TERT-BUTYLAMINE

amines, aliphatic 

2-AMINOISOBUTANE; 2-AMINO-2-METHYLPROPANE; TERTIARY BUTYLAMINE; T-BUTYLAMINE; TRIMETHYLAMINOMETHANE; 2-METHYL-2-PROPANAMINE; 1,1-DIMETHYLETHYLAMINE; 2-METHYL-2-AMINOPROPANE; C4H11N

Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: liquid

Odor:  ammonia odor 

Health Hazards:  harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  Extremely flammable liquid and vapor. Vapor may cause flash fire. 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 

For inhalation, consider oxygen. For ingestion, consider gastric lavage. 

See Section 9 for Flammability Properties 

Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive. 

regular dry chemical, carbon dioxide, water, regular foam, alcohol-resistant foam Large fires: Use regular foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 500 meters (1/3 mile). Consider downwind evacuation if material is leaking. 

Reduce vapors with water spray. Stay upwind and keep out of low areas. 

Dig holding area such as lagoon, pond or pit for containment. Dike for later disposal. Absorb with sand or other non-combustible material. Add dilute acid. 

Add a reducing agent. Absorb with activated carbon. Collect spilled material using mechanical equipment. 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store in a cool, dry place. Store in a tightly closed container. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

ethanol, ether, organic solvents 

Stable at normal temperatures and pressure. 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. 

acids, combustible materials, oxidizing materials, 

TERT-BUTYLAMINE: ACIDS (STRONG): Incompatible. ALCOHOLS: Incompatible. CARBON OXIDES: Incompatible. 2,2-DIBROMO-1,3-DIMETHYLCYCLOPROPANOIC ACID: Strong exothermic reaction. GLYCOL ETHERS: Incompatible. MONOMERS: Incompatible. NITROGEN OXIDES: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PLASTICS: May be attacked. PHENOLS: Incompatible. AMINES: ACROLEIN: Exothermic polymerization. CALCIUM HYPOCHLORITE: Formation of explosive chloroamine. MALEIC ANHYDRIDE: Explosive decomposition. NITROSYL PERCHLORATE: Explosive reaction. SODIUM HYPOCHLORITE: Formation of explosive chloroamine. TRI-ISO-BUTYL ALUMINUM: Violent reaction.

oxides of carbon, nitrogen 

Thermal decomposition products: oxides of carbon, nitrogen. test.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

CORROSIVE SUBSTANCES: May cause severe irritation of the respiratory tract with coughing, choking, pain and possibly burns of the mucous membranes In some cases, pulmonary edema may develop, either immediately or more often within a period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include moist rales, low blood pressure and high pulse pressure Severe cases may be fatal.

CORROSIVE SUBSTANCES Depending on the concentration and duration of exposure, repeated or prolonged exposure may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances.

TERT-BUTYLAMINE See information on corrosive substances.

CORROSIVE SUBSTANCES Direct contact may cause severe irritation, pain, and possibly burns.

CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in dermatitis or effects similar to acute exposure.

TERT-BUTYLAMINE See information on corrosive substances.

CORROSIVE SUBSTANCES: Direct contact may cause severe irritation, pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact The full extent of the injury may not be immediately apparent.

CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.

TERT-BUTYLAMINE See information on corrosive substances.

CORROSIVE SUBSTANCES: May cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur.

CORROSIVE SUBSTANCES Depending on the concentration, repeated ingestion may cause effects as with acute ingestion.

TERT-BUTYLAMINE: The lethal dose reported in rats was 78 mg/kg See information on corrosive substances.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. 

Component Waste Numbers 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Germany Water Classification 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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