Material Name: 2-NITRONAPHTHALENE SDS ID: ohs34531 Issue Date: 2016-06-23 Revision: 2.08 |
2-NITRONAPHTHALENE
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
nitroaromatic
BETA-NITRONAPHTHALENE; N-PHENYL-BETA-NAPHTHYLAMINE; BNN; UN 2538; C10H7NO2
Emergency Overview
Color: colorless to yellow
Change in color: Not available
Physical Form: crystals
Health Hazards: respiratory tract irritation, skin irritation, suspect cancer hazard (in animals)
Physical Hazards: Dust/air mixtures may ignite or explode. May decompose violently on heating.
Short Term: irritation, headache, dizziness, bluish skin color
Long Term: same as effects reported in short term exposure, blood disorders
Short Term: same as effects reported in short term inhalation, irritation
Long Term: same as effects reported in long term inhalation
Short Term: irritation
Long Term: no information is available
Short Term: same as effects reported in short term inhalation
Long Term: same as effects reported in long term inhalation
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
581-89-5 209-474-5 -- | 2-NITRONAPHTHALENE | Carc. 1B - H350 Aquatic Chronic 2 - H411 | 100.0 |
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If a large amount is swallowed, get medical attention.
See Section 9 for Flammability Properties
Moderate fire hazard. Dust/air mixtures may ignite or explode.
regular dry chemical, dry sand, earth, regular foam, water Large fires: Use regular foam or flood with fine water spray.
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products.
oxides of carbon, oxides of nitrogen
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Small spills: Collect spilled material in appropriate container for disposal. Move containers away from spill to a safe area. Large spills: Wet down area with water. Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Use methods to minimize dust.
Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Keep separated from incompatible substances.
Component Exposure Limits
Biological limit value
Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
rubber
The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. At any detectable concentration - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Appearance | Not available | Physical State | Solid |
Odor | Not available | Color | colorless to yellow |
Odor Threshold | Not available | pH | Not available |
Melting Point | 74 - 79 °C | Boiling Point | 314 °C |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | Not available |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | crystals |
Molecular Formula | C10-H7-N-O2 | Molecular Weight | 173.17 |
alcohol, ether
May decompose violently on heating.
Avoid heat, flames, sparks and other sources of ignition.
bases, cyanides, metals, oxidizing materials,
2-NITRONAPHTHALENE: BASES (STRONG): Incompatible. ALUMINUM: Incompatible. CYANIDES: Incompatible. ESTERS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PHOSPHORUS: Incompatible. THIOCYANATES: Incompatible. TIN CHLORIDES: Incompatible. SODIUM HYPOPHOSPHITE: Incompatible. See also information on nitroaromatics. NITROAROMATICS: ALKALIES: Possible violent decomposition or explosion when heated. CHLORINE TRIFLUORIDE: Solutions are extremely shock sensitive.
oxides of carbon, oxides of nitrogen
Will not polymerize.
Component Analysis - LD50/LC50
Component Carcinogenicity
2-NITRONAPHTHALENE | 581-89-5 |
IARC: | Monograph 46 [1989] (Diesel and Gasoline Engine Exhausts and Some Nitroarenes) (Group 3 (not classifiable)) |
DFG: | Category 2 (considered to be carcinogenic for man) |
history of alcoholism, blood system disorders, heart or cardiovascular disorders, immune system disorders or allergies, liver and/or kidney disorders, respiratory disorders,
2-NITRONAPHTHALENE: May cause irritation Many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, headache, dizziness, euphoria and flushed faces.
2-NITRONAPHTHALENE: Repeated or prolonged exposure to many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, anemia, Heinz bodies with hemolysis, central nervous system depression with dizziness, headache, euphoria, and liver and kidney effects Exposure to some aromatic nitro compounds has been associated with an increase in cancer, particularly of the bladder.
2-NITRONAPHTHALENE: May cause irritation Many liquid aromatic nitro compounds rapidly penetrate the skin and may cause methemoglobin formation resulting in cyanosis, headache, dizziness, euphoria and flushed faces Some aromatic nitro compounds are strong sensitizers.
2-NITRONAPHTHALENE: Repeated or prolonged exposure to irritants may cause dermatitis Repeated or prolonged exposure to many aromatic nitro compounds may cause methemoglobin formation resulting in cyanosis, anemia, Heinz bodies with hemolysis, central nervous system depression with dizziness, headache, euphoria, and liver and kidney effects Exposure to some aromatic nitro compounds has been associated with an increase in cancer, particularly of the bladder.
2-NITRONAPHTHALENE May cause irritation.
2-NITRONAPHTHALENE No data available.
2-NITRONAPHTHALENE Many aromatic nitro compounds are absorbed from the gastrointestinal tract and may cause effects as detailed in acute inhalation.
2-NITRONAPHTHALENE: A rehesus monkey receiving a daily dose of 242 mg/kg/6 days a week for 54 months developed 3 papillomas in the urinary bladder Repeated or prolonged exposure to some aromatic nitro compounds may cause effects as detailed in chronic inhalation.
Component Analysis - Aquatic Toxicity
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003.
Component Waste Numbers
Component Marine Pollutants (IMDG)
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Component | CAS | CA | MA | MN | NJ | PA |
2-NITRONAPHTHALENE | 581-89-5 | No | No | Yes | Yes | No |
Not listed under California Proposition 65
REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
2-NITRONAPHTHALENE | 581-89-5 | No | No | EIN | No | No | No | No | No | No |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Australia GHS Labeling Information
European Union GHS Classifications
European Union GHS Labeling Information
Indonesia GHS Classifications
Japan GHS Classifications
Japan GHS Labeling Information
Korea GHS Classifications
New Zealand GHS Classifications
South Africa GHS Classifications
Taiwan GHS Classifications
Taiwan: | Flammable Solids Category 2 H228 Flammable solid |
Acute toxicity Oral Category 5 H303 May be harmful if swallowed | |
Carcinogenicity Category 1 H350 May cause cancer | |
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects |
Taiwan GHS Labeling Information
No classification assigned.
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
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