Material Name: ZINC NITRATE SDS ID: ohs25460 Issue Date: 2016-06-23 Revision: 2.06 |
ZINC NITRATE
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inorganic, salt
ZINC DINITRATE; CELLOXAN; NITRIC ACID, ZINC SALT; ZINC(II) NITRATE; ZINC NITRATE, ANHYDROUS; UN 1514; N206Zn
Emergency Overview
Color: colorless to white
Change in color: hygroscopic
Physical Form: crystals
Odor: odorless
Health Hazards: respiratory tract irritation, skin irritation, eye irritation
Physical Hazards: May ignite combustibles.
Short Term: irritation, difficulty breathing
Long Term: no information is available
Short Term: irritation (possibly severe)
Long Term: same as effects reported in short term exposure
Short Term: irritation, blurred vision
Long Term: same as effects reported in short term exposure
Short Term: sore throat, metallic taste, nausea, vomiting, diarrhea
Long Term: digestive disorders, bluish skin color
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
7779-88-6 231-943-8 -- | ZINC NITRATE | -- | 100.0 |
This product may be regulated, have exposure limits or other information identified as the following: Zinc compounds.
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention.
For ingestion, consider gastric lavage.
calcium disodium edetate/dextrose, intravenous; calcium disodium edetate/procaine, intramuscular.
See Section 9 for Flammability Properties
Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials.
water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance.
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn.
Dig holding area such as lagoon, pond or pit for containment. Cover with plastic sheet or tarp to minimize spreading and protect from contact with water.
Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda ash).
Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Keep separated from incompatible substances.
Component Exposure Limits
Biological limit value
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Appearance | Not available | Physical State | Solid |
Odor | odorless | Color | colorless to white |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | Not available |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | Not available |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
Water Solubility | (soluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Change in color | hygroscopic | Density | Not available |
Physical Form | crystals | Taste | sour taste |
Molecular Formula | ZN-(N-O3)2 | Molecular Weight | 189.39 |
Stable at normal temperatures and pressure.
Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers.
combustible materials, cyanides, metals, reducing agents, metal salts, acids,
ZINC NITRATE: CARBON: When sprinkled on hot carbon, explodes. COMBUSTIBLE MATERIALS: May ignite readily on contact and burn fiercely; finely divided materials may react explosively. CYANIDES: Possible violent reaction. METALS (POWDER): Possible explosion hazard. ORGANIC MATERIALS: May ignite and burn readily on contact. PHOSPHOROUS: Possible explosion hazard. REDUCING MATERIALS: Violent reaction. SODIUM HYPOPHOSPHITE: Incompatible. STANNOUS CHLORIDE: Possible explosion hazard. THIOCYANATES: Possible violent reaction. METAL NITRATES: ALUMINUM + WATER: Metal nitrates may explode. CITRIC ACID: Possible explosion hazard. ESTERS: Possible explosion hazard. PHOSPHINATES: May explode when heated. PHOSPHOROUS: Possible explosive reaction. POTASSIUM HEXANITROCOBALTATE(3-): May explode violently. REDUCTANTS: Possible explosion hazard. TIN(II) CHLORIDE: Possible explosive hazard.
oxides of nitrogen, zinc
Thermal decomposition products: oxides of nitrogen, zinc.
Will not polymerize.
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
ZINC NITRATE Inhalation of dust may cause irritation of the nose and throat, coughing, labored breathing, and possibly lung edema.
ZINC NITRATE No data available.
ZINC NITRATE: Contact may cause irritation with redness, pain, and possibly skin burns Application of 500 mg of the hexahydrate to the skin of rabbits for 24 hours resulted in severe irritation Skin absorption may occur.
ZINC NITRATE Repeated and prolonged exposure to zinc salts may cause dermatitis or granuloma.
ZINC NITRATE: Contact may cause possibly delayed irritation with redness, tears, pain and blurred vision Application of 20 mg of the hexahydrate to the eyes of rabbits for 24 hours resulted in moderate irritation.
ZINC NITRATE Repeated and prolonged exposure to irritants may cause conjunctivitis.
ZINC NITRATE: Ingestion may cause sore throat, metallic taste, gastric irritation and pain, faintness, nausea, vomiting, cramps and bluish lips and skin Zinc salts may cause substernal pain and fever Ingestion of solutions of zinc salts may also cause diarrhea, shock, collapse and possibly death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach Rarely, inorganic nitrates may be converted to nitrites by nitrate-reducing bacteria in the upper digestive tract, resulting in methemoglobinemia.
ZINC NITRATE: Repeated oral administration of small doses of zinc salts may cause digestive disorders and constipation Repeated and prolonged exposure to nitrates may cause anemia, nephritis, and possibly methemoglobinemia.
Component Analysis - Aquatic Toxicity
ZINC NITRATE | 7779-88-6 |
Fish: | LC50 96 h Cyprinus carpio 7.8 mg/L [static] |
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
ADR Tunnel Code Restrictions
Component Marine Pollutants (IMDG)
ZINC NITRATE | 7779-88-6 |
SARA 313: | 1 % de minimis concentration (related to Zinc compounds) |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Component | CAS | CA | MA | MN | NJ | PA |
ZINC NITRATE | 7779-88-6 | Yes | Yes | No | Yes | Yes |
Not listed under California Proposition 65
Germany Water Classification
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
ZINC NITRATE | 7779-88-6 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
European Union GHS Classifications
Indonesia GHS Classifications
Japan GHS Classifications
Japan GHS Labeling Information
Korea GHS Classifications
New Zealand GHS Classifications
New Zealand GHS Labeling Information
South Africa GHS Classifications
Taiwan GHS Classifications
Taiwan: | Oxidizing Solids Category 2 H272 May intensify fire, oxidizer |
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation | |
Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation | |
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
Taiwan GHS Labeling Information
No classification assigned.
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
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