危险化学品
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Material Name: VERNAM 6E SDS ID: ohsae950 Issue Date: 2016-06-24 Revision: 2.07 |
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
VERNAM 6E | ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Chemical Family
sulfur compounds, carbamates Synonyms
476-1807 * * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Change in color: Not available
Physical Form: emulsifiable concentrate
Potential Health Effects
Inhalation
Short Term: no information on significant adverse effects Long Term: no information is available
Skin Contact
Short Term: no information on significant adverse effects Long Term: no information is available
Eye Contact
Short Term: irritation Long Term: no information on significant adverse effects
Ingestion
Short Term: no information on significant adverse effects Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
| CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
| 1929-77-7 217-681-7 -- | VERNOLATE | Acute Tox. 4 (Oral) - H302 Aquatic Chronic 2 - H411 | 77.3800 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Ingestion
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. Note to Physicians
For ingestion, consider activated charcoal slurry and catharsis. * * * Section 5 - FIRE FIGHTING MEASURES * * *
NFPA Ratings:
Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Slight fire hazard. Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. * * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. * * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. May be subject to EPA pesticide registration. * * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components
Component Analysis
Biological limit value There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Clothing
Wear appropriate chemical resistant clothing. Glove Recommendations
Wear appropriate chemical resistant gloves. Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. * * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
| Appearance | Not available | Physical State | Unknown |
| Odor | Not available | Color | Not available |
| Odor Threshold | Not available | pH | Not available |
| Melting Point | Not available | Boiling Point | Not available |
| Freezing point | Not available | Evaporation Rate | Not available |
| Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
| Autoignition | Not available | Flash Point | Not available |
| Lower Explosive Limit | Not available | Decomposition | Not available |
| Upper Explosive Limit | Not available | Vapor Pressure | Not available |
| Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
| Water Solubility | Not available | Partition coefficient: n-octanol/water | Not available |
| Viscosity | Not available | Solubility (Other) | Not available |
| Density | Not available | Physical Form | emulsifiable concentrate |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure. Stable at normal temperatures and pressure. VERNOLATE No data available.
Hazardous Decomposition Products
oxides of nitrogen, sulfur Thermal decomposition products: oxides of nitrogen, sulfur.
Possibility of Hazardous Reactions
Will not polymerize. Will not polymerize. * * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
VERNOLATE (1929-77-7)
Oral LD50 Rat 1200 mg/kg
Oral LD50 Rat 1200 mg/kg
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Inhalation - Acute Exposure
VERNOLATE Inhalation of excessive amounts of some thiocarbamates causes scratchy throat, sneezing, and coughing. Inhalation - Chronic Exposure
VERNOLATE No data available. Skin Contact - Acute Exposure
VERNOLATE A lethal dose in rabbits by dermal absorption is greater than 2955 mg/kg. Skin Contact - Chronic Exposure
VERNOLATE No data available. Eye Contact - Acute Exposure
VERNOLATE May cause irritation. Eye Contact - Chronic Exposure
VERNOLATE Prolonged or repeated exposure may cause irritation. Ingestion - Acute Exposure
VERNOLATE A lethal dose in rats was 1200 mg/kg. Ingestion - Chronic Exposure
VERNOLATE: A dose of 80 mg/kg/day for 51 weeks produced a significantly increased mortality in male rats due to hemorrhage A dose of 20 mg/kg/day for 51 weeks produced an increase in blood clotting time No delayed neurotoxicity was observed in a study of hens In a 24 month study of mice, no oncogenic effects were observed at levels as high as 100 mg/kg/day. * * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
May be subject to EPA pesticide registration. Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
No Classification assigned.
TDG Information:
No Classification assigned.
No Classification assigned.
ADR Information:
No Classification assigned.
No Classification assigned.
RID Information:
No Classification assigned.
No Classification assigned.
IATA Information:
No Classification assigned.
No Classification assigned.
ICAO Information:
No Classification assigned.
No Classification assigned.
IMDG Information:
No Classification assigned.
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: No Pressure: No Reactivity: No
U.S. State Regulations
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA
Not listed under California Proposition 65
Symbol(s)
Xn Harmful
N Dangerous for the Environment
Risk Phrases
R22 Harmful if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Xn Harmful
N Dangerous for the Environment
Risk Phrases
R22 Harmful if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Analysis - Inventory
| Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
| VERNOLATE | 1929-77-7 | No | No | EIN | Yes | No | No | No | No | No |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
VERNOLATE (1929-77-7)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
VERNOLATE (1929-77-7)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H411 Toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H411 Toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
VERNOLATE (1929-77-7)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
VERNOLATE (1929-77-7)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H411 Toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H411 Toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
VERNOLATE (1929-77-7) Approval: 23A5095
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (blood)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (blood)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
VERNOLATE (1929-77-7)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
South Africa GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Classification
No classification assigned. * * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved