危险化学品
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Material Name: 4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE SDS ID: ohs68904 Issue Date: 2016-06-23 Revision: 2.05 |
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE
| ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
nitriles, aromatic
1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE, 4,5-DICHLORO-3,6-DIOXO-; 2,3-DICHLORO-5,6-DICYANO-1,4-BENZOQUINONE; 2,3-DICHLORO-5,6-DICYANO-PARA-BENZOQUINONE; 2,3-DICHLORO-5,6-DICYANOBENZOQUINONE; DDQ (OXIDIZING AGENT); DICHLORODICYANOBENZOQUINONE; DICHLORODICYANO-PARA-BENZOQUINONE; DICHLORODICYANOQUINONE; C8CL2N202; RTECS: GU4825000
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: yellow to orange
Change in color: Not available
Physical Form: crystals, powder
Physical Hazards: Dust/air mixtures may ignite or explode. May ignite combustibles.
Short Term: irritation
Long Term: no information is available
Short Term: irritation
Long Term: no information is available
Short Term: irritation
Long Term: no information is available
Short Term: no information is available
Long Term: no information is available
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
| CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
| 84-58-2 201-542-2 -- | 4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE | -- | 100.0 |
* * * Section 4 - FIRST AID MEASURES * * *
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If a large amount is swallowed, get medical attention.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Slight fire hazard. Dust/air mixtures may ignite or explode. Oxidizer. May ignite or explode on contact with combustible materials.
water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance.
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile).
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Store and handle in accordance with all current regulations and standards. Store below 0 C. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
Biological limit value
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
| Appearance | Not available | Physical State | Solid |
| Odor | Not available | Color | yellow to orange |
| Odor Threshold | Not available | pH | Not available |
| Melting Point | Not available | Boiling Point | Not available |
| Freezing point | Not available | Evaporation Rate | Not available |
| Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
| Autoignition | Not available | Flash Point | Not available |
| Lower Explosive Limit | Not available | Decomposition | 210 - 216 °C |
| Upper Explosive Limit | Not available | Vapor Pressure | Not available |
| Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
| Water Solubility | (decomposes) | Partition coefficient: n-octanol/water | Not available |
| Viscosity | Not available | Solubility (Other) | Not available |
| Density | Not available | Physical Form | crystals, powder |
| Molecular Formula | C-O-C-CL-C-CL-C-O-C-(C-N)-C-C-N | Molecular Weight | 227.01 |
benzene, dioxane, acetic acid
chloroform, dichloromethane
* * * Section 10 - STABILITY AND REACTIVITY * * *
Stable at normal temperatures and pressure.
Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers.
acids, bases, combustible materials, reducing agents,
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE: ACIDS (STRONG): Incompatible. BASES (STRONG): Incompatible. COMBUSTIBLE MATERIALS: Fire and explosion hazard. REDUCING AGENTS: Fire and explosion hazard.
cyanides, hydrochloric acid, oxides of carbon, nitrogen
Thermal decomposition products: hydrogen cyanide, hydrochloric acid, oxides of carbon, nitrogen.
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE May cause irritation.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE No data available.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE May cause irritation.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE No data available.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE May cause irritation.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE No data available.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE No data available.
4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE No data available.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Dispose in accordance with all applicable regulations.
Component Waste Numbers
* * * Section 14 - TRANSPORT INFORMATION * * *
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
No Classification assigned.
Component Marine Pollutants (IMDG)
* * * Section 15 - REGULATORY INFORMATION * * *
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Not listed under California Proposition 65
O Oxidizing
Risk Phrases
R8 Contact with combustible material may cause fire.
| Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
| 4,5-DICHLORO-3,6-DIOXO-1,4-CYCLOHEXADIENE-1,2-DICARBONITRILE | 84-58-2 | Yes | DSL | EIN | Yes | Yes | Yes | No | Yes | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
This material may be hazardous according to published criteria for classification
European Union GHS Classifications
This material may be hazardous according to published criteria for classification
Indonesia GHS Classifications
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
This material may be hazardous according to published criteria for classification
Korea GHS Classifications
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
Oxidizing Liquids Category 3 H272 May intensify fire, oxidizer
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
New Zealand GHS Labeling Information
Symbol(s)
Signal Word Warning
Hazard(s)
H272 May intensify fire, oxidizer
H319 Causes serious eye irritation
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P370+P378 In case of fire: Use appropriate media for extinction
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
This material may be hazardous according to published criteria for classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
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