* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
ACTIVATOR BA-62
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Product Use
curing agents
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: amber to brown
Change in color: Not available
Physical Form: liquid
Odor: pungent odor
Health Hazards: harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns
Physical Hazards: Flash back hazard. Combustible liquid and vapor.
Potential Health Effects
Inhalation
Short Term: burns, difficulty breathing, symptoms of drunkenness, dizziness
Long Term: same as effects reported in short term exposure
Skin Contact
Short Term: irritation (possibly severe), hyperactivity
Long Term: same as effects reported in short term exposure
Eye Contact
Short Term: irritation (possibly severe), eye damage
Long Term: same as effects reported in short term exposure
Ingestion
Short Term: burns
Long Term: same as effects reported in short term exposure
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
11070-44-3 234-290-7 -- | METHYL TETRAHYDROPHTHALIC ANHYDRIDE | Eye Dam. 1 - H318 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Note(s): C | 99 |
103-83-3 203-149-1 -- | BENZYL DIMETHYLAMINE | Flam. Liq. 3 - H226 Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Skin Corr. 1B - H314 Aquatic Chronic 3 - H412 | 1.0 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention.
Note to Physicians
For inhalation, consider oxygen.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 2 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Moderate fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point.
Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not get water inside container. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store under an inert atmosphere. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Protective Materials
rubber
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Liquid |
Odor | pungent odor | Color | amber to brown |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | 176 °C |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | 54 °C TCC |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | >1 | Specific Gravity (water=1) | 1.2 |
Water Solubility | (soluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | 100 cP 20 - 25 °C | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Volatility | 0 % | OSHA Flammability Class | II |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Keep out of water supplies and sewers.
Incompatible Materials
acids, bases, oxidizing materials, combustible materials
ACTIVATOR BA-62 ACIDS: Incompatible. BASES: Incompatible. OXIDIZERS (STRONG): Will react vigorously. BENZYL DIMETHYLAMINE ACIDS: Incompatible. ACID ANHYDRIDES: Incompatible. ACID CHLORIDES: Incompatible. CELLULOSE NITRATE: When an ethyl acetate solution of cellulose nitrate and other components were mixed in a lagged boiling tube, it showed large exotherms (which boiled the solvent off). OXIDIZERS (STRONG): Incompatible. METHYL TETRAHYDROPHTHALIC ANHYDRIDE ACIDS: Incompatible. ALKALIES: Incompatible. BASES: Incompatible. EPOXY RESINS: Incompatible under uncontrolled conditions. OXIDIZERS (STRONG): Fire and explosion hazard.
Hazardous Decomposition Products
aldehydes, oxides of carbon, various organic fragments
Thermal decomposition products: aldehydes, oxides of carbon, organic compounds.
Do not mix with an epoxy over 2 pound mass.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Oral LD50 Rat 1900 mg/kg
Dermal LD50 Rabbit 1410 mg/kg
BENZYL DIMETHYLAMINE (103-83-3)
Oral LD50 Rat 265 mg/kg
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Inhalation - Acute Exposure
ACTIVATOR BA-62 (Bacon Industries, Inc. reports the following): May cause headache, muscular weakness, paralysis, and nausea, dizziness and respiratory irritation METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May cause nasal irritation, central nervous system depression, or lung injury CORROSIVE SUBSTANCES: May cause severe irritation of the respiratory tract with coughing, choking, pain and possibly burns of the mucous membranes In some cases, pulmonary edema may develop, either immediately or more often within a period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include moist rales, low blood pressure and high pulse pressure Severe cases may be fatal.
Inhalation - Chronic Exposure
ACTIVATOR BA-62 (Bacon Industries, Inc. reports the following): May cause irritation and sensitization METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: Depending on the concentration and duration of exposure, repeated or prolonged exposure may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances.
Inhalation - Other Toxicity Information
BENZYL DIMETHYLAMINE: Exposure to a vapor-saturated atmosphere for 50 minutes was lethal to all rats Symptoms included excess salivation, labored breathing, ataxic movements, and tremors Animal exposure to concentrations of 227 ppm or higher resulted in acute inflammatory changes in the nasal mucosa, including epithelial cell necrosis, and pulmonary congestion in the respiratory tract See also information on corrosive substances.
Skin Contact - Acute Exposure
METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May be highly irritating to the skin Repeated skin contact may cause sensitization BENZYL DIMETHYLAMINE: An undiluted application of 0.01 mL to non-occluded skin of rabbits produced marked local erythema and edema Necrosis occurred following a four hour undiluted application of 0.5 mL to occluded skin Lethal doses produced tremors and hyperactivity in rabbits and a red mottled appearance of the liver and kidneys.
Skin Contact - Chronic Exposure
METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available BENZYL DIMETHYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in dermatitis or effects similar to acute exposure.
Skin Contact - Other Toxicity Information
ACTIVATOR BA-62 (Bacon Industries Inc. has reported the following) May cause severe skin injury (reddening and swelling) and an allergic reaction which may be severe in certain individuals.
Eye Contact - Acute Exposure
METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May cause mild to moderate irritation, and possible minor temporary corneal injury BENZYL DIMETHYLAMINE: An undiluted application of 0.005 mL to animals produced severe corneal injury, marked conjunctivitis and iritis Within seven days, these symptoms slowly resolved to normalcy.
Eye Contact - Chronic Exposure
METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available BENZYL DIMETHYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.
Eye - Other Toxicity Information
ACTIVATOR BA-62 (Bacon Industries Inc. has reported the following): May cause irritation and redness, especially when heated Minor temporary corneal injury is possible.
Ingestion - Acute Exposure
ACTIVATOR BA-62: No data available METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: May cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur.
Ingestion - Chronic Exposure
ACTIVATOR BA-62: No data available METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion.
Ingestion - Other Toxicity Information
BENZYL DIMETHYLAMINE See information on corrosive substances.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
BENZYL DIMETHYLAMINE | 103-83-3 |
Fish: | LC50 96 h Pimephales promelas 35.8 - 39.9 mg/L [flow-through] |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
Shipping Name: CORROSIVE LIQUIDS, N.O.S.
Hazard Class: 8
UN/NA #: UN1760
Packing Group: I
Required Label(s): 8
TDG Information:
No Classification assigned.
ADR Information:
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN#: UN1760
Packing Group: I
Required Label(s): 8
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
BENZYL DIMETHYLAMINE (103-83-3)
Restriction(s): D/E [UN2619] (II)
RID Information:
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN#: UN1760
Packing Group: I
Required Label(s): 8
IATA Information:
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN#: UN1760
Packing Group: I
Required Label(s): 8
ICAO Information:
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN#: UN1760
Packing Group: I
Required Label(s): 8
IMDG Information:
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN#: UN1760
Packing Group: I
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: Yes Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
BENZYL DIMETHYLAMINE | 103-83-3 | No | No | No | Yes | No |
Not listed under California Proposition 65
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
BENZYL DIMETHYLAMINE | 103-83-3 |
| 1 % |
Germany Water Classification
BENZYL DIMETHYLAMINE (103-83-3)
ID Number 1577 , hazard class 2 - hazard to waters
Symbol(s)
Xi Irritant
Risk Phrases
R10 Flammable.
R41 Risk of serious damage to eyes.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
METHYL TETRAHYDROPHTHALIC ANHYDRIDE | 11070-44-3 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
BENZYL DIMETHYLAMINE | 103-83-3 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
BENZYL DIMETHYLAMINE (103-83-3)
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H318 Causes serious eye damage
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BENZYL DIMETHYLAMINE (103-83-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H412 Harmful to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
BENZYL DIMETHYLAMINE (103-83-3)
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H318 Causes serious eye damage
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BENZYL DIMETHYLAMINE (103-83-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H412 Harmful to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3) Approval: H27-B-006/C-027B_P
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Skin Corrosion/Irritation Category 2 H315 Causes skin irritation
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects
BENZYL DIMETHYLAMINE (103-83-3)
Flammable Liquids Category 3 H226 Flammable liquid and vapour Approval: 20A2158
Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Approval: 20A2158
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 20A2158
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 20A2158
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 20A2158
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H318 Causes serious eye damage
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BENZYL DIMETHYLAMINE (103-83-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H402 Harmful to aquatic life
H412 Harmful to aquatic life with long lasting effects
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
MOEL: | Acute toxicity Oral Category 4 H302 Harmful if swallowed Skin Corrosion/Irritation Category 2 H315 Causes skin irritation Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled Skin Sensitization Category 1 H317 May cause allergic skin reaction Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects |
BENZYL DIMETHYLAMINE (103-83-3)
NEMA: | Flammable Liquids Category 3 H226 Flammable liquid and vapour |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H412 Harmful to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H226 Flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3) Approval: HSR004149
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
BENZYL DIMETHYLAMINE (103-83-3) Approval: HSR004576
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Skin Corrosion/Irritation Category 1C H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,crustacean,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H318 Causes serious eye damage
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
BENZYL DIMETHYLAMINE (103-83-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H412 Harmful to aquatic life with long lasting effects
H433 Harmful to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
BENZYL DIMETHYLAMINE (103-83-3)
Listing: Present (>=25% by mass)
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
BENZYL DIMETHYLAMINE (103-83-3)
Taiwan: | Flammable Liquids Category 3 H226 Flammable liquid and vapour |
| Acute toxicity Oral Category 3 H301 Toxic if swallowed |
| Acute toxicity Dermal Category 4 H312 Harmful in contact with skin |
| Acute toxicity Inhalation Category 4 H332 Harmful if inhaled |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
BENZYL DIMETHYLAMINE (103-83-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H301 Toxic if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved