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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

2,3-DIHYDROPYRAN


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

heterocyclic 


Synonyms 

3,4-DIHYDRO-2H-PYRAN; DIHYDROPYRAN; DELTA-DIHYDROPYRAN; 2H-3,4-DIHYDROPYRAN; 3,4-DIHYDROPYRAN; UN 2376; 2H-PYRAN, 3,4-DIHYDRO-; 2,3-DIHYDRO-GAMMA-PYRAN; 2,3-DIHYDRO-4H-PYRAN; 3,4-DIHYDRO-2(H)-PYRAN; 5,6-DIHYDRO-4H-PYRAN; DIHYDRO-2H-PYRAN; PYRAN, DIHYDRO-









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: volatile liquid

Odor:  sweet odor 

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation 

Physical Hazards:  Extremely flammable liquid and vapor. Vapor may cause flash fire. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, difficulty breathing 

Long Term:  no information is available 




Skin Contact 

Short Term:  irritation 

Long Term:  no information is available 




Eye Contact 

Short Term:  irritation, blurred vision 

Long Term:  no information is available 




Ingestion 

Short Term:  sore throat, nausea, stomach pain 

Long Term:  no information is available 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
110-87-2 203-810-4 --2,3-DIHYDROPYRAN--100











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If a large amount is swallowed, get medical attention. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 2 Fire: 3 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. 


Extinguishing Media 

alcohol-resistant foam, carbon dioxide, regular dry chemical, water, alcohol-resistant foam Large fires: Use alcohol-resistant foam or flood with fine water spray. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Remove sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance clearPhysical State Liquid
Odor sweet odorColor colorless
Odor Threshold Not available pH Not available 
Melting Point 70 °CBoiling Point 86 °C
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point -18 °C TCC
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) 2.9Specific Gravity (water=1) 0.922 at 19 °C
Water Solubility (soluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form volatile liquid
Molecular Formula C5-H8-OMolecular Weight 84.13
OSHA Flammability Class IB  




Solvent Solubility 
Soluble 

alcohol 













* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. 


Incompatible Materials 

oxidizing materials 


2,3-DIHYDROPYRAN: OXIDIZING MATERIALS: Vigorous reaction

Hazardous Decomposition Products 

miscellaneous decomposition products 


Thermal decomposition products: miscellaneous decomposition products.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

2,3-DIHYDROPYRAN Inhalation may irritate the respiratory tract and may cause sore throat, coughing, and shortness of breath.


Inhalation - Chronic Exposure 

2,3-DIHYDROPYRAN No data available.


Skin Contact - Acute Exposure 

2,3-DIHYDROPYRAN It may cause redness and pain.


Skin Contact - Chronic Exposure 

2,3-DIHYDROPYRAN No data available.


Eye Contact - Acute Exposure 

2,3-DIHYDROPYRAN Exposure may cause redness, pain, and blurred vision.


Eye Contact - Chronic Exposure 

2,3-DIHYDROPYRAN No data available.


Ingestion - Acute Exposure 

2,3-DIHYDROPYRAN Ingestion may cause sore throat, abdominal pain, and nausea.


Ingestion - Chronic Exposure 

2,3-DIHYDROPYRAN No data available.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN/NA #: UN2376

Packing Group: II

Required Label(s): 3




TDG Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Required Label(s): 3




ADR Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Required Label(s): 3

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
2,3-DIHYDROPYRAN (110-87-2)

Restriction(s): D/E [UN2376] (II)








RID Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Required Label(s): 3




IATA Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Required Label(s): 3




ICAO Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Required Label(s): 3




IMDG Information:

Shipping Name: 2,3-DIHYDROPYRAN

Hazard Class: 3

UN#: UN2376

Packing Group: II

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
2,3-DIHYDROPYRAN110-87-2No Yes No Yes Yes 




Not listed under California Proposition 65 




Germany Water Classification 

2,3-DIHYDROPYRAN (110-87-2)

ID Number 8907 , hazard class 1 - low hazard to waters








Symbol(s)

F Highly Flammable

Xi Irritant

Risk Phrases

R11 Highly flammable.

R36 Irritating to eyes.

R37 Irritating to respiratory system.

R38 Irritating to skin.

Safety Phrases

S2 Keep out of the reach of children.

S24 Avoid contact with skin.

S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S46 If swallowed, seek medical advice immediately and show this container or label.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
2,3-DIHYDROPYRAN110-87-2Yes DSL EIN Yes Yes Yes No Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2,3-DIHYDROPYRAN (110-87-2) Approval: 21A3643

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Self-Reactive Substances and Mixtures Type G




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2,3-DIHYDROPYRAN (110-87-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
2,3-DIHYDROPYRAN (110-87-2)

NEMA:Flammable Liquids Category 2 H225 Highly flammable liquid and vapour




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
2,3-DIHYDROPYRAN (110-87-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
2,3-DIHYDROPYRAN (110-87-2) Approval: HSR001129

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 2 H315 Causes skin irritation

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal,crustacean)




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
2,3-DIHYDROPYRAN (110-87-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H332 Harmful if inhaled

H315 Causes skin irritation

H412 Harmful to aquatic life with long lasting effects

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P332+P313 If skin irritation occurs: Get medical advice/attention

P321 Specific treatment (see label)

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved