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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

704BT DIELECTRIC TAPE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Product Use 

process chemical 









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: film

Odor:  fruity odor 

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation 




Potential Health Effects 
Inhalation 

Short Term:  irritation, hair loss, metal fume fever, nausea, vomiting, diarrhea, loss of appetite, difficulty breathing, irregular heartbeat, headache, emotional disturbances, loss of coordination, blood disorders, paralysis, convulsions, coma 

Long Term:  weight loss, lung damage 




Skin Contact 

Short Term:  irritation, rash, absorption may occur, hair loss, nausea, vomiting, diarrhea, loss of appetite, headache, blood disorders, convulsions, coma 

Long Term:  irritation, rash, hair loss, vomiting, diarrhea, weight loss, blood disorders, convulsions 




Eye Contact 

Short Term:  irritation, tearing, blurred vision 

Long Term:  irritation 




Ingestion 

Short Term:  hair loss, fever, ringing in the ears, nausea, vomiting, digestive disorders, diarrhea, stomach pain, loss of appetite, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, emotional disturbances, tremors, internal bleeding, blood disorders, kidney damage, paralysis, convulsions, coma 

Long Term:  rash, hair loss, nausea, vomiting, diarrhea, loss of appetite, weight loss, headache, drowsiness, dizziness, pain in extremities, loss of coordination, blood disorders, heart disorders, effects on the brain, convulsions 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
12047-27-7 234-975-0 --BARIUM TITANIUM OXIDE-->60
7440-39-3 231-149-1 --BARIUM--<10
7440-42-8 231-151-2 --BORON--<10
7440-66-6 231-175-3 --ZINC--<10
7440-69-9 231-177-4 --BISMUTH--<10
Not Available -- --ACRYLIC RESIN--5 - 10
Not Available -- --POLYMERIZED ROSIN--<1
Not Available -- --ORGANIC ESTER--<1
Not Available -- --POLYCARBOXYLIC ACID SALT--<0.1




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Barium compounds, inorganic, Titanium compounds, Barium compounds, n.o.s., Zinc compounds, Bismuth compounds (inorganic).









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

Never make an unconscious person vomit or drink fluids. Give large amounts of water. DO NOT induce vomiting. If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 1 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Slight fire hazard. 


Extinguishing Media 

regular dry chemical, carbon dioxide, water, regular foam 


Large fires: Use regular foam or flood with fine water spray. 

Fire Fighting Measures 

Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Collect spilled material in appropriate container for disposal. Keep out of water supplies and sewers. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

BARIUM7440-39-3
ACGIH: 0.5 mg/m3 TWA




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor fruity odorColor white
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point >93.3 °C (calculated)
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form film











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. 


Incompatible Materials 

acids, halo carbons, metals, oxidizing materials, halogens, bases, metal carbide, metal oxides, metal salts, reducing agents, combustible materials, amines 


704BT DIELECTRIC TAPE ACETIC ANHYDRIDE: Incompatible. ACIDS: Incompatible. CHLORINATED RUBBER: Incompatible. MAGNESIUM: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. POTASSIUM: Incompatible. BISMUTH ACIDS: Possible exothermic reaction with release of toxic fumes. ALUMINUM: May form pyrophoric mixture. AMMONIUM NITRATE: Explosive reaction. BROMINE PENTAFLUORIDE: Incandescent reaction. CHLORIC ACID: Forms explosive compound. CHLORINE (GAS): Spontaneous ignition. IODINE PENTAFLUORIDE: Incandescent reaction. NITRIC ACID (CONCENTRATED): May explode at elevated temperatures. NITROSYL FLUORIDE: Incandescent reaction. OXIDIZERS: Fire and explosion hazard. PERCHLORIC ACID: Explosion hazard. BORON ACIDS: Incompatible. AMMONIA: When amorphous boron is heated in dry ammonia, the reaction proceeds with incandescence and hydrogen is evolved. BROMINE: Boron ignites in bromine vapor @ 700 C. BROMINE PENTAFLUORIDE: Violent reaction with possible ignition. BROMINE TRIFLUORIDE: Incandescent reaction. CALCIUM CHROMATE: Incompatible. CESIUM CARBIDE: Vigorous reaction when heated. CHLORINE: Boron burns spontaneously in gaseous chlorine. CHLORINE TRIFLUORIDE: May ignite. CUPRIC OXIDE: Boron reacts violently with cupric oxide after warming, melting glass tubing. FLUORINE: Fluorine attacks boron at ordinary temperatures, the mass becoming incandescent. IODIC ACID: Iodic acid attacks boron below 40 C and the mass becomes incandescent. IODINE PENTAFLUORIDE: Incandescence. LEAD FLUORIDE: May be explosive. LEAD (II) OXIDE: Incandescence on heating. LEAD (IV) OXIDE: A mixture of boron and lead dioxide explodes violently when ground in a mortar. NITRIC ACID: Incandescent reaction. NITRIC OXIDE: The reaction proceeds with blinding flashes. NITROSYL FLUORIDE: Incandescent reaction. NITROUS OXIDE: Amorphous boron ignites when heated in dry nitrous oxide. NITRYL FLUORIDE: Incompatible. OXIDIZERS: Incompatible. OXYGEN DIFLUORIDE: Sparks on heating. POTASSIUM CHLORATE: Vigorous reaction. POTASSIUM NITRATE: Possible fire and explosion. POTASSIUM NITRITE: Molten potassium nitrite may be violently decomposed. RUBIDIUM CARBIDE: Vigorous reaction. SILVER DIFLUORIDE: Detonates on contact with water. SILVER FLUORIDE: Fused silver fluoride reacts explosively with boron. SODIUM PEROXIDE: Possible explosion. SULFUR: Reaction becomes incandescent @ 600 C. ZINC ACIDS: Evolves hydrogen gas which may be ignited by the heat of the reaction ALKALIES: Evolves hydrogen gas which may be ignited by the heat of the reaction. ALUMINUM (POWDER): Possible ignition. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL: May spark on impact. AMMONIUM NITRATE: Violent reaction or formation of explosive mixture. AMMONIUM SULFIDE: May explode in a closed container. ARSENIC: Incandescent reaction when heated. ARSENIC TRIOXIDE: Explosive reaction on heating. BROMOMETHANE: Forms flammable compounds. CADMIUM: Incandescent reaction. CALCIUM CHLORIDE: Evolves hydrogen gas which may be ignited by the heat of the reaction. CARBON DISULFIDE: Incandescent reaction. CARBON TETRACHLORIDE + METHANOL: Extremely vigorous reaction. CHLORATES: Forms shock-sensitive mixtures. CHLORINATED RUBBER: Violent or explosive reaction at elevated temperatures. CHROMIC ANHYDRIDE: Violent reaction and possible ignition. COBALT HALIDE (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. ETHYL ACETOACETATE + TRIBROMONEOPENTYL ALCOHOL: May react explosively. HALOCARBONS: Possible violent reaction with ignition. HALOGENS: Possible ignition. HYDRAZINE NITRATE: Ignites on warming. HYDROXYLAMINE: May ignite or explode when heated. INTERHALOGENS: Violent reaction and possible ignition. LEAD AZIDE: Increased sensitivity to explosive decomposition. MANGANESE DICHLORIDE: Explosive reaction when heated. METAL OXIDES: Possible ignition or incandescent reaction. NITRIC ACID: Incandescent reaction. 2-NITROANISOLE + SODIUM HYDROXIDE: Exothermic reaction. NITROBENZENE: May form pyrophoric residue. NITRYL FLUORIDE: Incandesces when warmed. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXYFORMIC ACID: Violent explosion on contact. POTASSIUM NITRATE: Explosive reaction on heating. POTASSIUM PEROXIDE: Incandescent reaction. RHODIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. RUTHENIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. SELENIUM: Incandescent reaction. SELENINYL BROMIDE: Ignition. SILVER + ELECTROLYTES (BATTERIES): May spontaneously combust. SODIUM PEROXIDE: Incandescent reaction. SULFUR: Violent reaction. TELLURIUM: Incandescent reaction. ZINC CHLORIDE: May increase flammability. BARIUM ACIDS: Violent reaction. AMMONIA: Incompatible. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. CARBON TETRACHLORIDE: Violent reaction or possible explosion. FLUOROTRICHLOROMETHANE: Forms an explosive mixture. IODINE HEPTAFLUORIDE: Exothermic reaction. OXIDIZERS (STRONG): Fire and explosion hazard. TETRACHLOROETHYLENE: Forms an explosive mixture. TRICHLOROETHYLENE: Forms an explosive mixture. TRICHLOROTRIFLUOROETHANE: Forms an explosive mixture. BARIUM TITANIUM OXIDE No data available.

Hazardous Decomposition Products 

oxides of carbon, nitrogen, bismuth, zinc, ammonia, acrylic compounds 


Thermal decomposition products: oxides of carbon, nitrogen, bismuth, zinc, ammonia, ethyl methacrylate, methyl acrylate. 

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
BARIUM TITANIUM OXIDE (12047-27-7)

Oral LD50 Rat >12 g/kg

BARIUM (7440-39-3)

Oral LD50 Rat 132 mg/kg

BORON (7440-42-8)

Oral LD50 Rat 650 mg/kg

BISMUTH (7440-69-9)

Oral LD50 Rat 5 g/kg




Component Carcinogenicity

BARIUM7440-39-3
ACGIH: A4 - Not Classifiable as a Human Carcinogen








Medical Conditions Aggravated by Exposure 

respiratory disorders, skin disorders and allergies, 


Excessive zinc intake has been associated with a copper-deficiency anemia. 

Inhalation - Acute Exposure 

BARIUM: May cause sore throat, coughing, shortness of breath, vomiting, diarrhea, trembling, faintness, and paralysis of the arms and legs Barium and its soluble compounds may also cause dyspnea, weakness, anxiety, cardiac irregularity and other muscle stimulation effects, and convulsions BARIUM TITANIUM OXIDE: No data available BISMUTH: Bismuth compounds have little or no effect on intact mucous membranes BORON: May cause irritation of the upper respiratory tract May cause symptoms as detailed in ingestion ZINC: Inhalation of dust may cause irritation with difficulty in breathing and sneezing Neurological and psychiatric symptomology including irritability, upper extremity coarse intention tremor, incoordination, and ataxia have also been reported Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic, or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude, and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but it is quickly lost All symptoms usually subside within 24-36 hours.


Inhalation - Chronic Exposure 

BARIUM: No data available BARIUM TITANIUM OXIDE: Prolonged inhalation of barium oxides has been reported to cause a benign pneumoconiosis known as baritosis BISMUTH: No data available BORON: May cause temporary or permanent lung disease that may result in disability or death Prolonged or repeated inhalation may cause weight loss ZINC: Severe gastrointestinal disturbances and hypochromic anemia have been reported, but other chemicals may have contributed to the effects.


Skin Contact - Acute Exposure 

BARIUM: May cause irritation ZINC: Dust may cause mechanical irritation and mild dermatitis in intertriginous areas Reaction with moisture on skin may result in serious burns BORON: May cause irritation with discomfort or rash Skin absorption may occur resulting in symptoms as detailed in ingestion BISMUTH: Bismuth compounds have little or no effect on intact skin BARIUM TITANIUM OXIDE: No data available.


Skin Contact - Chronic Exposure 

BARIUM: Repeated or prolonged contact may cause dermatitis BARIUM TITANIUM OXIDE: No data available BISMUTH: No data available BORON: May cause anorexia, weight loss, vomiting, diarrhea, skin rash, alopecia, convulsions, and anemia ZINC: 300 ug applied to human skin intermittently for 3 days caused mild irritation Allergic reactions are rare, but have been reported.


Eye Contact - Acute Exposure 

BARIUM: Direct contact may cause irritation, redness, and pain BARIUM TITANIUM OXIDE: No data available BISMUTH: Direct contact with bismuth compounds is not expected to cause injury except in the case of strongly acidic salts BORON: May cause irritation with discomfort, tearing, blurring of vision, edema and conjunctivitis ZINC: Dust may cause mechanical irritation or injury to the surface of the eye, with discomfort, reddening, and tearing Direct contact may cause serious corneal burns.


Eye Contact - Chronic Exposure 

BARIUM: Repeated or prolonged exposure may cause conjunctivitis BARIUM TITANIUM OXIDE: No data available BISMUTH: No data available BORON: No data available ZINC: No data available.


Ingestion - Acute Exposure 

BARIUM TITANIUM OXIDE: Most water or acid soluble barium compounds are thought to be poisonous by ingestion If the barium ion is released, symptoms may include: Excessive salivation, vomiting, severe abdominal pain, violent purging with watery and bloody stools, tinnitus, giddiness, vertigo, anxiety, weakness, difficulty in breathing, cardiac irregularity, muscle twitchings progressing to convulsions and/or paralysis, collapse and death from cardiac and respiratory failure BISMUTH: No data available BORON: May cause nausea, vomiting, diarrhea, headache, loss of appetite, weakness, anemia, hair loss and damage, seizures, coma and death Spleen effects and abnormalities of the liver with jaundice have also been reported ZINC: Large oral doses may cause gastrointestinal distress with stomach cramps, dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting, hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, tightness in the throat, shock, collapse, renal failure, and death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach BARIUM: Barium and soluble barium compounds may cause salivation, vomiting, severe diarrhea with watery and bloody stools, colic, gastroenteritis, weakness, giddiness, anxiety, tinnitis, vertigo, confusion, and increasing somnolence without coma, dyspnea, slow pulse, hypokalemia, delayed kidney damage, and at high levels, hemolysis and hemorrhages in the stomach, intestines and kidneys may occur Stimulation of all muscle types may result in hyperperistalsis, bladder contraction, lumbar pain, muscle twitching progressing to convulsions and/or paralysis, vasoconstriction, and irregular contraction of the heart followed by arrest in systole Death may occur from cardiac or respiratory failure.


Ingestion - Chronic Exposure 

BARIUM TITANIUM OXIDE: No data available BISMUTH: No specific data available Repeated or prolonged ingestion of soluble bismuth compounds may cause decreased appetite, colic, nausea, vomiting, diarrhea, ulcerative stomatitis, foul breath, salivation, gingivitis, a blue-gray bismuth line on the gums or a diffuse or patchy bluish color of the mucosa, weakness, rheumatic pain, fever, headache, and skin rashes or lesions followed by exfoliative dermatitis Nephritis and diuresis may be manifestations of kidney damage Liver damage with mild jaundice and conjunctival hemorrhage are rare A reversible encephalopathy and osteodystrophy have been reported from bismuth salts BORON: May cause anorexia, weight loss, vomiting, mild diarrhea, skin rash, alopecia, convulsions, and anemia Animals tested experienced testicular effects and reproductive toxicity Repeated or prolonged ingestion may affect the brain, liver and heart ZINC: Patients taking zinc in amounts 10 times the RDA for months and years have not shown any adverse reactions Excessive absorption may cause copper-deficiency anemia Ingestion of approximately 85.7 mg/kg/day for 2 days caused lethargy, lightheadedness, staggering, and difficulty in writing clearly 2 people who ingested 40 ppm in drinking water for several months experienced lack of concentration, drowsiness, mental and physical fatigue, pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, nausea, weight loss, and lassitude 90 ppm in the diet for 5 weeks has resulted in a decrease in the HDL cholesterol level Pancreatic abnormalities have also been observed A diet of 0.25% in rats caused no injury; above 0.25% there was breakdown of the homeostatic mechanism, growth retardation, hypochromic anemia, and defective mineralization of the bones Mice fed 500 ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm for 13 weeks caused liver and kidney damage and some deaths Cows fed 2% for 2 days developed severe enteritis, with 7 of 40 dying Severe pulmonary emphysema and changes in the myocardium, kidneys, and liver were observed Pigs fed >1000 ppm had reduced food intake and weight gain; at >2000 ppm, death occurred after 2 weeks Bone changes were observed in foals fed 5400 ppm High dietary levels of zinc have been associated with reduced fetal weights, altered concentrations of fetal iron and copper, and alopecia and reduced growth of offspring in animals BARIUM: No effects have been reported in humans Animal studies have shown effects on the hemopoietic and central nervous systems.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

ZINC7440-66-6
Fish: LC50 96 h Pimephales promelas 2.16 - 3.05 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.211 - 0.269 mg/L [semi-static]; LC50 96 h Pimephales promelas 2.66 mg/L [static]; LC50 96 h Cyprinus carpio 30 mg/L; LC50 96 h Cyprinus carpio 0.45 mg/L [semi-static]; LC50 96 h Cyprinus carpio 7.8 mg/L [static]; LC50 96 h Lepomis macrochirus 3.5 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.59 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 0.41 mg/L [static]
Algae: EC50 96 h Pseudokirchneriella subcapitata 0.11 - 0.271 mg/L [static] EPA; EC50 72 h Pseudokirchneriella subcapitata 0.09 - 0.125 mg/L [static] EPA
Invertebrate: EC50 48 h Daphnia magna 0.139 - 0.908 mg/L [Static] EPA















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

BARIUM7440-39-3
RCRA: 100 mg/L regulatory level











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

No Classification assigned.




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
BARIUM TITANIUM OXIDE (12047-27-7)

Restriction(s): D/E [UN1564] (II); E [UN1564] (III) (related to Barium compounds)

BARIUM (7440-39-3)

Restriction(s): D/E [UN1400] (II)

ZINC (7440-66-6)

Restriction(s): E [UN1435] (III, ashes); E [UN1436] (I, dust or powder); D/E [UN1436] (II, dust or powder); E [UN1436] (III, dust or powder)








RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
BARIUM TITANIUM OXIDE12047-27-7
SARA 313: 1 % de minimis concentration (does not include Barium sulfate CAS 7727-43-7, Chemical Category N040) (related to Barium compounds)
BARIUM7440-39-3
SARA 313: 1 % de minimis concentration
ZINC7440-66-6
SARA 313: 1 % de minimis concentration (dust or fume only)
CERCLA: 454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: No Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
BARIUM TITANIUM OXIDE12047-27-7No No No Yes Yes 
BARIUM7440-39-3No Yes Yes Yes Yes 
BORON7440-42-8No No No Yes No 
ZINC7440-66-6Yes Yes No Yes Yes 




Not listed under California Proposition 65 




Germany Water Classification 

BARIUM (7440-39-3)

ID Number 9285 , hazard class 1 - low hazard to waters

BORON (7440-42-8)

ID Number 7094 , not considered hazardous to water

ZINC (7440-66-6)

ID Number 1349 , not considered hazardous to water (particle size >1mm)

ID Number 7325 , hazard class 2 - hazard to waters (particle size <=1 mm)

BISMUTH (7440-69-9)

ID Number 1443 , not considered hazardous to water








None needed according to classification criteria. 




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
BARIUM TITANIUM OXIDE12047-27-7Yes DSL EIN Yes Yes Yes Yes Yes Yes 
BARIUM7440-39-3Yes DSL EIN Yes Yes No Yes Yes Yes 
BORON7440-42-8Yes DSL EIN Yes Yes No Yes Yes Yes 
ZINC7440-66-6Yes DSL EIN Yes Yes No Yes Yes Yes 
BISMUTH7440-69-9Yes DSL EIN Yes Yes No Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ZINC (7440-66-6)

Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (dust and powder; pyrophoric)

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (dust and powder; pyrophoric)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (dust and powder; stabilised)

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (dust and powder, pyrophoric)

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H250 Catches fire spontaneously if exposed to air

H260 In contact with water releases flammable gases which may ignite spontaneously

H410 Very toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P222 Do not allow contact with air

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P422 Store contents under appropriate liquid or inert gas as specified

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
BARIUM (7440-39-3) Approval: 175

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

BORON (7440-42-8)

Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 490

ZINC (7440-66-6)

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 20A2067

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 20A2067

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 20A2067

BISMUTH (7440-69-9)

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (joint,kidneys,nervous system) Approval: 21A3764

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (joint,kidneys,nervous system) Approval: 21A3764




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
BARIUM (7440-39-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H261 In contact with water releases flammable gases

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P402+P404 Store in a dry place. Store in a closed container

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BORON (7440-42-8)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

Prevention

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H320 Causes eye irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P391 Collect spillage

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BISMUTH (7440-69-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
BARIUM (7440-39-3)

MOEL:Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects
NEMA:Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air


BORON (7440-42-8)

MOEL:Acute toxicity Oral Category 4 H302 Harmful if swallowed


ZINC (7440-66-6)

MOEL:Acute toxicity Oral Category 3 H301 Toxic if swallowed

Carcinogenicity Category 1A H350 May cause cancer

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
NEMA:Flammable Solids Category 2 H228 Flammable solid




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
BARIUM (7440-39-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H261 In contact with water releases flammable gases

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H412 Harmful to aquatic life with long lasting effects

Prevention

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P402+P404 Store in a dry place. Store in a closed container

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H250 Catches fire spontaneously if exposed to air

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P222 Do not allow contact with air

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P422 Store contents under appropriate liquid or inert gas as specified

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

Prevention

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H350 May cause cancer

H400 Very toxic to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H228 Flammable solid

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
BARIUM TITANIUM OXIDE (12047-27-7) Approval: HSR004800

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates

BARIUM (7440-39-3) Approval: HSR001265

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (blood,body weight,Cardiovascular system,kidneys,liver,lungs)

Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (Cardiovascular system,kidneys)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

BORON (7440-42-8) Approval: HSR003311

Acute toxicity Oral Category 4 H302 Harmful if swallowed

ZINC (7440-66-6) Approval: HSR001301

Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder/dust, PG I)

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder/dust, PG I)

Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled (powder/dust, PG I)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder/dust, PG I)




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
BARIUM TITANIUM OXIDE (12047-27-7)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

H433 Harmful to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BARIUM (7440-39-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H261 In contact with water releases flammable gases

H301 Toxic if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H372 Causes damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

H432 Toxic to terrestrial vertebrates

Prevention

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P402+P404 Store in a dry place. Store in a closed container

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BORON (7440-42-8)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

Prevention

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H251 Self-heating, may catch fire

H260 In contact with water releases flammable gases which may ignite spontaneously

H333 May be harmful if inhaled

H400 Very toxic to aquatic life

Prevention

P235+P410 Keep cool. Protect from sunlight

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P407 Maintain air gap between stacks/pallets

P413 Store bulk masses at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
ZINC (7440-66-6)

Listing: Present (powder)




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BARIUM (7440-39-3)

Taiwan:Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation


ZINC (7440-66-6)

Taiwan:Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder)
 Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder)
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation (powder)
 Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (powder)




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BARIUM (7440-39-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H261 In contact with water releases flammable gases

H335 May cause respiratory irritation

Prevention

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P402+P404 Store in a dry place. Store in a closed container

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H250 Catches fire spontaneously if exposed to air

H261 In contact with water releases flammable gases

H316 Causes mild skin irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P222 Do not allow contact with air

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P332+P313 If skin irritation occurs: Get medical advice/attention

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P422 Store contents under appropriate liquid or inert gas as specified

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved