Safety Data Sheet: Material Name: VERSILOK 201 SDS ID: ohshu030 Issue Date: 2016-06-24 Revision: 2.08

                

VERSILOK 201

ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237 E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.

Emergency Overview 

Change in color: Not available

Physical Form: liquid

Health Hazards:  harmful on contact with the skin, respiratory tract burns, skin burns, eye burns, mucous membrane burns, central nervous system depression, allergic reactions 

Physical Hazards:  Flammable liquid and vapor. Vapor may cause flash fire. May polymerize. Containers may rupture or explode. 

Short Term:  irritation (possibly severe), changes in blood pressure, difficulty breathing, headache, drowsiness, dizziness, loss of coordination, unconsciousness 

Long Term:  burns, changes in blood pressure, difficulty breathing, headache, fatigue, sleep disturbances, pain in extremities 

Short Term:  irritation (possibly severe), allergic reactions, tingling sensation 

Long Term:  irritation (possibly severe), allergic reactions 

Short Term:  irritation (possibly severe), eye damage 

Long Term:  burns, eye damage 

Short Term:  irritation (possibly severe), allergic reactions, nausea, vomiting, headache, drowsiness, dizziness, loss of coordination, kidney damage, liver damage 

Long Term:  allergic reactions, burns 

CAS EC No Registration No	Component Name Synonyms	1272/2008 (CLP)	Percent
80-62-6 201-297-1 --	METHYL METHACRYLATE	Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 STOT SE 3 - H335 Note(s): D	50.0
79-41-4 201-204-4 --	METHACRYLIC ACID	Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Skin Corr. 1A - H314 Note(s): D	10.0

This product may be regulated, have exposure limits or other information identified as the following: Methacrylates.









If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 



Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 



Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 



Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 



For inhalation, consider oxygen. For ingestion, consider gastric lavage. 









See Section 9 for Flammability Properties 



Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. 



regular dry chemical, carbon dioxide, water, regular foam 

Large fires: Use regular foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Do not get water inside container. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 



Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 



Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 



Wear appropriate chemical resistant clothing. Remove any chemical soaked clothing immediately. 



Wear appropriate chemical resistant gloves. 



Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

Appearance	Not available	Physical State	Liquid
Odor	Not available	Color	Not available
Odor Threshold	Not available	pH	Not available
Melting Point	Not available	Boiling Point	100 - 120 °C
Freezing point	Not available	Evaporation Rate	<1 (ether=1)
Boiling Point Range	Not available	Flammability (solid, gas)	Not available
Autoignition	Not available	Flash Point	18 °C
Lower Explosive Limit	2.1 %	Decomposition	Not available
Upper Explosive Limit	Not available	Vapor Pressure	Not available
Vapor Density (air=1)	>1	Specific Gravity (water=1)	Not available
Water Solubility	(insoluble)	Partition coefficient: n-octanol/water	Not available
Viscosity	Not available	Solubility (Other)	Not available
Density	Not available	Physical Form	liquid
Volatility	50 - 60 %

Stable at normal temperatures and pressure. May polymerize. Avoid contact with air, light or storage and use above room temperature. Polymerizes with evolution of heat. Avoid storage and use above room temperature. 



acids, bases, peroxides, metals, oxidizing materials, combustible materials 

METHYL METHACRYLATE ACIDS (STRONG): Initiates explosive polymerization reaction. ALKALIES (STRONG): Initiates explosive polymerization reaction. AZOISOBUTYRONITRILE: Possible violent polymerization reaction. BENZOYL PEROXIDE: Explosive runaway polymerization reaction. CARBON STEEL: 60 F and above greater than 50 mils per year corrosion. DI-TERT-BUTYL PEROXIDE: Explosive runaway polymerization reaction. METALS: May initiate exothermic polymerization. NITRATES: Fire and explosion hazard. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN: May initiate violent exothermic polymerization. OZONE: May initiate polymerization. PEROXIDES: May initiate violent exothermic polymerization. PROPIONALDEHYDE: Possible rapid exothermic reaction. STAINLESS STEEL: Between 60 and 80 F less than 20 mils per year corrosion. METHACRYLIC ACID HYDROCHLORIC ACID: May cause hazardous polymerization. METALS: Attacks. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXIDES: May cause hazardous polymerization.

miscellaneous decomposition products 

Thermal decomposition products: miscellaneous decomposition products. 

Will not polymerize. May polymerize. Avoid contact with heat, air, light, initiators or curing agents. Closed containers may rupture violently. Polymerizes with evolution of heat. Store in a cool, dry place. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

kidney disorders, liver disorders, respiratory disorders, skin disorders and allergies, central nervous system disorders, 



METHYL METHACRYLATE: Inhalation of 170-250 ppm has been reported to cause mucous membrane irritation in exposed workers High concentrations may cause central nervous system depression with headache, drowsiness, dizziness, difficult breathing and loss of consciousness Death may be due to pulmonary edema Severe hypotension possibly resulting in heart failure has been reported Other effects reported in animals include decrease in neuronal firing rate, fall in blood pressure, loss of reflexes, exhaustion, or hypoactivity, vomiting, and liver and kidney damage Death in animals given lethal concentrations was due to respiratory arrest METHACRYLIC ACID: Inhalation of acidic fumes or mist may cause coughing, choking, headache, dizziness, weakness, hypotension, and delayed pulmonary edema with chest tightness, apnea, frothy sputum, and cyanosis Dyspnea and hemoptysis are possible for several weeks after exposure After inhalation of corrosive atmospheres, convalescence may be prolonged and frequent relapses may occur.



METHYL METHACRYLATE: Repeated occupational exposure produced dyspnea, hypertension and erythroderma Workers exposed to 0.5-50 ppm reported headache, pain in the extremities, irritability, loss of memory, excessive fatigue and sleep disturbances Pulmonary edema and centrilobular necrosis of the liver were noted following a 22 hour exposure of a rhesus monkey Kidney and liver degeneration, loss of cilia from the tracheal mucosa, a decreased number of microvilli on the epithelium and death were also reported in animals In a 2 year study at concentrations up to 1000 ppm, inflammation and epithelial hyperplasia of the nasal cavity, degeneration of the olfactory sensory epithelium, renal and liver necrosis and histologic changes in the brain were noted Rats exposed on days 6-15 of pregnancy showed maternal toxicity, a significant increase in fetal deaths, hematomas and skeletal anomalies Other reproductive effects have been reported in animals METHACRYLIC ACID: Repeated or prolonged exposure to acidic fumes may cause erosion of teeth followed by jaw necrosis Bronchial irritation with cough and frequent attacks of bronchial pneumonia may occur Gastrointestinal disturbances are also possible.



METHYL METHACRYLATE: Contact may cause irritation with redness and tenderness Burns may possibly occur Dermatitis with paresthesias of the fingertips characterized by a burning and tingling sensation and a slight numbness that may persist for several weeks has been reported Eczematous or urticarial sensitization dermatitis has occurred in previously exposed individuals Allergic reactions may also occur involving the nails and nailbeds METHACRYLIC ACID: Contact may cause severe irritation and pain, burns, and vesiculation Toxic and may be absorbed producing symptoms similar to those of inhalation.



METHYL METHACRYLATE: Repeated or prolonged exposure may cause dryness and fissuring Repeated or prolonged contact may lead to sensitization dermatitis METHACRYLIC ACID: Repeated or prolonged exposure may cause dermatitis.



METHYL METHACRYLATE: Vapors have been reported to cause transient irritation in workers Tearing and burns may also occur Application of the liquid to rabbit eyes produced irritation requiring several days to heal Corneal damage has also been reported METHACRYLIC ACID: Direct contact with the concentrated acid solution may cause severe damage, often leading to blindness Dilute solutions produce more transient effects from which recovery may be complete Exposure to the mist may cause eye irritation and lacrimation.



METHYL METHACRYLATE: Prolonged contact with acrylic monomers may result in severe tissue damage METHACRYLIC ACID: Repeated or prolonged exposure may cause conjunctivitis and lacrimation.



METHYL METHACRYLATE: Ingestion may cause irritation of the mouth and stomach with nausea and vomiting Dizziness, drowsiness, liver or kidney injury have been reported Animals studies indicate central nervous system depression, respiratory depression and coma, fall in blood pressure and death due to respiratory arrest may occur Sensitization may occur in previously exposed individuals METHACRYLIC ACID: May cause severe, burning pain in the mouth, pharynx, and abdomen and vomiting and diarrhea of dark precipitated blood Hypotension may develop rapidly Discoloration may be found around the mouth and throat Asphyxia may occur from edema of the glottis After initial recovery, onset of fever indicates mediastinitis or peritonitis from perforation of the esophagus or stomach The patient may have a rigid abdomen without perforation If the patient recovers, scar formation is more apt to produce stricture of the pylorus than stricture of the esophagus.



METHYL METHACRYLATE: No significant adverse effects or compound-related tumors were noted in animals given doses up to 2000 ppm in drinking water An allergic contact type of eczematous reaction of the oral mucosa has been reported METHACRYLIC ACID: No data available.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Australia GHS Labeling Information 

European Union GHS Classifications 

European Union GHS Labeling Information 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 









ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 



Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.  Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 







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