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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

CHROMATED COPPER ARSENATE (CCA) PRESSURE-TREATED WOOD

ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.







Synonyms 

CCA PRESSURE-TREATED WOOD; CCA TREATED WOOD








* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  green 

Change in color: Not available

Physical Form: solid

Health Hazards:  harmful if swallowed, respiratory tract irritation, skin irritation, eye irritation, nervous system damage, allergic reactions, cancer hazard (in humans) 

Physical Hazards:  Dust/air mixtures may ignite or explode. 



Potential Health Effects 
Inhalation 

Short Term:  irritation 

Long Term:  hair loss, tearing, vomiting, digestive disorders, allergic reactions, chest pain, difficulty breathing, asthma, irregular heartbeat, headache, drowsiness, visual disturbances, dilated pupils, lung damage, cancer 



Skin Contact 

Short Term:  irritation, absorption may occur, allergic reactions, blisters, rash, itching, hair loss, diarrhea, difficulty breathing, irregular heartbeat, headache, visual disturbances 

Long Term:  irritation, skin disorders, cancer 



Eye Contact 

Short Term:  irritation, sensitivity to light, tearing, blurred vision, eye damage 

Long Term:  irritation, eye damage 



Ingestion 

Short Term:  same as effects reported in long term inhalation, nausea 

Long Term:  reproductive effects, cancer 














* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
Not Available -- --NON-HAZARDOUS SUBSTANCE-->92
7440-38-2 231-148-6 --ARSENICAcute Tox. 3 (Oral) - H301 Acute Tox. 3 (Inh.) - H331 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410<2
7440-47-3 231-157-5 --CHROMIUM--<2
7440-50-8 231-159-6 --COPPER--<2
8002-74-2 232-315-6 --PARAFFIN WAX--<1
Not Available -- --WOOD DUST, SOFTWOODS-->1



Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Chromium compounds, Copper, inorganic compounds, Copper compounds, n.o.s., Arsenic compounds, n.o.s., Arsenic, inorganic compounds,.








* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Ingestion 

If a large amount is swallowed, get medical attention. 








* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 1 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe



Flammable Properties 

Slight fire hazard. Dust/air mixtures may ignite or explode. 

Extinguishing Media 

carbon dioxide, regular dry chemical, regular foam, water 

Fire Fighting Measures 

Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 

Thermal Decomposition of Products 
Combustion: 

oxides of carbon, oxides of chromium, oxides of nitrogen, oxides of copper, oxides of arsenic, smoke 

Acids: 

metals 












* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Water Release 

Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. 

Occupational spill/release 

Collect spilled material in appropriate container for disposal. Keep out of water supplies and sewers. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 








* * * Section 7 - HANDLING AND STORAGE  * * *


Handling Procedures 

Use methods to minimize dust. 

Storage Procedures 

Store and handle in accordance with all current regulations and standards. Avoid generating dust. See original container for storage recommendations. Keep separated from incompatible substances. 








* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ARSENIC7440-38-2
ACGIH: 0.01 mg/m3 TWA
NIOSH: 0.002 mg/m3 Ceiling 15 min
 5 mg/m3 IDLH
OSHA (US): 10 µg/m3 TWA as As (related to Arsenic inorganic compounds)
 10 µg/m3 TWA (See 29 CFR 1910.1018, except Arsine) as As; 5 µg/m3 Action Level (See 29 CFR 1910.1018, except Arsine) as As (related to Arsenic inorganic compounds)
Mexico: 0.01 mg/m3 TWA VLE-PPT
CHROMIUM7440-47-3
ACGIH: 0.5 mg/m3 TWA
NIOSH: 0.5 mg/m3 TWA
 250 mg/m3 IDLH
Europe: 2 mg/m3 TWA
OSHA (US): 1 mg/m3 TWA
Mexico: 0.5 mg/m3 TWA VLE-PPT
COPPER7440-50-8
ACGIH: 0.2 mg/m3 TWA fume
NIOSH: 1 mg/m3 TWA dust and mist; 0.1 mg/m3 TWA fume
 100 mg/m3 IDLH dust, fume and mist
OSHA (US): 0.1 mg/m3 TWA fume; 1 mg/m3 TWA dust and mist
Mexico: 0.2 mg/m3 TWA VLE-PPT as Cu fume; 1 mg/m3 TWA VLE-PPT as Cu dust and mist
 2 mg/m3 STEL [PPT-CT] as Cu fume; 2 mg/m3 STEL [PPT-CT] as Cu dust and mist
PARAFFIN WAX8002-74-2
ACGIH: 2 mg/m3 TWA fume
NIOSH: 2 mg/m3 TWA fume
Mexico: 2 mg/m3 TWA VLE-PPT fume
 6 mg/m3 STEL [PPT-CT] fume
WOOD DUST, SOFTWOODSNot Available
NIOSH: 1 mg/m3 TWA (related to Wood dust, all soft and hard woods)



Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 



Ventilation 

Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 

PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Protective Clothing 

Wear appropriate chemical resistant clothing. 

Glove Recommendations 

Wear appropriate chemical resistant gloves. 

Respiratory Protection 

No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. 








* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor Not available Color green
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form solid










* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 

Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. 

Incompatible Materials 

acids, oxidizing materials 

ARSENIC ACIDS: Reacts vigorously. BROMATES: Reacts vigorously. CHLORATES: Reacts vigorously. FLUORINE: Reacts vigorously. HYDROGEN GAS: Reacts vigorously. LITHIUM: Reacts vigorously. OXIDIZING MATERIALS: Reacts vigorously. PALLADIUM: Reacts vigorously. POTASSIUM: Reacts vigorously. CHROMIUM ALKALI CARBONATES: Attacked. ALKALIES (CAUSTIC): Attacked. AMMONIUM NITRATE (FUSED): Violent or explosive reaction. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. HYDROGEN PEROXIDE: Violent decomposition reaction. LITHIUM (MOLTEN): Vigorous reaction at elevated temperatures. NITROGEN OXIDE: Incandescent reaction. OXIDIZERS (STRONG): Fire and explosion hazard. POTASSIUM CHLORATE (FUSED): Vigorous incandescent reaction. SULPHUR DIOXIDE: Incandescent reaction. WOOD DUST, SOFTWOODS: OXIDIZERS (STRONG): Fire and explosion hazard. COPPER ACETYLENE: Forms explosive copper acetylide. ACETYLENIC COMPOUNDS: Formation of explosive acetylides. ACIDS: May react. ALUMINUM + SULFUR: Possible explosion. AMMONIUM NITRATE: Violent or explosive reaction. BARIUM BROMATE: Explosive reaction by heat, impact or friction. BARIUM CHLORATE: Explosive reaction by heat, impact or friction. BARIUM IODATE: Explosive reaction by heat, impact or friction. BASES: May react. 1-BROMO-2-PROPYNE: Formation of explosive compound. CALCIUM BROMATE: Explosive reaction by heat, impact or friction. CALCIUM CHLORATE: Explosive reaction by heat, impact or friction. CALCIUM IODATE: Explosive reaction by heat, impact or friction. CHLORATES: Explosive reaction. CHLORINE: Ignition reaction. CHLORINE + OXYGEN DIFLUORIDE: Explosive reaction at -10 C. CHLORINE TRIFLUORIDE: Intense reaction with possible ignition. DIMETHYL SULFOXIDE + TRICHLOROACETIC ACID: Possible explosion. ETHYLENE OXIDE: Possible explosion. FLUORINE: Ignition reaction. HYDRAZINIUM NITRATE: Ignition reaction. HYDRAZOIC ACID: Possible explosion. HYDROGEN PEROXIDE: Violent decomposition. HYDROGEN SULFIDE: Intense exothermic reaction with possible ignition. LEAD AZIDE: Forms explosive copper azide. MAGNESIUM BROMATE: Explosive reaction by heat, impact or friction. MAGNESIUM CHLORATE: Explosive reaction by heat, impact or friction. MAGNESIUM IODATE: Explosive reaction by heat, impact or friction. OXIDIZERS: May react. PHOSPHORUS: Incandescent reaction. POTASSIUM BROMATE: Explosive reaction by heat, impact or friction. POTASSIUM CHLORATE: Explosive reaction by heat, impact or friction. POTASSIUM DIOXIDE: Incandescent reaction. POTASSIUM IODATE: Explosive reaction by heat, impact or friction. SODIUM AZIDE: Forms explosive compound. SODIUM BROMATE: Explosive reaction by heat, impact or friction. SODIUM CHLORATE: Explosive reaction by heat, impact or friction. SODIUM IODATE: Explosive reaction by heat, impact or friction. SODIUM PEROXIDE: Incandescent reaction. SULFUR + CHLORATES: Spontaneous explosion. SULFURIC ACID: Intense reaction. ZINC BROMATE: Explosive reaction by heat, impact or friction. ZINC CHLORATE: Explosive reaction by heat, impact or friction. ZINC IODATE: Explosive reaction by heat, impact or friction.

Thermal Decomposition of Products 
Combustion: 

oxides of carbon, oxides of chromium, oxides of nitrogen, oxides of copper, oxides of arsenic, smoke 

Acids: 

metals 





Possibility of Hazardous Reactions 

Will not polymerize. 








* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
ARSENIC (7440-38-2)

Oral LD50 Rat 15 mg/kg

PARAFFIN WAX (8002-74-2)

Oral LD50 Rat >3750 mg/kg

Dermal LD50 Rabbit >3600 mg/kg



Component Carcinogenicity

ARSENIC7440-38-2
ACGIH: A1 - Confirmed Human Carcinogen
IARC: Monograph 100C [2012]; Monograph 84 [2004] (in drinking water); Supplement 7 [1987]; Monograph 23 [1980] (Group 1 (carcinogenic to humans))
NTP: Known Human Carcinogen
DFG: Category 1 (causes cancer in man)
OSHA: Present
OSHA: see 29 CFR 1910.1018 except Arsine) (related to Arsenic inorganic compounds)
CHROMIUM7440-47-3
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 49 [1990]; Supplement 7 [1987] (Group 3 (not classifiable))
WOOD DUST, SOFTWOODSNot Available
IARC: Monograph 100C [2012]; Monograph 62 [1995] (related to Wood dust, all soft and hard woods) (Group 1 (carcinogenic to humans))
NTP: Known Human Carcinogen (related to Wood dust, all soft and hard woods)
DFG: Category 3B (could be carcinogenic for man, except beech and oak wood dust) (related to Wood dust, all soft and hard woods)
OSHA: Present (related to Wood dust, all soft and hard woods)







An increased risk of adenocarcinoma of the nasal cavities and paranasal sinuses has been reported in various wood working industries This risk occurs mainly in those exposed to wood dust Some studies have suggested there is a moderately high incidence of nasal cancers and Hodgkin's disease in workers exposed to various types of wood dust An increased incidence of urinary bladder, skin, lung, liver, and kidney cancer has been associated with inorganic arsenic compounds through medical treatment, contaminated drinking water, arsenical pesticide residues or occupational exposure Cancers at other sites have also been reported, but a clear association has not been confirmed. 

Medical Conditions Aggravated by Exposure 

blood system disorders, diabetes, respiratory disorders, kidney disorders, heart or cardiovascular disorders, skin disorders and allergies, liver disorders, immune system disorders or allergies, respiratory disorders, kidney disorders, skin disorders and allergies, liver disorders, nervous system disorders, skin disorders and allergies, 

Additional Data 

May cross the placenta May be excreted in breast milk. 

Inhalation - Acute Exposure 

ARSENIC: Inhalation of inorganic arsenic compounds may cause severe irritation of the nasal mucosa, larynx, and bronchi, cough with foamy sputum, pain in the chest on inspiration, dyspnea, lassitude, cyanosis, giddiness, headache, extreme general weakness, nausea, vomiting, colic, diarrhea, pain in the limbs, initial rise and then fall of temperature, leucocytosis, hypotension, and possibly pulmonary edema CHROMIUM: High concentrations of dusts or fumes may cause irritation WOOD DUST: The dust may be irritating to the mucous membranes COPPER: Powdered dust may cause irritation of the upper respiratory tract and ulceration and perforation of the nasal septum A feeling of illness similar to the common cold has been reported with symptoms of chills and stuffiness of the head Workers exposed to copper dust in concentrations of 0.075 to 0.120 mg/m3 complained of mild nasal discomfort Exposure to copper fume may cause irritation to the mucous membranes Freshly formed copper fumes may cause metal fume fever Symptoms may include a sweet, metallic, or foul taste in the mouth, dry throat, coughing, fever, chills, muscle aches, weakness, lassitude, nausea, rarely vomiting, mild to severe headaches, and sometimes exaggerated mental activity Workers exposed to concentrations of 1 to 3 mg/m3 experienced an altered taste response but no nausea.

Inhalation - Chronic Exposure 

CHROMIUM: Repeated or prolonged exposure to various chromium compounds has been reported to result in ulceration and perforation of the nasal septum, irritation of the throat and lower respiratory tract, less commonly in gastrointestinal disturbances, blood changes, pulmonary sensitization, pulmonary pneumoconiosis or fibrosis, and rarely liver effects These effects have not been reported from exposure to the metal per se COPPER: Prolonged industrial exposure may cause a green discoloration of the skin, hair and teeth Welders exposed to copper fume experienced atrophic rhinitis, metallic taste, runny nose, and mucosal irritation of the mouth and eyes Exposure in animals has caused destruction of red blood cells and lung cell injury It is inconclusive as to whether prolonged exposure has any affect on the nervous system A small number of studies suggest an affinity of copper for the sympathetic system, however, there is no proof that chronic poisoning will affect either the central or peripheral nervous system ARSENIC: May cause weakness, loss of appetite, nausea, occasional vomiting, a sense of heaviness in the stomach, diarrhea, salivation, upper respiratory inflammation and discharge, conjunctivitis, a catarrhal state of the mucous membranes of the nose, larynx, and respiratory passages, coryza, hoarseness, mild tracheobronchitis, and perforation of the nasal septum Skin lesions may occur and take many forms including increased pigmentation, keratosis of palms and soles eczema-like lesions, pale bands on the fingernails, alopecia and vitiligo Peripheral neuritis may develop initially of the hands and feet, which is usually sensory In very severe cases, motor paralysis may occur; the first muscles affected are usually the toe extensors and the peronei, and in only the most severe cases will paralysis of the flexor muscles of the feet or of the extensor muscles of the hands occur Liver disease with cirrhosis, and depression of bone marrow may occur with various blood dyscrasias including aplastic anemia Inorganic arsenic compounds have been shown to be lung carcinogens in humans The latency time between onset of exposure and the appearance of cancer is usually between 15 and 30 years WOOD DUST: Depending on the species of tree, inhalation of wood dust may cause irritation of the upper respiratory tract, dryness and soreness in the nose and throat which may extend to the larynx and trachea, sneezing, coughing, hoarseness, impairment of nasal mucociliary clearance, nasal obstruction, sweating and frequent headaches Atrophic changes in tissue may occur Various pulmonary diseases may occur such as obstructive lung disease, decreased pulmonary function, and recurrent bronchitis or pneumonitis which may lead to chronic lung damage Studies have revealed that exposure to levels greater than 5 mg/m3 may produce a chronic respiratory disease characterized by prolonged colds, inflammation of the middle ear, sinus, and nosebleeds Allergic reactions to wood dust appear to be very species specific Persons previously exposed to some wood dusts may become sensitized and develop asthma with watery eyes and a runny nose, bouts of sinusitis, right sided pluritic chest pain, cough, yellow sputum, wheezing and dyspnea Hypersensitivity pneumonitis has been reported in several woodworking occupations, however it has been found to be due to microorganisms living on the bark of the tree and not to the wood dust Adverse effects of exotic woods are generally more severe than those woods that grow in temperate climates Therefore, if exposure is to a tropical or exotic wood, irritant and allergic reactions may be more severe than reported above Systemic toxicity may occur due to the presence of alkaloids, glycosides or other toxins with symptoms which may include mydriasis, visual disturbances, salivation, thirst, giddiness, hyperemia, flushed face, swelling and stiffness of the hands and fingers associated with a heavy feeling in the arms, severe headaches, colic, nausea, vomiting, bradycardia, anorexia, somnolence, chest tightness, dyspnea, tachycardia, dysphagia, watery diarrhea with dehydration, anemia, hepatitis, abnormal renal and gastroenteric function, and depressed heart function Prolonged exposure to wood dust of any kind is suspected of causing adenocarcinomas, nasal, lung, larynx, and tongue cancer and Hodgkin's disease especially in the furniture and cabinet-making industries Although there have been differences in the incidences of cancer depending on the type of wood, this difference is thought to be due more to the difference in working conditions, frequency and duration of exposure, and the particle size instead of the difference in woods The average time between the first exposure and the diagnosis of a tumor is 39-43 years and the length of exposure has been reported to be as short as 5 years.

Skin Contact - Acute Exposure 

COPPER: May be irritating and cause keratinization Allergic dermatitis although rare, has been reported Dermal absorption is negligible through intact skin CHROMIUM: Contact with dusts or powder may cause irritation ARSENIC: Arsenic and inorganic arsenic compounds irritate the skin with erythema, itching and burning Sensitization dermatitis may occur in previously exposed persons, characterized by eczema with scaling and hyperpigmentation of the skin and hyperkeratosis of the palms of the hands and the soles of the feet Inorganic arsenic compounds are slightly absorbed through the skin when administered in a lipid vehicle Poisoning has caused alopecia, bronzing of the skin, and brittle nails WOOD DUST: Wood dust may cause irritation by mechanical or chemical action Mechanical irritation may occur when splinters become embedded in the skin which are extremely slow to heal and which may become secondarily infected, or when dust mechanically plugs the follicules of exposed skin causing a follicular acneform eruption, or more frequently when dust particles become trapped in clothing causing abrasions Chemical irritation may occur through direct contact with certain woods and cause an irritant dermatitis with possible erythema and blistering of the exposed skin often complicated by erosions and secondary infection The severity however depends on the type of wood and whether the dust particles are hard, soft, dry or moist Some tropical wood dust has been reported to cause intense irritation with multiforme-like eruptions and sometimes a dark brown punctate pigmentation of the skin Skin absorption of the alkaloids, glycosides, or other toxins present in tropical wood may cause systemic toxicity with swelling and stiffness of the hands and fingers associated with a heavy feeling in the arms, severe headaches, visual disturbances, dyspnea, tachycardia, dysphagia and watery diarrhea with dehydration Abnormal renal and gastroenteric function has also been reported to occur Another type of dermatitis termed "woodcutter's eczema" has been reported by woodworkers but studies show this skin disorder is due not to wood dust but to liverworts and lichens which may be present on the wood.

Skin Contact - Chronic Exposure 

WOOD DUST: Repeated or prolonged exposure may result in sensitization dermatitis The rash usually begins on the dorsa of the hands and forearms, eyelids, face, and neck and may rapidly spread to the genitals through handling in urination In bald men the scalp may also become affected, and if dust drifts inside clothing the sweaty area of the axille, waistband, and groin and sometimes the ankles and dorsa of the feet become affected Mild cases usually have only erythema and slight irritation, but often there is papular or vesicular dermatitis which may progress to chronic dermatitis Severe fissured lichenification of the palms has been reported to occur ARSENIC: Occupational exposure to airborne arsenic may cause two types of skin disorders due to local irritation An eczematous type with erythema, swelling and papules or vesicles and a follicular type with erythema and follicular swelling or follicular pustules Dermatitis is usually localized on the most heavily exposed areas such as the face, back of the neck, forearms, wrists and hands Less frequently the scrotum, the inner surfaces of the thighs, the upper chest and back, and the lower legs around the ankles may be affected Chronic dermal lesions may follow this type of initial reaction but usually only after many years of exposure Hyperkeratosis, warts and melanosis of the skin are conspicuous signs In severe cases, arsenomelanosis is observed on the abdomen, chest, back and scrotum These skin lesions may develop into precancerous and cancerous lesions COPPER: Repeated or prolonged contact may cause irritation and discoloration of the skin CHROMIUM: Repeated or prolonged exposure to various chromium compounds has been reported to cause various types of dermatitis, including eczema, "chrome holes", sensitization, and, in contact with damaged skin, kidney damage These effects have not been reported from exposure to the metal per se.

Eye Contact - Acute Exposure 

WOOD DUST: Wood dust may cause irritation by mechanical and/or chemical action Depending on the species of the tree, a variety of effects may occur, especially from tropical wood dust Symptoms may include irritation and inflammation with hyperemia of the conjunctiva, swelling of the lids, discomfort, lacrimation, photophobia, burning pain, edema, complete closure of the eyelids, and occasionally keratitis epithelialis, which may lead to disorders of vision, corneal damage, and blindness COPPER: The dust may cause irritation with redness and pain, tearing, and blurred vision Copper particles in the eye may result in a foreign body response with characteristic discoloration of ocular tissue, degeneration and/or detachment of the retina, and atrophy of the globe CHROMIUM: Contact with dusts or powders may cause irritation ARSENIC: Arsenical dust may cause irritation characterized by itching, burning, watering of the eyes, photophobia and sometimes hyperemia and chemosis.

Eye Contact - Chronic Exposure 

COPPER: Repeated or prolonged exposure to irritants may cause conjunctivitis ARSENIC: Repeated or prolonged eye contact with arsenic dust may cause conjunctivitis WOOD DUST: Repeated or prolonged exposure may cause conjunctivitis CHROMIUM: Repeated or prolonged exposure to some chromium compounds may cause conjunctivitis and lacrimation These effects have not been reported from exposure to the metal per se.

Ingestion - Acute Exposure 

ARSENIC: Ingestion of large doses may cause systemic poisoning with delayed symptoms usually appearing one hour after absorption Symptoms may include burning and colicky pains in the esophagus, stomach and bowel, contriction in the throat, difficulty in swallowing, muscular cramps, weakness, a sweetish metallic taste and a garlicky odor of the breath and feces Violent gastroenteritis may occur with vomiting, copious watery or bloody diarrhea containing shreds of mucus, and dehydration with intense thirst and muscular cramps Vertigo, frontal headache, delirium and even mania may develop without prominent gastrointestinal signs Later symptoms may include, cold and clammy skin, fall in blood pressure, extreme weakness, edema of the face and eyelids, tachycardia, vasomotor collapse, convulsions, shock, coma and death due to circulatory failure Death after a fatal dose occurs usually between 12 and 48 hours If the victim recovers, a symmetrical peripheral neuropathy may occur with numbness and paresthesias beginning in the distal extremities, lower limbs before the upper, which spreads rapidly and increases in intensity Motor weakness of the distal extremities may occur and the palsy is likely to affect the long extensors of fingers and toes Horizontal white lines (striations) on the fingernails and toenails are commonly seen and are considered to be a diagnostic accompaniment of arsenical polyneuritis Other adverse effects seen after recovery may include jaundice, oliguria or anuria, anemia, leukopenia and exfoliative dermatitis Inorganic arsenic crosses the placenta barrier, and neonatal death from arsenic has been reported following acute maternal intoxication CHROMIUM: Chromium metal is poorly absorbed by the intestinal tract Absorption of sufficient amounts of some chromium compounds may result in dizziness, intense thirst, abdominal pain, vomiting, shock, oliguria or anuria, and uremia, which may be fatal COPPER: May cause headache, weakness, diarrhea, or weight loss 120 ug/kg ingested by a human caused gastrointestinal disorder with nausea and vomiting WOOD DUST: Hard and soft wood dust has been reported to be non-toxic when ingested However, ingestion of alkaloids, glycosides, or other toxins present in tropical woods may cause systemic toxicity with symptoms of headache, anorexia, nausea, vomiting, bradycardia, dyspnea and somnolence.

Ingestion - Chronic Exposure 

ARSENIC: Repeated ingestion of small amounts may cause gastrointestinal symptoms such as diarrhea alternating with constipation, nausea, vomiting, abdominal cramps, salivation, malaise, fatigue, and loss of appetite and weight Damage to the nervous system may be apparent with polyneuritis, anesthesias, paresthesia such as burning pain in the hands and feet, and optic neuritis The skin may be affected with pigmentation, localized edema, dermatitis, hyperkeratosis, and alopecia Eye involvement may occur causing conjunctivitis with a sensation of irritation and tearing Pigment spots in the epithelium of both the cornea and conjunctiva may appear Other signs of poisoning may include anemia, leukopenia, thrombocytopenia, disturbed erythropoiesis in the bone marrow cells, depressed or disturbed myelopoiesis, hepatitis, cirrhosis or noncirrhotic portal entry Skin and lung cancer in humans is associated with chronic exposure to arsenic Repeated administration to female rats prior to mating produced effects on fertility Repeated administration during gestation produced specific developmental abnormalities in the offspring CHROMIUM: No data available WOOD DUST: No data available COPPER: Copper is an essential element and is found in most human diets in minute amounts Prolonged ingestion through the diet is not known to cause toxic effects except in people with a recessive gene disorder termed Wilson's disease which causes an abnormally high absorption, retention, and storage of copper by the body This disease may cause a dysfunction of and structural damage to the liver, central nervous system, kidney, bones and eyes The disease is usually progressive and may be fatal if left untreated Reproductive effects have been reported in animals.








* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

COPPER7440-50-8
Fish: LC50 96 h Pimephales promelas 0.0068 - 0.0156 mg/L; LC50 96 h Pimephales promelas <0.3 mg/L [static]; LC50 96 h Pimephales promelas 0.2 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.052 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 1.25 mg/L [static]; LC50 96 h Cyprinus carpio 0.3 mg/L [semi-static]; LC50 96 h Cyprinus carpio 0.8 mg/L [static]; LC50 96 h Poecilia reticulata 0.112 mg/L [flow-through]
Algae: EC50 72 h Pseudokirchneriella subcapitata 0.0426 - 0.0535 mg/L [static] EPA; EC50 96 h Pseudokirchneriella subcapitata 0.031 - 0.054 mg/L [static] EPA
Invertebrate: EC50 48 h Daphnia magna 0.03 mg/L [Static] EPA














* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. Hazardous Waste Number(s): D007. Dispose of in accordance with U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory level- 5.0 mg/L. Hazardous Waste Number(s): D004. Dispose of in accordance with U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory level- 5.0 mg/L. 

Component Waste Numbers 

ARSENIC7440-38-2
RCRA: 5 mg/L regulatory level
CHROMIUM7440-47-3
RCRA: 5 mg/L regulatory level










* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

No Classification assigned.

Component Marine Pollutants 

This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants 
Component CAS # Minimum Concentration 
COPPER7440-50-8DOT regulated severe marine pollutant (powder)







TDG Information:

No Classification assigned.



ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
ARSENIC (7440-38-2)

Restriction(s): D/E [UN1558] (II); D/E [UN1562] (II)







RID Information:

No Classification assigned.



IATA Information:

No Classification assigned.



ICAO Information:

No Classification assigned.



IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

This material contains one or more of the following chemicals required by IMDG to be identified as marine pollutants 
COPPER7440-50-8
 IMDG regulated marine pollutant (Listed in the index)














* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
ARSENIC7440-38-2
SARA 313: 0.1 % de minimis concentration
CERCLA: 1 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 0.454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
CHROMIUM7440-47-3
SARA 313: 1 % de minimis concentration
CERCLA: 5000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 2270 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
COPPER7440-50-8
SARA 313: 1 % de minimis concentration
CERCLA: 5000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 2270 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)



SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: No Pressure: No Reactivity: No







U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
ARSENIC7440-38-2Yes Yes Yes Yes Yes 
CHROMIUM7440-47-3Yes Yes Yes Yes Yes 
COPPER7440-50-8Yes Yes Yes Yes Yes 
PARAFFIN WAX8002-74-2Yes Yes Yes Yes Yes 
WOOD DUST, SOFTWOODSNot AvailableNo No Yes Yes No 



The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): 

WARNING! This product contains a chemical known to the state of California to cause cancer



Component Analysis 
ARSENIC7440-38-2
Carc: carcinogen , 2/27/1987 (related to Arsenic inorganic compounds)
WOOD DUST, SOFTWOODSNot Available
Carc: carcinogen , 12/18/2009 (related to Wood dust, all soft and hard woods)











Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
ARSENIC7440-38-2
 0.1 %
CHROMIUM7440-47-3
 0.1 %
COPPER7440-50-8
 1 %







Germany Water Classification 

ARSENIC (7440-38-2)

ID Number 7954 , hazard class 3 - severe hazard to waters

CHROMIUM (7440-47-3)

ID Number 1443 , not considered hazardous to water

COPPER (7440-50-8)

ID Number 1443 , not considered hazardous to water

PARAFFIN WAX (8002-74-2)

ID Number 268 , not considered hazardous to water

ID Number 0268 , not considered hazardous to water (not classified as carcinogenic (H350))



REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 
ARSENIC (7440-38-2)

Use restricted. See item 19. (related to Arsenic compounds)

WOOD DUST, SOFTWOODS (Not Available)

Use restricted. See item 9[f]. (powder) (related to Wood dust, all soft and hard woods)







Risk Phrases

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R64 May cause harm to breastfed babies.



Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
ARSENIC7440-38-2Yes DSL EIN Yes Yes No Yes Yes Yes 
CHROMIUM7440-47-3Yes DSL EIN Yes Yes No Yes Yes Yes 
COPPER7440-50-8Yes DSL EIN Yes Yes No Yes Yes Yes 
PARAFFIN WAX8002-74-2Yes DSL EIN Yes Yes Yes Yes Yes Yes 







Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ARSENIC (7440-38-2)

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1A H350 May cause cancer

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H331 Toxic if inhaled

H341 Suspected of causing genetic defects

H350 May cause cancer

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
ARSENIC (7440-38-2)

Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification)

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects



European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H331 Toxic if inhaled

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ARSENIC (7440-38-2)

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 20A2336

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 20A2336

Carcinogenicity Category 1A H350 May cause cancer Approval: 20A2336

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 20A2336

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Hematopoietic System,circulatory system,digestive system,kidneys,liver,nervous system,respiratory system,skin) Approval: 20A2336

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Hematopoietic System,circulatory system,digestive system,kidneys,liver,nervous system,respiratory system,skin) Approval: 20A2336

Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life Approval: 54

CHROMIUM (7440-47-3)

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 108

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled Approval: 108

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 108

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 108

Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (systemic toxicity) Approval: 108

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 108

COPPER (7440-50-8)

Skin Sensitization Category 1A H317 May cause allergic skin reaction Approval: 25B0005

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (digestive system) Approval: 25B0005

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25B0005

PARAFFIN WAX (8002-74-2)

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 720

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 21B3029



Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H319 Causes serious eye irritation

H350 May cause cancer

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H413 May cause long lasting harmful effects to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

CHROMIUM (7440-47-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H320 Causes eye irritation

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H371 May cause damage to organs

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

COPPER (7440-50-8)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H317 May cause allergic skin reaction

H370 Causes damage to organs

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PARAFFIN WAX (8002-74-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H320 Causes eye irritation

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ARSENIC (7440-38-2)

MOE:Acute toxicity Oral Category 3 H301 Toxic if swallowed.

Acute toxicity Inhalation Category 3 H331 Toxic if inhaled.

Carcinogenicity Category 1 H350 May cause cancer.

Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life.

Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects.
MOEL:Acute toxicity Oral Category 4 H302 Harmful if swallowed

Carcinogenicity Category 1A H350 May cause cancer

Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child

Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life


CHROMIUM (7440-47-3)

MOEL:Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs body

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation


COPPER (7440-50-8)

MOEL:Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure liver

Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life


PARAFFIN WAX (8002-74-2)

MOEL:Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation



Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H331 Toxic if inhaled

H350 May cause cancer

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H350 May cause cancer

H360 May damage fertility or the unborn child

H413 May cause long lasting harmful effects to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H371 May cause damage to organs

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H335 May cause respiratory irritation

H372 Causes damage to organs through prolonged or repeated exposure

H413 May cause long lasting harmful effects to aquatic life

Prevention

P271 Use only outdoors or in a well-ventilated area

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
ARSENIC (7440-38-2) Approval: HSR001528

Acute toxicity Oral Category 2 H300 Fatal if swallowed

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Carcinogenicity Category 1 H350 May cause cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (brain,Nervous System)

Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (circulatory system,liver,Nervous System,skin)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean)

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates

CHROMIUM (7440-47-3) Approval: HSR002943

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

COPPER (7440-50-8) Approval: HSR002948

Acute toxicity Oral Category 2 H300 Fatal if swallowed (powder)

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled (powder)

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation (powder)

Skin Sensitization Category 1 H317 May cause allergic skin reaction (powder)

Germ Cell Mutagenicity Category 1 H340 May cause genetic defects (powder)

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (digestive system,Hematopoietic System,kidneys,nose,upper respiratory system,skin) (powder)

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (kidneys,liver,stomach) (powder)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder)

Hazardous to the Terrestrial Environment - Soil Category 4 H423 Harmful to the soil environment (powder)

Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates (powder)



New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H300 Fatal if swallowed

H330 Fatal if inhaled

H341 Suspected of causing genetic defects

H350 May cause cancer

H372 Causes damage to organs through prolonged or repeated exposure

H400 Very toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

H431 Very toxic to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

CHROMIUM (7440-47-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H361 Suspected of damaging fertility or the unborn child

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

COPPER (7440-50-8)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H300 Fatal if swallowed

H330 Fatal if inhaled

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H340 May cause genetic defects

H373 May cause damage to organs through prolonged or repeated exposure

H400 Very toxic to aquatic life

H423 Harmful to the soil environment

H431 Very toxic to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ARSENIC (7440-38-2)

Taiwan:Acute toxicity Oral Category 4 H302 Harmful if swallowed
 Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
 Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects
 Carcinogenicity Category 1 H350 May cause cancer
 Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure
 Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects


PARAFFIN WAX (8002-74-2)

Taiwan:Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation



Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ARSENIC (7440-38-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H331 Toxic if inhaled

H341 Suspected of causing genetic defects

H350 May cause cancer

H372 Causes damage to organs through prolonged or repeated exposure

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PARAFFIN WAX (8002-74-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H316 Causes mild skin irritation

H320 Causes eye irritation

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations











Classification 

No classification assigned. 








* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 





Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved