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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

TETRAFLUOROMETHANE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

halogenated, aliphatic 


Synonyms 

CARBON TETRAFLUORIDE; CARBON FLUORIDE (CF4); CARBON FLUORIDE; FC 14; PERFLUOROMETHANE; R 14; R 14 (REFRIGERANT); METHANE, TETRAFLUORO-; FREON 14; TETRAFLUOROCARBON; HALOCARBON 14 (AIRCO); UN 1982; CF4









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: gas

Odor:  odorless 

Health Hazards:  difficulty breathing 

Physical Hazards:  Containers may rupture or explode if exposed to heat. 




Potential Health Effects 
Inhalation 

Short Term:  nausea, vomiting, symptoms of drunkenness, disorientation, suffocation 

Long Term:  no information is available 




Skin Contact 

Short Term:  irritation 

Long Term:  no information is available 




Eye Contact 

Short Term:  frostbite 

Long Term:  no information is available 




Ingestion 

Short Term:  no information on significant adverse effects 

Long Term:  no information is available 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
75-73-0 200-896-5 --TETRAFLUOROMETHANE--100




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Fluorides.









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 


Skin 

If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. 


Eyes 

Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids, until no evidence of chemical remains. Get medical attention immediately. 


Ingestion 

If a large amount is swallowed, get medical attention. 


Note to Physicians 

For inhalation, consider oxygen. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 1 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. 


Extinguishing Media 

carbon dioxide, regular dry chemical Large fires: Use regular foam or flood with fine water spray. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Use extinguishing agents appropriate for surrounding fire. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Consider downwind evacuation if material is leaking. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Stop leak if possible without personal risk. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

TETRAFLUOROMETHANE75-73-0
ACGIH: 2.5 mg/m3 TWA as F (related to Fluorides)
OSHA (US): 2.5 mg/m3 TWA as F; 2.5 mg/m3 TWA dust (related to Fluorides)
Mexico: 2.5 mg/m3 TWA VLE-PPT as F (related to Fluorides)




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Based on available information, additional ventilation is not required. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. 


Glove Recommendations 

Wear insulated gloves. 


Respiratory Protection 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Any powered, air-purifying respirator with a full facepiece and organic vapor and acid gas cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor and acid gas cartridge(s). For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Gas
Odor odorlessColor colorless
Odor Threshold Not available pH Not available 
Melting Point -187 °CBoiling Point -128 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure 799 mmHg at -127 °C
Vapor Density (air=1) 3.05Specific Gravity (water=1) 1.89 at -183 °C
Water Solubility 0.0015 % (25 °C)Partition coefficient: n-octanol/water Not available 
Viscosity 0.17 cP -60 °CSolubility (Other) Not available 
Density Not available Physical Form gas
Molecular Formula C-F4Molecular Weight 88.01











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Protect from physical damage and heat. Containers may rupture or explode if exposed to heat. 


Incompatible Materials 

metals 


TETRAFLUOROMETHANE: ALUMINUM: Exothermic reaction.

Hazardous Decomposition Products 

halogenated compounds 


Thermal decomposition products: fluorinated compounds.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

TETRAFLUOROMETHANE75-73-0
ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Fluorides)








Stimulants such as epinephrine may induce ventricular arrhythmias. 

Inhalation - Acute Exposure 

TETRAFLUOROMETHANE High concentrations may cause hypoxia with dizziness, disorientation, incoordination, narcosis, nausea, and vomiting.


Inhalation - Chronic Exposure 

TETRAFLUOROMETHANE No data available.


Skin Contact - Acute Exposure 

TETRAFLUOROMETHANE Skin contact with the liquid may cause irritation or frostbite.


Skin Contact - Chronic Exposure 

TETRAFLUOROMETHANE No data available.


Eye Contact - Acute Exposure 

TETRAFLUOROMETHANE Liquid splashed in the eye may cause freezing resulting in frostbite, temporary irritation or serious damage.


Eye Contact - Chronic Exposure 

TETRAFLUOROMETHANE No data available.


Ingestion - Acute Exposure 

TETRAFLUOROMETHANE Ingestion of a gas is unlikely.


Ingestion - Chronic Exposure 

TETRAFLUOROMETHANE Ingestion of a gas is unlikely.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2.2

UN/NA #: UN1982

Required Label(s): 2.2




TDG Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2.2

UN#: UN1982

Required Label(s): 2.2




ADR Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2

UN#: UN1982

Required Label(s): 2.2

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
TETRAFLUOROMETHANE (75-73-0)

Restriction(s): C/E [UN1982]








RID Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2

UN#: UN1982

Required Label(s): 2.2 (+13)




IATA Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2.2

UN#: UN1982

Required Label(s): 2.2




ICAO Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2.2

UN#: UN1982

Required Label(s): 2.2




IMDG Information:

Shipping Name: TETRAFLUOROMETHANE

Hazard Class: 2.2

UN#: UN1982

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: No Pressure: Yes Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
TETRAFLUOROMETHANE75-73-0Yes No Yes Yes No 




Not listed under California Proposition 65 




None needed according to classification criteria. 




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
TETRAFLUOROMETHANE75-73-0Yes DSL EIN Yes Yes Yes Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
TETRAFLUOROMETHANE (75-73-0) Approval: 21A3559

Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
TETRAFLUOROMETHANE (75-73-0)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H280 Contains gas under pressure, may explode when heated

H336 May cause drowsiness or dizziness

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P410+P403 Protect from sunlight. Store in a well-ventilated place

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
TETRAFLUOROMETHANE (75-73-0)

Listing: Present




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
TETRAFLUOROMETHANE (75-73-0)

Taiwan:Gases Under Pressure Compressed gas H280 Contains gas under pressure, may explode when heated
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
TETRAFLUOROMETHANE (75-73-0)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H280 Contains gas under pressure, may explode when heated

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P410+P403 Protect from sunlight. Store in a well-ventilated place

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved