危险化学品
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Material Name: VITAVAX TECHNICAL SDS ID: ohsbz523 Issue Date: 2016-06-24 Revision: 2.07 |
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
VITAVAX TECHNICAL | ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Chemical Family
sulfuryl compounds Synonyms
SLN WA-790022 * * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Change in color: Not available
Physical Form: technical chemical
Health Hazards: harmful if swallowed
Potential Health Effects
Inhalation
Short Term: no information on significant adverse effects Long Term: no information is available
Skin Contact
Short Term: no information on significant adverse effects Long Term: no information on significant adverse effects
Eye Contact
Short Term: irritation Long Term: no information is available
Ingestion
Short Term: bone disorders, liver damage Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
| CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
| 5234-68-4 226-031-1 -- | CARBOXIN | -- | 97.0000 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Ingestion
Get medical attention immediately. Note to Physicians
For ingestion, consider gastric lavage and catharsis. Consider oxygen. * * * Section 5 - FIRE FIGHTING MEASURES * * *
NFPA Ratings:
Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Slight fire hazard. Dust/air mixtures may ignite or explode. Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. * * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. * * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. May be subject to EPA pesticide registration. Keep separated from incompatible substances. * * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components
Component Analysis
Biological limit value There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Clothing
Wear appropriate chemical resistant clothing. Glove Recommendations
Wear appropriate chemical resistant gloves. Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying half-mask respirator equipped with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece, organic vapor cartridge(s) and high-efficiency particulate filter(s). Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. * * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
| Appearance | Not available | Physical State | Unknown |
| Odor | Not available | Color | Not available |
| Odor Threshold | Not available | pH | Not available |
| Melting Point | Not available | Boiling Point | Not available |
| Freezing point | Not available | Evaporation Rate | Not available |
| Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
| Autoignition | Not available | Flash Point | Not available |
| Lower Explosive Limit | Not available | Decomposition | Not available |
| Upper Explosive Limit | Not available | Vapor Pressure | Not available |
| Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
| Water Solubility | Not available | Partition coefficient: n-octanol/water | Not available |
| Viscosity | Not available | Solubility (Other) | Not available |
| Density | Not available | Physical Form | technical chemical |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure. Stable at normal temperatures and pressure. Incompatible Materials
acids, bases, oxidizing materials CARBOXIN ACIDS (STRONG): Incompatible. HIGHLY ALKALINE CONDITIONS: Incompatible. OXIDIZERS: Incompatible.
Hazardous Decomposition Products
oxides of nitrogen, sulfur Thermal decomposition products: oxides of nitrogen, sulfur.
Possibility of Hazardous Reactions
Will not polymerize. Will not polymerize. * * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
CARBOXIN (5234-68-4)
Oral LD50 Rat 430 mg/kg
Inhalation LC50 Rat >20 g/m3 1 h
Oral LD50 Rat 430 mg/kg
Inhalation LC50 Rat >20 g/m3 1 h
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Inhalation - Acute Exposure
CARBOXIN No mortality was observed in rats after a one hour exposure to a concentration of 20 ml/l. Inhalation - Chronic Exposure
CARBOXIN No data available. Skin Contact - Acute Exposure
CARBOXIN: 500 mg applied to rabbit skin did not produced irritation A dose of 8 gm/kg of a 50% aqueous slurry was not lethal to rabbits by dermal absorption. Skin Contact - Chronic Exposure
CARBOXIN No adverse effects in rabbits were reported from a 21-day dermal study of 3.0 gm/kg. Eye Contact - Acute Exposure
CARBOXIN: May cause eye irritation A 100 mg of 75% wettable powder/dust formulation applied to rabbit eyes produced marked and persistent conjunctival effects, iris irritation, and corneal opacity that was still present after 14 days of application. Eye Contact - Chronic Exposure
CARBOXIN No data available. Ingestion - Acute Exposure
CARBOXIN: A lethal dose in rats was 430 mg/kg Carboxin inhibits oxidative metabolism and succinic dehydrogenase in mitochondria of liver and bone. Ingestion - Chronic Exposure
CARBOXIN: Degenerative renal changes were observed in a 90-day feeding study in rats at the 600 ppm level Poor survival and weight gain depression were reported in rats from a 2 year feeding study at the 600 ppm level. * * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
| CARBOXIN | 5234-68-4 |
| Fish: | LC50 96 h Lepomis macrochirus 2.7 - 4.3 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 1 - 1.4 mg/L [static]; LC50 96 h Oncorhynchus mykiss 1.5 - 2.4 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 1.6 - 2.5 mg/L [static] |
| Invertebrate: | LC50 48 h Daphnia magna >54 mg/L IUCLID; EC50 48 h Daphnia magna >57 mg/L [Flow through] EPA; EC50 48 h Daphnia magna 73 - 97.6 mg/L [Static] EPA |
Bioconcentration Factor
| CARBOXIN | 5234-68-4 |
| BCF | 39.1 - 260 species: fish |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
May be subject to EPA pesticide registration. Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
No Classification assigned.
TDG Information:
No Classification assigned.
No Classification assigned.
ADR Information:
No Classification assigned.
No Classification assigned.
RID Information:
No Classification assigned.
No Classification assigned.
IATA Information:
No Classification assigned.
No Classification assigned.
ICAO Information:
No Classification assigned.
No Classification assigned.
IMDG Information:
No Classification assigned.
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
| CARBOXIN | 5234-68-4 |
| SARA 313: | 1 % de minimis concentration |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: No Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
| Component | CAS | CA | MA | MN | NJ | PA |
| CARBOXIN | 5234-68-4 | No | No | No | Yes | No |
Not listed under California Proposition 65
Symbol(s)
Xn Harmful
Risk Phrases
R22 Harmful if swallowed.
Xn Harmful
Risk Phrases
R22 Harmful if swallowed.
Component Analysis - Inventory
| Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
| CARBOXIN | 5234-68-4 | No | No | EIN | Yes | No | No | Yes | No | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
European Union GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Korea GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
CARBOXIN (5234-68-4) Approval: HSR003121
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (kidneys)
Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (fish,algal)
Acute toxicity Oral Category 5 H303 May be harmful if swallowed
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (kidneys)
Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (fish,algal)
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
CARBOXIN (5234-68-4)
Symbol(s)
Signal Word Warning
Hazard(s)
H303 May be harmful if swallowed
H319 Causes serious eye irritation
H373 May cause damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H303 May be harmful if swallowed
H319 Causes serious eye irritation
H373 May cause damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
This material may be hazardous according to published criteria for classification
Classification
No classification assigned. * * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved