and tumors of the circulatory system in rats and lungs tumors in mice It produced skin, lung and forestomach tumors in mice after topical administration Technical-grade 1,3-dichloropropene (containing 1.0% epichlorohydrin) administered by gavage, produced malignant tumors of the urinary bladder, lung and forestomach in mice and of the forestomach in rats After subcutaneous administration to mice, the purified cis-isomer produced malignant tumors at the site of injection In a two year exposure by gavage, there was clear evidence of carcinogenic activity in both male and female rats based on increased incidences of tumors of the oral mucosa, forestomach, and Zymbal gland Male rats had increased incidences of adenomas of the pancreas and kidney, and adenoma or carcinoma of the preputial gland Female rats developed adenomas or carcinomas of the clitoral gland and adenocarcinomas of the mammary glands There was clear evidence of carcinogenic activity in both male and female mice based on increased incidences tumors of the forestomach, liver, and Harderian gland The females also developed tumors of the oral mucosa and uterus 1,2-Dibromo-3-chloropropane produced squamous-cell carcinomas of the forestomach in rats and mice and carcinomas of the mammary gland in female rats by chronic oral ingestion Chronic inhalation studies in rats and mice reported an increased incidence of lung and nasal cavity tumors in mice, tumors of the nasal cavity and tongue in both sexes of rats, and cortical adenomas in the adrenal gland of female rats Oral administration to mice and rats resulted in a significant increase in tumors at various sites in both species In mice, mammary adenocarcinomas and endometrial tumors were seen in females, hepatocellular carcinomas in males, and alveolar/bronchiolar adenomas and malignant lymphomas in both sexes In rats, squamous-cell carcinomas of the forestomach, and subcutaneous fibromas were seen in males, mammary adenocarcinomas developed in the females, and hemangiosarcomas developed in both sexes Evidence of carcinogenicity in humans comes from seven cohort studies with specific trichloroethylene exposures well characterized for individual study subjects A meta-analysis of these studies found that occupational exposure was associated with excess incidences of liver cancer, kidney cancer, non-Hodgkin's lymphoma, prostate cancer, and multiple myeloma, with the strongest evidence for the first three cancers Exposure was assessed less acurately in case-control studies In many of these studies, exposure was estimated from exposure to solvents in general Elevated risks were most consistently observed for kidney cancer, liver cancer, Hodgkin's disease, non-Hodgkin's lymphoma, and cervical cancer Repeated oral administration produced hepatocellular carcinomas in male and female mice; hepatocellular adenomas in female mice; tubular cell neoplasms of the kidney and interstitial cell neoplasms of the testis in rats Inhalation exposures resulted in increased incidences of liver and lung tumors in male and female mice and low incidences of adenocarcinomas of the renal tubules in rats Increased incidences of interstitial testicular tumors in male rats were also observed.

Medical Conditions Aggravated by Exposure

eye disorders, heart or cardiovascular disorders, heart problems, heart or cardiovascular disorders, genitourinary disorders, kidney disorders, kidney disorders, heart problems, kidney disorders, kidney disorders, liver disorders, skin disorders and allergies, kidney disorders, liver disorders, liver disorders, respiratory disorders, liver disorders, respiratory disorders, skin disorders and allergies, skin disorders and allergies, respiratory disorders, skin disorders and allergies,

Additional Data

May cross the placenta May cross the placenta Stimulants such as epinephrine may induce ventricular fibrillation Stimulants such as epinephrine may induce ventricular fibrillation Stimulants such as epinephrine may induce ventricular fibrillation Alcohol may enhance the toxic effects May be excreted in breast milk Stimulants such as epinephrine may induce ventricular fibrillation Alcohol may enhance the toxic effects May cause blindness.

This chemical was reported to have induced sterility among exposed male workers The human and animal data reported in the health effects sections below have been reported from exposures to technical grade mixtures which may contain from 88-98% dichloropropene and various other isomers, related compounds, and stabilizers The presence of tetrachloroethane as an impurity, or the consumption of alcoholic beverages, caffeine, or other drugs may enhance the systemic toxicity One study shows an increased risk of leukemia for children whose fathers had occupational exposure to chlorinated solvents after the birth of the child The incidence of kidney cancer is statistically elevated among workers exposed to trichloroethylene One study suggest that exposure to high concentrations over prolonged periods of time may cause renal tumors in humans Animal studies indicate that the risk of cancer may be increased when the exposure to ethylene dibromide is in combination with disulfiram (antabuse) or thiram.

Inhalation - Acute Exposure

METHYL ALCOHOL: May cause irritation of the mucous membranes, coughing, oppression in the chest, tracheitis, bronchitis, tinnitus, unsteady gait, twitching, colic, constipation, nystagmus, and blepharospasm Symptoms from occupational exposure include paresthesias, numbness and shooting pains in the hands and forearms Metabolic acidosis, and effects on the eyes and central nervous system may occur as detailed in acute ingestion.

Inhalation - Chronic Exposure

METHYL ALCOHOL: Repeated or prolonged exposure may cause effects as in acute ingestion Repeated exposure to 200-375 ppm caused recurrent headaches in workers Exposure for 4 years to 1200-8000 ppm resulted in marked diminution of vision and enlargement of the liver in a workman Reproductive effects have been reported in animals.

Skin Contact - Acute Exposure

METHYL ALCOHOL: Contact with liquid may cause irritation Skin absorption may occur and cause metabolic acidosis and effects on the eyes and central nervous system as detailed in acute ingestion.

Skin Contact - Chronic Exposure

METHYL ALCOHOL: Repeated or prolonged contact with the liquid may cause defatting of the skin resulting in erythema, scaling, and eczematoid dermatitis Chronic absorption may result in metabolic acidosis and effects as detailed in acute ingestion.

Eye Contact - Acute Exposure

METHYL ALCOHOL: Vapors may cause irritation High concentrations have been reported to cause violent inflammation of the conjunctiva and epithelial defects on the cornea Mild irritation may occur with dilute solutions; the undiluted liquid has produced moderate corneal opacity and conjunctival redness in rabbits Application of a drop of methanol in rabbit eyes caused a mild reversible reaction, graded 3 on a scale of 1-10 after 24 hours.

Eye Contact - Chronic Exposure

METHYL ALCOHOL Repeated or prolonged contact may cause conjunctivitis.

Ingestion - Acute Exposure

METHYL ALCOHOL: May cause mild and transient inebriation and subsequent drowsiness followed by an asymptomatic period lasting 8-48 hours Following the delay, coughing, dyspnea, headache, dullness, weakness, vertigo or dizziness, nausea, vomiting, occasional diarrhea, anorexia, violent pain in the back, abdomen, and extremities, restlessness, apathy or delirium, and rarely, excitement and mania may occur Rapid, shallow respiration due to metabolic acidosis, cold and clammy skin, hypotension, cyanosis, opisthotonos, convulsions, mild tachycardia, cardiac depression, peripheral neuritis, cerebral and pulmonary edema, unconsciousness, and coma are possible Effects on the eye may include optic neuritis, blurred or dimmed vision, dilated, unresponsive pupils, ptosis, eye pain, concentric constriction of visual fields, diplopia, change in color perception, photophobia, and optic nerve atrophy Partial blindness or possibly delayed transient or permanent blindness may occur Bilateral sensorineural deafness has been reported in a single case Liver, kidney, heart, stomach, intestinal and pancreatic damage may also occur Death may be due to respiratory failure or rarely from circulatory collapse As little as 15 ml has caused blindness; the usual fatal dose is 60-240 ml Prolonged asthenia and irreversible effects on the nervous system including difficulty in speech, motor dysfunction with rigidity, spasticity, and hypokinesis have been reported.

Ingestion - Chronic Exposure

METHYL ALCOHOL: Repeated ingestion may cause visual impairment and blindness and other systemic effects as detailed in acute ingestion Reproductive effects have been reported in animals.

* * * Section 12 - ECOLOGICAL INFORMATION * * *

Component Analysis - Aquatic Toxicity

METHYL ALCOHOL	67-56-1
Fish:	LC50 96 h Pimephales promelas 28200 mg/L [flow-through]; LC50 96 h Pimephales promelas >100 mg/L [static]; LC50 96 h Oncorhynchus mykiss 19500 - 20700 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 18 - 20 mL/L [static]; LC50 96 h Lepomis macrochirus 13500 - 17600 mg/L [flow-through]
PROPYLENE DICHLORIDE	78-87-5
Fish:	LC50 96 h Pimephales promelas 127 mg/L [static]; LC50 96 h Pimephales promelas 119 - 135 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 220 - 340 mg/L [static]
Invertebrate:	LC50 48 h Daphnia magna 45 mg/L IUCLID
1,1,2-TRICHLOROETHANE	79-00-5
Fish:	LC50 96 h Pimephales promelas 81.6 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 35 - 47 mg/L [static]
Algae:	EC50 96 h Desmodesmus subspicatus 167 mg/L [static] EPA
Invertebrate:	EC50 48 h Daphnia magna 18 mg/L IUCLID; EC50 48 h Daphnia magna 57 - 110 mg/L [Static] EPA
TRICHLOROETHYLENE	79-01-6
Fish:	LC50 96 h Pimephales promelas 31.4 - 71.8 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 39 - 54 mg/L [static]
Algae:	EC50 96 h Desmodesmus subspicatus 450 mg/L IUCLID; EC50 96 h Pseudokirchneriella subcapitata 175 mg/L IUCLID
Invertebrate:	EC50 48 h Daphnia magna 2.2 mg/L IUCLID
1,1,2,2-TETRACHLOROETHANE	79-34-5
Fish:	LC50 96 h Pimephales promelas 19.9 - 20.7 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 20 - 22 mg/L [static]
Algae:	EC50 96 h Pseudokirchneriella subcapitata 40.7 - 344 mg/L EPA; EC50 72 h Pseudokirchneriella subcapitata 31.4 - 188 mg/L EPA; EC50 96 h Desmodesmus subspicatus 47 mg/L [static] EPA
Invertebrate:	EC50 48 h Daphnia magna 16 - 35 mg/L IUCLID; EC50 48 h Daphnia magna 16 - 35 mg/L [Static] EPA
HEXACHLOROBUTADIENE	87-68-3
Fish:	LC50 96 h Pimephales promelas 0.09 - 0.11 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 0.312 - 0.337 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 0.64 - 0.91 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.268 - 0.381 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.2 - 0.3 mg/L [static]
1,2,3-TRICHLOROPROPANE	96-18-4
Fish:	LC50 96 h Pimephales promelas 50.8 mg/L [flow-through]; LC50 96 h Pimephales promelas 25.9 - 28.9 mg/L [static]; LC50 96 h Lepomis macrochirus 75 mg/L [static]
Invertebrate:	LC50 48 h Daphnia magna 20 mg/L IUCLID; EC50 48 h Daphnia magna 27.8 - 41.1 mg/L [semi-static] EPA
ETHYLENE DIBROMIDE	106-93-4
Fish:	LC50 96 h Oryzias latipes 27.6 - 37.4 mg/L [flow-through]
ETHYLENE DICHLORIDE	107-06-2
Fish:	LC50 96 h Pimephales promelas 110 - 123 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 225 mg/L [static] (1.8 g); LC50 96 h Lepomis macrochirus 230 - 710 mg/L [flow-through] (0.12 g)
Algae:	EC50 96 h Pseudokirchneriella subcapitata >433 mg/L IUCLID; EC50 96 h Desmodesmus subspicatus 166 mg/L [static] EPA
Invertebrate:	EC50 48 h Daphnia magna 140 - 190 mg/L [Static] EPA
1,3-DICHLOROPROPANE	142-28-9
Fish:	LC50 96 h Pimephales promelas 94.2 mg/L [flow-through]; LC50 96 h Lepomis macrochirus >520 mg/L [static]; LC50 96 h Oncorhynchus mykiss 100 - 130 mg/L [static]
1,3-DICHLOROPROPENE	542-75-6
Fish:	LC50 96 h Pimephales promelas 1.52 - 2.68 mg/L [static]; LC50 96 h Pimephales promelas 0.211 - 0.271 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 3.1 - 4.9 mg/L [static]; LC50 96 h Oncorhynchus mykiss 4.5 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 2 mg/L; LC50 96 h Lepomis macrochirus 5.1 - 6.8 mg/L [static]
Algae:	EC50 96 h Pseudokirchneriella subcapitata 2.45 - 6.45 mg/L EPA; EC50 72 h Pseudokirchneriella subcapitata 3.12 - 10.5 mg/L EPA
Invertebrate:	EC50 48 h Daphnia magna 0.063 - 0.129 mg/L [Static] EPA; EC50 48 h Daphnia magna 0.09 mg/L IUCLID

Bioconcentration Factor

METHYL ALCOHOL	67-56-1
BCF	<10 species: fish
PROPYLENE DICHLORIDE	78-87-5
BCF	0.5 - 7 BCF method: OECD 305C
1,1,2-TRICHLOROETHANE	79-00-5
BCF	0.7 - 6.7 species: fish
TRICHLOROETHYLENE	79-01-6
BCF	17 - 90 species: fish
1,1,2,2-TETRACHLOROETHANE	79-34-5
BCF	4.5 - 13.2 species: fish
ETHYLENE DIBROMIDE	106-93-4
BCF	<10 species: fish
ETHYLENE DICHLORIDE	107-06-2
BCF	2 species: fish

* * * Section 13 - DISPOSAL CONSIDERATIONS * * *

Disposal Methods

Dispose in accordance with all applicable regulations.

Component Waste Numbers

METHYL ALCOHOL	67-56-1
RCRA:	waste number U154 (Ignitable waste)
PROPYLENE DICHLORIDE	78-87-5
RCRA:	waste number U083
1,1,2-TRICHLOROETHANE	79-00-5
RCRA:	waste number U227
TRICHLOROETHYLENE	79-01-6
RCRA:	waste number U228
	0.5 mg/L regulatory level
1,1,2,2-TETRACHLOROETHANE	79-34-5
RCRA:	waste number U209
HEXACHLOROBUTADIENE	87-68-3
RCRA:	waste number U128
	0.5 mg/L regulatory level
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
RCRA:	waste number U066
ETHYLENE DIBROMIDE	106-93-4
RCRA:	waste number U067
ETHYLENE DICHLORIDE	107-06-2
RCRA:	waste number U077
	0.5 mg/L regulatory level
1,3-DICHLOROPROPENE	542-75-6
RCRA:	waste number U084
1,1,1,2-TETRACHLOROETHANE	630-20-6
RCRA:	waste number U208

* * * Section 14 - TRANSPORT INFORMATION * * *

US DOT Information:

No Classification assigned.

TDG Information:

No Classification assigned.

ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations

METHYL ALCOHOL (67-56-1)

Restriction(s): D/E [UN1230] (II)

PROPYLENE DICHLORIDE (78-87-5)

Restriction(s): D/E [UN1279] (II)

TRICHLOROETHYLENE (79-01-6)

Restriction(s): E [UN1710] (III)

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Restriction(s): D/E [UN1702] (II)

HEXACHLOROBUTADIENE (87-68-3)

Restriction(s): E [UN2279] (III)

ETHYLENE DIBROMIDE (106-93-4)

Restriction(s): C/D [UN1605] (I)

ETHYLENE DICHLORIDE (107-06-2)

Restriction(s): D/E [UN1184] (II)

RID Information:

No Classification assigned.

IATA Information:

No Classification assigned.

ICAO Information:

No Classification assigned.

IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG)

Not regulated as dangerous goods.

* * * Section 15 - REGULATORY INFORMATION * * *

US Federal Regulations

This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan

METHYL ALCOHOL	67-56-1
SARA 313:	1 % de minimis concentration
CERCLA:	5000 lb final RQ; 2270 kg final RQ
PROPYLENE DICHLORIDE	78-87-5
SARA 313:	1 % de minimis concentration
CERCLA:	1000 lb final RQ; 454 kg final RQ
1,1,2-TRICHLOROETHANE	79-00-5
SARA 313:	1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ
TRICHLOROETHYLENE	79-01-6
SARA 313:	0.1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ
TSCA 12b:	Section 5 , 0.1 % de minimus concentration
1,1,2,2-TETRACHLOROETHANE	79-34-5
SARA 313:	1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ
HEXACHLOROBUTADIENE	87-68-3
SARA 313:	1 % de minimis concentration
CERCLA:	1 lb final RQ; 0.454 kg final RQ
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
SARA 313:	0.1 % de minimis concentration
CERCLA:	1 lb final RQ; 0.454 kg final RQ
1,2,3-TRICHLOROPROPANE	96-18-4
SARA 313:	0.1 % de minimis concentration
ETHYLENE DIBROMIDE	106-93-4
SARA 313:	0.1 % de minimis concentration
CERCLA:	1 lb final RQ; 0.454 kg final RQ
ETHYLENE DICHLORIDE	107-06-2
SARA 313:	0.1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ
TSCA 12b:	Section 4 , 0.1 % de minimus concentration
1,3-DICHLOROPROPANE	142-28-9
CERCLA:	1000 lb final RQ; 454 kg final RQ
1,3-DICHLOROPROPENE	542-75-6
SARA 313:	0.1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ
1,1,1,2-TETRACHLOROETHANE	630-20-6
SARA 313:	1 % de minimis concentration
CERCLA:	100 lb final RQ; 45.4 kg final RQ

SARA Section 311/312 (40 CFR 370 Subparts B and C)

Fire: Yes Pressure: No Reactivity: No

U.S. State Regulations

The following components appear on one or more of the following state hazardous substances lists:

Component	CAS	CA	MA	MN	NJ	PA
METHYL ALCOHOL	67-56-1	Yes	Yes	Yes	Yes	Yes
PROPYLENE DICHLORIDE	78-87-5	Yes	Yes	Yes	Yes	Yes
1,1,2-TRICHLOROETHANE	79-00-5	Yes	Yes	Yes	Yes	Yes
TRICHLOROETHYLENE	79-01-6	Yes	Yes	Yes	Yes	Yes
1,1,2,2-TETRACHLOROETHANE	79-34-5	Yes	Yes	Yes	Yes	Yes
HEXACHLOROBUTADIENE	87-68-3	Yes	Yes	Yes	Yes	Yes
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8	Yes	Yes	Yes	Yes	Yes
1,2,3-TRICHLOROPROPANE	96-18-4	Yes	Yes	Yes	Yes	Yes
ETHYLENE DIBROMIDE	106-93-4	Yes	Yes	Yes	Yes	Yes
ETHYLENE DICHLORIDE	107-06-2	Yes	Yes	Yes	Yes	Yes
1,3-DICHLOROPROPANE	142-28-9	Yes	Yes	No	No	Yes
1,3-DICHLOROPROPENE	542-75-6	Yes	Yes	Yes	Yes	Yes
1,1-DICHLOROPROPENE	563-58-6	No	Yes	No	No	No
1,1,1,2-TETRACHLOROETHANE	630-20-6	Yes	Yes	No	Yes	Yes

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):

WARNING! This product contains a chemical known to the state of California to cause cancer

WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects

Component Analysis

METHYL ALCOHOL	67-56-1
Repro/Dev. Tox	developmental toxicity , 3/16/2012
PROPYLENE DICHLORIDE	78-87-5
Carc:	carcinogen , 1/1/1990
1,1,2-TRICHLOROETHANE	79-00-5
Carc:	carcinogen , 10/1/1990
TRICHLOROETHYLENE	79-01-6
Carc:	carcinogen , 4/1/1988
Repro/Dev. Tox	developmental toxicity , 1/31/2014
	male reproductive toxicity , 1/31/14
1,1,2,2-TETRACHLOROETHANE	79-34-5
Carc:	carcinogen , 7/1/1990
HEXACHLOROBUTADIENE	87-68-3
Carc:	carcinogen , 5/3/2011
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
Carc:	carcinogen , 7/1/1987
Repro/Dev. Tox	male reproductive toxicity , 2/27/87
1,2,3-TRICHLOROPROPANE	96-18-4
Carc:	carcinogen , 10/1/1992
ETHYLENE DIBROMIDE	106-93-4
Carc:	carcinogen , 7/1/1987
Repro/Dev. Tox	developmental toxicity , 5/15/1998
	male reproductive toxicity , 5/15/98
ETHYLENE DICHLORIDE	107-06-2
Carc:	carcinogen , 10/1/1987
1,3-DICHLOROPROPENE	542-75-6
Carc:	carcinogen , 1/1/1989
1,1,1,2-TETRACHLOROETHANE	630-20-6
Carc:	carcinogen , 9/13/2013

Canadian WHMIS Ingredient Disclosure List (IDL)

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL

METHYL ALCOHOL	67-56-1
	1 %
PROPYLENE DICHLORIDE	78-87-5
	1 %
1,1,2-TRICHLOROETHANE	79-00-5
	1 %
TRICHLOROETHYLENE	79-01-6
	1 %
1,1,2,2-TETRACHLOROETHANE	79-34-5
	1 %
HEXACHLOROBUTADIENE	87-68-3
	0.1 %
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8
	0.1 %
1,2,3-TRICHLOROPROPANE	96-18-4
	1 %
ETHYLENE DIBROMIDE	106-93-4
	0.1 %
ETHYLENE DICHLORIDE	107-06-2
	1 %
1,3-DICHLOROPROPENE	542-75-6
	1 %
1,1,1,2-TETRACHLOROETHANE	630-20-6
	1 %

Germany Water Classification

METHYL ALCOHOL (67-56-1)

ID Number 145 , hazard class 1 - low hazard to waters

ID Number 145 , hazard class 2 - hazard to waters

PROPYLENE DICHLORIDE (78-87-5)

ID Number 446 , hazard class 3 - severe hazard to waters

1,1,2-TRICHLOROETHANE (79-00-5)

ID Number 796 , hazard class 3 - severe hazard to waters

TRICHLOROETHYLENE (79-01-6)

ID Number 199 , hazard class 3 - severe hazard to waters

ID Number 199 , hazard class 3 - severe hazard to waters

1,1,2,2-TETRACHLOROETHANE (79-34-5)

ID Number 797 , hazard class 3 - severe hazard to waters

HEXACHLOROBUTADIENE (87-68-3)

ID Number 123 , hazard class 3 - severe hazard to waters

1,2,3-TRICHLOROPROPANE (96-18-4)

ID Number 7988 , hazard class 3 - severe hazard to waters

ETHYLENE DIBROMIDE (106-93-4)

ID Number 241 , hazard class 3 - severe hazard to waters

ETHYLENE DICHLORIDE (107-06-2)

ID Number 102 , hazard class 3 - severe hazard to waters

ID Number 102 , hazard class 3 - severe hazard to waters

1,3-DICHLOROPROPENE (542-75-6)

ID Number 245 , hazard class 3 - severe hazard to waters

REACH Candidate List of Substances Subject to Authorization (Article 59(1)) - Reg. (EU) No. 1907/2006

This list includes substances listed on the candidate list of substances subject to Authorisation. Once listed on the candidate list, substances present in articles in concentrations meeting or exceeding 0.1 % w/w must be disclosed according to Article 33 of REACH

TRICHLOROETHYLENE	79-01-6
	Reason for inclusion: Carcinogenic, Article 57a
1,2,3-TRICHLOROPROPANE	96-18-4
	Reason for inclusion: Carcinogenic, Article 57a;Toxic for reproduction, Article 57c
ETHYLENE DICHLORIDE	107-06-2
	Reason for inclusion: Carcinogenic, Article 57a

REACH List of Substances Subject to Authorization (Annex XIV) - Reg. (EU) No. 1907/2006

This list includes substances subject to Authorisation. Under the Authorization requirement of REACH, manufacturers, importers, and downstream users will have to apply for the 'authorisation' to use certain substances

TRICHLOROETHYLENE (79-01-6)

Intrisic properties: Carcinogenic Category 1B,Article 57 Application date: October 21, 2014 Sunset date: April 21, 2016 Exempted uses: None

ETHYLENE DICHLORIDE (107-06-2)

Intrisic properties: Carcinogenic Category 1B,Article 57 Application date: May 22, 2016 Sunset date: November 22, 2017 Exempted uses: None

REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

1,1,2-TRICHLOROETHANE (79-00-5)

Use restricted. See item 34

TRICHLOROETHYLENE (79-01-6)

Use restricted. See item 28.

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Use restricted. See item 35.

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Use restricted. See item 28.; Use restricted. See item 29.; Use restricted. See item 30.

1,2,3-TRICHLOROPROPANE (96-18-4)

Use restricted. See item 28.; Use restricted. See item 30.

ETHYLENE DIBROMIDE (106-93-4)

Use restricted. See item 28.

ETHYLENE DICHLORIDE (107-06-2)

Use restricted. See item 28.

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Use restricted. See item 36.

REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006

This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process

METHYL ALCOHOL (67-56-1)

Assigned to Member State Poland (Initial Grounds for Concern: Human health/Suspected CMR, Exposure/High exposure for workers and the environment, wide dispersive use, consumer use)

Symbol(s)

T Toxic

Risk Phrases

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

R45 May cause cancer.

R46 May cause heritable genetic damage.

Component Analysis - Inventory

Component	CAS#	US	CA	EU	AU	PH	JP	KR	CN	NZ
METHYL ALCOHOL	67-56-1	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
PROPYLENE DICHLORIDE	78-87-5	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
1,1,2-TRICHLOROETHANE	79-00-5	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
TRICHLOROETHYLENE	79-01-6	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
1,1,2,2-TETRACHLOROETHANE	79-34-5	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
HEXACHLOROBUTADIENE	87-68-3	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	No
1,2-DIBROMO-3-CHLOROPROPANE	96-12-8	Yes	NSL	EIN	No	Yes	Yes	Yes	No	No
1,2,3-TRICHLOROPROPANE	96-18-4	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
ETHYLENE DIBROMIDE	106-93-4	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
ETHYLENE DICHLORIDE	107-06-2	Yes	DSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
1,3-DICHLOROPROPANE	142-28-9	Yes	NSL	EIN	Yes	Yes	Yes	No	Yes	Yes
1,3-DICHLOROPROPENE	542-75-6	Yes	NSL	EIN	Yes	Yes	Yes	Yes	Yes	Yes
1,1-DICHLOROPROPENE	563-58-6	No	No	EIN	No	No	No	No	No	No
1,1,1,2-TETRACHLOROETHANE	630-20-6	Yes	DSL	EIN	Yes	No	Yes	No	No	No

Globally Harmonized System of Classification and Labeling (GHS)

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements

Australia GHS Classifications

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)

METHYL ALCOHOL (67-56-1)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs

PROPYLENE DICHLORIDE (78-87-5)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

1,1,2-TRICHLOROETHANE (79-00-5)

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Carcinogenicity Category 2 H351 Suspected of causing cancer

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Acute toxicity Dermal Category 1 H310 Fatal in contact with skin

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Germ Cell Mutagenicity Category 1B H340 May cause genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 1A H360F May damage fertility

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

1,2,3-TRICHLOROPROPANE (96-18-4)

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 1B H360F May damage fertility

ETHYLENE DIBROMIDE (106-93-4)

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 1 H330 Fatal if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

ETHYLENE DICHLORIDE (107-06-2)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

1,3-DICHLOROPROPENE (542-75-6)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

1,1-DICHLOROPROPENE (563-58-6)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

Australia GHS Labeling Information

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H370 Causes damage to organs

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE DICHLORIDE (78-87-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H332 Harmful if inhaled

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2-TRICHLOROETHANE (79-00-5)

Symbol(s)

Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H351 Suspected of causing cancer

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P322 Specific measures (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H310 Fatal in contact with skin

H330 Fatal if inhaled

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P262 Do not get in eyes, on skin, or on clothing

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P320 Specific treatment is urgent (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H340 May cause genetic defects

H350 May cause cancer

H360F May damage fertility

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2,3-TRICHLOROPROPANE (96-18-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H350 May cause cancer

H360F May damage fertility

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P322 Specific measures (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DIBROMIDE (106-93-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H330 Fatal if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H335 May cause respiratory irritation

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DICHLORIDE (107-06-2)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H335 May cause respiratory irritation

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPENE (542-75-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H335 May cause respiratory irritation

H304 May be fatal if swallowed and enters airways

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P331 Do NOT induce vomiting

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1-DICHLOROPROPENE (563-58-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H301 Toxic if swallowed

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

European Union GHS Classifications

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)

METHYL ALCOHOL (67-56-1)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification)

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (No information to prove exclusion of certain routes of exposure)

PROPYLENE DICHLORIDE (78-87-5)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

1,1,2-TRICHLOROETHANE (79-00-5)

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

Carcinogenicity Category 2 H351 Suspected of causing cancer

Supplemental Hazards EUH066 Repeated exposure may cause skin dryness or cracking

TRICHLOROETHYLENE (79-01-6)

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Acute toxicity Dermal Category 1 H310 Fatal in contact with skin

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled (Minimum classification)

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Germ Cell Mutagenicity Category 1B H340 May cause genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 1A H360F May damage fertility (Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development: May damage/Suspected of damaging fertility or the unborn child; According to the criteria, the general hazard statement can be replaced by the hazard statement indicating the specific effect of concern in accordance with section 1.1.2.1.2; When the other differentiation is not mentioned, this is due to evidence proving no such effect, inconclusive data or no data and the obligations in Article 4(3) shall apply for that differentiation)

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

1,2,3-TRICHLOROPROPANE (96-18-4)

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 1B H360F May damage fertility (Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development: May damage/Suspected of damaging fertility or the unborn child; According to the criteria, the general hazard statement can be replaced by the hazard statement indicating the specific effect of concern in accordance with section 1.1.2.1.2; When the other differentiation is not mentioned, this is due to evidence proving no such effect, inconclusive data or no data and the obligations in Article 4(3) shall apply for that differentiation)

ETHYLENE DIBROMIDE (106-93-4)

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification)

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Carcinogenicity Category 1B H350 May cause cancer

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

ETHYLENE DICHLORIDE (107-06-2)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Carcinogenicity Category 1B H350 May cause cancer

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

1,3-DICHLOROPROPENE (542-75-6)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

1,1-DICHLOROPROPENE (563-58-6)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

European Union GHS Labeling Information

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H336 May cause drowsiness or dizziness

H412 Harmful to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H350 May cause cancer

H335 May cause respiratory irritation

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DICHLORIDE (107-06-2)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H315 Causes skin irritation

H319 Causes serious eye irritation

H350 May cause cancer

H335 May cause respiratory irritation

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPENE (542-75-6)

Symbol(s)

Indonesia GHS Classifications

No published information available

This material may be hazardous according to published criteria for classification

Japan GHS Classifications

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

METHYL ALCOHOL (67-56-1) Approval: 21B3012

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System,retina,systemic toxicity)

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Central Nervous System,retina)

PROPYLENE DICHLORIDE (78-87-5)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: 20A2375

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 20A2375

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 20A2375

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Approval: 20A2375

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 20A2375

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 20A2375

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 20A2375

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (blood,kidneys,liver) Approval: 20A2375

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 20A2375

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 20A2375

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Hematopoietic System,kidneys,liver) Approval: 20A2375

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (respiratory system) Approval: 20A2375

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 20A2375

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 20A2375

1,1,2-TRICHLOROETHANE (79-00-5)

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 160

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Approval: 160

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 160

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 160

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 160

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (liver) Approval: 160

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 160

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 160

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (digestive system,kidneys,nervous system,respiratory system) Approval: 160

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (liver) Approval: 160

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 160

TRICHLOROETHYLENE (79-01-6)

Acute toxicity Inhalation - Vapour Category 4 H332 Harmful if inhaled Approval: 161

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 161

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Approval: 161

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 161

Carcinogenicity Category 1B H350 May cause cancer Approval: 161

Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child Approval: 161

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 161

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 161

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Central Nervous System) Approval: 161

Aspiration Hazard Category 2 H305 May be harmful if swallowed and enters airways Approval: 161

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: 161

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects Approval: 161

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 22B4514

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Approval: 22B4514

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 22B4514

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Approval: 234

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: H26-B-066 / -

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: H26-B-066 / -

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System,kidneys,liver) Approval: 234

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 234

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 234

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Central Nervous System,liver) Approval: 234

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: 234

HEXACHLOROBUTADIENE (87-68-3)

Flammable Liquids Category 4 H227 Combustible liquid (flash point >60°C and <=93°C) Approval: 1012

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 1012

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin Approval: 1012

Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled Approval: 1012

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 1012

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 1012

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 1012

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 1012

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (kidneys) Approval: 1012

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (bone marrow,kidneys,liver) Approval: 1012

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 1012

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 1012

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Flammable Liquids Category 4 H227 Combustible liquid Approval: 587

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 587

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin Approval: 587

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Approval: 587

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 587

Germ Cell Mutagenicity Category 1B H340 May cause genetic defects Approval: 587

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 587

Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Approval: 587

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 587

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Hematopoietic System,Central Nervous System,kidneys,liver,respiratory system) Approval: 587

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 587

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 587

1,2,3-TRICHLOROPROPANE (96-18-4)

Flammable Liquids Category 4 H227 Combustible liquid Approval: 859

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 859

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Approval: 859

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Approval: 859

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 859

Carcinogenicity Category 1B H350 May cause cancer Approval: 859

Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child Approval: 859

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (liver) Approval: 859

Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (adrenal gland) Approval: 859

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 859

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 859

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (blood,liver,respiratory system) Approval: 859

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (heart,kidneys) Approval: 859

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: 859

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects Approval: 859

ETHYLENE DIBROMIDE (106-93-4)

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 586

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Approval: 586

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Approval: 586

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 586

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 586

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 586

Carcinogenicity Category 1B H350 May cause cancer Approval: 586

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 586

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System,kidneys,liver) Approval: 586

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 586

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (kidneys,liver,respiratory system) Approval: 586

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: / R-105

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects Approval: / R-105

ETHYLENE DICHLORIDE (107-06-2)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: H27-B-062/C-098B_P

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: H27-B-062/C-098B_P

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Approval: H27-B-062/C-098B_P

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: H27-B-062/C-098B_P

Carcinogenicity Category 1B H350 May cause cancer Approval: H27-B-062/C-098B_P

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System,respiratory system,cardiovascular system,Hematopoietic System,liver,kidneys,digestive system) Approval: H27-B-062/C-098B_P

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: H27-B-062/C-098B_P

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (nervous system,liver,cardiovascular system,thyroid gland) Approval: H27-B-062/C-098B_P

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Hematopoietic System,kidneys) Approval: H27-B-062/C-098B_P

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: H27-B-062/C-098B_P

1,3-DICHLOROPROPANE (142-28-9)

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: 22A4203

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 22A4203

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 22A4203

Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (Hematopoietic System,Central Nervous System,kidneys,liver,respiratory system) Approval: 22A4203

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 22A4203

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 22A4203

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 22A4203

1,3-DICHLOROPROPENE (542-75-6)

Flammable Liquids Category 3 H226 Flammable liquid and vapour Approval: 22B4513

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 137

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Approval: 22B4513

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Approval: 22B4513

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 137

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Approval: 137

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 137

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 22B4513

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (lungs,nervous system) Approval: 137

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (bladder,stomach,upper respiratory system) Approval: 137

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 137

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 137

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: H27-A-036/C-066A_P

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Approval: H27-A-036/C-066A_P

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: H27-A-036/C-066A_P

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: H27-A-036/C-066A_P

Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: H27-A-036/C-066A_P

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: H27-A-036/C-066A_P

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (liver) Approval: H27-A-036/C-066A_P

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: H27-A-036/C-066A_P

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: H27-A-036/C-066A_P

Japan GHS Labeling Information

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H319 Causes serious eye irritation

H360 May damage fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE DICHLORIDE (78-87-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2-TRICHLOROETHANE (79-00-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H320 Causes eye irritation

H351 Suspected of causing cancer

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

TRICHLOROETHYLENE (79-01-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H360 May damage fertility or the unborn child

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H305 May be harmful if swallowed and enters airways

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P331 Do NOT induce vomiting

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

HEXACHLOROBUTADIENE (87-68-3)

Symbol(s)

Signal Word Danger

Hazard(s)

H227 Combustible liquid

H301 Toxic if swallowed

H312 Harmful in contact with skin

H330 Fatal if inhaled

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Symbol(s)

Signal Word Danger

Hazard(s)

H227 Combustible liquid

H301 Toxic if swallowed

H312 Harmful in contact with skin

H330 Fatal if inhaled

H320 Causes eye irritation

H340 May cause genetic defects

H351 Suspected of causing cancer

H360 May damage fertility or the unborn child

H335 May cause respiratory irritation

H372 Causes damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2,3-TRICHLOROPROPANE (96-18-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H227 Combustible liquid

H301 Toxic if swallowed

H311 Toxic in contact with skin

H330 Fatal if inhaled

H319 Causes serious eye irritation

H350 May cause cancer

H360 May damage fertility or the unborn child

H370 Causes damage to organs

H371 May cause damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DIBROMIDE (106-93-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H330 Fatal if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H373 May cause damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DICHLORIDE (107-06-2)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H331 Toxic if inhaled

H320 Causes eye irritation

H350 May cause cancer

H370 Causes damage to organs

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPANE (142-28-9)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H315 Causes skin irritation

H317 May cause allergic skin reaction

H371 May cause damage to organs

H336 May cause drowsiness or dizziness

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPENE (542-75-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

H370 Causes damage to organs

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H320 Causes eye irritation

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H335 May cause respiratory irritation

H373 May cause damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Korea GHS Classifications

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)

METHYL ALCOHOL (67-56-1)

MOE:	Flammable liquids Category 2 H225 Highly flammable liquid and vapour. Acute toxicity Oral Category 3 H301 Toxic if swallowed. Acute toxicity Dermal Category 3 H311 Toxic in contact with skin. Acute toxicity Inhalation Category 3 H331 Toxic if inhaled. Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - Single exposure Category 1 H370 Causes damage to organs.
MOEL:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs body,Central Nervous System,optic nerve Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure Central Nervous System,eyes
NEMA:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

PROPYLENE DICHLORIDE (78-87-5)

MOEL:

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs blood,kidneys,liver

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure blood,kidneys,liver

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure respiratory system

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

NEMA:

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

1,1,2-TRICHLOROETHANE (79-00-5)

MOEL:

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation - Dust and Mist Category 3 H331 Toxic if inhaled

Acute toxicity Inhalation - Gas Category 3 H331 Toxic if inhaled

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs

TRICHLOROETHYLENE (79-01-6)

MOE:

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation.

Carcinogenicity Category 1 H350 May cause cancer.

Hazardous to aquatic environment - chronic hazard Category 3 H412 Harmful to aquatic life with long lasting effects.

MOEL:

Acute toxicity Inhalation - Vapour Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

1,1,2,2-TETRACHLOROETHANE (79-34-5)

MOEL:

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs liver

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure liver,nervous system

HEXACHLOROBUTADIENE (87-68-3)

MOEL:

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

MOE:

Acute toxicity Oral Category 3 H301 Toxic if swallowed.

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin.

Germ cell mutagenicity Category 1 H340 May cause genetic defects.

Carcinogenicity Category 2 H351 Suspected of causing cancer.

Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child.

Specific target organ toxicity - Repeated exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure.

Hazardous to aquatic environment - chronic hazard Category 3 H412 Harmful to aquatic life with long lasting effects.

MOEL:

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation - Dust and Mist Category 2 H330 Fatal if inhaled

Acute toxicity Inhalation - Gas Category 2 H330 Fatal if inhaled

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled

Germ Cell Mutagenicity Category 1A H340 May cause genetic defects

Carcinogenicity Category 1A H350 May cause cancer

Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

1,2,3-TRICHLOROPROPANE (96-18-4)

MOEL:

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs liver

Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs adrenal gland

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure blood,liver,respiratory system

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure heart,kidneys

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

ETHYLENE DIBROMIDE (106-93-4)

MOE:

Acute toxicity Oral Category 3 H301 Toxic if swallowed.

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin.

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled.

Skin corrosion/irritation Category 2 H315 Causes skin irritation.

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation.

Carcinogenicity Category 1 H350 May cause cancer.

Specific target organ toxicity - Single exposure Category 3 H335 May cause respiratory irritation.

Hazardous to aquatic environment - chronic hazard Category 3 H412 Harmful to aquatic life with long lasting effects.

MOEL:

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1B H350 May cause cancer

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs Central Nervous System,kidneys,liver

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure kidneys,liver,respiratory system

ETHYLENE DICHLORIDE (107-06-2)

MOE:	Flammable liquids Category 2 H225 Highly flammable liquid and vapour. Acute toxicity Oral Category 4 H302 Harmful if swallowed. Skin corrosion/irritation Category 2 H315 Causes skin irritation. Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation. Carcinogenicity Category 1 H350 May cause cancer. Specific target organ toxicity - Single exposure Category 3 H335 May cause respiratory irritation.
MOEL:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Acute toxicity Oral Category 4 H302 Harmful if swallowed Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Carcinogenicity Category 2 H351 Suspected of causing cancer Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs adrenal gland,Central Nervous System,kidneys,liver Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure liver,nervous system,thyroid gland Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure kidneys Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
NEMA:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

1,3-DICHLOROPROPANE (142-28-9)

NEMA:

Flammable Liquids Category 3 H226 Flammable liquid and vapour

1,3-DICHLOROPROPENE (542-75-6)

MOE:	Flammable liquids Category 3 H226 Flammable liquid and vapour. Acute toxicity Oral Category 3 H301 Toxic if swallowed. Acute toxicity Dermal Category 3 H311 Toxic in contact with skin. Acute toxicity Inhalation Category 4 H332 Harmful if inhaled. Skin corrosion/irritation Category 2 H315 Causes skin irritation. Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation. Skin sensitizers Category 1 H317 May cause allergic skin reaction. Specific target organ toxicity - Single exposure Category 3 H335 May cause respiratory irritation. Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life. Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects.
MOEL:	Flammable Liquids Category 3 H226 Flammable liquid and vapour Acute toxicity Oral Category 3 H301 Toxic if swallowed Acute toxicity Dermal Category 3 H311 Toxic in contact with skin Acute toxicity Inhalation - Dust and Mist Category 3 H331 Toxic if inhaled Acute toxicity Inhalation - Gas Category 3 H331 Toxic if inhaled Acute toxicity Inhalation - Vapour Category 3 H331 Toxic if inhaled Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Skin Sensitization Category 1 H317 May cause allergic skin reaction Carcinogenicity Category 1A H350 May cause cancer Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
NEMA:	Flammable Liquids Category 3 H226 Flammable liquid and vapour

1,1-DICHLOROPROPENE (563-58-6)

NEMA:

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Korea GHS Labeling Information

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H319 Causes serious eye irritation

H370 Causes damage to organs

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H319 Causes serious eye irritation

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H370 Causes damage to organs

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H319 Causes serious eye irritation

H350 May cause cancer

H412 Harmful to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H360 May damage fertility or the unborn child

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H304 May be fatal if swallowed and enters airways

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P331 Do NOT induce vomiting

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H370 Causes damage to organs

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H312 Harmful in contact with skin

H330 Fatal if inhaled

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H312 Harmful in contact with skin

H340 May cause genetic defects

H351 Suspected of causing cancer

H360 May damage fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H312 Harmful in contact with skin

H330 Fatal if inhaled

H340 May cause genetic defects

H350 May cause cancer

H360 May damage fertility or the unborn child

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H330 Fatal if inhaled

H319 Causes serious eye irritation

H370 Causes damage to organs

H371 May cause damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H350 May cause cancer

H335 May cause respiratory irritation

H412 Harmful to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H330 Fatal if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H335 May cause respiratory irritation

H373 May cause damage to organs through prolonged or repeated exposure

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H370 Causes damage to organs

H336 May cause drowsiness or dizziness

H372 Causes damage to organs through prolonged or repeated exposure

H373 May cause damage to organs through prolonged or repeated exposure

H304 May be fatal if swallowed and enters airways

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P331 Do NOT induce vomiting

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H335 May cause respiratory irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H350 May cause cancer

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

New Zealand GHS Classifications

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html

METHYL ALCOHOL (67-56-1) Approval: HSR001186

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Inhalation Category 1 H370 Causes damage to organs if inhaled (eyes,Nervous System)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates

PROPYLENE DICHLORIDE (78-87-5) Approval: HSR002810

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (liver)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,crustacean,fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates

1,1,2-TRICHLOROETHANE (79-00-5) Approval: HSR003095

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

TRICHLOROETHYLENE (79-01-6) Approval: HSR001555

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1 H350 May cause cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (algal,crustacean,fish)

1,1,2,2-TETRACHLOROETHANE (79-34-5) Approval: HSR001524

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 5 H313 May be harmful in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (liver)

Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (algal,crustacean)

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

Terrestrial Invertebrate Ecotoxicity Category 3 H443 Harmful to terrestrial invertebrates

1,2,3-TRICHLOROPROPANE (96-18-4) Approval: HSR003096

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Carcinogenicity Category 2 H351 Suspected of causing cancer

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

ETHYLENE DIBROMIDE (106-93-4) Approval: HSR002992

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Carcinogenicity Category 1 H350 May cause cancer

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (algal,crustacean,fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates

ETHYLENE DICHLORIDE (107-06-2) Approval: HSR001152

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 5 H313 May be harmful in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (liver)

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (liver)

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

1,3-DICHLOROPROPANE (142-28-9) Approval: HSR003110

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Specific Target Organ Toxicity - Single Exposure Oral Category 2 H371 May cause damage to organs if swallowed (liver)

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish,algal)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates

1,3-DICHLOROPROPENE (542-75-6) Approval: HSR001383

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Dermal Category 3 H311 Toxic in contact with skin

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (liver)

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (blood,Hematopoietic System)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (fish)

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (algal,crustacean)

Hazardous to the Terrestrial Environment - Soil Category 4 H423 Harmful to the soil environment

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

Terrestrial Invertebrate Ecotoxicity Category 2 H442 Toxic to terrestrial invertebrates

New Zealand GHS Labeling Information

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H319 Causes serious eye irritation

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H433 Harmful to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE DICHLORIDE (78-87-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H331 Toxic if inhaled

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H361 Suspected of damaging fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

H433 Harmful to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2-TRICHLOROETHANE (79-00-5)

Symbol(s)

Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H432 Toxic to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P322 Specific measures (see label)

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

TRICHLOROETHYLENE (79-01-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H373 May cause damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H313 May be harmful in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H351 Suspected of causing cancer

H373 May cause damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

H432 Toxic to terrestrial vertebrates

H443 Harmful to terrestrial invertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2,3-TRICHLOROPROPANE (96-18-4)

Symbol(s)

Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H351 Suspected of causing cancer

H432 Toxic to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P322 Specific measures (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DIBROMIDE (106-93-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H350 May cause cancer

H411 Toxic to aquatic life with long lasting effects

H431 Very toxic to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DICHLORIDE (107-06-2)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H313 May be harmful in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H373 May cause damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

H432 Toxic to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPANE (142-28-9)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H371 May cause damage to organs

H402 Harmful to aquatic life

H433 Harmful to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPENE (542-75-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H373 May cause damage to organs through prolonged or repeated exposure

H400 Very toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

H423 Harmful to the soil environment

H432 Toxic to terrestrial vertebrates

H442 Toxic to terrestrial invertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

South Africa GHS Classifications

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website

METHYL ALCOHOL (67-56-1)

Listing: Present

Listing: Present (>=3% and <10% by mass)

PROPYLENE DICHLORIDE (78-87-5)

Listing: Present

TRICHLOROETHYLENE (79-01-6)

Listing: Present

ETHYLENE DICHLORIDE (107-06-2)

Listing: Present

1,3-DICHLOROPROPENE (542-75-6)

Listing: Present

1,1-DICHLOROPROPENE (563-58-6)

Listing: Present

Taiwan GHS Classifications

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS

METHYL ALCOHOL (67-56-1)

Taiwan:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
	Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (eyes)

PROPYLENE DICHLORIDE (78-87-5)

Taiwan:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

1,1,2-TRICHLOROETHANE (79-00-5)

Taiwan:	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation

TRICHLOROETHYLENE (79-01-6)

Taiwan:	Acute toxicity Oral Category 5 H303 May be harmful if swallowed
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects
	Carcinogenicity Category 1 H350 May cause cancer
	Aspiration Hazard Category 2 H305 May be harmful if swallowed and enters airways
	Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Taiwan:	Acute toxicity Oral Category 3 H301 Toxic if swallowed
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
	Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

HEXACHLOROBUTADIENE (87-68-3)

Taiwan:	Acute toxicity Oral Category 3 H301 Toxic if swallowed
	Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
	Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Taiwan:	Acute toxicity Oral Category 3 H301 Toxic if swallowed
	Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Carcinogenicity Category 2 H351 Suspected of causing cancer
	Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child
	Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
	Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

1,2,3-TRICHLOROPROPANE (96-18-4)

Taiwan:	Flammable Liquids Category 4 H227 Combustible liquid
	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

ETHYLENE DIBROMIDE (106-93-4)

Taiwan:	Acute toxicity Oral Category 3 H301 Toxic if swallowed
	Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Carcinogenicity Category 1 H350 May cause cancer
	Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
	Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

ETHYLENE DICHLORIDE (107-06-2)

Taiwan:	Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Carcinogenicity Category 2 H351 Suspected of causing cancer
	Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (liver,kidneys)

1,3-DICHLOROPROPANE (142-28-9)

Taiwan:	Flammable Liquids Category 3 H226 Flammable liquid and vapour
	Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

1,3-DICHLOROPROPENE (542-75-6)

Taiwan:	Flammable Liquids Category 3 H226 Flammable liquid and vapour
	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
	Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
	Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
	Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
	Skin Sensitization Category 1 H317 May cause allergic skin reaction
	Carcinogenicity Category 2 H351 Suspected of causing cancer
	Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
	Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Taiwan:	Acute toxicity Oral Category 4 H302 Harmful if swallowed
	Acute toxicity Dermal Category 1 H310 Fatal in contact with skin
	Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
	Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation
	Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Taiwan GHS Labeling Information

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS

METHYL ALCOHOL (67-56-1)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H319 Causes serious eye irritation

H361 Suspected of damaging fertility or the unborn child

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE DICHLORIDE (78-87-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H320 Causes eye irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

TRICHLOROETHYLENE (79-01-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H303 May be harmful if swallowed

H315 Causes skin irritation

H319 Causes serious eye irritation

H341 Suspected of causing genetic defects

H350 May cause cancer

H305 May be harmful if swallowed and enters airways

H412 Harmful to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P331 Do NOT induce vomiting

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,2,2-TETRACHLOROETHANE (79-34-5)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H373 May cause damage to organs through prolonged or repeated exposure

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

HEXACHLOROBUTADIENE (87-68-3)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H402 Harmful to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2-DIBROMO-3-CHLOROPROPANE (96-12-8)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H312 Harmful in contact with skin

H315 Causes skin irritation

H351 Suspected of causing cancer

H360 May damage fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,2,3-TRICHLOROPROPANE (96-18-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H227 Combustible liquid

H302 Harmful if swallowed

H312 Harmful in contact with skin

H331 Toxic if inhaled

H316 Causes mild skin irritation

H319 Causes serious eye irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DIBROMIDE (106-93-4)

Symbol(s)

Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ETHYLENE DICHLORIDE (107-06-2)

Symbol(s)

Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H302 Harmful if swallowed

H331 Toxic if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H351 Suspected of causing cancer

H373 May cause damage to organs through prolonged or repeated exposure

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPANE (142-28-9)

Symbol(s)

Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H336 May cause drowsiness or dizziness

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,3-DICHLOROPROPENE (542-75-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H311 Toxic in contact with skin

H332 Harmful if inhaled

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

H335 May cause respiratory irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,1,2-TETRACHLOROETHANE (630-20-6)

Symbol(s)

Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H310 Fatal in contact with skin

H331 Toxic if inhaled

H320 Causes eye irritation

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P262 Do not get in eyes, on skin, or on clothing

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Classification

No classification assigned.

* * * Section 16 - OTHER INFORMATION * * *

Key / Legend

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States

Other Information

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.

Disclaimer:

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved

危险化学品

* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *

* * * Section 2 - HAZARDS IDENTIFICATION * * *

* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *

* * * Section 4 - FIRST AID MEASURES * * *

* * * Section 5 - FIRE FIGHTING MEASURES * * *

* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *

* * * Section 7 - HANDLING AND STORAGE * * *

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *

* * * Section 10 - STABILITY AND REACTIVITY * * *

* * * Section 11 - TOXICOLOGICAL INFORMATION * * *

* * * Section 12 - ECOLOGICAL INFORMATION * * *

* * * Section 13 - DISPOSAL CONSIDERATIONS * * *

* * * Section 14 - TRANSPORT INFORMATION * * *

* * * Section 15 - REGULATORY INFORMATION * * *

* * * Section 16 - OTHER INFORMATION * * *