ZIRCONYL NITRATE

inorganic, salt 

ZIRCONIUM, BIS(NITRATO-O)OXO-; ZIRCONIUM, DINITRATOOXO-; DINITRATOOXOZIRCONIUM; BIS(NITRATO)OXOZIRCONIUM; BIS(NITRATO-O)OXOZIRCONIUM; ZIRCONIUM DINITRATE OXIDE; ZIRCONIUM OXIDE DINITRATE; ZIRCONIUM OXYNITRATE; ZIRCONIUM OXYNITRATE (ZRO(NO3)2); ZIRCONYL DINITRATE; ZIRCONYL NITRATE (ZRO(NO3)2); N2O7ZR

Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: crystals

Physical Hazards:  May ignite combustibles. 

Short Term:  irritation, vomiting, headache, dizziness, bluish skin color, coma 

Long Term:  no information on significant adverse effects 

Short Term:  no information on significant adverse effects 

Long Term:  no information on significant adverse effects 

Short Term:  irritation 

Long Term:  no information is available 

Short Term:  same as effects reported in other routes of exposure 

Long Term:  diarrhea, bluish skin color, liver damage 

This product may be regulated, have exposure limits or other information identified as the following: Zirconium compounds, n.o.s.

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 

For ingestion, consider gastric lavage and activated charcoal slurry. 

See Section 9 for Flammability Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 

water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance. 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile). 

Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. 

Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: Zirconium (Zr) 25 mg/m3 Any quarter-mask respirator. 50 mg/m3 Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any supplied-air respirator. Any self-contained breathing apparatus with a full facepiece. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. 

Stable at normal temperatures and pressure. 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers. 

combustible materials, reducing agents, 

ZIRCONYL NITRATE: COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. REDUCING AGENTS: Fire and explosion hazard.

oxides of nitrogen 

Thermal decomposition products: oxides of nitrogen.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

respiratory disorders, skin disorders and allergies, 

ZIRCONYL NITRATE: Some zirconium compounds may cause irritation to the mucous membranes of the respiratory tract Nitrate poisoning may cause headache, flushing of the skin, vomiting, dizziness, cyanosis, fall in blood pressure, collapse, coma, and possible death from respiratory paralysis.

ZIRCONYL NITRATE: Studies of occupational zirconium inhalation failed to detect pulmonary abnormalities However, animal experiments have produced interstitial pneumonitis, peribronchial abscesses, peribronchiolar granuloma, and lobular pneumonia Intratracheal doses with various zirconium compounds caused fibrous lung changes and liver necrosis in animals.

ZIRCONYL NITRATE Some zirconium compounds may cause sensitization reactions, including granulomas, in previously exposed persons.

ZIRCONYL NITRATE Repeated contact with some zirconium compounds have produced allergic granulomas and sensitization dermatitis, characterized by dusky red-brown papules.

ZIRCONYL NITRATE Some zirconium compounds dust may cause irritation.

ZIRCONYL NITRATE No data available.

ZIRCONYL NITRATE: Oral administration of zirconium compounds to animals caused gastrointestinal tract necrosis, renal and hepatic dystrophy, hemorrhage, weakness, and death by respiratory and circulatory paralysis Nitrate poisoning may cause symptoms as detailed in acute inhalation Rarely, inorganic nitrates may be converted to nitrites by nitrate-reducing bacteria in the digestive tract, resulting in methemoglobinemia.

ZIRCONYL NITRATE: Repeated administration of zirconium compounds caused weight loss, weakness, diarrhea, liver damage, and death in animals Repeated or prolonged exposure to nitrates may cause anemia, nephritis, and possibly methemoglobinemia.

Component Analysis - Aquatic Toxicity 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Korea GHS Classifications 

New Zealand GHS Classifications 

South Africa GHS Classifications 

Taiwan GHS Classifications 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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