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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

UREA NITRATE, WET


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

carbamides 


Synonyms 

UREA NITRATE; ACIDOGEN NITRATE; UREA MONONITRATE; UREA MONONITRATE (8CI, 9CI); URONIUM NITRATE; UN 1357; STCC 4917170









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless, white 

Change in color: Not available

Physical Form: crystals, flakes

Odor:  odorless 

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation 

Physical Hazards:  May explode if exposed to shock, friction or heating. Explosive if dry. Dust/air mixtures may ignite or explode. May decompose violently on heating. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, difficulty breathing, bluish skin color, convulsions 

Long Term:  same as effects reported in short term exposure 




Skin Contact 

Short Term:  irritation 

Long Term:  same as effects reported in short term exposure 




Eye Contact 

Short Term:  irritation, blurred vision 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  nausea, vomiting, stomach pain, headache, bluish skin color, convulsions 

Long Term:  no information on significant adverse effects 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
124-47-0 204-703-5 --UREA NITRATE, WET--<80.0
7732-18-5 231-791-2 --WATER-->20.0











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 


Note to Physicians 

For ingestion, consider gastric lavage and activated charcoal slurry. 


Antidote 

methylene blue, intravenous; ascorbic acid, intravenous. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 2 Reactivity: 3

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Moderate fire hazard. Severe explosion hazard. Dust/air mixtures may ignite or explode. Flood with water. If no water is available, use dry chemical or earth. 


Fire Fighting Measures 

For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Small spills: Flood with water. Large spills: Wet down area with water. Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. Store at room temperature. Avoid heat, flames, sparks and other sources of ignition. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Based on available information, additional ventilation is not required. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying half-mask respirator equipped with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece, organic vapor cartridge(s) and high-efficiency particulate filter(s). Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor odorlessColor colorless,white
Odor Threshold Not available pH (acidic in solution)
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition 152 °C
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) 1.7
Water Solubility (slightly soluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form crystals, flakes
Molecular Formula C-H5-N3-O4  




Solvent Solubility 
Soluble 

alcohol 


Insoluble 

nitric acid 













* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

May decompose violently on heating. Explosive if dry. May explode if exposed to shock, friction or heating. 


Conditions to Avoid 

Keep material wetted. Avoid heat, flames, sparks and other sources of ignition. Avoid shock or friction. 


Incompatible Materials 

reducing agents 


UREA NITRATE, WET: REDUCING AGENTS: Violent reaction.

Hazardous Decomposition Products 

oxides of nitrogen 


Thermal decomposition products: oxides of nitrogen.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
WATER (7732-18-5)

Oral LD50 Rat >90 mL/kg




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

May cause coughing, shortness of breath, or respiratory tract irritation Severe exposure may cause excitation, convulsions, and methemoglobinemia.


Inhalation - Chronic Exposure 

May cause respiratory tract irritation, shortness of breath, and coughing.


Skin Contact - Acute Exposure 

Contact may cause irritation.


Skin Contact - Chronic Exposure 

Repeated or prolonged contact may cause dermatitis.


Eye Contact - Acute Exposure 

May cause redness, pain, and blurred vision.


Eye Contact - Chronic Exposure 

Repeated or prolonged contact may cause conjunctivitis.


Ingestion - Acute Exposure 

UREA NITRATE May cause headache, nausea, vomiting, cyanosis, spasms, hypotension, abdominal cramps, unconsciousness, convulsions, respiratory paralysis, and formation of methemoglobin.


Ingestion - Chronic Exposure 

UREA NITRATE None known









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003. Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN/NA #: UN1357

Packing Group: I

Required Label(s): 4.1




TDG Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Required Label(s): 4.1




ADR Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Required Label(s): 4.1




RID Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Required Label(s): 4.1




IATA Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Required Label(s): 4.1




ICAO Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Required Label(s): 4.1




IMDG Information:

Shipping Name: UREA NITRATE, WETTED

Hazard Class: 4.1

UN#: UN1357

Packing Group: I

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: Yes Reactivity: Yes








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
UREA NITRATE, WET124-47-0No No No Yes No 




Not listed under California Proposition 65 




None needed according to classification criteria. 




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
UREA NITRATE, WET124-47-0No No EIN Yes Yes No No Yes Yes 
WATER7732-18-5Yes DSL EIN Yes Yes No Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
UREA NITRATE, WET (124-47-0) Approval: 07-D17

Explosives Division 1.1 H201 Explosive; mass explosion hazard

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
UREA NITRATE, WET (124-47-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H201 Explosive; mass explosion hazard

H316 Causes mild skin irritation

H320 Causes eye irritation

H335 May cause respiratory irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P230 Keep wetted

P240 Ground/Bond container and receiving equipment

P250 Do not subject to grinding/shock/friction

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P380 In case of fire: Evacuate area

P372 Explosion risk in case of fire

P373 DO NOT fight fire when fire reaches explosives

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
UREA NITRATE, WET (124-47-0) Approval: HSR007601

Flammable Solids Category 1 H228 Flammable solid (wetted with >=20 water by mass)




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
UREA NITRATE, WET (124-47-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H228 Flammable solid

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
UREA NITRATE, WET (124-47-0)

Taiwan:Flammable Solids Category 1 H228 Flammable solid




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
UREA NITRATE, WET (124-47-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H228 Flammable solid

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved