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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *

Material Name:

1-ETHOXY-4-NITROBENZENE

ChemADVISOR, Inc.

Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237

E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.

Chemical Family

aromatic, nitro, ethers

Synonyms

4-NITROPHENETOLE; BENZENE, 1-ETHOXY-4-NITRO-; 4-ETHOXY-1-NITROBENZENE; 4-ETHOXYNITROBENZENE; 4-NITROPHENYL ETHYL ETHER; ETHYL P-NITROPHENYL ETHER; ETHYL PARA-NITROPHENYL ETHER; P-ETHOXYNITROBENZENE; PARA-ETHOXYNITROBENZENE; P-NITROBENZENE ETHYL ETHER; PARA-NITROBENZENE ETHYL ETHER; P-NITROPHENETOLE; PARA-NITROPHENETOLE; PHENETOLE, P-NITRO-; PHENETOLE, PARA-NITRO-; 4-NITROPHENETOL; C8H9NO3

* * * Section 2 - HAZARDS IDENTIFICATION * * *

Emergency Overview

Color: colorless

Change in color: Not available

Physical Form: crystals

Physical Hazards: Dust/air mixtures may ignite or explode.

Potential Health Effects

Inhalation

Short Term: no information is available

Long Term: no information is available

Skin Contact

Short Term: no information on significant adverse effects

Long Term: no information is available

Eye Contact

Short Term: no information on significant adverse effects

Long Term: no information is available

Ingestion

Short Term: no information is available

Long Term: no information is available

* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *

CAS EC No Registration No	Component Name Synonyms	1272/2008 (CLP)	Percent
100-29-8 202-837-9 --	1-ETHOXY-4-NITROBENZENE	--	100.0

* * * Section 4 - FIRST AID MEASURES * * *

Inhalation

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.

Skin

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

Ingestion

If a large amount is swallowed, get medical attention.

* * * Section 5 - FIRE FIGHTING MEASURES * * *

See Section 9 for Flammability Properties

NFPA Ratings:

Health: 0 Fire: 1 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

Flammable Properties

Slight fire hazard. Dust/air mixtures may ignite or explode.

Extinguishing Media

regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray.

Fire Fighting Measures

Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *

Occupational spill/release

Collect spilled material in appropriate container for disposal. Keep out of water supplies and sewers. Keep unnecessary people away, isolate hazard area and deny entry.

* * * Section 7 - HANDLING AND STORAGE * * *

Handling Procedures

Use methods to minimize dust.

Storage Procedures

Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances.

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *

Component Exposure Limits

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components

Component Analysis

Biological limit value

There are no biological limit values for any of this product's components.

Ventilation

Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

Protective Clothing

Wear appropriate chemical resistant clothing.

Glove Recommendations

Wear appropriate chemical resistant gloves.

Respiratory Protection

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying half-mask respirator equipped with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *

Appearance	Not available	Physical State	Solid
Odor	Not available	Color	colorless
Odor Threshold	Not available	pH	7
Melting Point	54 - 60 °C	Boiling Point	283 °C (decomposes)
Freezing point	Not available	Evaporation Rate	Not available
Boiling Point Range	Not available	Flammability (solid, gas)	Not available
Autoignition	>310 °C [DIN 51794]	Flash Point	140 °C DIN 51758
Lower Explosive Limit	Not available	Decomposition	Not available
Upper Explosive Limit	Not available	Vapor Pressure	(negligible)
Vapor Density (air=1)	Not available	Specific Gravity (water=1)	1.18 at 15 °C
Water Solubility	0.150 g/L (20 °C)	Partition coefficient: n-octanol/water	Not available
Viscosity	Not available	Solubility (Other)	Not available
Bioconcentration Factor (BCF)	46.77	Density	1.14 g/mL at 80 °C
KOC	545.76 (estimated from Kow)	pH Solution	(aqueous solution)
Physical Form	crystals	Molecular Formula	O2-N-C6-H4-O-C2-H5
Molecular Weight	167.18

Solvent Solubility

Soluble

acetone, ether, hot ethanol

Slightly Soluble

ethanol

* * * Section 10 - STABILITY AND REACTIVITY * * *

Chemical Stability

Stable at normal temperatures and pressure.

Conditions to Avoid

Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.

Incompatible Materials

oxidizing materials

1-ETHOXY-4-NITROBENZENE: OXIDIZERS (STRONG): Fire and explosion hazard.

Hazardous Decomposition Products

oxides of carbon, oxides of nitrogen

Possibility of Hazardous Reactions

Will not polymerize.

* * * Section 11 - TOXICOLOGICAL INFORMATION * * *

Component Analysis - LD50/LC50

The components of this material have been reviewed in various sources and the following selected endpoints are published:

1-ETHOXY-4-NITROBENZENE (100-29-8)

Oral LD50 Rat 3300 mg/kg

Dermal LD50 Rabbit >7940 mg/kg

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

Inhalation - Acute Exposure

1-ETHOXY-4-NITROBENZENE No data available.

Inhalation - Chronic Exposure

1-ETHOXY-4-NITROBENZENE No data available.

Skin Contact - Acute Exposure

1-ETHOXY-4-NITROBENZENE: Found to be non-irritating when tested on rabbit skin Found to be non-sensitizing when tested on guinea pig skin.

Skin Contact - Chronic Exposure

1-ETHOXY-4-NITROBENZENE No data available.

Eye Contact - Acute Exposure

1-ETHOXY-4-NITROBENZENE Found to be non-irritating when tested in rabbit eyes.

Eye Contact - Chronic Exposure

1-ETHOXY-4-NITROBENZENE No data available.

Ingestion - Acute Exposure

1-ETHOXY-4-NITROBENZENE No data available.

Ingestion - Chronic Exposure

1-ETHOXY-4-NITROBENZENE No data available.

* * * Section 12 - ECOLOGICAL INFORMATION * * *

Component Analysis - Aquatic Toxicity

1-ETHOXY-4-NITROBENZENE	100-29-8
Fish:	LC50 96 h Brachydanio rerio 59.6 mg/L [static]

* * * Section 13 - DISPOSAL CONSIDERATIONS * * *

Disposal Methods

Dispose in accordance with all applicable regulations.

Component Waste Numbers

The U.S. EPA has not published waste numbers for this product's components

* * * Section 14 - TRANSPORT INFORMATION * * *

US DOT Information:

No Classification assigned.

TDG Information:

No Classification assigned.

ADR Information:

No Classification assigned.

RID Information:

No Classification assigned.

IATA Information:

No Classification assigned.

ICAO Information:

No Classification assigned.

IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG)

Not regulated as dangerous goods.

* * * Section 15 - REGULATORY INFORMATION * * *

US Federal Regulations

None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan

SARA Section 311/312 (40 CFR 370 Subparts B and C)

Acute Health: No Chronic Health: No Fire: No Pressure: No Reactivity: No

U.S. State Regulations

None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA

Not listed under California Proposition 65

Canadian WHMIS Ingredient Disclosure List (IDL)

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL

1-ETHOXY-4-NITROBENZENE	100-29-8
	1 %

Germany Water Classification

1-ETHOXY-4-NITROBENZENE (100-29-8)

ID Number 7872 , hazard class 2 - hazard to waters

None needed according to classification criteria.

Component Analysis - Inventory

Component	CAS#	US	CA	EU	AU	PH	JP	KR	CN	NZ
1-ETHOXY-4-NITROBENZENE	100-29-8	Yes	NSL	EIN	No	No	Yes	No	Yes	No

Globally Harmonized System of Classification and Labeling (GHS)

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements

Australia GHS Classifications