* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
TEFLON DRY LUBE (NON-CHLORINATED)
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Change in color: Not available
Physical Form: liquid
Odor: distinct odor
Health Hazards: respiratory tract irritation, skin irritation, aspiration hazard, central nervous system depression, difficulty breathing, nerve damage, kidney damage, birth defects, suspect cancer hazard (in animals)
Physical Hazards: Containers may rupture or explode if exposed to heat.
Potential Health Effects
Inhalation
Short Term: irritation, nausea, vomiting, diarrhea, constipation, stomach pain, chest pain, difficulty breathing, irregular heartbeat, headache, drowsiness, fatigue, dizziness, disorientation, sleep disturbances, emotional disturbances, mood swings, tingling sensation, muscle cramps, loss of coordination, visual disturbances, suffocation, kidney damage, liver damage, paralysis, brain damage, convulsions, unconsciousness, coma
Long Term: same as effects reported in short term exposure, irritation, changes in blood pressure, nausea, vomiting, loss of appetite, weight loss, irregular heartbeat, headache, drowsiness, dizziness, disorientation, mood swings, joint pain, loss of coordination, eye damage, hormonal disorders, suffocation, blood disorders, nerve damage, reproductive effects, birth defects, convulsions, unconsciousness, coma
Skin Contact
Short Term: irritation, blisters
Long Term: irritation
Eye Contact
Short Term: irritation, blurred vision
Long Term: irritation
Ingestion
Short Term: ingestion of a gas is unlikely, same as effects reported in short term inhalation, headache, drowsiness, dizziness, loss of coordination, aspiration hazard
Long Term: ingestion of a gas is unlikely, same as effects reported in long term inhalation
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
15748-73-9 239-839-4 -- | LEAD SALICYLATE | Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332 Repr. 1A - H360Df STOT RE 2 - H373 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Note(s): A, 1 | 70 - 80 |
74-98-6 200-827-9 -- | PROPANE | Flam. Gas 1 - H220 Gases under press. - H280 Note(s): U | <30 |
75-28-5 200-857-2 -- | ISOBUTANE | Flam. Gas 1 - H220 Gases under press. - H280 Note(s): C, U | <30 |
106-97-8 203-448-7 -- | N-BUTANE | Flam. Gas 1 - H220 Gases under press. - H280 Note(s): C, U | <30 |
110-82-7 203-806-2 -- | CYCLOHEXANE | Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 STOT SE 3 - H336 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 | 2.9 - 3.2 |
108-88-3 203-625-9 -- | TOLUENE | Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 Repr. 2 - H361d STOT SE 3 - H336 STOT RE 2 - H373 Asp. Tox. 1 - H304 | <1 |
Not Available -- -- | NON-HAZARDOUS SUBSTANCE | -- | <1 |
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Lead compounds, Lead compounds, organic, Aliphatic hydrocarbon gases (Alkane [C1-C4]).
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Get medical attention.
Skin
If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention.
Eyes
Flush eyes with plenty of water.
Ingestion
If a large amount is swallowed, get medical attention.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 2 Fire: 4 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Severe fire hazard. Containers may rupture or explode if exposed to heat.
Extinguishing Media
carbon dioxide, regular dry chemical
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Small spills of the liquid component: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Spills with a large number of canisters: Reduce vapors with water spray. Remove sources of ignition. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. See original container for storage recommendations. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Exposure Guidelines
If an employee is exposed to lead for more than 8 hours in any work day, the permissible exposure limit, as a time weighted average (TWA) for that day, shall be reduced according to the following formula: Maximum permissible limit (in ug/m3) = 400 divided by hours worked in the day.
Component Exposure Limits
LEAD SALICYLATE | 15748-73-9 |
NIOSH: | 0.05 mg/m3 TWA as Pb (related to Lead compounds) |
| 100 mg/m3 IDLH as Pb (related to Lead compounds) |
PROPANE | 74-98-6 |
ACGIH: | (See Appendix F: Minimal Oxygen Content) |
NIOSH: | 1000 ppm TWA; 1800 mg/m3 TWA |
| 2100 ppm IDLH (10% LEL) |
OSHA (US): | 1000 ppm TWA; 1800 mg/m3 TWA |
ISOBUTANE | 75-28-5 |
ACGIH: | 1000 ppm STEL |
NIOSH: | 800 ppm TWA; 1900 mg/m3 TWA |
N-BUTANE | 106-97-8 |
ACGIH: | 1000 ppm STEL |
NIOSH: | 800 ppm TWA; 1900 mg/m3 TWA |
Mexico: | 800 ppm TWA VLE-PPT; 1900 mg/m3 TWA VLE-PPT |
CYCLOHEXANE | 110-82-7 |
ACGIH: | 100 ppm TWA |
NIOSH: | 300 ppm TWA; 1050 mg/m3 TWA |
| 1300 ppm IDLH (10% LEL) |
Europe: | 200 ppm TWA; 700 mg/m3 TWA |
OSHA (US): | 300 ppm TWA; 1050 mg/m3 TWA |
Mexico: | 300 ppm TWA VLE-PPT; 1050 mg/m3 TWA VLE-PPT |
| 375 ppm STEL [PPT-CT]; 1300 mg/m3 STEL [PPT-CT] |
TOLUENE | 108-88-3 |
ACGIH: | 20 ppm TWA |
NIOSH: | 100 ppm TWA; 375 mg/m3 TWA |
| 150 ppm STEL; 560 mg/m3 STEL |
| 500 ppm IDLH |
Europe: | 50 ppm TWA; 192 mg/m3 TWA |
| Possibility of significant uptake through the skin |
| 100 ppm STEL; 384 mg/m3 STEL |
OSHA (US): | 200 ppm TWA |
| 300 ppm Ceiling |
Mexico: | 50 ppm TWA VLE-PPT; 188 mg/m3 TWA VLE-PPT |
| Skin - potential for cutaneous absorption |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing.
Glove Recommendations
Wear insulated gloves.
Respiratory Protection
No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | clear | Physical State | Aerosol |
Odor | distinct odor | Color | Not available |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | -40 - 100 °C |
Freezing point | Not available | Evaporation Rate | >1 (butyl acetate=1) |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | -40 °C TOC |
Lower Explosive Limit | 1.8 % | Decomposition | Not available |
Upper Explosive Limit | 12 % | Vapor Pressure | Not available |
Vapor Density (air=1) | 4 | Specific Gravity (water=1) | 0.7 |
Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat.
Incompatible Materials
oxidizing materials
Hazardous Decomposition Products
oxides of carbon, miscellaneous decomposition products
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
PROPANE (74-98-6)
Inhalation LC50 Rat 658 mg/L 4 h
ISOBUTANE (75-28-5)
Inhalation LC50 Rat 658 mg/L 4 h
N-BUTANE (106-97-8)
Inhalation LC50 Rat 658 g/m3 4 h
CYCLOHEXANE (110-82-7)
Oral LD50 Rat 12705 mg/kg
Dermal LD50 Rabbit >2000 mg/kg
Inhalation LC50 Rat 13.9 mg/L 4 h
TOLUENE (108-88-3)
Oral LD50 Rat 2600 mg/kg
Dermal LD50 Rabbit 12000 mg/kg
Inhalation LC50 Rat 12.5 mg/L 4 h
Component Carcinogenicity
LEAD SALICYLATE | 15748-73-9 |
IARC: | Monograph 87 [2006] (ionic lead generated from organic lead that is present in the body will be expected to exert the toxicities associated with inorganic lead which is classified as Group 2A); Supplement 7 [1987] (related to Lead compounds, organic) (Group 3 (not classifiable)) |
NTP: | Reasonably Anticipated To Be A Human Carcinogen (related to Lead compounds) |
OSHA: | Present (related to Lead compounds) |
TOLUENE | 108-88-3 |
ACGIH: | A4 - Not Classifiable as a Human Carcinogen |
IARC: | Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable)) |
Renal tumors were produced in animals by lead acetate, lead subacetate, and lead phosphate given orally, subcutaneously, or intraperitoneally No evaluation could be made of the carcinogenicity of powdered lead.
Medical Conditions Aggravated by Exposure
kidney disorders, blood system disorders, liver disorders, gastrointestinal disorders, respiratory disorders, nervous system disorders, skin disorders and allergies, respiratory disorders, heart or respiratory disorders,
Additional Data
Stimulants such as epinephrine may induce ventricular fibrillation Stimulants such as epinephrine may induce ventricular fibrillation Alcohol may enhance the toxic effects Stimulants such as epinephrine may induce ventricular fibrillation Smoking may result in higher blood lead levels.
May potentiate the effects of toxic agents, such as tri-o-cresyl phosphate.
Inhalation - Acute Exposure
CYCLOHEXANE: Low concentrations may cause irritation of the respiratory tract Exposure to concentrations above 12,000 ppm may cause central nervous system depression with excitement, headache, dizziness, dullness, nausea, vomiting, narcosis, coma, and possibly death due to respiratory failure Lethal concentrations to animals caused convulsions and generalized vascular damage with severe degenerative changes in the heart, lungs, liver, kidneys, and brain ISOBUTANE: Vapors may be irritating to the mucous membranes Humans exposed to 250-1000 ppm for 1 minute to 8 hours did not exhibit any adverse effects Higher concentrations may cause central nervous system depression and asphyxiation Symptoms may include dizziness, difficulty in breathing, loss of consciousness, muscular incoordination, headache, weakness, emotional instability, nausea, vomiting, prostration, convulsions, coma, and death Animals exposed to near lethal levels exhibited central nervous system depression, rapid and shallow respiration, and apnea Cardiac sensitization has been reported in animals LEAD COMPOUNDS: Absorption of large amounts of lead may cause a metallic taste, thirst, a burning sensation in the mouth and throat, salivation, abdominal pain with severe colic, vomiting, diarrhea of black or bloody stools, constipation, fatigue, sleep disturbances, dullness, restlessness, irritability, memory loss, loss of concentration, delirium, oliguria often with hematuria and albuminuria, encephalopathy with visual failure, paresthesias, muscle pain and weakness, convulsions, and paralysis Death may result from cardiorespiratory arrest or shock Survivors of acute exposure may experience the onset of chronic intoxication Liver effects may include enlargement and tenderness, and jaundice The fatal dose of absorbed lead is approximately 0.5 grams Pathological findings include gastrointestinal inflammation and renal tubular degeneration LPG: Vapors may cause narcosis with headache, dullness, difficulty breathing, lightheadedness, drowsiness, unconsciousness and possibly death Concentrations for 10 minutes may cause dizziness Very high concentrations may cause asphyxiation with rapid respiration, dyspnea, reduced mental alertness and muscle coordination, nausea, vomiting, prostration, unconsciousness, convulsions, coma and death PROPANE: Brief exposure to 10,000 ppm caused no symptoms in human subjects; 100,000 ppm produced slight dizziness in a few minutes but was not noticeably irritating to the nose or respiratory tract High levels may produce disorientation, excitation, excessive salivation, headache and vomiting In primates, 100,000 ppm produced some myocardial effects and at 200,000 ppm aggravation of these parameters and respiratory depression Concentrations of 100,000 ppm in mice and 150,000 ppm in dogs appear to produce no arrhythmia but weak cardiac sensitization Concentrations of 75% may produce nausea, vomiting, prostration, unconsciousness, convulsions, deep coma and death SIMPLE ASPHYXIANTS: The symptoms of asphyxia depend on the rapidity with which the oxygen deficiency develops and how long it continues In sudden acute asphyxia, unconsciousness may be immediate With slow development there may be rapid respiration and pulse, air hunger, dizziness, reduced awareness, tightness in the head, tingling sensations, incoordination, faulty judgement, emotional instability, and rapid fatigue As the asphyxia progresses, nausea, vomiting, collapse, unconsciousness, convulsions, deep coma and death are possible.
Inhalation - Chronic Exposure
ISOBUTANE: No adverse effects have been reported from human exposure to 500 ppm for 1-8 hours/day for 10 days LEAD COMPOUNDS: Prolonged or repeated exposure to low levels of lead may result in an accumulation in body tissues and exert adverse effects on the blood, nervous systems, heart, endocrine and immune systems, kidneys, and reproduction Early stages of lead poisoning, "plumbism", may be evidenced by anorexia, weight loss, constipation, apathy or irritability, occasional vomiting, fatigue, headache, weakness, metallic taste in the mouth, gingival lead line in persons with poor dental hygiene, and anemia Loss of recently developed motor skills is generally observed only in children More advanced stages of poisoning may be characterized by intermittent vomiting, irritability and nervousness, myalgia of the arms, legs, joints and abdomen, paralysis of the extensor muscles of the arms and legs with wrist and/or foot drop Severe "plumbism" may result in persistent vomiting, ataxia, periods of stupor or lethargy, encephalopathy with visual disturbances which may progress to optic neuritis and atrophy, hypertension, papilledema, cranial nerve paralysis, delirium, convulsions, and coma Neurologic sequelae may include mental retardation, seizures, cerebral palsy, and dystonia musculorum deformans Irreversible kidney damage has been associated with industrial exposure Reproductive effects have been exhibited in both males and females Paternal effects may include decreased sex drive, impotence, sterility and adverse effects on the sperm which may increase the risk of birth defects Maternal effects may include miscarriage and stillbirths in exposed women or women whose husbands were exposed, abortion, sterility or decreased fertility, and abnormal menstrual cycles Lead crosses the placenta and may affect the fetus causing birth defects, mental retardation, behavioral disorders, and death during the first year of childhood Animal studies indicate that reproductive effects may be additive if both parents are exposed to lead LPG: No data available PROPANE: Repeated contact may result in symptoms as described in acute exposure CYCLOHEXANE: Repeated or prolonged exposure to concentrations above 300 ppm may produce mild irritation of the upper respiratory tract Repeated exposures caused microscopic changes in the liver and kidneys, lethargy, light narcosis, diarrhea, and some deaths in animals Developmental toxicity studies in rats at 7000 ppm produced significantly decreased maternal body weight and food consumption and diminished response or no response to sound stimulus In the same studies, there was no evidence of developmental toxicity in any test concentrations (500, 2000 or 7000 ppm) In another study, no evidence of maternal or developmental toxicity was found in rabbits (500, 2000, or 7000 ppm) SIMPLE ASPHYXIANTS: No data available.
Inhalation - Other Toxicity Information
LEAD SALICYLATE: See information on lead compounds N-BUTANE: A 1% concentration for 10 minutes may cause drowsiness Higher concentrations may cause respiratory tract irritation, headache, dullness, shortness of breath, muscular weakness and paralysis, unconsciousness, and death Butane is a weak cardiac sensitizer in the dog Unless an odorant is added, the lack of warning properties may make overexposure more likely See information on LPG and simple asphyxiants.
Skin Contact - Acute Exposure
LEAD COMPOUNDS: Contact with lead powders or dust may be irritating PROPANE: No adverse effects have been reported from the gas Due to rapid evaporation, the liquid may cause frostbite with redness, tingling and pain or numbness In more severe cases, the skin may become hard and white and develop blisters N-BUTANE: No adverse effects have been reported from the gas Due to rapid evaporation, the liquid may cause frostbite with redness, tingling and pain or numbness In more severe cases, the skin may become hard and white and develop blisters ISOBUTANE: No adverse effects have been reported from the gas Due to rapid evaporation, the liquid may cause frostbite with redness, tingling and pain or numbness In more severe cases, the skin may become hard and white and develop blisters CYCLOHEXANE: May cause irritation with redness and dryness Massive applications to rabbit skin have produced microscopic changes in the liver and kidneys.
Skin Contact - Chronic Exposure
N-BUTANE: No effects have been reported ISOBUTANE: No data available CYCLOHEXANE: Repeated or prolonged contact with the liquid may cause irritation, defatting of the skin, and a dry, scaly, fissured dermatitis PROPANE: No data available LEAD COMPOUNDS: Prolonged or repeated exposure to the powder or dust may result in dermatitis.
Skin Contact - Other Toxicity Information
LEAD SALICYLATE See information on lead compounds.
Eye Contact - Acute Exposure
CYCLOHEXANE: Contact with liquid or high vapor concentrations may cause irritation with tearing and redness, and a mild conjunctivitis ISOBUTANE: No adverse effects have been reported from the gas Due to rapid evaporation, the liquid may cause frostbite with redness, pain and blurred vision LEAD COMPOUNDS: Lead dust or powders may be irritating Metallic lead particles may cause an inflammatory foreign body reaction Injury is generally thought to be mechanical and not toxic N-BUTANE: No adverse effects have been reported from the gas Due to rapid evaporation, the liquid may cause frostbite with redness, pain and blurred vision PROPANE: Vapor concentrations of 100,000 ppm were not noticeably irritating to the eyes Due to rapid evaporation, the liquid may cause frostbite with redness, pain and blurred vision.
Eye Contact - Chronic Exposure
PROPANE: No data available N-BUTANE: No data available LEAD COMPOUNDS: Prolonged exposure may cause conjunctivitis ISOBUTANE: No data available CYCLOHEXANE: Repeated or prolonged exposure to irritants may cause conjunctivitis.
Eye - Other Toxicity Information
LEAD SALICYLATE See information on lead compounds.
Ingestion - Acute Exposure
CYCLOHEXANE: Lung damage may occur if aspirated into the lungs and may be fatal Symptoms may include coughing, difficulty breathing, cyanosis, and pulmonary edema May cause symptoms of central nervous system depression as detailed in acute inhalation ISOBUTANE: Ingestion of a gas is unlikely If the liquid is swallowed, frostbite damage of the lips, mouth and mucous membranes may occur PROPANE: Ingestion of a gas is unlikely If the liquid is swallowed, frostbite damage of the lips, mouth and mucous membranes may occur N-BUTANE: Ingestion of a gas is unlikely If liquid is swallowed, frostbite damage to the lips, mouth and mucous membranes may occur LEAD COMPOUNDS: Absorption of large amounts of lead from the intestinal tract may cause effects as detailed in acute inhalation The fatal dose of absorbed lead is approximately 0.5 grams.
Ingestion - Chronic Exposure
PROPANE: Ingestion of a gas is unlikely N-BUTANE: Ingestion of a gas is unlikely LEAD COMPOUNDS: Prolonged or repeated exposure to low levels of lead may result in an accumulation in body tissues and adverse effects on the kidneys, heart and blood and on the nervous, reproductive, endocrine and immune systems as detailed in chronic inhalation ISOBUTANE: Ingestion of a gas is unlikely CYCLOHEXANE: No data available.
Ingestion - Other Toxicity Information
LEAD SALICYLATE See information on lead compounds.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
CYCLOHEXANE | 110-82-7 |
Fish: | LC50 96 h Pimephales promelas 3.96 - 5.18 mg/L [flow-through]; LC50 96 h Pimephales promelas 23.03 - 42.07 mg/L [static]; LC50 96 h Lepomis macrochirus 24.99 - 44.69 mg/L [static]; LC50 96 h Poecilia reticulata 48.87 - 68.76 mg/L [static] |
Algae: | EC50 72 h Desmodesmus subspicatus >500 mg/L IUCLID |
TOLUENE | 108-88-3 |
Fish: | LC50 96 h Pimephales promelas 15.22 - 19.05 mg/L [flow-through] (1 day old); LC50 96 h Pimephales promelas 12.6 mg/L [static]; LC50 96 h Oncorhynchus mykiss 5.89 - 7.81 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 14.1 - 17.16 mg/L [static]; LC50 96 h Oncorhynchus mykiss 5.8 mg/L [semi-static]; LC50 96 h Lepomis macrochirus 11 - 15 mg/L [static]; LC50 96 h Oryzias latipes 54 mg/L [static]; LC50 96 h Poecilia reticulata 28.2 mg/L [semi-static]; LC50 96 h Poecilia reticulata 50.87 - 70.34 mg/L [static] |
Algae: | EC50 96 h Pseudokirchneriella subcapitata >433 mg/L IUCLID; EC50 72 h Pseudokirchneriella subcapitata 12.5 mg/L [static] EPA |
Invertebrate: | EC50 48 h Daphnia magna 5.46 - 9.83 mg/L [Static] EPA; EC50 48 h Daphnia magna 11.5 mg/L IUCLID |
Bioconcentration Factor
ISOBUTANE | 75-28-5 |
BCF | 1.57 - 1.97 |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
CYCLOHEXANE | 110-82-7 |
RCRA: | waste number U056 (Ignitable waste) |
TOLUENE | 108-88-3 |
RCRA: | waste number U220 |
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
TDG Information:
No Classification assigned.
ADR Information:
No Classification assigned.
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
PROPANE (74-98-6)
Restriction(s): B/D [UN1978]
ISOBUTANE (75-28-5)
Restriction(s): B/D [UN1969]
N-BUTANE (106-97-8)
Restriction(s): B/D [UN1011]
CYCLOHEXANE (110-82-7)
Restriction(s): D/E [UN1145] (II)
TOLUENE (108-88-3)
Restriction(s): D/E [UN1294] (II)
RID Information:
No Classification assigned.
IATA Information:
No Classification assigned.
ICAO Information:
No Classification assigned.
IMDG Information:
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
LEAD SALICYLATE | 15748-73-9 |
SARA 313: | 1 % Supplier notification limit (related to Lead compounds, organic) |
CYCLOHEXANE | 110-82-7 |
SARA 313: | 1 % de minimis concentration |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
TOLUENE | 108-88-3 |
SARA 313: | 1 % de minimis concentration |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: Yes Pressure: Yes Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
LEAD SALICYLATE | 15748-73-9 | Yes | No | No | Yes | Yes |
PROPANE | 74-98-6 | No | Yes | Yes | Yes | Yes |
ISOBUTANE | 75-28-5 | No | Yes | No | Yes | Yes |
N-BUTANE | 106-97-8 | Yes | Yes | Yes | Yes | Yes |
CYCLOHEXANE | 110-82-7 | Yes | Yes | Yes | Yes | Yes |
TOLUENE | 108-88-3 | Yes | Yes | Yes | Yes | Yes |
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects
Component Analysis
LEAD SALICYLATE | 15748-73-9 |
Carc: | carcinogen , 10/1/1992 (related to Lead compounds) |
TOLUENE | 108-88-3 |
Repro/Dev. Tox | developmental toxicity , 1/1/1991 |
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
N-BUTANE | 106-97-8 |
| 1 % |
CYCLOHEXANE | 110-82-7 |
| 1 % |
TOLUENE | 108-88-3 |
| 1 % |
Germany Water Classification
PROPANE (74-98-6)
ID Number 560 , not considered hazardous to water
ISOBUTANE (75-28-5)
ID Number 562 , not considered hazardous to water (ratio 1,3-butadiene <0.1%)
N-BUTANE (106-97-8)
ID Number 561 , not considered hazardous to water (1,3-Butadiene <0.1%)
CYCLOHEXANE (110-82-7)
ID Number 63 , hazard class 2 - hazard to waters
TOLUENE (108-88-3)
ID Number 194 , hazard class 2 - hazard to waters
REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006
This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
LEAD SALICYLATE (15748-73-9)
Use restricted. See item 30. (except those specified elsewhere in Annex XVII to Regulation 1907/2006) (related to Lead compounds)
ISOBUTANE (75-28-5)
Use restricted. See item 28. (containing >=0.1% Butadiene); Use restricted. See item 29. (containing >=0.1% Butadiene)
N-BUTANE (106-97-8)
Use restricted. See item 28. (containing >=0.1% Butadiene); Use restricted. See item 29. (containing >=0.1% Butadiene)
CYCLOHEXANE (110-82-7)
Use restricted. See item 57. (Conditions of restrictions 27 June 2010)
TOLUENE (108-88-3)
Use restricted. See item 48.
REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006
This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process
TOLUENE (108-88-3)
Assigned to Member State Finland (Initial Grounds for Concern: Human health/CMR and systemic toxicity, Exposure/Wide dispersive use, consumer use, high aggregated tonnage)
Symbol(s)
F Highly Flammable
T Toxic
N Dangerous for the Environment
Risk Phrases
R11 Highly flammable.
R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R62 Possible risk of impaired fertility.
R61 May cause harm to the unborn child.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
LEAD SALICYLATE | 15748-73-9 | Yes | DSL | EIN | Yes | Yes | Yes | No | Yes | Yes |
PROPANE | 74-98-6 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
ISOBUTANE | 75-28-5 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
N-BUTANE | 106-97-8 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
CYCLOHEXANE | 110-82-7 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
TOLUENE | 108-88-3 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
LEAD SALICYLATE (15748-73-9)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
PROPANE (74-98-6)
Flammable Gases Category 1 H220 Extremely flammable gas
Gases Under Pressure H280 Contains gas under pressure, may explode when heated
ISOBUTANE (75-28-5)
Flammable Gases Category 1 H220 Extremely flammable gas (containing >=0.1% Butadiene)
Gases Under Pressure H280 Contains gas under pressure, may explode when heated (containing >=0.1% Butadiene)
Germ Cell Mutagenicity Category 1B H340 May cause genetic defects (containing >=0.1% Butadiene)
Carcinogenicity Category 1A H350 May cause cancer (containing >=0.1% Butadiene)
N-BUTANE (106-97-8)
Flammable Gases Category 1 H220 Extremely flammable gas (containing >=0.1% Butadiene)
Gases Under Pressure H280 Contains gas under pressure, may explode when heated (containing >=0.1% Butadiene)
Germ Cell Mutagenicity Category 1B H340 May cause genetic defects (containing >=0.1% Butadiene)
Carcinogenicity Category 1A H350 May cause cancer (containing >=0.1% Butadiene)
CYCLOHEXANE (110-82-7)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
TOLUENE (108-88-3)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
LEAD SALICYLATE (15748-73-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer
H360Df May damage the unborn child. Suspected of damaging fertility
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPANE (74-98-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
ISOBUTANE (75-28-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H340 May cause genetic defects
H350 May cause cancer
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
N-BUTANE (106-97-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H340 May cause genetic defects
H350 May cause cancer
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
CYCLOHEXANE (110-82-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H336 May cause drowsiness or dizziness
H304 May be fatal if swallowed and enters airways
H410 Very toxic to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
TOLUENE (108-88-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H360 May damage fertility or the unborn child
H336 May cause drowsiness or dizziness
H373 May cause damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
LEAD SALICYLATE (15748-73-9)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification, except those specified elsewhere in this Annex)
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification, except those specified elsewhere in this Annex)
Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility (except those specified elsewhere in this Annex)
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure; except those specified elsewhere in this Annex)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (except those specified elsewhere in this Annex)
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (except those specified elsewhere in this Annex)
PROPANE (74-98-6)
Flammable Gases Category 1 H220 Extremely flammable gas
Gases Under Pressure H280 Contains gas under pressure, may explode when heated
ISOBUTANE (75-28-5)
Flammable Gases Category 1 H220 Extremely flammable gas
Gases Under Pressure H280 Contains gas under pressure, may explode when heated
N-BUTANE (106-97-8)
Flammable Gases Category 1 H220 Extremely flammable gas
Gases Under Pressure H280 Contains gas under pressure, may explode when heated
CYCLOHEXANE (110-82-7)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
TOLUENE (108-88-3)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Reproductive Toxicity Category 2 H361d Suspected of damaging the unborn child (Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development: May damage/Suspected of damaging fertility or the unborn child; According to the criteria, the general hazard statement can be replaced by the hazard statement indicating the specific effect of concern in accordance with section 1.1.2.1.2; When the other differentiation is not mentioned, this is due to evidence proving no such effect, inconclusive data or no data and the obligations in Article 4(3) shall apply for that differentiation)
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure)
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
LEAD SALICYLATE (15748-73-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H360Df May damage the unborn child. Suspected of damaging fertility
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
PROPANE (74-98-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
ISOBUTANE (75-28-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
N-BUTANE (106-97-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
CYCLOHEXANE (110-82-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H336 May cause drowsiness or dizziness
H304 May be fatal if swallowed and enters airways
H410 Very toxic to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
TOLUENE (108-88-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H361d Suspected of damaging the unborn child
H336 May cause drowsiness or dizziness
H373 May cause damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
PROPANE (74-98-6) Approval: 1404
Flammable Gases Category 1 H220 Extremely flammable gas
Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
ISOBUTANE (75-28-5)
Flammable Gases Category 1 H220 Extremely flammable gas Approval: 21A3704
Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated Approval: 21A3704
Acute toxicity Inhalation - Gas Category 4 H332 Harmful if inhaled Approval: 21A3704
Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (heart) Approval: 21A3704
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 21A3704
N-BUTANE (106-97-8)
Flammable Gases Category 1 H220 Extremely flammable gas Approval: 918
Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated Approval: 918
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 918
CYCLOHEXANE (110-82-7)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: 25B0027
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 25B0027
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 25B0027
Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs (Hematopoietic System) Approval: 25B0027
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25B0027
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 25B0027
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 25B0027
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 25B0027
TOLUENE (108-88-3)
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Approval: 24B6503
Acute toxicity Inhalation - Vapour Category 4 H332 Harmful if inhaled Approval: 24B6503
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Approval: 24B6503
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 24B6503
Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Approval: 24B6503
Reproductive Toxicity Effects on or via lactation H362 May cause harm to breast-fed children Approval: 24B6503
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Central Nervous System) Approval: 24B6503
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 24B6503
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 24B6503
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Central Nervous System,kidneys) Approval: 24B6503
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways Approval: 24B6503
Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life Approval: 24B6503
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 24B6503
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
PROPANE (74-98-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H336 May cause drowsiness or dizziness
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ISOBUTANE (75-28-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H332 Harmful if inhaled
H371 May cause damage to organs
H336 May cause drowsiness or dizziness
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P271 Use only outdoors or in a well-ventilated area
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
N-BUTANE (106-97-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H336 May cause drowsiness or dizziness
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
CYCLOHEXANE (110-82-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H319 Causes serious eye irritation
H371 May cause damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H400 Very toxic to aquatic life
H412 Harmful to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
TOLUENE (108-88-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H332 Harmful if inhaled
H315 Causes skin irritation
H320 Causes eye irritation
H360 May damage fertility or the unborn child
H362 May cause harm to breast-fed children
H370 Causes damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H372 Causes damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
H401 Toxic to aquatic life
H412 Harmful to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P263 Avoid contact during pregnancy/while nursing
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
LEAD SALICYLATE (15748-73-9)
MOE: | Acute toxicity Oral Category 4 H302 Harmful if swallowed. (Except substances specified in the public notice) Acute toxicity Inhalation Category 4 H332 Harmful if inhaled. (Except substances specified in the public notice) Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child. (Except substances specified in the public notice) Specific target organ toxicity - Repeated exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure. (Except substances specified in the public notice) Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life. (Except substances specified in the public notice) Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects. (Except substances specified in the public notice) |
N-BUTANE (106-97-8)
MOEL: | Flammable Gases Category 1 H220 Extremely flammable gas Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness |
CYCLOHEXANE (110-82-7)
MOEL: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 2 H371 May cause damage to organs circulatory system Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Aspiration Hazard Category 2 H305 May be harmful if swallowed and enters airways Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
NEMA: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
TOLUENE (108-88-3)
MOE: | Flammable liquids Category 2 H225 Highly flammable liquid and vapour. Skin corrosion/irritation Category 2 H315 Causes skin irritation. Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child. Specific target organ toxicity - Single exposure Category 3 H336 May cause drowsiness or dizziness. Specific target organ toxicity - Repeated exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Category 1 H304 May be fatal if swallowed and enters airways. |
MOEL: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour Acute toxicity Inhalation - Vapour Category 4 H332 Harmful if inhaled Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways |
NEMA: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
LEAD SALICYLATE (15748-73-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H360 May damage fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
H336 May cause drowsiness or dizziness
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P410+P403 Protect from sunlight. Store in a well-ventilated place
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H371 May cause damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H305 May be harmful if swallowed and enters airways
H400 Very toxic to aquatic life
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H315 Causes skin irritation
H361 Suspected of damaging fertility or the unborn child
H336 May cause drowsiness or dizziness
H373 May cause damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H360 May damage fertility or the unborn child
H370 Causes damage to organs
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H372 Causes damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
PROPANE (74-98-6) Approval: HSR001010
Flammable Gases Category 1 H220 Extremely flammable gas
ISOBUTANE (75-28-5) Approval: HSR001003
Flammable Gases Category 1 H220 Extremely flammable gas
N-BUTANE (106-97-8) Approval: HSR000989
Flammable Gases Category 1 H220 Extremely flammable gas
CYCLOHEXANE (110-82-7) Approval: HSR001111
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (crustacean,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
TOLUENE (108-88-3) Approval: HSR001227
Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (Central Nervous System)
Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (algal,fish)
Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life (crustacean)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
PROPANE (74-98-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403 Store in a well-ventilated place
ISOBUTANE (75-28-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403 Store in a well-ventilated place
N-BUTANE (106-97-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P403 Store in a well-ventilated place
CYCLOHEXANE (110-82-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H302 Harmful if swallowed
H332 Harmful if inhaled
H316 Causes mild skin irritation
H411 Toxic to aquatic life with long lasting effects
H433 Harmful to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
TOLUENE (108-88-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
H413 May cause long lasting harmful effects to aquatic life
H433 Harmful to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
PROPANE (74-98-6)
Listing: Present
ISOBUTANE (75-28-5)
Listing: Present
Listing: Present (>=0.1% Butadiene)
N-BUTANE (106-97-8)
Listing: Present
Listing: Present (>=0.1% Butadiene)
CYCLOHEXANE (110-82-7)
Listing: Present
TOLUENE (108-88-3)
Listing: Present
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
PROPANE (74-98-6)
Taiwan: | Flammable Gases Category 1 H220 Extremely flammable gas |
| Gases Under Pressure Compressed gas H280 Contains gas under pressure, may explode when heated |
ISOBUTANE (75-28-5)
Taiwan: | Flammable Gases Category 1 H220 Extremely flammable gas |
| Gases Under Pressure Compressed gas H280 Contains gas under pressure, may explode when heated |
N-BUTANE (106-97-8)
Taiwan: | Flammable Gases Category 1 H220 Extremely flammable gas |
| Gases Under Pressure Compressed gas H280 Contains gas under pressure, may explode when heated |
CYCLOHEXANE (110-82-7)
Taiwan: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
| Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation |
| Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways |
| Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects |
TOLUENE (108-88-3)
Taiwan: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
| Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Skin Corrosion/Irritation Category 2 H315 Causes skin irritation |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (kidneys) |
| Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways |
| Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
PROPANE (74-98-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
ISOBUTANE (75-28-5)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
N-BUTANE (106-97-8)
Symbol(s)
Signal Word Danger
Hazard(s)
H220 Extremely flammable gas
H280 Contains gas under pressure, may explode when heated
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
Storage
P410+P403 Protect from sunlight. Store in a well-ventilated place
CYCLOHEXANE (110-82-7)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H316 Causes mild skin irritation
H304 May be fatal if swallowed and enters airways
H411 Toxic to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
TOLUENE (108-88-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H225 Highly flammable liquid and vapour
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H373 May cause damage to organs through prolonged or repeated exposure
H304 May be fatal if swallowed and enters airways
H402 Harmful to aquatic life
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
P331 Do NOT induce vomiting
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved