* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
3-DIETHYLAMINOPROPYLAMINE
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Chemical Family
amines, aliphatic
Synonyms
N,N-DIETHYL-1,3-PROPANEDIAMINE; N,N-DIETHYL-1,3-DIAMINOPROPANE; 1-AMINO-3-(DIETHYLAMINO)PROPANE; N-(3-DIETHYLAMINOPROPYL) AMINE; N,N-DIETHYLAMINOPROPYLAMINE; 3-(DIETHYLAMINO)PROPYLAMINE; DIETHYLAMINOTRIMETHYLENAMINE; CURING AGENT A; UN 2684
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: colorless
Change in color: Not available
Physical Form: liquid
Odor: fishy odor
Health Hazards: harmful on contact with the skin, respiratory tract burns, skin burns, eye burns, mucous membrane burns
Physical Hazards: Flash back hazard. Combustible liquid and vapor.
Potential Health Effects
Inhalation
Short Term: burns
Long Term: same as effects reported in short term exposure
Skin Contact
Short Term: burns
Long Term: same as effects reported in short term exposure
Eye Contact
Short Term: burns
Long Term: same as effects reported in short term exposure
Ingestion
Short Term: burns
Long Term: same as effects reported in short term exposure
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
104-78-9 203-236-4 -- | 3-DIETHYLAMINOPROPYLAMINE | Flam. Liq. 3 - H226 Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Dermal) - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 | 100 |
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Get medical attention immediately.
Note to Physicians
For inhalation, consider oxygen. For ingestion, consider gastric lavage.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 2 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Moderate fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point.
Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam, alcohol-resistant foam Large fires: Use regular foam or flood with fine water spray.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not get water inside container. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Do not get water directly on material. Large fires: Flood with fine water spray. Reduce vapors with water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Liquid |
Odor | fishy odor | Color | colorless |
Odor Threshold | Not available | pH | Not available |
Melting Point | -100 °C | Boiling Point | 169 °C |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | 365 °C | Flash Point | 59 °C OC |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | 1 mmHg at 20 °C |
Vapor Density (air=1) | 4.48 | Specific Gravity (water=1) | 0.826 |
Water Solubility | (soluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
OSHA Flammability Class | II | | |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Keep out of water supplies and sewers.
Incompatible Materials
acids,
3-DIETHYLAMINOPROPYLAMINE: MINERAL ACIDS (STRONG): May react.
Hazardous Decomposition Products
oxides of carbon, nitrogen
Thermal decomposition products: oxides of carbon, nitrogen. test.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Oral LD50 Rat 550 mg/kg
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Inhalation - Acute Exposure
Vapors may severely irritate mucous membranes of the throat Diethylaminoethanol, a similar compound, has caused nausea and vomiting, respiratory difficulties, and pulmonary edema Convulsions have been reported in animals.
Inhalation - Chronic Exposure
No data available, however, repeated daily exposures of of rats to 500 ppm diethylaminoethanol, a similar compound, produced nasal irritation, tremors, weight loss, purulent bronchitis, bronchopneumonia, and death of 20% of the animals tested by the fifth exposure.
Skin Contact - Acute Exposure
May cause severe irritation and possible skin burns 100 micrograms applied to open rabbit skin caused irritation after 24 hours 750 mg/kg was the reported lethal dose in rabbits Symptoms were not reported.
Skin Contact - Chronic Exposure
Repeated or prolonged contact may cause dermatitis Diethylaminoethanol, a similar compound, has caused weight loss and a slight increase in blood clotting time.
Eye Contact - Acute Exposure
May cause severe irritation, redness, pain, and possible eye burns Diethylaminoethanol, a similar compound caused edema and wrinkling of the posterior surface of the cornea, iritis, and cataract formation.
Eye Contact - Chronic Exposure
Repeated or prolonged contact may cause conjunctivitis Rats exposed to diethylaminoetanol at 500 ppm for 6 hours per day developed corneal opacity after 3 days.
Ingestion - Acute Exposure
1410 mg/kg was the reported lethal dose in rats Symptoms were not reported Corrosive substances may cause severe pain, vomiting, diarrhea and collapse Vomitus may contain blood and mucosal lining If death does not occur within 24 hours, victim may improve for 2-4 days, followed by onset of severe abdominal pain, boardlike abdominal rigidity and rapid fall in blood pressure due to delayed gastric or esophageal perforation Esophageal stricture may occur later, making swallowing difficult.
Ingestion - Chronic Exposure
No data available.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN/NA #: UN2684
Packing Group: III
Required Label(s): 3, 8
TDG Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Required Label(s): 3, 8
ADR Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Required Label(s): 3 + 8
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Restriction(s): D/E [UN2684] (III)
RID Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Required Label(s): 3 + 8
IATA Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Required Label(s): 3, 8
ICAO Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Required Label(s): 3, 8
IMDG Information:
Shipping Name: 3-DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN#: UN2684
Packing Group: III
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
3-DIETHYLAMINOPROPYLAMINE | 104-78-9 | No | Yes | No | Yes | Yes |
Not listed under California Proposition 65
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
3-DIETHYLAMINOPROPYLAMINE | 104-78-9 |
| 1 % |
Germany Water Classification
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
ID Number 1580 , hazard class 1 - low hazard to waters
Symbol(s)
C Corrosive
Risk Phrases
R10 Flammable.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
Safety Phrases
S1/2 Keep locked up and out of the reach of children.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
3-DIETHYLAMINOPROPYLAMINE | 104-78-9 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause allergic skin reaction
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause allergic skin reaction
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
3-DIETHYLAMINOPROPYLAMINE (104-78-9) Approval: 21A3650
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 3 H311 Toxic in contact with skin
Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
NEMA: | Flammable Liquids Category 3 H226 Flammable liquid and vapour |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Warning
Hazard(s)
H226 Flammable liquid and vapour
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
3-DIETHYLAMINOPROPYLAMINE (104-78-9) Approval: HSR004263
Flammable Liquids Category 3 H226 Flammable liquid and vapour
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Dermal Category 4 H312 Harmful in contact with skin
Skin Corrosion/Irritation Category 1C H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H433 Harmful to terrestrial vertebrates
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Listing: Present (>=25% by mass)
Listing: Present (>=5% and <10%)
Listing: Present (>=10% and <25% by mass)
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Taiwan: | Flammable Liquids Category 3 H226 Flammable liquid and vapour |
| Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
| Skin Sensitization Category 1 H317 May cause allergic skin reaction |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
3-DIETHYLAMINOPROPYLAMINE (104-78-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
Prevention
P233 Keep container tightly closed
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P370+P378 In case of fire: Use appropriate media for extinction
Storage
P403+P235 Store in a well-ventilated place. Keep cool
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved