Material Name: TRIETHOXYVINYLSILANE SDS ID: ohs62020 Issue Date: 2016-06-23 Revision: 2.07 |
TRIETHOXYVINYLSILANE
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
silanes
ETHENYLTRIETHOXYSILANE; TRI(ETHOXO)(VINYL)SILANE; VINYLTRIETHOXYSILANE; C8H18O3Si; RTECS: VV6700000
Emergency Overview
Color: pale
Change in color: Not available
Physical Form: liquid
Odor: distinct odor
Health Hazards: eye irritation
Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire. May polymerize. Containers may rupture or explode. May react on contact with water.
Short Term: irritation, chest pain, dizziness, tremors, loss of coordination, lung congestion, lung damage
Long Term: no information is available
Short Term: irritation, bluish skin color
Long Term: irritation
Short Term: irritation (possibly severe), eye damage
Long Term: irritation
Short Term: nausea, vomiting, diarrhea, headache, drowsiness, dizziness, loss of coordination, coma
Long Term: no information is available
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
78-08-0 201-081-7 -- | TRIETHOXYVINYLSILANE | -- | 100 |
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If a large amount is swallowed, get medical attention.
See Section 9 for Flammability Properties
The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. Severe fire hazard.
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray.
Move container from fire area if it can be done without risk. Dike for later disposal. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
ethanol
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Avoid contact with water or moisture. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances.
Component Exposure Limits
Biological limit value
Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
rubber, neoprene, nitrile
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Appearance | clear | Physical State | Liquid |
Odor | distinct odor | Color | pale |
Odor Threshold | Not available | pH | Not available |
Melting Point | <0 °C | Boiling Point | 160 - 161 °C |
Freezing point | Not available | Evaporation Rate | <1 (butyl acetate=1) |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | 268 °C | Flash Point | 93.2 °C CC |
Lower Explosive Limit | 0.53 % | Decomposition | Not available |
Upper Explosive Limit | 15 % | Vapor Pressure | 5 mmHg at 20 °C (approximate) |
Vapor Density (air=1) | 7.5 (approximate) | Specific Gravity (water=1) | 0.894 - 0.903 |
Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Volatility | 100 % | Molecular Formula | H2-C-C-H-Si-(O-C2-H5)3 |
Molecular Weight | 190.31 | OSHA Flammability Class | II |
May polymerize. Avoid contact with temperatures above 100 C. May react on contact with water. Releases flammable gases.
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. Avoid contact with water or moisture.
acids, bases, metals, halogens, oxidizing materials, peroxides, reducing agents,
TRIETHOXYVINYLSILANE: ACIDS: Incompatible. BASES: Incompatible. CATALYTIC METALS: May polymerize. HALOGENS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXIDES: May polymerize. REDUCING AGENTS: Incompatible.
oxides of carbon, oxides of silicon, organic acids
ethanol
Thermal decomposition products: oxides of carbon, silicon.
May polymerize. Avoid contact with temperatures above 100 C.
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
TRIETHOXYVINYLSILANE: May cause irritation, dizziness, incoordination, tremors and a burning sensation in the chest May produce delayed pulmonary edema May form a siloxane polymer on the lung Overexposure may cause lung damage.
TRIETHOXYVINYLSILANE No data available.
TRIETHOXYVINYLSILANE: May cause irritation and cyanosis of the extremities May form a siloxane polymer on the skin.
TRIETHOXYVINYLSILANE Prolonged or repeated skin contact may cause dermatitis.
TRIETHOXYVINYLSILANE: May cause severe irritation, conjunctivitis and corneal damage May form a siloxane polymer on the eye.
TRIETHOXYVINYLSILANE Repeated or prolonged exposure to irritants may cause conjunctivitis.
TRIETHOXYVINYLSILANE May cause dizziness, faintness, drowsiness, decreased awareness, euphoria, abdominal discomfort, nausea, vomiting, diarrhea, headache, staggering gait, lack of coordination, and coma.
TRIETHOXYVINYLSILANE No data available.
Component Analysis - Aquatic Toxicity
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
Component Marine Pollutants (IMDG)
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Not listed under California Proposition 65
Germany Water Classification
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
TRIETHOXYVINYLSILANE | 78-08-0 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
European Union GHS Classifications
Indonesia GHS Classifications
Japan GHS Classifications
Korea GHS Classifications
New Zealand GHS Classifications
New Zealand GHS Labeling Information
South Africa GHS Classifications
Taiwan GHS Classifications
No classification assigned.
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
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