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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

ZINC BROMATE HEXAHYDRATE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

inorganic, salt 


Synonyms 

ZINC BROMATE; UN 2469; Br2H12O7Zn









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  white 

Change in color: deliquescent

Physical Form: solid

Physical Hazards:  May ignite combustibles. 




Potential Health Effects 
Inhalation 

Short Term:  no information is available 

Long Term:  no information is available 




Skin Contact 

Short Term:  burns 

Long Term:  no information on significant adverse effects 




Eye Contact 

Short Term:  no information is available 

Long Term:  no information is available 




Ingestion 

Short Term:  nausea, vomiting, diarrhea, stomach pain 

Long Term:  digestive disorders 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
13517-27-6 -- --ZINC BROMATE HEXAHYDRATE--100.0











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 


Note to Physicians 

For ingestion, consider gastric lavage. 


Antidote 

calcium disodium edetate/dextrose, intravenous; calcium disodium edetate/procaine, intramuscular. sodium thiosulfate, intravenous. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 1 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 


Extinguishing Media 

water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile). 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor Not available Color white
Odor Threshold Not available pH Not available 
Melting Point 100 °CBoiling Point 200 °C (becomes anhydrous)
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) 2.566
Water Solubility (soluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Change in color deliquescentDensity Not available 
Physical Form solidMolecular Formula Zn-(Br-O3)2.6H2-O
Molecular Weight 349.29  











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers. 


Incompatible Materials 

combustible materials, reducing agents, 


See oxidizers. OXIDIZERS: COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. REDUCING MATERIALS: Fire and explosion hazard.

Hazardous Decomposition Products 

miscellaneous decomposition products 


Thermal decomposition products: miscellaneous decomposition products.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

ZINC BROMATE No data available.


Inhalation - Chronic Exposure 

ZINC BROMATE No data available.


Skin Contact - Acute Exposure 

ZINC SALTS Soluble zinc salts are astringent and corrosive and may be easily absorbed through the skin.


Skin Contact - Chronic Exposure 

ZINC SALTS No data available.


Skin Contact - Other Toxicity Information 

ZINC BROMATE See information on zinc salts.


Eye Contact - Acute Exposure 

ZINC BROMATE No data available.


Eye Contact - Chronic Exposure 

ZINC BROMATE No data available.


Ingestion - Acute Exposure 

ZINC SALTS: Small doses may cause nausea and vomiting In addition to these symptoms, large doses may cause fever, stomach cramps, diarrhea, and fatal collapse due to serious damage to the buccal and gastroenteric mucous membranes.


Ingestion - Chronic Exposure 

ZINC SALTS Continued administration of small doses may cause digestive disorders and constipation.


Ingestion - Other Toxicity Information 

ZINC BROMATE: Toxic doses of bromates may cause nausea and vomiting with epigastric pain They may also affect the kidneys, liver, heart, and the central nervous system See information on zinc salts.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN/NA #: UN2469

Packing Group: III

Required Label(s): 5.1




TDG Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Required Label(s): 5.1




ADR Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Required Label(s): 5.1




RID Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Required Label(s): 5.1




IATA Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Required Label(s): 5.1




ICAO Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Required Label(s): 5.1




IMDG Information:

Shipping Name: ZINC BROMATE

Hazard Class: 5.1

UN#: UN2469

Packing Group: III

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: No Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA 




Not listed under California Proposition 65 




Risk Phrases

R8 Contact with combustible material may cause fire.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
ZINC BROMATE HEXAHYDRATE13517-27-6No No No No No No No No No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved