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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

TERT-OCTYLAMINE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

amines, aliphatic 


Synonyms 

1,1,3,3-TETRAMETHYL BUTYLAMINE; BIS(1,3-DIMETHYL)-BUTYLAMINE; 2,4,4-TRIMETHYL-2-PENTANAMINE; 1,1,3,3-TETRAMETHYLBUTANAMINE; 1,1,3,3-TETRAMETHYLBUTYLAMINE









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: liquid

Odor:  fishy odor 

Health Hazards:  respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  Flammable liquid and vapor. Vapor may cause flash fire. 




Potential Health Effects 
Inhalation 

Short Term:  burns, difficulty breathing, dizziness, bluish skin color, lung congestion 

Long Term:  digestive disorders 




Skin Contact 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 




Eye Contact 

Short Term:  irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
107-45-9 203-491-1 --TERT-OCTYLAMINE--100











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 


Eyes 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 


Note to Physicians 

For inhalation, consider oxygen. For ingestion, consider gastric lavage. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 3 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. 


Extinguishing Media 

regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Do not get water inside container. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance clearPhysical State Liquid
Odor fishy odorColor colorless
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point 140 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point 33 °C OC
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) 4.46Specific Gravity (water=1) 1.41
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form liquid
Molecular Formula C8-H19-NMolecular Weight 129.25
OSHA Flammability Class IC  




Solvent Solubility 
Soluble 

organic solvents 













* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. 


Incompatible Materials 

oxidizing materials, 


TERT-OCTYLAMINE: OXIDIZING MATERIALS: May react in their presence.

Hazardous Decomposition Products 

oxides of carbon, nitrogen 


Thermal decomposition products: oxides of carbon, nitrogen. test.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
TERT-OCTYLAMINE (107-45-9)

Oral LD50 Rat 218 mg/kg




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

TERT-OCTYLAMINE: Inhalation of corrosive substances may cause symptoms of respiratory tract irritation possibly including coughing, choking, pain in the nose, mouth and throat and burns of the mucous membranes If sufficient quantities are inhaled, pulmonary edema may develop, often with a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include weak, rapid pulse, hypotension, hemoconcentration and moist rales.


Inhalation - Chronic Exposure 

TERT-OCTYLAMINE Depending on the concentration and duration of exposure, repeated or prolonged exposure to corrosive substances may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances.


Skin Contact - Acute Exposure 

TERT-OCTYLAMINE Direct contact with corrosive substances may cause severe irritation, pain and possibly burns.


Skin Contact - Chronic Exposure 

TERT-OCTYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact with corrosive substances may result in dermatitis or effects similar to acute exposure.


Eye Contact - Acute Exposure 

TERT-OCTYLAMINE: Direct contact with corrosive substances may cause severe irritation, pain, and burns, possibly severe The degree of injury depends on the concentration and duration of contact The full extent of the injury may not be immediately apparent.


Eye Contact - Chronic Exposure 

TERT-OCTYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact with corrosive substances may result in conjunctivitis or effects as in acute exposure.


Ingestion - Acute Exposure 

TERT-OCTYLAMINE: 70 mg/kg is the lowest reported lethal dose in rats Corrosive substances may cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur.


Ingestion - Chronic Exposure 

TERT-OCTYLAMINE Depending on the concentration, repeated ingestion of corrosive substances may cause effects as with acute ingestion.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

TERT-OCTYLAMINE107-45-9
Fish: LC50 96 h Pimephales promelas 22.1 - 27.2 mg/L [flow-through]















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN/NA #: UN2734

Packing Group: I

Required Label(s): 8, 3




TDG Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN#: UN2734

Packing Group: I

Required Label(s): 8, 3




ADR Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN#: UN2734

Packing Group: I

Required Label(s): 8 + 3




RID Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN#: UN2734

Packing Group: I

Required Label(s): 8 + 3




IATA Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN#: UN2734

Packing Group: I

Required Label(s): 8, 3




ICAO Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., (Contains:TERT-OCTYLAMINE)

Hazard Class: 8

UN#: UN2734

Packing Group: I

Required Label(s): 8, 3




IMDG Information:

Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.

Hazard Class: 8

UN#: UN2734

Packing Group: I

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
TERT-OCTYLAMINE107-45-9No Yes No No Yes 




Not listed under California Proposition 65 




Germany Water Classification 

TERT-OCTYLAMINE (107-45-9)

ID Number 2555 , hazard class 2 - hazard to waters








Symbol(s)

Xn Harmful

C Corrosive

Risk Phrases

R10 Flammable.

R22 Harmful if swallowed.

R34 Causes burns.

Safety Phrases

S2 Keep out of the reach of children.

S13 Keep away from food, drink and animal feedingstuffs.

S20 When using do not eat or drink.

S24 Avoid contact with skin.

S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36 Wear suitable protective clothing.

S39 Wear eye/face protection.

S46 If swallowed, seek medical advice immediately and show this container or label.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
TERT-OCTYLAMINE107-45-9Yes DSL EIN No Yes Yes Yes Yes No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved