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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

ACTIVATOR BA-62

ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.







Product Use 

curing agents 








* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  amber to brown 

Change in color: Not available

Physical Form: liquid

Odor:  pungent odor 

Health Hazards:  harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  Flash back hazard. Combustible liquid and vapor. 



Potential Health Effects 
Inhalation 

Short Term:  burns, difficulty breathing, symptoms of drunkenness, dizziness 

Long Term:  same as effects reported in short term exposure 



Skin Contact 

Short Term:  irritation (possibly severe), hyperactivity 

Long Term:  same as effects reported in short term exposure 



Eye Contact 

Short Term:  irritation (possibly severe), eye damage 

Long Term:  same as effects reported in short term exposure 



Ingestion 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 














* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
11070-44-3 234-290-7 --METHYL TETRAHYDROPHTHALIC ANHYDRIDEEye Dam. 1 - H318 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Note(s): C99
103-83-3 203-149-1 --BENZYL DIMETHYLAMINEFlam. Liq. 3 - H226 Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Acute Tox. 4 (Inh.) - H332 Skin Corr. 1B - H314 Aquatic Chronic 3 - H4121.0










* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 

Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 

Eyes 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Ingestion 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention. 

Note to Physicians 

For inhalation, consider oxygen. 








* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 2 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe



Flammable Properties 

Moderate fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. 

Extinguishing Media 

regular dry chemical, carbon dioxide, water, regular foam 

Large fires: Use regular foam or flood with fine water spray. 

Fire Fighting Measures 

Move container from fire area if it can be done without risk. Do not get water inside container. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 








* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 








* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store under an inert atmosphere. Keep separated from incompatible substances. 








* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 



Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 



Ventilation 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 

PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Protective Clothing 

Wear appropriate chemical resistant clothing. 

Glove Recommendations 

Wear appropriate chemical resistant gloves. 

Protective Materials 

rubber 

Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 








* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Liquid
Odor pungent odorColor amber to brown
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point 176 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point 54 °C TCC
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) >1Specific Gravity (water=1) 1.2
Water Solubility (soluble)Partition coefficient: n-octanol/water Not available 
Viscosity 100 cP 20 - 25 °CSolubility (Other) Not available 
Density Not available Physical Form liquid
Volatility 0 %OSHA Flammability Class II










* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 

Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Keep out of water supplies and sewers. 

Incompatible Materials 

acids, bases, oxidizing materials, combustible materials 

ACTIVATOR BA-62 ACIDS: Incompatible. BASES: Incompatible. OXIDIZERS (STRONG): Will react vigorously. BENZYL DIMETHYLAMINE ACIDS: Incompatible. ACID ANHYDRIDES: Incompatible. ACID CHLORIDES: Incompatible. CELLULOSE NITRATE: When an ethyl acetate solution of cellulose nitrate and other components were mixed in a lagged boiling tube, it showed large exotherms (which boiled the solvent off). OXIDIZERS (STRONG): Incompatible. METHYL TETRAHYDROPHTHALIC ANHYDRIDE ACIDS: Incompatible. ALKALIES: Incompatible. BASES: Incompatible. EPOXY RESINS: Incompatible under uncontrolled conditions. OXIDIZERS (STRONG): Fire and explosion hazard.

Hazardous Decomposition Products 

aldehydes, oxides of carbon, various organic fragments 

Thermal decomposition products: aldehydes, oxides of carbon, organic compounds. 

Do not mix with an epoxy over 2 pound mass. 






* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Oral LD50 Rat 1900 mg/kg

Dermal LD50 Rabbit 1410 mg/kg

BENZYL DIMETHYLAMINE (103-83-3)

Oral LD50 Rat 265 mg/kg



Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA



Inhalation - Acute Exposure 

ACTIVATOR BA-62 (Bacon Industries, Inc. reports the following): May cause headache, muscular weakness, paralysis, and nausea, dizziness and respiratory irritation METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May cause nasal irritation, central nervous system depression, or lung injury CORROSIVE SUBSTANCES: May cause severe irritation of the respiratory tract with coughing, choking, pain and possibly burns of the mucous membranes In some cases, pulmonary edema may develop, either immediately or more often within a period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include moist rales, low blood pressure and high pulse pressure Severe cases may be fatal.

Inhalation - Chronic Exposure 

ACTIVATOR BA-62 (Bacon Industries, Inc. reports the following): May cause irritation and sensitization METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: Depending on the concentration and duration of exposure, repeated or prolonged exposure may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances.

Inhalation - Other Toxicity Information 

BENZYL DIMETHYLAMINE: Exposure to a vapor-saturated atmosphere for 50 minutes was lethal to all rats Symptoms included excess salivation, labored breathing, ataxic movements, and tremors Animal exposure to concentrations of 227 ppm or higher resulted in acute inflammatory changes in the nasal mucosa, including epithelial cell necrosis, and pulmonary congestion in the respiratory tract See also information on corrosive substances.

Skin Contact - Acute Exposure 

METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May be highly irritating to the skin Repeated skin contact may cause sensitization BENZYL DIMETHYLAMINE: An undiluted application of 0.01 mL to non-occluded skin of rabbits produced marked local erythema and edema Necrosis occurred following a four hour undiluted application of 0.5 mL to occluded skin Lethal doses produced tremors and hyperactivity in rabbits and a red mottled appearance of the liver and kidneys.

Skin Contact - Chronic Exposure 

METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available BENZYL DIMETHYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in dermatitis or effects similar to acute exposure.

Skin Contact - Other Toxicity Information 

ACTIVATOR BA-62 (Bacon Industries Inc. has reported the following) May cause severe skin injury (reddening and swelling) and an allergic reaction which may be severe in certain individuals.

Eye Contact - Acute Exposure 

METHYL TETRAHYDROPHTHALIC ANHYDRIDE: May cause mild to moderate irritation, and possible minor temporary corneal injury BENZYL DIMETHYLAMINE: An undiluted application of 0.005 mL to animals produced severe corneal injury, marked conjunctivitis and iritis Within seven days, these symptoms slowly resolved to normalcy.

Eye Contact - Chronic Exposure 

METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available BENZYL DIMETHYLAMINE: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.

Eye - Other Toxicity Information 

ACTIVATOR BA-62 (Bacon Industries Inc. has reported the following): May cause irritation and redness, especially when heated Minor temporary corneal injury is possible.

Ingestion - Acute Exposure 

ACTIVATOR BA-62: No data available METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: May cause immediate pain and severe burns of the mucous membranes There may be discoloration of the tissues Swallowing and speech may be difficult at first and then almost impossible The effects on the esophagus and gastrointestinal tract may range from irritation to severe corrosion Edema of the epiglottis and shock may occur.

Ingestion - Chronic Exposure 

ACTIVATOR BA-62: No data available METHYL TETRAHYDROPHTHALIC ANHYDRIDE: No data available CORROSIVE SUBSTANCES: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion.

Ingestion - Other Toxicity Information 

BENZYL DIMETHYLAMINE See information on corrosive substances.








* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

BENZYL DIMETHYLAMINE103-83-3
Fish: LC50 96 h Pimephales promelas 35.8 - 39.9 mg/L [flow-through]














* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 










* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: CORROSIVE LIQUIDS, N.O.S.

Hazard Class: 8

UN/NA #: UN1760

Packing Group: I

Required Label(s): 8



TDG Information:

No Classification assigned.



ADR Information:

Shipping Name: CORROSIVE LIQUID, N.O.S.

Hazard Class: 8

UN#: UN1760

Packing Group: I

Required Label(s): 8

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
BENZYL DIMETHYLAMINE (103-83-3)

Restriction(s): D/E [UN2619] (II)







RID Information:

Shipping Name: CORROSIVE LIQUID, N.O.S.

Hazard Class: 8

UN#: UN1760

Packing Group: I

Required Label(s): 8



IATA Information:

Shipping Name: CORROSIVE LIQUID, N.O.S.

Hazard Class: 8

UN#: UN1760

Packing Group: I

Required Label(s): 8



ICAO Information:

Shipping Name: CORROSIVE LIQUID, N.O.S.

Hazard Class: 8

UN#: UN1760

Packing Group: I

Required Label(s): 8



IMDG Information:

Shipping Name: CORROSIVE LIQUID, N.O.S.

Hazard Class: 8

UN#: UN1760

Packing Group: I

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 














* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 



SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: Yes Pressure: No Reactivity: No







U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
BENZYL DIMETHYLAMINE103-83-3No No No Yes No 



Not listed under California Proposition 65 



Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
BENZYL DIMETHYLAMINE103-83-3
 1 %







Germany Water Classification 

BENZYL DIMETHYLAMINE (103-83-3)

ID Number 1577 , hazard class 2 - hazard to waters







Symbol(s)

Xi Irritant

Risk Phrases

R10 Flammable.

R41 Risk of serious damage to eyes.



Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE11070-44-3Yes DSL EIN Yes Yes Yes Yes Yes Yes 
BENZYL DIMETHYLAMINE103-83-3Yes DSL EIN Yes Yes Yes Yes Yes Yes 







Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

BENZYL DIMETHYLAMINE (103-83-3)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H318 Causes serious eye damage

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BENZYL DIMETHYLAMINE (103-83-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H314 Causes severe skin burns and eye damage

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

BENZYL DIMETHYLAMINE (103-83-3)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects



European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H318 Causes serious eye damage

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BENZYL DIMETHYLAMINE (103-83-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H314 Causes severe skin burns and eye damage

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3) Approval: H27-B-006/C-027B_P

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

BENZYL DIMETHYLAMINE (103-83-3)

Flammable Liquids Category 3 H226 Flammable liquid and vapour Approval: 20A2158

Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Approval: 20A2158

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 20A2158

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life Approval: 20A2158

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects Approval: 20A2158



Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H315 Causes skin irritation

H318 Causes serious eye damage

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H402 Harmful to aquatic life

H411 Toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BENZYL DIMETHYLAMINE (103-83-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H402 Harmful to aquatic life

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

MOEL:Acute toxicity Oral Category 4 H302 Harmful if swallowed

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects


BENZYL DIMETHYLAMINE (103-83-3)

NEMA:Flammable Liquids Category 3 H226 Flammable liquid and vapour



Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H315 Causes skin irritation

H319 Causes serious eye irritation

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H412 Harmful to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3) Approval: HSR004149

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

BENZYL DIMETHYLAMINE (103-83-3) Approval: HSR004576

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Skin Corrosion/Irritation Category 1C H314 Causes severe skin burns and eye damage

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,crustacean,fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates



New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
METHYL TETRAHYDROPHTHALIC ANHYDRIDE (11070-44-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H318 Causes serious eye damage

H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled

H317 May cause allergic skin reaction

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

BENZYL DIMETHYLAMINE (103-83-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H412 Harmful to aquatic life with long lasting effects

H433 Harmful to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
BENZYL DIMETHYLAMINE (103-83-3)

Listing: Present (>=25% by mass)



Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BENZYL DIMETHYLAMINE (103-83-3)

Taiwan:Flammable Liquids Category 3 H226 Flammable liquid and vapour
 Acute toxicity Oral Category 3 H301 Toxic if swallowed
 Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
 Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
 Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage
 Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage



Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BENZYL DIMETHYLAMINE (103-83-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H301 Toxic if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations











Classification 

No classification assigned. 








* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 





Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved