危险化学品
收录危险化学品目录，并提供相应的化学品安全技术说明书(Material Safety Data Sheet，简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。
Material Name: TERT-AMYL PEROXYNEODECANOATE SDS ID: ohs22610 Issue Date: 2016-06-23 Revision: 2.06 |
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
TERT-AMYL PEROXYNEODECANOATE
| ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
organic peroxides
NEODECANEPEROXOIC ACID, 1,1-DIMETHYLPROPYL ESTER; TERT-AMYL PERNEODECANOATE; ESPSEROX 545M; LUPERSOL 546M75; LUPERSOL TA 46; UN 2891; C15H30O3
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: colorless to pale
Change in color: Not available
Physical Form: liquid
Physical Hazards: May explode if exposed to shock, friction or heating. Flammable liquid and vapor. Vapor may cause flash fire. Organic peroxide. May ignite or explode on contact with combustible materials.
Short Term: irritation, headache
Long Term: no information is available
Short Term: no information is available
Long Term: no information on significant adverse effects
Short Term: no information is available
Long Term: no information is available
Short Term: difficulty breathing
Long Term: no information is available
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
| CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
| 68299-16-1 269-597-5 -- | TERT-AMYL PEROXYNEODECANOATE | -- | 100 |
* * * Section 4 - FIRST AID MEASURES * * *
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
For inhalation, consider oxygen. For ingestion, consider gastric lavage.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Severe fire hazard. Vapor/air mixtures are explosive. Organic peroxide. Flammable. Burns faster as the fire progresses. May ignite or explode on contact with combustible materials. Containers may rupture or explode if exposed to heat.
regular dry chemical, carbon dioxide, water, regular foam Large fires: Flood with water. Apply water from a protected location or from a safe distance.
For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Explosive. Evacuation radius: 800 meters (1/2 mile).
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Move containers away from spill to a safe area. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
Biological limit value
Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
| Appearance | Not available | Physical State | Liquid |
| Odor | Not available | Color | colorless to pale |
| Odor Threshold | Not available | pH | Not available |
| Melting Point | Not available | Boiling Point | Not available |
| Freezing point | Not available | Evaporation Rate | Not available |
| Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
| Autoignition | Not available | Flash Point | Not available |
| Lower Explosive Limit | Not available | Decomposition | Not available |
| Upper Explosive Limit | Not available | Vapor Pressure | Not available |
| Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
| Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
| Viscosity | Not available | Solubility (Other) | Not available |
| Density | Not available | Physical Form | liquid |
| Molecular Formula | C15-H30-O3 | Molecular Weight | 258.4 |
* * * Section 10 - STABILITY AND REACTIVITY * * *
May explode if exposed to shock, friction or heating.
Avoid contact with air. Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. Keep out of water supplies and sewers.
combustible materials,
TERT-AMYL PEROXYNEODECANOATE: ACRYLIC COMPOUNDS: Polymerization may be initiated by organic peroxides. FINELY DIVIDED MATERIALS: Can form explosive mixtures. VINYL COMPOUNDS: Polymerization may be initiated by organic peroxides.
oxides of carbon
Thermal decomposition products: oxides of carbon.
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
TERT-AMYL PEROXYNEODECANOATE: No data available However, organic peroxides may irritate mucous membranes The vapors of some organic peroxides may cause headaches, intoxication similar to alcohol, and lung edema if inhaled in high concentrations.
TERT-AMYL PEROXYNEODECANOATE No data available.
TERT-AMYL PEROXYNEODECANOATE: No data available Organic peroxides are likely to cause skin irritation.
TERT-AMYL PEROXYNEODECANOATE: No data available However, prolonged or repeated exposure to organic peroxides may lead to sensitization dermatitis.
TERT-AMYL PEROXYNEODECANOATE: No data available However, organic peroxides are likely to irritate the eyes.
TERT-AMYL PEROXYNEODECANOATE No data available.
TERT-AMYL PEROXYNEODECANOATE: No data available Ingestion of organic peroxides may cause decreased pulse and temperature, dyspnea, and stupor.
TERT-AMYL PEROXYNEODECANOATE No data available.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Dispose in accordance with all applicable regulations.
Component Waste Numbers
* * * Section 14 - TRANSPORT INFORMATION * * *
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED, (Contains:TERT-AMYL PEROXYNEODECANOATE)
Hazard Class: 5.2
UN/NA #: UN3115
Required Label(s): 5.2
No Classification assigned.
No Classification assigned.
No Classification assigned.
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED
Hazard Class: 5.2
UN#: UN3115
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED
Hazard Class: 5.2
UN#: UN3115
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED
Hazard Class: 5.2
UN#: UN3115
Component Marine Pollutants (IMDG)
* * * Section 15 - REGULATORY INFORMATION * * *
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Not listed under California Proposition 65
Germany Water Classification
ID Number 1465 , hazard class 2 - hazard to waters (footnote 21)
O Oxidizing
Xi Irritant
Risk Phrases
R2 Risk of explosion by shock, friction, fire or other sources of ignition.
R7 May cause fire.
R36 Irritating to eyes.
Safety Phrases
S2 Keep out of the reach of children.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S46 If swallowed, seek medical advice immediately and show this container or label.
| Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
| TERT-AMYL PEROXYNEODECANOATE | 68299-16-1 | Yes | NSL | EIN | No | Yes | Yes | Yes | No | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
This material may be hazardous according to published criteria for classification
European Union GHS Classifications
This material may be hazardous according to published criteria for classification
Indonesia GHS Classifications
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
This material may be hazardous according to published criteria for classification
Korea GHS Classifications
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
This material may be hazardous according to published criteria for classification
South Africa GHS Classifications
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
This material may be hazardous according to published criteria for classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved