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危险化学品

收录危险化学品目录，并提供相应的化学品安全技术说明书(Material Safety Data Sheet，简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                

* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *

Material Name: 

TETRAMETHYL LEAD


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

organometallic 


Synonyms 

TML; TETRAMETHYLPLUMBANE; TETRAMETHYLLEAD; TML COMPOUND; MOTOR FUEL ANTIKNOCK COMPOUND; UN 1649; C4H12PB








* * * Section 2 - HAZARDS IDENTIFICATION  * * *

Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: Not available

Odor:  fruity odor 

Health Hazards:  harmful if swallowed, respiratory tract irritation, skin irritation, eye irritation 

Physical Hazards:  May explode when heated. Flash back hazard. Combustible liquid and vapor. May react on contact with water. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, digestive disorders, headache, dizziness, hyperactivity, lung congestion, nerve damage, convulsions, coma 

Long Term:  same as effects reported in short term exposure 




Skin Contact 

Short Term:  irritation 

Long Term:  burns 




Eye Contact 

Short Term:  irritation 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  metallic taste, vomiting, diarrhea, stomach pain, disorientation, hyperactivity, nerve damage, convulsions, coma 

Long Term:  same as effects reported in short term exposure 














* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *

CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
75-74-1 200-897-0 --TETRAMETHYL LEADAcute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332 Repr. 1A - H360Df STOT RE 2 - H373 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Note(s): A, 1100




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Lead compounds, Lead compounds, organic.








* * * Section 4 - FIRST AID MEASURES  * * *

Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention, if needed. 








* * * Section 5 - FIRE FIGHTING MEASURES  * * *

See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 2 Reactivity: 3 Other: W

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. 


Extinguishing Media 

regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. 








* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *

Water Release 

Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. 


Occupational spill/release 

Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Small dry spills: Move containers away from spill to a safe area. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 








* * * Section 7 - HANDLING AND STORAGE  * * *

Storage Procedures 

Store and handle in accordance with all current regulations and standards. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355 Part B). 








* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *

Component Exposure Limits 

TETRAMETHYL LEAD75-74-1
ACGIH: 0.15 mg/m3 TWA as Pb
 Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH: 0.075 mg/m3 TWA as Pb
 Potential for dermal absorption
 40 mg/m3 IDLH as Pb
OSHA (US): 0.075 mg/m3 TWA as Pb
 prevent or reduce skin absorption
Mexico: 0.15 mg/m3 TWA VLE-PPT as Pb
 0.5 mg/m3 STEL [PPT-CT] as Pb
 Skin - potential for cutaneous absorption




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: Lead (Pb) 0.75 mg/m3 Any supplied-air respirator. 1.875 mg/m3 Any supplied-air respirator operated in a continuous-flow mode. 3.75 mg/m3 Any supplied-air respirator with a tight-fitting facepiece that is operated in a continuous-flow mode. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 40 mg/m3 Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister. Any appropriate escape-type, self-contained breathing apparatus. 








* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *

Appearance Not available Physical State Liquid
Odor fruity odorColor colorless
Odor Threshold Not available pH Not available 
Melting Point -28 °CBoiling Point 110 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point 38 °C
Lower Explosive Limit 1.8 %Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure 22 mmHg at 20 °C
Vapor Density (air=1) 6.5Specific Gravity (water=1) 1.995
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Texture oily
Molecular Formula C4-H12-PBMolecular Weight 267.35
OSHA Flammability Class II  




Solvent Solubility 
Soluble 

benzene, petroleum, ether, gasolines, alcohol 












* * * Section 10 - STABILITY AND REACTIVITY  * * *

Chemical Stability 

May react with evolution of heat on contact with water. May explode when heated. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Avoid friction or contamination. 


Incompatible Materials 

oxidizing materials, combustible materials, metals, metal oxides, 


TETRAMETHYL LEAD: OXIDIZERS: May react violently or vigorously. SULFURYL CHLORIDE: May explode and ignite. POTASSIUM PERMANGANATE: May explode and ignite. RUBBER: Attacked. METALS: May cause decomposition. RUST: May cause decomposition. TETRACHLOROTRIFLUOROMETHYLPHOSPHORANE: Interaction under vacuum to form methyltrichlorotrifluoromethylphosphorane is hazardous, violent explosions having occurred twice after 30 minutes at ambient temperatures.

Hazardous Decomposition Products 

miscellaneous decomposition products 


Thermal decomposition products: miscellaneous decomposition products.

Possibility of Hazardous Reactions 

Will not polymerize. 








* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *

Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
TETRAMETHYL LEAD (75-74-1)

Oral LD50 Rat 105 mg/kg

Inhalation LC50 Rat 8.87 ppm 1 h




Component Carcinogenicity

TETRAMETHYL LEAD75-74-1
IARC: Monograph 87 [2006]; Supplement 7 [1987]; Monograph 23 [1980] (Group 3 (not classifiable))
NTP: Reasonably Anticipated To Be A Human Carcinogen
OSHA: Present








Inhalation - Acute Exposure 

TETRAMETHYL LEAD: May cause irritation to the mucous membranes May also affect the central nervous system causing insomnia, excitement, confusion, headache, vertigo, disturbing dreams, tremors, twitching and spasticity More severe intoxication may cause irritability, hyperactivity, pain in muscles, gastrointestinal distress, maniacal or violent convulsive seizures, psychosis, pulmonary edema, coma and death.


Inhalation - Chronic Exposure 

TETRAMETHYL LEAD May cause weight loss, anemia, insomnia, emotional instability, hyperactivity, convulsions and toxic psychosis.


Skin Contact - Acute Exposure 

TETRAMETHYL LEAD: May cause irritation with smarting and redness May be absorbed through the skin and cause irritability, psychosis, and convulsion Animal studies indicate lethal amounts can be absorbed through the skin.


Skin Contact - Chronic Exposure 

TETRAMETHYL LEAD May cause dermatitis and secondary burns when exposure is prolonged.


Eye Contact - Acute Exposure 

TETRAMETHYL LEAD: May cause irritation with redness and smarting When tetraethyl lead, a closely related compound, was dropped onto the eye of a rabbit it caused immediate pain and blepharospasm When tetraethyl lead was applied to the eye of a rabbit 10 times within 5 minutes it produced conjunctival hyperemia and moderate flocculent discharge, but no damage to the cornea or conjunctiva.


Eye Contact - Chronic Exposure 

TETRAMETHYL LEAD May cause conjunctivitis after repeated or prolonged exposure.


Ingestion - Acute Exposure 

TETRAMETHYL LEAD: May cause metallic taste, abdominal pain, vomiting, diarrhea black stools, oliguria, weakness, disturbing dreams, tremors, and mental depression In severe intoxication symptoms may be increased irritability, disorientation, hallucinations, visual difficulties, hyperactivity, pain in muscles, psychosis, coma and death Oral administration to rats caused death in some with tremor, marked hyperactivity, and convulsions.


Ingestion - Chronic Exposure 

TETRAMETHYL LEAD May cause insomnia, disturbing dreams, emotional instability, hyperactivity, convulsions, and toxic psychosis.








* * * Section 12 - ECOLOGICAL INFORMATION  * * *

Component Analysis - Aquatic Toxicity 

TETRAMETHYL LEAD75-74-1
Fish: LC50 96 h Lepomis macrochirus 84 mg/L [static]; LC50 96 h Pimephales promelas 19.3 mg/L
Invertebrate: EC50 48 h Artemia salina 0.25 mg/L IUCLID








Bioconcentration Factor 

TETRAMETHYL LEAD75-74-1
BCF 1412 - 17329 species: fish










* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *

Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 










* * * Section 14 - TRANSPORT INFORMATION  * * *

US DOT Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURES

Hazard Class: 6.1

UN/NA #: UN1649

Packing Group: I

Required Label(s): 6.1

Component Marine Pollutants 

This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants 
Component CAS # Minimum Concentration 
TETRAMETHYL LEAD75-74-1DOT regulated marine pollutant








TDG Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Required Label(s): 6.1




ADR Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Required Label(s): 6.1




RID Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Required Label(s): 6.1




IATA Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Required Label(s): 6.1




ICAO Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Required Label(s): 6.1




IMDG Information:

Shipping Name: MOTOR FUEL ANTI-KNOCK MIXTURE

Hazard Class: 6.1

UN#: UN1649

Packing Group: I

Component Marine Pollutants (IMDG) 

This material contains one or more of the following chemicals required by IMDG to be identified as marine pollutants 
TETRAMETHYL LEAD75-74-1
 IMDG regulated marine pollutant (Listed in the index)














* * * Section 15 - REGULATORY INFORMATION  * * *

US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
TETRAMETHYL LEAD75-74-1
SARA 302: 100 lb TPQ
SARA 313: 1 % Supplier notification limit (related to Lead compounds, organic)
OSHA (safety): 1000 lb TQ
SARA 304: 100 lb EPCRA RQ




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: Yes Fire: Yes Pressure: Yes Reactivity: Yes








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
TETRAMETHYL LEAD75-74-1Yes Yes Yes Yes Yes 




The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): 

WARNING! This product contains a chemical known to the state of California to cause cancer




Component Analysis 
TETRAMETHYL LEAD75-74-1
Carc: carcinogen , 10/1/1992 (related to Lead compounds)












Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
TETRAMETHYL LEAD75-74-1
 1 %








Germany Water Classification 

TETRAMETHYL LEAD (75-74-1)

ID Number 538 , hazard class 3 - severe hazard to waters




REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 
TETRAMETHYL LEAD (75-74-1)

Use restricted. See item 30. (except those specified elsewhere in Annex XVII to Regulation 1907/2006) (related to Lead compounds)








Symbol(s)

T Toxic

N Dangerous for the Environment

Risk Phrases

R20/22 Harmful by inhalation and if swallowed.

R33 Danger of cumulative effects.

R50 Very toxic to aquatic organisms.

R53 May cause long-term adverse effects in the aquatic environment.

R61 May cause harm to the unborn child.

R62 Possible risk of impaired fertility.

Safety Phrases

S53 Avoid exposure - obtain special instructions before use.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S60 This material and its container must be disposed of as hazardous waste.

S61 Avoid release to the environment. Refer to special instructions/ Safety Data Sheets.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
TETRAMETHYL LEAD75-74-1Yes DSL EIN Yes Yes No Yes Yes No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
TETRAMETHYL LEAD (75-74-1)

Acute toxicity Oral Category 1 H300 Fatal if swallowed

Acute toxicity Dermal Category 1 H310 Fatal in contact with skin

Acute toxicity Inhalation Category 1 H330 Fatal if inhaled

Carcinogenicity Category 2 H351 Suspected of causing cancer

Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
TETRAMETHYL LEAD (75-74-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H300 Fatal if swallowed

H310 Fatal in contact with skin

H330 Fatal if inhaled

H351 Suspected of causing cancer

H360Df May damage the unborn child. Suspected of damaging fertility

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P262 Do not get in eyes, on skin, or on clothing

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P361+P364 Remove/Take off immediately all contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
TETRAMETHYL LEAD (75-74-1)

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification, except those specified elsewhere in this Annex)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification, except those specified elsewhere in this Annex)

Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility (except those specified elsewhere in this Annex)

Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure; except those specified elsewhere in this Annex)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (except those specified elsewhere in this Annex)

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (except those specified elsewhere in this Annex)




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
TETRAMETHYL LEAD (75-74-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

H360Df May damage the unborn child. Suspected of damaging fertility

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
TETRAMETHYL LEAD (75-74-1)

Flammable Liquids Category 3 H226 Flammable liquid and vapour Approval: 20A2142

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 46

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled Approval: 46

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (nervous system) Approval: 46

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (liver,nervous system) Approval: 46

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 46

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 46




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
TETRAMETHYL LEAD (75-74-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H330 Fatal if inhaled

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
TETRAMETHYL LEAD (75-74-1)

MOE:Flammable liquids Category 3 H226 Flammable liquid and vapour.

Acute toxicity Oral Category 3 H301 Toxic if swallowed.

Hazardous to aquatic environment - chronic hazard Category 3 H412 Harmful to aquatic life with long lasting effects.
MOEL:Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Acute toxicity Inhalation - Vapour Category 2 H330 Fatal if inhaled

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
NEMA:Flammable Liquids Category 3 H226 Flammable liquid and vapour




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
TETRAMETHYL LEAD (75-74-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H330 Fatal if inhaled

H351 Suspected of causing cancer

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
TETRAMETHYL LEAD (75-74-1)

Taiwan:Flammable Liquids Category 3 H226 Flammable liquid and vapour
 Acute toxicity Oral Category 3 H301 Toxic if swallowed
 Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
 Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
 Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
TETRAMETHYL LEAD (75-74-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H361 Suspected of damaging fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 








* * * Section 16 - OTHER INFORMATION  * * *

Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved