1-BROMO-3-NITROBENZENE

halogenated, aromatic, nitro 

BENZENE, 1-BROMO-3-NITRO-; M-BROMONITROBENZENE; 3-BROMONITROBENZENE; M-NITROBROMOBENZENE; 3-NITROBROMOBENZENE; M-NITROPHENYL BROMIDE; 3-NITROPHENYL BROMIDE; C6H4BRNO2; RTECS: CY9040500

Emergency Overview 

Color:  yellow to gray 

Change in color: Not available

Physical Form: crystals

Odor:  faint odor 

Health Hazards:  blood damage 

Physical Hazards:  May explode when heated. Dust/air mixtures may ignite or explode. 

Short Term:  irritation, bluish skin color 

Long Term:  no information is available 

Short Term:  irritation, bluish skin color 

Long Term:  no information is available 

Short Term:  irritation 

Long Term:  no information is available 

Short Term:  rash, nausea, vomiting, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, bluish skin color, paralysis, convulsions, coma 

Long Term:  same as effects reported in short term exposure 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If a large amount is swallowed, get medical attention. 

methylene blue, intravenous; ascorbic acid, intravenous. sodium chloride, oral, intravenous; diuretics. 

See Section 9 for Flammability Properties 

Slight fire hazard. Dust/air mixtures may ignite or explode. 

regular dry chemical, regular foam, water Large fires: Use regular foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Fight large fires from a protected location or safe distance. Stay away from the ends of tanks. Dike for later disposal. Do not scatter spilled material with high-pressure water streams. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 

Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Small dry spills: Move containers away from spill to a safe area. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. 

Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

alcohol 

May decompose explosively when heated above 100 C. 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. 

oxidizing materials 

1-BROMO-3-NITROBENZENE: OXIDIZERS (STRONG): Fire and explosion hazard.

oxides of carbon, nitrogen, acid halides 

Thermal decomposition products: oxides of carbon, nitrogen, hydrogen bromide.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

BROMONITROBENZENE: May cause irritation If sufficient amounts are absorbed, methemoglobinemia may occur as detailed in ingestion.

BROMONITROBENZENE No data available.

BROMONITROBENZENE: May cause irritation Skin absorption may occur and may result in methemoglobinemia as detailed in ingestion.

BROMONITROBENZENE No data available.

BROMONITROBENZENE May cause irritation.

BROMONITROBENZENE No data available.

METHEMOGLOBIN FORMERS: At about 15% concentration of methemoglobin, observable cyanosis of the lips, nose and earlobes may appear Symptoms may be absent although euphoria, flushed face and headache are common At 25-40%, cyanosis is marked, but little disability occurs except on exertion At 40-60%, symptoms may include weakness, dizziness, lightheadedness, increasingly severe headache, ataxia, rapid, shallow respiration, drowsiness, nausea, vomiting, confusion, lethargy, and stupor Above 60%, dyspnea, respiratory depression, tachycardia or bradycardia, convulsions, and coma may occur Levels above 70% may be fatal.

METHEMOGLOBIN FORMERS Compounds with cumulative properties may produce a persistent chronic type of methemoglobinemia which is the same as that produced by single large exposures.

BROMONITROBENZENE: See information on methemoglobin formers Large doses of bromides cause nausea and vomiting, abdominal pain, coma, and paralysis Symptoms from overdosage of bromides may include acneiform eruption, confusion, irritability, tremor, memory loss, anorexia, emaciation, headache, slurred speech, delusions, psychotic behavior, ataxia, stupor, and coma Blepharitis and conjunctivitis have been reported in some cases.

Component Analysis - Aquatic Toxicity 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D003. Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Korea GHS Classifications 

New Zealand GHS Classifications 

South Africa GHS Classifications 

Taiwan GHS Classifications 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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