* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
ULTRAFERRATE-50
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: amber
Change in color: Not available
Physical Form: liquid
Odor: faint odor
Health Hazards: skin burns, eye burns, mucous membrane burns
Physical Hazards: May ignite combustibles.
Potential Health Effects
Inhalation
Short Term: irritation
Long Term: no information is available
Skin Contact
Short Term: burns
Long Term: same as effects reported in short term exposure
Eye Contact
Short Term: burns
Long Term: same as effects reported in short term exposure
Ingestion
Short Term: burns, metallic taste, digestive disorders, difficulty breathing, bluish skin color, lung congestion, convulsions, coma
Long Term: kidney damage, liver damage
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
10421-48-4 233-899-5 -- | FERRIC NITRATE | -- | <50.0 |
7732-18-5 231-791-2 -- | WATER | -- | <50.0 |
7697-37-2 231-714-2 -- | NITRIC ACID | Ox. Liq. 2 - H272 Skin Corr. 1A - H314 Note(s): B | <1.0 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
Note to Physicians
For inhalation, consider oxygen. Avoid gastric lavage or emesis.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials.
Use water only. Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents.
Fire Fighting Measures
Flood with water. Avoid inhalation of material or combustion by-products. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small liquid spills: Flood with water. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Store with acids. Keep separated from incompatible substances. Provide fire protection and spill control systems suitable for the hazards of the material.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
NITRIC ACID | 7697-37-2 |
ACGIH: | 2 ppm TWA |
| 4 ppm STEL |
NIOSH: | 2 ppm TWA; 5 mg/m3 TWA |
| 4 ppm STEL; 10 mg/m3 STEL |
| 25 ppm IDLH |
Europe: | 1 ppm STEL; 2.6 mg/m3 STEL |
OSHA (US): | 2 ppm TWA; 5 mg/m3 TWA |
Mexico: | 2 ppm TWA VLE-PPT; 5 mg/m3 TWA VLE-PPT |
| 4 ppm STEL [PPT-CT]; 10 mg/m3 STEL [PPT-CT] |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with acid gas cartridge(s). Any chemical cartridge respirator with a full facepiece and acid gas cartridge(s). Any air-purifying respirator with a full facepiece and an acid gas canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Liquid |
Odor | faint odor | Color | amber |
Odor Threshold | Not available | pH | <1 |
Melting Point | Not available | Boiling Point | 101 °C |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | Not available |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | 754 mmHg |
Vapor Density (air=1) | 0.62 | Specific Gravity (water=1) | Not available |
Water Solubility | 100 % | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Volatility | 50 % | | |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers.
Incompatible Materials
metals, combustible materials, cyanides, reducing agents, metal salts, acids
FERRIC NITRATE ALUMINUM: Incompatible. COMBUSTIBLE MATERIALS: May increase the burning rate. Finely divided materials. may ignite or explode. CYANIDE: Incompatible. DIMETHYL SULFOXIDE: Forms explosive mixture. METALS (COMMON): Incompatible. ORGANIC MATERIALS: May increase the burning rate. Finely divided materials may. ignite or explode. REDUCING AGENTS: May increase the burning rate. Finely divided materials may. ignite or explode on contact. SODIUM HYPOPHOSPHATE: Incompatible. SULFUR: Incompatible. METAL NITRATES ALUMINUM + WATER: Metal nitrates may explode. CITRIC ACID: Possible explosion hazard. ESTERS: Possible explosion hazard. PHOSPHINATES: May explode when heated. PHOSPHOROUS: Possible explosive reaction. POTASSIUM HEXANITROCOBALTATE(3-): May explode violently. REDUCTANTS: Possible explosion hazard. TIN(II) CHLORIDE: Possible explosive hazard.
Hazardous Decomposition Products
miscellaneous decomposition products
Thermal decomposition products: miscellaneous decomposition products.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
WATER (7732-18-5)
Oral LD50 Rat >90 mL/kg
NITRIC ACID (7697-37-2)
Inhalation LC50 Rat 67 ppm 4 h
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Medical Conditions Aggravated by Exposure
eye disorders, kidney disorders, liver disorders, respiratory disorders, skin disorders and allergies,
Inhalation - Acute Exposure
FERRIC NITRATE May cause irritation.
Inhalation - Chronic Exposure
FERRIC NITRATE No data available.
Skin Contact - Acute Exposure
CORROSIVE SUBSTANCES Direct contact may cause severe irritation, pain, and possibly burns.
Skin Contact - Chronic Exposure
CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in dermatitis or effects similar to acute exposure.
Skin Contact - Other Toxicity Information
FERRIC NITRATE See information on corrosive substances.
Eye Contact - Acute Exposure
CORROSIVE SUBSTANCES: Direct contact may cause severe irritation, pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact The full extent of the injury may not be immediately apparent.
Eye Contact - Chronic Exposure
CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.
Eye - Other Toxicity Information
FERRIC NITRATE See information on corrosive substances.
Ingestion - Acute Exposure
CORROSIVE SUBSTANCES: May cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur IRON SALTS: Ten minutes to several hours after excessive ingestion of soluble iron salts, severe gastritis or gastroenteritis may develop with abdominal pain, nausea, vomiting, hematemesis, watery or tarry diarrhea from corrosion of the gastric mucosa, dehydration, leukocytosis, and fever Metallic taste, restlessness, lethargy, hypotonia, coma, pallor, cyanosis, a fast or weak pulse, hypotension, hyperventilation due to acidosis, shock, vasomotor instability, and cardiovasuclar collapse may occur Severe cases may lead to death in 4 to 6 hours After an asymptomatic period of 12 to 72 hours, symptoms of the initial stage may recur Pneumonitis, pulmonary edema and hemorrhage, and convulsions may also be present Liver impairment with jaundice, hypoglycemia, multiple coagulation defects, kidney damage with anuria, pancreatic damage, vascular damage, hypovolemia, hemoconcentration, profound shock, and vascular collapse may develop At this stage, death may occur in one to three days or up to a week after ingestion, due to shock, hepatic failure, or pneumonia Survivors may display gastric scarring or obstruction, pyloric obstruction or stenosis, mild hepatic cirrhosis, and, in at least one reported instance, neurologic sequelae.
Ingestion - Chronic Exposure
CORROSIVE SUBSTANCES: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion IRON SALTS: Repeated therapeutic use of iron preparations may cause gastrointestinal tract irritation with nausea, vomiting, heartburn, anorexia, constipation, and diarrhea Chronic excessive iron intake can lead to hemosiderosis with possible damage to the liver and pancreas.
Ingestion - Other Toxicity Information
FERRIC NITRATE: Rarely, inorganic nitrates may be converted to nitrites by nitrate-reducing bacteria in the digestive tract, resulting in methemoglobinemia Repeated or prolonged exposure to nitrates may cause anemia, nephritis, and possibly methemoglobinemia See information on corrosive substances and iron salts.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
Shipping Name: CORROSIVE LIQUIDS, OXIDIZING, N.O.S., (Contains:FERRIC NITRATE NITRIC ACID)
Hazard Class: 8
UN/NA #: UN3093
Packing Group: I
Required Label(s): 8, 5.1
TDG Information:
No Classification assigned.
ADR Information:
Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.
Hazard Class: 8
UN#: UN3093
Packing Group: I
Required Label(s): 8 + 5.1
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
FERRIC NITRATE (10421-48-4)
Restriction(s): E [UN1466] (III)
NITRIC ACID (7697-37-2)
Restriction(s): E [UN2031] (I); E [UN2031] (II); C/D [UN2032] (I, red fuming)
RID Information:
Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.
Hazard Class: 8
UN#: UN3093
Packing Group: I
Required Label(s): 8 + 5.1
IATA Information:
Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.
Hazard Class: 8
UN#: UN3093
Packing Group: I
Required Label(s): 8, 5.1
ICAO Information:
Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.
Hazard Class: 8
UN#: UN3093
Packing Group: I
Required Label(s): 8, 5.1
IMDG Information:
Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.
Hazard Class: 8
UN#: UN3093
Packing Group: I
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
FERRIC NITRATE | 10421-48-4 |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
NITRIC ACID | 7697-37-2 |
SARA 302: | 1000 lb TPQ |
SARA 313: | 1 % de minimis concentration |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
OSHA (safety): | 500 lb TQ >=94.5% by weight) |
SARA 304: | 1000 lb EPCRA RQ |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: Yes Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
FERRIC NITRATE | 10421-48-4 | Yes | Yes | No | Yes | Yes |
NITRIC ACID | 7697-37-2 | Yes | Yes | Yes | Yes | Yes |
Not listed under California Proposition 65
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
Germany Water Classification
FERRIC NITRATE (10421-48-4)
ID Number 516 , hazard class 1 - low hazard to waters (footnote 8)
NITRIC ACID (7697-37-2)
ID Number 414 , hazard class 1 - low hazard to waters (except fuming)
Symbol(s)
C Corrosive
Risk Phrases
R34 Causes burns.
R41 Risk of serious damage to eyes.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
FERRIC NITRATE | 10421-48-4 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
WATER | 7732-18-5 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
NITRIC ACID | 7697-37-2 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
NITRIC ACID (7697-37-2)
Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H272 May intensify fire, oxidizer
H314 Causes severe skin burns and eye damage
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
NITRIC ACID (7697-37-2)
Oxidizing Liquids Category 2 H272 May intensify fire, oxidizer
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
Supplemental Hazards EUH071 Corrosive to respiratory tract
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H272 May intensify fire, oxidizer
H314 Causes severe skin burns and eye damage
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
NITRIC ACID (7697-37-2)
Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer Approval: 597
Corrosive to Metals Category 1 H290 May be corrosive to metals Approval: H26-B-114 / R-054
Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled Approval: H26-B-114 / R-054
Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Approval: H26-B-114 / R-054
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 597
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 597
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system,teeth) Approval: 597
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: H26-B-112 / R-053
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H272 May intensify fire, oxidizer
H290 May be corrosive to metals
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P370+P378 In case of fire: Use appropriate media for extinction
P390 Absorb spillage to prevent material-damage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
NITRIC ACID (7697-37-2)
MOE: | Oxidizing liquids Category 1 H271 May cause fire or explosion, strong oxidizer. Skin corrosion/irritation Category 1 H314 Causes severe skin burns and eye damage. |
MOEL: | Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer Acute toxicity Inhalation - Dust and Mist Category 2 H330 Fatal if inhaled Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure respiratory system,teeth Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways |
NEMA: | Oxidizing Liquids Category 1 H271 May cause fire or explosion, strong oxidizer |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H271 May cause fire or explosion, strong oxidizer
H314 Causes severe skin burns and eye damage
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P283 Wear fire/flame resistant/retardant clothing
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H272 May intensify fire, oxidizer
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P320 Specific treatment is urgent (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H271 May cause fire or explosion, strong oxidizer
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P283 Wear fire/flame resistant/retardant clothing
Response
P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P370+P378 In case of fire: Use appropriate media for extinction
P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
FERRIC NITRATE (10421-48-4) Approval: HSR001325
Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
NITRIC ACID (7697-37-2) Approval: HSR000982
Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer (red fuming)
Corrosive to Metals Category 1 H290 May be corrosive to metals (red fuming)
Acute toxicity Inhalation Category 1 H330 Fatal if inhaled (red fuming)
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage (red fuming)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage (red fuming)
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (upper respiratory system,teeth) (red fuming)
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (fish) (red fuming)
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
FERRIC NITRATE (10421-48-4)
Symbol(s)
Signal Word Warning
Hazard(s)
H272 May intensify fire, oxidizer
H302 Harmful if swallowed
H316 Causes mild skin irritation
H319 Causes serious eye irritation
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H272 May intensify fire, oxidizer
H290 May be corrosive to metals
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H373 May cause damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P370+P378 In case of fire: Use appropriate media for extinction
P390 Absorb spillage to prevent material-damage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
NITRIC ACID (7697-37-2)
Listing: Present (>70% by mass)
Listing: Present (<=70% by mass)
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
FERRIC NITRATE (10421-48-4)
Taiwan: | Oxidizing Solids Category 3 H272 May intensify fire, oxidizer |
| Acute toxicity Oral Category 5 H303 May be harmful if swallowed |
| Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
NITRIC ACID (7697-37-2)
Taiwan: | Oxidizing Liquids Category 1 H271 May cause fire or explosion, strong oxidizer |
| Corrosive to Metals Category 1 H290 May be corrosive to metals |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
| Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (lungs) |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
FERRIC NITRATE (10421-48-4)
Symbol(s)
Signal Word Warning
Hazard(s)
H272 May intensify fire, oxidizer
H303 May be harmful if swallowed
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P332+P313 If skin irritation occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
NITRIC ACID (7697-37-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H271 May cause fire or explosion, strong oxidizer
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P234 Keep only in original container
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P283 Wear fire/flame resistant/retardant clothing
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
P390 Absorb spillage to prevent material-damage
Storage
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved