2,4-DINITROPHENYLHYDRAZINE, 70%

aqueous 

INV# 00188

Emergency Overview 

Color:  orange 

Change in color: Not available

Physical Form: powder

Health Hazards:  skin irritation, eye irritation, allergic reactions 

Physical Hazards:  May explode if exposed to shock, friction or heating. Explosive if dry. 

Short Term:  irritation, nausea, bluish skin color, convulsions 

Long Term:  same as effects reported in short term exposure 

Short Term:  same as effects reported in short term inhalation, irritation, allergic reactions 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation 

Long Term:  same as effects reported in short term exposure 

Short Term:  same as effects reported in short term inhalation 

Long Term:  same as effects reported in other routes of exposure 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If a large amount is swallowed, get medical attention. 

See Section 9 for Flammability Properties 

Slight fire hazard. Severe explosion hazard. 

Flood with water. If no water is available, use dry chemical or earth. 

For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Explosive. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 500 feet. 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Small spills: Flood with water. Large spills: Wet down area with water. Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 

Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

Explosive if dry. Avoid contact with temperatures above 160 C. 

oxidizing materials, bases, halogens 

2,4-DINITROPHENYLHYDRAZINE OXIDIZERS (STRONG): Fire and explosion hazard. NITROAROMATICS ALKALIES: Possible violent decomposition or explosion when heated. CHLORINE TRIFLUORIDE: Solutions are extremely shock sensitive.

oxides of carbon, nitrogen 

Thermal decomposition products: oxides of carbon, nitrogen. test. 

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

2,4-DINITROPHENYLHYDRAZINE: May cause irritation and cyanosis Hydrazines may cause nausea, central nervous system effects with tremores, excitability, convulsions progressing to depression, respiratory arrest, and death Other symptoms may include effects on the liver, kidney, heart and hematopoietic system.

2,4-DINITROPHENYLHYDRAZINE Absorption into the body may cause cyanosis with a bluish color of the skin, lips, fingernails and tongue.

2,4-DINITROPHENYLHYDRAZINE: May cause irritation Skin absorption may occur Sensitization dermatitis may occur in previously exposed persons If sufficient amounts are absorbed, systemic toxicity may occur as detailed in acute inhalation.

2,4-DINITROPHENYLHYDRAZINE: Repeated or prolonged contact may cause sensitization dermatitis Absorption into the body may cause effects as detailed in chronic inhalation.

2,4-DINITROPHENYLHYDRAZINE May cause irritation.

2,4-DINITROPHENYLHYDRAZINE Repeated or prolonged contact with irritants may cause conjunctivitis.

2,4-DINITROPHENYLHYDRAZINE If sufficient amounts of hydrazines are ingested, systemic toxicity may occur as detailed in acute inhalation.

2,4-DINITROPHENYLHYDRAZINE Absorption into the body may cause effects as detailed in chronic inhalation.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Korea GHS Classifications 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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