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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

ZINC AMMONIUM NITRITE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

inorganic, salt 


Synonyms 

UN 1512; STCC 4918756









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: powder

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation 

Physical Hazards:  May ignite combustibles. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, nausea, vomiting, difficulty breathing, headache 

Long Term:  no information is available 




Skin Contact 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 




Eye Contact 

Short Term:  irritation, blurred vision 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  burns, sore throat, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, headache, dizziness, bluish skin color 

Long Term:  same as effects reported in short term exposure 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
63885-01-8 -- --ZINC AMMONIUM NITRITE--100




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Zinc compounds.









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 


Note to Physicians 

For ingestion, consider gastric lavage. 


Antidote 

methylene blue, intravenous; ascorbic acid, intravenous. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 


Extinguishing Media 

water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor Not available Color white
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility (soluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form powder
Molecular Formula ZN-N-H4-(N-O2)3Molecular Weight 221.5











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers. 


Incompatible Materials 

combustible materials, cyanides, 


ZINC AMMONIUM NITRITE: AMMONIUM SALTS: Violent explosion when melted together. COMBUSTIBLE MATERIALS: Fire hazard if contamination occurs. CYANIDE SALTS: Violent explosion when melted together. ORGANIC MATERIALS: Fire hazard if contamination occurs.

Hazardous Decomposition Products 

oxides of zinc, oxides of nitrogen 


Thermal decomposition products: zinc oxide, oxides of nitrogen.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

ZINC AMMONIUM NITRITE Sore throat, coughing, dyspnea, flushing of the skin, headache, nausea and vomiting.


Inhalation - Chronic Exposure 

ZINC AMMONIUM NITRITE No data available.


Skin Contact - Acute Exposure 

ZINC AMMONIUM NITRITE Direct contact may cause redness, pain and burns.


Skin Contact - Chronic Exposure 

ZINC AMMONIUM NITRITE Repeated or prolonged exposure may cause dermatitis.


Eye Contact - Acute Exposure 

ZINC AMMONIUM NITRITE Direct contact may cause redness, pain, and blurred vision.


Eye Contact - Chronic Exposure 

ZINC AMMONIUM NITRITE Repeated or prolonged contact with dust may cause conjunctivitis.


Ingestion - Acute Exposure 

ZINC AMMONIUM NITRITE: May cause sore throat, abdominal pain, nausea and faintness There is no information on this compound, however, some nitrates can cause methemoglobinemia with symptoms of cyanosis, headache, weakness, dizziness, and dyspnea Some soluble zinc salts are corrosive and emetic and may cause gastroenteric irritation, nausea, vomiting, diarrhea and gastroenteric pain.


Ingestion - Chronic Exposure 

ZINC AMMONIUM NITRITE: Repeated exposure may cause disordered digestion and constipation Some nitrates can cause weakness, general depression, headache and mental impairment.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN/NA #: UN1512

Packing Group: II

Required Label(s): 5.1




TDG Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Packing Group: II

Required Label(s): 5.1




ADR Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Packing Group: II

Required Label(s): 5.1

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
ZINC AMMONIUM NITRITE (63885-01-8)

Restriction(s): E [UN1512] (II)








RID Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Packing Group: II

Required Label(s): 5.1




IATA Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Packing Group: II

Required Label(s): 5.1




ICAO Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Packing Group: II

Required Label(s): 5.1




IMDG Information:

Shipping Name: ZINC AMMONIUM NITRITE

Hazard Class: 5.1

UN#: UN1512

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
ZINC AMMONIUM NITRITE63885-01-8
SARA 313: 1 % de minimis concentration (related to Zinc compounds)




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
ZINC AMMONIUM NITRITE63885-01-8Yes No No Yes Yes 




Not listed under California Proposition 65 




Symbol(s)

O Oxidizing

Xi Irritant

Risk Phrases

R8 Contact with combustible material may cause fire.

R36 Irritating to eyes.

R37 Irritating to respiratory system.

R38 Irritating to skin.

Safety Phrases

S2 Keep out of the reach of children.

S24 Avoid contact with skin.

S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S46 If swallowed, seek medical advice immediately and show this container or label.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
ZINC AMMONIUM NITRITE63885-01-8No No No No Yes No No No No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC AMMONIUM NITRITE (63885-01-8)

Taiwan:Oxidizing Solids Category 2 H272 May intensify fire, oxidizer
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC AMMONIUM NITRITE (63885-01-8)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved