你好,欢迎来到试验技术专业知识服务系统

危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

ULTRAFERRATE-50


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.















* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  amber 

Change in color: Not available

Physical Form: liquid

Odor:  faint odor 

Health Hazards:  skin burns, eye burns, mucous membrane burns 

Physical Hazards:  May ignite combustibles. 




Potential Health Effects 
Inhalation 

Short Term:  irritation 

Long Term:  no information is available 




Skin Contact 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 




Eye Contact 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  burns, metallic taste, digestive disorders, difficulty breathing, bluish skin color, lung congestion, convulsions, coma 

Long Term:  kidney damage, liver damage 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
10421-48-4 233-899-5 --FERRIC NITRATE--<50.0
7732-18-5 231-791-2 --WATER--<50.0
7697-37-2 231-714-2 --NITRIC ACIDOx. Liq. 2 - H272 Skin Corr. 1A - H314 Note(s): B<1.0











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 


Eyes 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 


Note to Physicians 

For inhalation, consider oxygen. Avoid gastric lavage or emesis. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 


Use water only. Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. 

Fire Fighting Measures 

Flood with water. Avoid inhalation of material or combustion by-products. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small liquid spills: Flood with water. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Store with acids. Keep separated from incompatible substances. Provide fire protection and spill control systems suitable for the hazards of the material. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

NITRIC ACID7697-37-2
ACGIH: 2 ppm TWA
 4 ppm STEL
NIOSH: 2 ppm TWA; 5 mg/m3 TWA
 4 ppm STEL; 10 mg/m3 STEL
 25 ppm IDLH
Europe: 1 ppm STEL; 2.6 mg/m3 STEL
OSHA (US): 2 ppm TWA; 5 mg/m3 TWA
Mexico: 2 ppm TWA VLE-PPT; 5 mg/m3 TWA VLE-PPT
 4 ppm STEL [PPT-CT]; 10 mg/m3 STEL [PPT-CT]




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with acid gas cartridge(s). Any chemical cartridge respirator with a full facepiece and acid gas cartridge(s). Any air-purifying respirator with a full facepiece and an acid gas canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Liquid
Odor faint odorColor amber
Odor Threshold Not available pH <1
Melting Point Not available Boiling Point 101 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure 754 mmHg
Vapor Density (air=1) 0.62Specific Gravity (water=1) Not available 
Water Solubility 100 %Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form liquid
Volatility 50 %  











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. 


Incompatible Materials 

metals, combustible materials, cyanides, reducing agents, metal salts, acids 


FERRIC NITRATE ALUMINUM: Incompatible. COMBUSTIBLE MATERIALS: May increase the burning rate. Finely divided materials. may ignite or explode. CYANIDE: Incompatible. DIMETHYL SULFOXIDE: Forms explosive mixture. METALS (COMMON): Incompatible. ORGANIC MATERIALS: May increase the burning rate. Finely divided materials may. ignite or explode. REDUCING AGENTS: May increase the burning rate. Finely divided materials may. ignite or explode on contact. SODIUM HYPOPHOSPHATE: Incompatible. SULFUR: Incompatible. METAL NITRATES ALUMINUM + WATER: Metal nitrates may explode. CITRIC ACID: Possible explosion hazard. ESTERS: Possible explosion hazard. PHOSPHINATES: May explode when heated. PHOSPHOROUS: Possible explosive reaction. POTASSIUM HEXANITROCOBALTATE(3-): May explode violently. REDUCTANTS: Possible explosion hazard. TIN(II) CHLORIDE: Possible explosive hazard.

Hazardous Decomposition Products 

miscellaneous decomposition products 


Thermal decomposition products: miscellaneous decomposition products. 

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
WATER (7732-18-5)

Oral LD50 Rat >90 mL/kg

NITRIC ACID (7697-37-2)

Inhalation LC50 Rat 67 ppm 4 h




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Medical Conditions Aggravated by Exposure 

eye disorders, kidney disorders, liver disorders, respiratory disorders, skin disorders and allergies, 


Inhalation - Acute Exposure 

FERRIC NITRATE May cause irritation.


Inhalation - Chronic Exposure 

FERRIC NITRATE No data available.


Skin Contact - Acute Exposure 

CORROSIVE SUBSTANCES Direct contact may cause severe irritation, pain, and possibly burns.


Skin Contact - Chronic Exposure 

CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in dermatitis or effects similar to acute exposure.


Skin Contact - Other Toxicity Information 

FERRIC NITRATE See information on corrosive substances.


Eye Contact - Acute Exposure 

CORROSIVE SUBSTANCES: Direct contact may cause severe irritation, pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact The full extent of the injury may not be immediately apparent.


Eye Contact - Chronic Exposure 

CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.


Eye - Other Toxicity Information 

FERRIC NITRATE See information on corrosive substances.


Ingestion - Acute Exposure 

CORROSIVE SUBSTANCES: May cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur IRON SALTS: Ten minutes to several hours after excessive ingestion of soluble iron salts, severe gastritis or gastroenteritis may develop with abdominal pain, nausea, vomiting, hematemesis, watery or tarry diarrhea from corrosion of the gastric mucosa, dehydration, leukocytosis, and fever Metallic taste, restlessness, lethargy, hypotonia, coma, pallor, cyanosis, a fast or weak pulse, hypotension, hyperventilation due to acidosis, shock, vasomotor instability, and cardiovasuclar collapse may occur Severe cases may lead to death in 4 to 6 hours After an asymptomatic period of 12 to 72 hours, symptoms of the initial stage may recur Pneumonitis, pulmonary edema and hemorrhage, and convulsions may also be present Liver impairment with jaundice, hypoglycemia, multiple coagulation defects, kidney damage with anuria, pancreatic damage, vascular damage, hypovolemia, hemoconcentration, profound shock, and vascular collapse may develop At this stage, death may occur in one to three days or up to a week after ingestion, due to shock, hepatic failure, or pneumonia Survivors may display gastric scarring or obstruction, pyloric obstruction or stenosis, mild hepatic cirrhosis, and, in at least one reported instance, neurologic sequelae.


Ingestion - Chronic Exposure 

CORROSIVE SUBSTANCES: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion IRON SALTS: Repeated therapeutic use of iron preparations may cause gastrointestinal tract irritation with nausea, vomiting, heartburn, anorexia, constipation, and diarrhea Chronic excessive iron intake can lead to hemosiderosis with possible damage to the liver and pancreas.


Ingestion - Other Toxicity Information 

FERRIC NITRATE: Rarely, inorganic nitrates may be converted to nitrites by nitrate-reducing bacteria in the digestive tract, resulting in methemoglobinemia Repeated or prolonged exposure to nitrates may cause anemia, nephritis, and possibly methemoglobinemia See information on corrosive substances and iron salts.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: CORROSIVE LIQUIDS, OXIDIZING, N.O.S., (Contains:FERRIC NITRATE NITRIC ACID)

Hazard Class: 8

UN/NA #: UN3093

Packing Group: I

Required Label(s): 8, 5.1




TDG Information:

No Classification assigned.




ADR Information:

Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.

Hazard Class: 8

UN#: UN3093

Packing Group: I

Required Label(s): 8 + 5.1

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
FERRIC NITRATE (10421-48-4)

Restriction(s): E [UN1466] (III)

NITRIC ACID (7697-37-2)

Restriction(s): E [UN2031] (I); E [UN2031] (II); C/D [UN2032] (I, red fuming)








RID Information:

Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.

Hazard Class: 8

UN#: UN3093

Packing Group: I

Required Label(s): 8 + 5.1




IATA Information:

Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.

Hazard Class: 8

UN#: UN3093

Packing Group: I

Required Label(s): 8, 5.1




ICAO Information:

Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.

Hazard Class: 8

UN#: UN3093

Packing Group: I

Required Label(s): 8, 5.1




IMDG Information:

Shipping Name: CORROSIVE LIQUID, OXIDIZING, N.O.S.

Hazard Class: 8

UN#: UN3093

Packing Group: I

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
FERRIC NITRATE10421-48-4
CERCLA: 1000 lb final RQ; 454 kg final RQ
NITRIC ACID7697-37-2
SARA 302: 1000 lb TPQ
SARA 313: 1 % de minimis concentration
CERCLA: 1000 lb final RQ; 454 kg final RQ
OSHA (safety): 500 lb TQ >=94.5% by weight)
SARA 304: 1000 lb EPCRA RQ




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
FERRIC NITRATE10421-48-4Yes Yes No Yes Yes 
NITRIC ACID7697-37-2Yes Yes Yes Yes Yes 




Not listed under California Proposition 65 




Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
NITRIC ACID7697-37-2
 1 %








Germany Water Classification 

FERRIC NITRATE (10421-48-4)

ID Number 516 , hazard class 1 - low hazard to waters (footnote 8)

NITRIC ACID (7697-37-2)

ID Number 414 , hazard class 1 - low hazard to waters (except fuming)








Symbol(s)

C Corrosive

Risk Phrases

R34 Causes burns.

R41 Risk of serious damage to eyes.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
FERRIC NITRATE10421-48-4Yes DSL EIN Yes Yes Yes Yes Yes Yes 
WATER7732-18-5Yes DSL EIN Yes Yes No Yes Yes Yes 
NITRIC ACID7697-37-2Yes DSL EIN Yes Yes Yes Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
NITRIC ACID (7697-37-2)

Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer

Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H314 Causes severe skin burns and eye damage

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
NITRIC ACID (7697-37-2)

Oxidizing Liquids Category 2 H272 May intensify fire, oxidizer

Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage

Supplemental Hazards EUH071 Corrosive to respiratory tract




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H314 Causes severe skin burns and eye damage

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
NITRIC ACID (7697-37-2)

Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer Approval: 597

Corrosive to Metals Category 1 H290 May be corrosive to metals Approval: H26-B-114 / R-054

Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled Approval: H26-B-114 / R-054

Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Approval: H26-B-114 / R-054

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 597

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 597

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system,teeth) Approval: 597

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: H26-B-112 / R-053




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H290 May be corrosive to metals

H330 Fatal if inhaled

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

Prevention

P234 Keep only in original container

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P370+P378 In case of fire: Use appropriate media for extinction

P390 Absorb spillage to prevent material-damage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
NITRIC ACID (7697-37-2)

MOE:Oxidizing liquids Category 1 H271 May cause fire or explosion, strong oxidizer.

Skin corrosion/irritation Category 1 H314 Causes severe skin burns and eye damage.
MOEL:Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer

Acute toxicity Inhalation - Dust and Mist Category 2 H330 Fatal if inhaled

Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure respiratory system,teeth

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
NEMA:Oxidizing Liquids Category 1 H271 May cause fire or explosion, strong oxidizer




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H271 May cause fire or explosion, strong oxidizer

H314 Causes severe skin burns and eye damage

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P283 Wear fire/flame resistant/retardant clothing

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H330 Fatal if inhaled

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H304 May be fatal if swallowed and enters airways

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P320 Specific treatment is urgent (see label)

P331 Do NOT induce vomiting

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H271 May cause fire or explosion, strong oxidizer

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P283 Wear fire/flame resistant/retardant clothing

Response

P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes

P370+P378 In case of fire: Use appropriate media for extinction

P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
FERRIC NITRATE (10421-48-4) Approval: HSR001325

Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

NITRIC ACID (7697-37-2) Approval: HSR000982

Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer (red fuming)

Corrosive to Metals Category 1 H290 May be corrosive to metals (red fuming)

Acute toxicity Inhalation Category 1 H330 Fatal if inhaled (red fuming)

Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage (red fuming)

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage (red fuming)

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (upper respiratory system,teeth) (red fuming)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (fish) (red fuming)




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
FERRIC NITRATE (10421-48-4)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H272 May intensify fire, oxidizer

H302 Harmful if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H290 May be corrosive to metals

H330 Fatal if inhaled

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

Prevention

P234 Keep only in original container

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P370+P378 In case of fire: Use appropriate media for extinction

P390 Absorb spillage to prevent material-damage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
NITRIC ACID (7697-37-2)

Listing: Present (>70% by mass)

Listing: Present (<=70% by mass)




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
FERRIC NITRATE (10421-48-4)

Taiwan:Oxidizing Solids Category 3 H272 May intensify fire, oxidizer
 Acute toxicity Oral Category 5 H303 May be harmful if swallowed
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation


NITRIC ACID (7697-37-2)

Taiwan:Oxidizing Liquids Category 1 H271 May cause fire or explosion, strong oxidizer
 Corrosive to Metals Category 1 H290 May be corrosive to metals
 Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage
 Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
 Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (lungs)




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
FERRIC NITRATE (10421-48-4)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H272 May intensify fire, oxidizer

H303 May be harmful if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

NITRIC ACID (7697-37-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H271 May cause fire or explosion, strong oxidizer

H290 May be corrosive to metals

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H373 May cause damage to organs through prolonged or repeated exposure

Prevention

P234 Keep only in original container

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

P283 Wear fire/flame resistant/retardant clothing

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion

P390 Absorb spillage to prevent material-damage

Storage

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved