危险化学品
收录危险化学品目录，并提供相应的化学品安全技术说明书(Material Safety Data Sheet，简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。
Material Name: 3-NITROBENZYL ALCOHOL SDS ID: ohs69033 Issue Date: 2016-06-23 Revision: 2.05 |
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
3-NITROBENZYL ALCOHOL
| ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
alcohols, aromatic, nitro
BENZENEMETHANOL, 3-NITRO-; 3-NITRO-BENZENEMETHANOL; BENZYL ALCOHOL, M-NITRO-; M-NITRO-BENZYL ALCOHOL; 3-NITROBENZENEMETHANOL; M-NITROBENZYL ALCOHOL; C7H7NO3; RTECS: DP0657000
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: yellow
Change in color: Not available
Physical Form: crystals, liquid
Short Term: irritation, symptoms of drunkenness, bluish skin color
Long Term: no information on significant adverse effects
Short Term: irritation, bluish skin color
Long Term: no information on significant adverse effects
Short Term: irritation
Long Term: no information is available
Short Term: symptoms of drunkenness, bluish skin color
Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
| CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
| 619-25-0 210-588-2 -- | 3-NITROBENZYL ALCOHOL | -- | 100.0 |
* * * Section 4 - FIRST AID MEASURES * * *
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give water, milk or activated charcoal slurry. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
For ingestion, consider gastric lavage.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Slight fire hazard.
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray.
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
Biological limit value
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
| Appearance | Not available | Physical State | Liquid |
| Odor | Not available | Color | yellow |
| Odor Threshold | Not available | pH | Not available |
| Melting Point | 27 - 32 °C | Boiling Point | 175 - 180 °C at 3 mmHg |
| Freezing point | Not available | Evaporation Rate | Not available |
| Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
| Autoignition | Not available | Flash Point | >110 °C |
| Lower Explosive Limit | Not available | Decomposition | Not available |
| Upper Explosive Limit | Not available | Vapor Pressure | Not available |
| Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
| Water Solubility | (slightly soluble) | Partition coefficient: n-octanol/water | Not available |
| Viscosity | Not available | Solubility (Other) | Not available |
| Density | Not available | Physical Form | crystals, liquid |
| Molecular Formula | NO2-C6-H4-CH2-OH | Molecular Weight | 153.14 |
| OSHA Flammability Class | IIIB |
alcohol
* * * Section 10 - STABILITY AND REACTIVITY * * *
Stable at normal temperatures and pressure.
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.
combustible materials, acids, halogens, oxidizing materials, metal salts, bases,
3-NITROBENZYL ALCOHOL: ACID ANHYDRIDES: Incompatible. ACID CHLORIDES: Incompatible. ACIDS: Incompatible. CHLORINE TRIFLUORIDE: Sensitive to shock. OXIDIZERS (STRONG): Fire and explosion hazard. NITROAROMATICS: ALKALIES: Possible violent decomposition or explosion when heated. CHLORINE TRIFLUORIDE: Solutions are extremely shock sensitive. ALCOHOLS: ACETALDEHYDE: Violent condensation reaction. BARIUM PERCHLORATE: Formation of highly explosive perchloric ester on refluxing. CHLORINE: Formation of highly explosive alkyl hypochlorites. DIETHYL ALUMINUM BROMIDE: Spontaneous ignition. ETHYLENE OXIDE: Possible explosion. HEXAMETHYLENE DIISOCYANATE: Possible explosion in absence of solvent. HYDROGEN PEROXIDE + SULFURIC ACID: Possible explosion. HYPOCHLOROUS ACID: Formation of highly explosive alkyl hypochlorites. ISOCYANATES: Possible explosion in absence of solvent. LITHIUM ALUMINUM HYDRIDE: Vigorous reaction. NITROGEN TETROXIDE: Possible explosion. PERCHLORIC ACID (HOT): Dangerous interaction. PERMONOSULFURIC ACID: Possible explosion on contact with primary or secondary alcohols. TRI-ISO-BUTYL ALUMINUM: Violent reaction.
oxides of carbon, nitrogen
Thermal decomposition products: oxides of carbon, nitrogen. test.
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
history of alcoholism, blood system disorders, heart or cardiovascular disorders, immune system disorders or allergies, kidney disorders, liver disorders, respiratory disorders,
May cross the placenta May be excreted in breast milk.
3-NITROBENZYL ALCOHOL: No specific data available Some alcohols may cause irritation and central nervous system depression Some aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis.
3-NITROBENZYL ALCOHOL: No specific data available Some aromatic nitro compounds have been associated with an increase in cancer, particularly of the bladder.
3-NITROBENZYL ALCOHOL: May cause irritation Skin absorption may occur Some alcohols may cause contact dermatitis Some aromatic nitro compounds rapidly penetrate the skin and may produce methemoglobin formation with cyanosis.
3-NITROBENZYL ALCOHOL: No specific data available Some aromatic nitro compounds have been associated with an increased incidence of cancer, particularly of the bladder.
3-NITROBENZYL ALCOHOL May cause irritation.
3-NITROBENZYL ALCOHOL No data available.
3-NITROBENZYL ALCOHOL: No specific data available Some alcohols may cause central nervous system depression Some aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis.
3-NITROBENZYL ALCOHOL: No specific data available Some aromatic nitro compounds have been associated with an increased incidence of cancer, particularly of the bladder in humans, and corneal and len opacities in animals.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Dispose in accordance with all applicable regulations.
Component Waste Numbers
* * * Section 14 - TRANSPORT INFORMATION * * *
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
Component Marine Pollutants (IMDG)
* * * Section 15 - REGULATORY INFORMATION * * *
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Not listed under California Proposition 65
R64 May cause harm to breastfed babies.
| Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
| 3-NITROBENZYL ALCOHOL | 619-25-0 | Yes | NSL | EIN | No | Yes | No | No | No | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
This material may be hazardous according to published criteria for classification
European Union GHS Classifications
This material may be hazardous according to published criteria for classification
Indonesia GHS Classifications
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
This material may be hazardous according to published criteria for classification
Korea GHS Classifications
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
This material may be hazardous according to published criteria for classification
South Africa GHS Classifications
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
| Taiwan: | Acute toxicity Oral Category 4 H302 Harmful if swallowed (suggested classification obtained through foreign chemical related database) |
| Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (suggested classification obtained through foreign chemical related database) | |
| Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (suggested classification obtained through foreign chemical related database) | |
| Skin Corrosion/Irritation Category 2 H315 Causes skin irritation (suggested classification obtained through foreign chemical related database) | |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation (suggested classification obtained through foreign chemical related database) | |
| Skin Sensitization Category 1 H317 May cause allergic skin reaction (suggested classification obtained through foreign chemical related database) | |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation (suggested classification obtained through foreign chemical related database) |
Taiwan GHS Labeling Information
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
H335 May cause respiratory irritation
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved