0.1 MG/ML 2,4-DINITROPHENOL (10-15% WATER ADDED) IN METHANOL

hydroxyls, aliphatic 

T16055

Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: liquid

Health Hazards:  skin irritation, eye irritation, central nervous system depression, nerve damage 

Physical Hazards:  Flammable liquid and vapor. Vapor may cause flash fire. 

Short Term:  irritation, cough, ringing in the ears, constipation, headache, drowsiness, dizziness, tingling sensation, pain in extremities, tremors, loss of coordination, blood disorders, nerve damage 

Long Term:  irritation, sensitivity to light, changes in blood pressure, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, pain in extremities, loss of coordination, visual disturbances, dilated pupils or pin-point pupils, blindness, bluish skin color, lung congestion, heart damage, kidney damage, liver damage, nerve damage, reproductive effects, effects on the brain, convulsions, unconsciousness, coma 

Short Term:  irritation, absorption may occur, headache, drowsiness, dizziness, loss of coordination, blood disorders 

Long Term:  irritation, headache, drowsiness, dizziness, loss of coordination, blood disorders, nerve damage 

Short Term:  irritation, eye damage 

Long Term:  irritation 

Short Term:  irritation, sensitivity to light, changes in blood pressure, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, pain in extremities, loss of coordination, visual disturbances, dilated pupils or pin-point pupils, blindness, bluish skin color, lung congestion, heart damage, kidney damage, liver damage, nerve damage, effects on the brain, convulsions, unconsciousness, coma 

Long Term:  changes in blood pressure, headache, drowsiness, dizziness, loss of coordination, visual disturbances, blindness, bluish skin color, blood disorders, heart damage, kidney damage, liver damage, nerve damage, reproductive effects 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 

For ingestion, consider gastric lavage. 

See Section 9 for Flammability Properties 

Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. 

alcohol-resistant foam, carbon dioxide, regular dry chemical, water 

Large fires: Use alcohol-resistant foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Dike for later disposal. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances. Store in a tightly closed container. Store in a cool, dry place. Store in a well-ventilated area. Store under an inert atmosphere. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. Remove any chemical soaked clothing immediately. 

Wear appropriate chemical resistant gloves. 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 2000 ppm Any supplied-air respirator. 5000 ppm Any supplied-air respirator operated in a continuous-flow mode. 6000 ppm Any supplied-air respirator with a tight-fitting facepiece that is operated in a continuous-flow mode. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

Stable at normal temperatures and pressure. 

halo carbons, combustible materials, metals, oxidizing materials, halogens, metal carbide, bases, acids 

METHYL ALCOHOL ACETYL BROMIDE: Violent reaction with formation of hydrogen bromide. ALKYLALUMINUM SOLUTIONS: Violent reaction. ALUMINUM: Corrodes. BARIUM PERCHLORATE: Distillation yields highly explosive alkyl perchlorate. BERYLLIUM HYDRIDE: Violent reaction, even at -196 C. BROMINE: Vigorously exothermic reaction. CALCIUM CARBIDE: Violent reaction. CHLORINE: Possible ignition and explosion hazard. CHLOROFORM AND SODIUM HYDROXIDE: Explosive reaction. CHROMIUM TRIOXIDE (CHROMIC ANHYDRIDE): Possible ignition. CYANURIC CHLORIDE: Violent reaction. DICHLOROMETHANE: Possible ignition and explosion. DIETHYL ZINC: Possible ignition and explosion. HYDROGEN PEROXIDE + WATER: Explosion hazard. IODINE + ETHANOL + MERCURIC OXIDE: Explosion hazard. LEAD: Corrodes. LEAD PERCHLORATE: Explosion hazard. MAGNESIUM: Violent reaction. MAGNESIUM (POWDERED): Mixtures are capable of detonation. METALS: Incompatible. NICKEL: Possible ignition in the presence of nickel catalyst. NITRIC ACID (CONCENTRATED): Mixtures of greater than 25% acid may decompose violently. OXIDIZERS (STRONG): Fire and explosion hazard. PERCHLORIC ACID: Explosion hazard. PHOSPHOROUS TRIOXIDE: Possible violent reaction and ignition. PLASTICS, RUBBER, COATINGS: May be attacked. POTASSIUM: Possible dangerous reaction. POTASSIUM HYDROXIDE + CHLOROFORM: Exothermic reaction. POTASSIUM TERT-BUTOXIDE: Fire and explosion hazard. SODIUM + CHLOROFORM: Possible explosion. SODIUM HYPOCHLORITE: Explosion hazard. SODIUM METHOXIDE + CHLOROFORM: Violent reaction. SULFURIC ACID: Fire and explosion hazard. ZINC: Explosion hazard.

oxides of carbon 

Thermal decomposition products: oxides of carbon. 

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

eye disorders, kidney disorders, skin disorders and allergies, 

May cause blindness. 

METHYL ALCOHOL: May cause irritation of the mucous membranes, coughing, oppression in the chest, tracheitis, bronchitis, tinnitus, unsteady gait, twitching, colic, constipation, nystagmus, and blepharospasm Symptoms from occupational exposure include paresthesias, numbness and shooting pains in the hands and forearms Metabolic acidosis, and effects on the eyes and central nervous system may occur as detailed in acute ingestion.

METHYL ALCOHOL: Repeated or prolonged exposure may cause effects as in acute ingestion Repeated exposure to 200-375 ppm caused recurrent headaches in workers Exposure for 4 years to 1200-8000 ppm resulted in marked diminution of vision and enlargement of the liver in a workman Reproductive effects have been reported in animals.

METHYL ALCOHOL: Contact with liquid may cause irritation Skin absorption may occur and cause metabolic acidosis and effects on the eyes and central nervous system as detailed in acute ingestion.

METHYL ALCOHOL: Repeated or prolonged contact with the liquid may cause defatting of the skin resulting in erythema, scaling, and eczematoid dermatitis Chronic absorption may result in metabolic acidosis and effects as detailed in acute ingestion.

METHYL ALCOHOL: Vapors may cause irritation High concentrations have been reported to cause violent inflammation of the conjunctiva and epithelial defects on the cornea Mild irritation may occur with dilute solutions; the undiluted liquid has produced moderate corneal opacity and conjunctival redness in rabbits Application of a drop of methanol in rabbit eyes caused a mild reversible reaction, graded 3 on a scale of 1-10 after 24 hours.

METHYL ALCOHOL Repeated or prolonged contact may cause conjunctivitis.

METHYL ALCOHOL: May cause mild and transient inebriation and subsequent drowsiness followed by an asymptomatic period lasting 8-48 hours Following the delay, coughing, dyspnea, headache, dullness, weakness, vertigo or dizziness, nausea, vomiting, occasional diarrhea, anorexia, violent pain in the back, abdomen, and extremities, restlessness, apathy or delirium, and rarely, excitement and mania may occur Rapid, shallow respiration due to metabolic acidosis, cold and clammy skin, hypotension, cyanosis, opisthotonos, convulsions, mild tachycardia, cardiac depression, peripheral neuritis, cerebral and pulmonary edema, unconsciousness, and coma are possible Effects on the eye may include optic neuritis, blurred or dimmed vision, dilated, unresponsive pupils, ptosis, eye pain, concentric constriction of visual fields, diplopia, change in color perception, photophobia, and optic nerve atrophy Partial blindness or possibly delayed transient or permanent blindness may occur Bilateral sensorineural deafness has been reported in a single case Liver, kidney, heart, stomach, intestinal and pancreatic damage may also occur Death may be due to respiratory failure or rarely from circulatory collapse As little as 15 ml has caused blindness; the usual fatal dose is 60-240 ml Prolonged asthenia and irreversible effects on the nervous system including difficulty in speech, motor dysfunction with rigidity, spasticity, and hypokinesis have been reported.

METHYL ALCOHOL: Repeated ingestion may cause visual impairment and blindness and other systemic effects as detailed in acute ingestion Reproductive effects have been reported in animals.

Component Analysis - Aquatic Toxicity 

Bioconcentration Factor 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Australia GHS Labeling Information 

European Union GHS Classifications 

European Union GHS Labeling Information 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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