Safety Data Sheet: Material Name: WASP & HORNET KILLER II SDS ID: ohsei406 Issue Date: 2016-06-27 Revision: 2.09

                

WASP & HORNET KILLER II

ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237 E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.

pesticide 

Emergency Overview 

Color:  yellow 

Change in color: Not available

Physical Form: aerosol

Odor:  distinct odor 

Health Hazards:  aspiration hazard, central nervous system depression, difficulty breathing 

Physical Hazards:  Containers may rupture or explode if exposed to heat. 

Short Term:  irritation, ringing in the ears, nausea, irregular heartbeat, headache, drowsiness, symptoms of drunkenness, tingling sensation, visual disturbances, suffocation, lung congestion 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation, tearing, blurred vision 

Long Term:  no information on significant adverse effects 

Short Term:  ingestion of a gas is unlikely 

Long Term:  no information is available 

CAS EC No Registration No	Component Name Synonyms	1272/2008 (CLP)	Percent
64742-48-9 265-150-3 --	HYDROTREATED HEAVY NAPHTHA	Muta. 1B - H340 Carc. 1B - H350 Asp. Tox. 1 - H304 Note(s): P	96.74
124-38-9 204-696-9 --	CARBON DIOXIDE, GAS	--	3.00
28057-48-9 -- --	D-TRANS ALLETHRIN	--	0.129
26002-80-2 247-404-5 --	PHENOTHRIN	--	0.120

This product may be regulated, have exposure limits or other information identified as the following: Carbon dioxide and ethylene oxide mixtures (8070-50-6), D-Trans-allethrin [D-trans-Chrysanthemic acid of D-allethrone] (28057-48-9).









If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 



Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 



Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 



If a large amount is swallowed, get medical attention. 









See Section 9 for Flammability Properties 



Severe fire hazard. Containers may rupture or explode if exposed to heat. 



carbon dioxide, regular dry chemical 



Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Small spills of the liquid component: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Spills with a large number of canisters: Reduce vapors with water spray. Remove sources of ignition. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Grounding and bonding required. See original container for storage recommendations. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 



Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 



Eyes/Face Eye protection not required under normal conditions. 



Protective clothing is not required under normal conditions. 



Protective gloves are not required under normal conditions. 



No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. 

Appearance	Not available	Physical State	Aerosol
Odor	distinct odor	Color	yellow
Odor Threshold	Not available	pH	Not available
Melting Point	Not available	Boiling Point	Not available
Freezing point	Not available	Evaporation Rate	Not available
Boiling Point Range	Not available	Flammability (solid, gas)	Not available
Autoignition	Not available	Flash Point	62 °C TCC
Lower Explosive Limit	Not available	Decomposition	Not available
Upper Explosive Limit	Not available	Vapor Pressure	100 psig at 21 °C
Vapor Density (air=1)	Not available	Specific Gravity (water=1)	0.8
Water Solubility	(almost insoluble)	Partition coefficient: n-octanol/water	Not available
Viscosity	Not available	Solubility (Other)	Not available
Density	Not available	Physical Form	aerosol
Volatility	100 %

Stable at normal temperatures and pressure. 



Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Containers may rupture or explode if exposed to heat. 



oxidizing materials, combustible materials, metal salts, reducing agents, metal carbide, metals, bases 

WASP & HORNET KILLER II No data available. CARBON DIOXIDE ACRYLALDEHYDE: Exothermic polymerization. BARIUM PEROXIDE: Incandescent reaction. CESIUM OXIDE: Ignition. DIETHYL MAGNESIUM: Ignition. ETHYLENEIMINE: Explosive polymerization. HYDRAZINE: Decomposition. METAL ACETYLIDES: Ignition or incandescence. METAL HYDRIDES: Reduction reaction. METALS: Dusts of many metals suspended in carbon dioxide atmospheres are ignitable and explosive; some bulk metals will burn in the gas at elevated temperatures. POTASSIUM: Mixtures of the solids are impact-sensitive. POTASSIUM-SODIUM ALLOY: Mixtures of the solids are impact-sensitive. SODIUM: Mixtures of the solids are impact-sensitive. SODIUM PEROXIDE: Highly exothermic reaction; may be explosive in the presence of metals. HYDROTREATED HEAVY NAPHTHA OXIDIZERS (STRONG): Fire and explosion hazard.

oxides of carbon 

Thermal decomposition products: oxides of carbon. 

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

heart or cardiovascular disorders, respiratory disorders, skin disorders, 



HYDROTREATED HEAVY NAPHTHA: Petroleum hydrocarbons within this carbon range may cause irritation of the mucous membranes, giddiness, vertigo, incoordination, headache, loss of appetite, nausea, confusion, drowsiness, tremors, and anesthetic stupor Massive acute exposure may result in rapid central nervous system depression with sudden collapse, deep coma and death There may be convulsions indicative of brain irritation or apneic anoxia Full recovery without sequelae may occur but cerebral microhemorrhages or focal postinflammatory scarring may result in epileptiform seizures months after the acute episode Direct contact with the lungs may cause chemical pneumonitis with pulmonary edema, and hemorrhaging Some light hydrocarbons may cause kidney effects which are reported to be temporary Some C4-C7 hydrocarbons may be neurotoxic CARBON DIOXIDE: In the solid or liquid form carbon dioxide is very volatile, readily releasing the gas At concentrations from 2-10% it may cause acidic taste, dyspnea, headache, vertigo, nausea, labored breathing, weakness, drowsiness, mental confusion, and increase in blood pressure, pulse, and respiratory rate Exposure to 10% for a few minutes has been reported to cause visual disturbances, tinnitus, tremors, profuse perspiration, restlessness, paresthesias, general feeling of discomfort, loss of consciousness, and coma Concentrations of 25-30% may cause coma and convulsions within one minute Tachycardia and arrhythmias are possible Concentrations of 50% may cause symptoms of hypocalcemia including carpopedal spasms Excessive carbon dioxide for a time period of not more than 5 minutes was reported to cause effects on vision with constriction of visual fields, enlargement of blind spots, photophobia, loss of convergence and accommodation, and deficient dark adaptation as well as headache, insomnia, and personality changes, largely depression and irritability Even when there is sufficient oxygen present to prevent simple asphyxiation by carbon dioxide, high concentrations may cause adverse effects by interfering with its normal elimination from the body Initially, exposure to increased carbon dioxide concentrations results in a compensatory increase in both rate and depth of ventilation Beyond a certain point, however, this may reverse to hypoventilation resulting in respiratory acidosis Death from asphyxia may occur if the concentration and duration of exposure are sufficient Reproductive effects have been reported in animals.



HYDROTREATED HEAVY NAPHTHA: Workers repeatedly exposed to petroleum hydrocarbons complained of visual disturbances A study of workers repeatedly exposed to aliphatic and aromatic hydrocarbons found psychological and neurophysical differences between exposed and nonexposed workers CARBON DIOXIDE: It has been reported that persons may tolerate 1.5% in inhaled air for prolonged periods without adverse effects, but calcium/phosphorus metabolism may be affected with serum levels of calcium and urinary phosphorus progressively falling At 2% concentration, deepened respiration may occur At 3% impairment of performance has been noted It has, however, been demonstrated that the development of tolerance may occur during prolonged exposure to low levels Reproductive effects have been reported in animals.



HYDROTREATED HEAVY NAPHTHA: Contact may cause slight to moderate irritation with redness and drying CARBON DIOXIDE: No adverse effects have been reported from exposure to the gas Due to rapid evaporation, the liquid or solid may cause frostbite with redness, tingling, pain, or numbness In more severe cases, the skin may become hard, white, and blistered.



HYDROTREATED HEAVY NAPHTHA: Repeated and prolonged contact with hydrocarbons may cause defatting of the skin resulting in irritation and dermatitis The irritated surface may be prone to cracking and bacterial infection Repeated or prolonged dermal absorption of some light hydrocarbons may cause kidney effects which are reported to be temporary CARBON DIOXIDE: No adverse effects are expected from exposure at low levels.



HYDROTREATED HEAVY NAPHTHA: Contact or high vapor concentrations may cause slight reversible irritation with tearing and itching, and smarting pain on splash contact CARBON DIOXIDE: At high concentrations in air, carbon dioxide may cause a stinging sensation of the eyes Exposure to 200,000 ppm (20%) of the gas may cause irritation Due to rapid evaporation, the liquid or solid may cause frostbite with redness, pain, and blurred vision.



HYDROTREATED HEAVY NAPHTHA: No data available CARBON DIOXIDE: No adverse effects are expected from exposure to low levels.



HYDROTREATED HEAVY NAPHTHA: Lung damage may occur if aspirated into the lungs and may be fatal Symptoms may include coughing, difficulty breathing, cyanosis, and pulmonary edema Hydrocarbons may have a direct irritative action on the pharynx, esophagus, stomach and small intestine with edema and mucosal ulceration and occasional myocardial injury with arrhythmias and electrocardiographic changes Central nervous system depression may also occur with effects as detailed in acute inhalation CARBON DIOXIDE: Ingestion of a gas is unlikely If the liquid or solid is swallowed, frostbite damage to the lips, mouth, and mucous membranes may occur.



HYDROTREATED HEAVY NAPHTHA: No data available CARBON DIOXIDE: No data available.

Component Analysis - Aquatic Toxicity 

Bioconcentration Factor 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Australia GHS Labeling Information 

European Union GHS Classifications 

European Union GHS Labeling Information 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 









ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 



Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.  Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 







Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved