1-(CHLOROMETHYL)-4-NITROBENZENE

nitro, hydrocarbons, aromatic, halogens 

ALPHA-CHLORO-P-NITROTOLUENE; P-(CHLOROMETHYL)NITROBENZENE; 4-(CHLOROMETHYL)NITROBENZENE; P-NITROBENZYL CHLORIDE; 4-NITROBENZYL CHLORIDE; RTECS: XS9093000

Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: crystals

Health Hazards:  respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  Dust/air mixtures may ignite or explode. May decompose violently on heating. 

Short Term:  irritation (possibly severe), lung congestion 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 

For inhalation, consider oxygen. For ingestion, consider gastric lavage. 

See Section 9 for Flammability Properties 

Slight fire hazard. Dust/air mixtures may ignite or explode. 

regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 

Do not touch spilled material. Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Small dry spills: Move containers away from spill to a safe area. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 

Store and handle in accordance with all current regulations and standards. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355 Part B). 

Component Exposure Limits 

Biological limit value 

Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

acetone, benzene, alcohol, ether, dimethyl sulfoxide 

May decompose violently on heating. 

Avoid heat, flames, sparks and other sources of ignition. Dangerous gases may accumulate in confined spaces. May ignite or explode on contact with combustible materials. 

oxidizing materials, bases, acids, 

1-(CHLOROMETHYL)-4-NITRO-BENZENE: STRONG OXIDIZERS: Incompatible. SODIUM HYDROXIDE: Violent reaction. SULFURIC ACID: Fire and explosion hazard.

acid halides, oxides of carbon, nitrogen 

Thermal decomposition products: hydrogen chloride, oxides of carbon, nitrogen.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

1-(CHLOROMETHYL)-4-NITROBENZENE: May cause severe irritation of the respiratory tract Animal studies indicate that exposure to low concentrations may result in death, however the symptoms were not reported If sufficient quantities of a corrosive material are inhaled pulmonary edema may develop, often with a latency period of 48-72 hours.

1-(CHLOROMETHYL)-4-NITROBENZENE Depending on concentration and duration of exposure, repeated or prolonged contact may result in symptoms as those in acute exposure.

1-(CHLOROMETHYL)-4-NITROBENZENE May cause severe irritating and possible tissue destruction.

1-(CHLOROMETHYL)-4-NITROBENZENE Depending on concentration and duration of exposure, repeated or prolonged contact may result in symptoms as those in acute exposure.

1-(CHLOROMETHYL)-4-NITROBENZENE May cause severe irritation and possible tissue destruction.

1-(CHLOROMETHYL)-4-NITROBENZENE Depending on concentration and duration of exposure, repeated or prolonged contact may result in symptoms as those in acute exposure.

1-(CHLOROMETHYL)-4-NITROBENZENE May cause severe irritation of the gastrointestinal tract.

1-(CHLOROMETHYL)-4-NITROBENZENE No data available.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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