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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

2-NITRONAPHTHALENE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

nitroaromatic 


Synonyms 

BETA-NITRONAPHTHALENE; N-PHENYL-BETA-NAPHTHYLAMINE; BNN; UN 2538; C10H7NO2









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless to yellow 

Change in color: Not available

Physical Form: crystals

Health Hazards:  respiratory tract irritation, skin irritation, suspect cancer hazard (in animals) 

Physical Hazards:  Dust/air mixtures may ignite or explode. May decompose violently on heating. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, headache, dizziness, bluish skin color 

Long Term:  same as effects reported in short term exposure, blood disorders 




Skin Contact 

Short Term:  same as effects reported in short term inhalation, irritation 

Long Term:  same as effects reported in long term inhalation 




Eye Contact 

Short Term:  irritation 

Long Term:  no information is available 




Ingestion 

Short Term:  same as effects reported in short term inhalation 

Long Term:  same as effects reported in long term inhalation 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
581-89-5 209-474-5 --2-NITRONAPHTHALENECarc. 1B - H350 Aquatic Chronic 2 - H411100.0











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If a large amount is swallowed, get medical attention. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 2 Reactivity: 2

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Moderate fire hazard. Dust/air mixtures may ignite or explode. 


Extinguishing Media 

regular dry chemical, dry sand, earth, regular foam, water Large fires: Use regular foam or flood with fine water spray. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. 


Thermal Decomposition of Products 
Combustion: 

oxides of carbon, oxides of nitrogen 













* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Small spills: Collect spilled material in appropriate container for disposal. Move containers away from spill to a safe area. Large spills: Wet down area with water. Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Handling Procedures 

Use methods to minimize dust. 


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Protective Materials 

rubber 


Respiratory Protection 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. At any detectable concentration - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor Not available Color colorless to yellow
Odor Threshold Not available pH Not available 
Melting Point 74 - 79 °CBoiling Point 314 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form crystals
Molecular Formula C10-H7-N-O2Molecular Weight 173.17




Solvent Solubility 
Soluble 

alcohol, ether 













* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

May decompose violently on heating. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. 


Incompatible Materials 

bases, cyanides, metals, oxidizing materials, 


2-NITRONAPHTHALENE: BASES (STRONG): Incompatible. ALUMINUM: Incompatible. CYANIDES: Incompatible. ESTERS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PHOSPHORUS: Incompatible. THIOCYANATES: Incompatible. TIN CHLORIDES: Incompatible. SODIUM HYPOPHOSPHITE: Incompatible. See also information on nitroaromatics. NITROAROMATICS: ALKALIES: Possible violent decomposition or explosion when heated. CHLORINE TRIFLUORIDE: Solutions are extremely shock sensitive.

Thermal Decomposition of Products 
Combustion: 

oxides of carbon, oxides of nitrogen 






Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
2-NITRONAPHTHALENE (581-89-5)

Oral LD50 Rat 4400 mg/kg




Component Carcinogenicity

2-NITRONAPHTHALENE581-89-5
IARC: Monograph 46 [1989] (Diesel and Gasoline Engine Exhausts and Some Nitroarenes) (Group 3 (not classifiable))
DFG: Category 2 (considered to be carcinogenic for man)








Medical Conditions Aggravated by Exposure 

history of alcoholism, blood system disorders, heart or cardiovascular disorders, immune system disorders or allergies, liver and/or kidney disorders, respiratory disorders, 


Inhalation - Acute Exposure 

2-NITRONAPHTHALENE: May cause irritation Many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, headache, dizziness, euphoria and flushed faces.


Inhalation - Chronic Exposure 

2-NITRONAPHTHALENE: Repeated or prolonged exposure to many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, anemia, Heinz bodies with hemolysis, central nervous system depression with dizziness, headache, euphoria, and liver and kidney effects Exposure to some aromatic nitro compounds has been associated with an increase in cancer, particularly of the bladder.


Skin Contact - Acute Exposure 

2-NITRONAPHTHALENE: May cause irritation Many liquid aromatic nitro compounds rapidly penetrate the skin and may cause methemoglobin formation resulting in cyanosis, headache, dizziness, euphoria and flushed faces Some aromatic nitro compounds are strong sensitizers.


Skin Contact - Chronic Exposure 

2-NITRONAPHTHALENE: Repeated or prolonged exposure to irritants may cause dermatitis Repeated or prolonged exposure to many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, anemia, Heinz bodies with hemolysis, central nervous system depression with dizziness, headache, euphoria, and liver and kidney effects Exposure to some aromatic nitro compounds has been associated with an increase in cancer, particularly of the bladder.


Eye Contact - Acute Exposure 

2-NITRONAPHTHALENE May cause irritation.


Eye Contact - Chronic Exposure 

2-NITRONAPHTHALENE No data available.


Ingestion - Acute Exposure 

2-NITRONAPHTHALENE Many aromatic nitro compounds are absorbed from the gastrointestinal tract and may cause effects as detailed in acute inhalation.


Ingestion - Chronic Exposure 

2-NITRONAPHTHALENE: A rehesus monkey receiving a daily dose of 242 mg/kg/6 days a week for 54 months developed 3 papillomas in the urinary bladder Repeated or prolonged exposure to some aromatic nitro compounds may cause effects as detailed in chronic inhalation.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN/NA #: UN2538

Packing Group: III

Required Label(s): 4.1




TDG Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Required Label(s): 4.1




ADR Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Required Label(s): 4.1




RID Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Required Label(s): 4.1




IATA Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Required Label(s): 4.1




ICAO Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Required Label(s): 4.1




IMDG Information:

Shipping Name: NITRONAPHTHALENE

Hazard Class: 4.1

UN#: UN2538

Packing Group: III

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: Yes








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
2-NITRONAPHTHALENE581-89-5No No Yes Yes No 




Not listed under California Proposition 65 




REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 
2-NITRONAPHTHALENE (581-89-5)

Use restricted. See item 28.








Symbol(s)

T Toxic

N Dangerous for the Environment

Risk Phrases

R45 May cause cancer.

R51 Toxic to aquatic organisms.

R53 May cause long-term adverse effects in the aquatic environment.

Safety Phrases

S53 Avoid exposure - obtain special instructions before use.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S61 Avoid release to the environment. Refer to special instructions/ Safety Data Sheets.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
2-NITRONAPHTHALENE581-89-5No No EIN No No No No No No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
2-NITRONAPHTHALENE (581-89-5)

Carcinogenicity Category 1B H350 May cause cancer

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
2-NITRONAPHTHALENE (581-89-5)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H350 May cause cancer

H411 Toxic to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
2-NITRONAPHTHALENE (581-89-5)

Carcinogenicity Category 1B H350 May cause cancer

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
2-NITRONAPHTHALENE (581-89-5)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H350 May cause cancer

H411 Toxic to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2-NITRONAPHTHALENE (581-89-5) Approval: 42

Flammable Solids Category 2 H228 Flammable solid

Self-Reactive Substances and Mixtures Type G

Acute toxicity Oral Category 5 H303 May be harmful if swallowed

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2-NITRONAPHTHALENE (581-89-5)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H228 Flammable solid

H303 May be harmful if swallowed

H341 Suspected of causing genetic defects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
2-NITRONAPHTHALENE (581-89-5)

Taiwan:Flammable Solids Category 2 H228 Flammable solid
 Acute toxicity Oral Category 5 H303 May be harmful if swallowed
 Carcinogenicity Category 1 H350 May cause cancer
 Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
2-NITRONAPHTHALENE (581-89-5)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H228 Flammable solid

H303 May be harmful if swallowed

H350 May cause cancer

H411 Toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved