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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 
(Z)-9-TETRADECENOIC ACID



ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 
fatty acids 



Synonyms 
9-TETRADECENOIC ACID, (Z)-; MYRISTOLEIC ACID; MYRISTOLENIC ACID; CIS-DELTA(9)-TETRADECENOIC ACID; CIS-9-TETRADECENOIC ACID; CIS-TETRADEC-9-ENOIC ACID; 9-CIS-TETRADECENOIC ACID; 9(Z)-TETRADECENOIC ACID; C14H26O2










* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: liquid

Physical Hazards:  Combustible liquid and vapor. 





Potential Health Effects 
Inhalation 
Short Term:  irritation 

Long Term:  no information is available 





Skin Contact 
Short Term:  irritation 

Long Term:  no information is available 





Eye Contact 
Short Term:  irritation 

Long Term:  no information is available 





Ingestion 
Short Term:  no information is available 

Long Term:  no information is available 
















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration No Component Name Synonyms 1272/2008 (CLP) Percent
544-64-9 208-876-8 -- (Z)-9-TETRADECENOIC ACID -- 100.0











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 



Skin 
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 



Eyes 
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 



Ingestion 
If a large amount is swallowed, get medical attention. 










* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 
NFPA Ratings: 
Health: 1 Fire: 2 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 
Moderate fire hazard. Vapor/air mixtures are explosive above flash point. 



Extinguishing Media 
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. 



Fire Fighting Measures 
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 










* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 










* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store below 0 C. Keep separated from incompatible substances. 










* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 
Biological limit value 
There are no biological limit values for any of this product's components. 




Ventilation 
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 



PERSONAL PROTECTIVE EQUIPMENT 
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 



Protective Clothing 
Wear appropriate chemical resistant clothing. 



Glove Recommendations 
Wear appropriate chemical resistant gloves. 



Respiratory Protection 
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 










* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance  Not available  Physical State  Liquid
Odor  Not available  Color  colorless
Odor Threshold  Not available  pH  Not available 
Melting Point  -5 - -4 °C Boiling Point  144 °C at 0.6 mmHg
Freezing point  Not available  Evaporation Rate  Not available 
Boiling Point Range  Not available  Flammability (solid, gas)  Not available 
Autoignition  Not available  Flash Point  62 °C CC
Lower Explosive Limit  Not available  Decomposition  Not available 
Upper Explosive Limit  Not available  Vapor Pressure  Not available 
Vapor Density (air=1)  Not available  Specific Gravity (water=1)  0.9
Water Solubility  Not available  Partition coefficient: n-octanol/water  Not available 
Viscosity  Not available  Solubility (Other)  Not available 
Density  Not available  Physical Form  liquid
Molecular Formula  C-H3-(C-H2)3-C-H-C-H-(C-H2)7-C-O-O-H Molecular Weight  226.36
OSHA Flammability Class  IIIA











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 
Stable at normal temperatures and pressure. 



Conditions to Avoid 
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. 



Incompatible Materials 
oxidizing materials 



(Z)-9-TETRADECENOIC ACID: OXIDIZERS (STRONG): Fire and explosion hazard.

Hazardous Decomposition Products 
oxides of carbon 



Thermal decomposition products: oxides of carbon.

Possibility of Hazardous Reactions 
Will not polymerize. 










* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA





Additional Data 
May cross the placenta. 



Inhalation - Acute Exposure 
(Z)-9-TETRADECENOIC ACID May cause irritation.



Inhalation - Chronic Exposure 
(Z)-9-TETRADECENOIC ACID No data available.



Skin Contact - Acute Exposure 
(Z)-9-TETRADECENOIC ACID May cause irritation.



Skin Contact - Chronic Exposure 
(Z)-9-TETRADECENOIC ACID No data available.



Eye Contact - Acute Exposure 
(Z)-9-TETRADECENOIC ACID May cause irritation.



Eye Contact - Chronic Exposure 
(Z)-9-TETRADECENOIC ACID No data available.



Ingestion - Acute Exposure 
(Z)-9-TETRADECENOIC ACID No data available.



Ingestion - Chronic Exposure 
(Z)-9-TETRADECENOIC ACID No data available.










* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 
Dispose in accordance with all applicable regulations. 



Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: COMBUSTIBLE LIQUID, N.O.S., (Contains:(Z)-9-TETRADECENOIC ACID)

Hazard Class: 3

UN/NA #: NA1993

Packing Group: III




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.




RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: No Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA 




Not listed under California Proposition 65 





None needed according to classification criteria. 




Component Analysis - Inventory 
Component  CAS#  US  CA  EU  AU  PH  JP  KR  CN  NZ 
(Z)-9-TETRADECENOIC ACID 544-64-9 Yes  DSL  EIN  No  Yes  Yes  Yes  Yes  Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 
No classification assigned. 










* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 



Other Information 
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 
Disclaimer: 
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 







Copyright 
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved