ZINC PERMANGANATE

inorganic, salt 

PERMANGANIC ACID (HMnO4), ZINC SALT; UN 1515; Mn2O8Zn

Emergency Overview 

Color:  purple to black 

Change in color: hygroscopic

Physical Form: crystals

Physical Hazards:  May ignite combustibles. 

Short Term:  no information is available 

Long Term:  loss of appetite, headache, difficulty speaking, sleep disturbances, mood swings, loss of coordination, hearing loss, visual disturbances, lung damage, blood disorders, kidney damage, nerve damage 

Short Term:  irritation 

Long Term:  allergic reactions 

Short Term:  irritation 

Long Term:  no information is available 

Short Term:  nausea, vomiting, diarrhea 

Long Term:  same as effects reported in long term inhalation 

This product may be regulated, have exposure limits or other information identified as the following: Zinc compounds, Manganese compounds, n.o.s.

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

If a large amount is swallowed, get medical attention. 

calcium disodium edetate/dextrose, intravenous; calcium disodium edetate/procaine, intramuscular. 

See Section 9 for Flammability Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 

water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance. 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile). 

Avoid contact with combustible materials. Do not touch spilled material. Small dry spills: Move containers away from spill to a safe area. Small liquid spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. 

Use methods to minimize dust. 

Store and handle in accordance with all current regulations and standards. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Store in a tightly closed container. Keep in the dark. Keep separated from incompatible substances. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: Manganese (Mn) 10 mg/m3 Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any supplied-air respirator. 25 mg/m3 Any supplied-air respirator operated in a continuous-flow mode. Any powered, air-purifying respirator with a high-efficiency particulate filter. 50 mg/m3 Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any supplied-air respirator with a tight-fitting facepiece that is operated in a continuous-flow mode. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 500 mg/m3 Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. 

Stable at normal temperatures and pressure. 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Keep out of water supplies and sewers. 

combustible materials, cyanides, peroxides, acids, reducing agents, 

ZINC PERMANGANATE: AMMONIUM COMPOUNDS: May form explosive mixtures which are sensitive to friction and may ignite. CELLULOSE: Possible explosion. COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. CYANIDES: Reacts fiercely when heated or by friction. HYDROGEN PEROXIDE: Reacts vigorously. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. REDUCING MATERIALS: Fire and explosion hazard. SULFURIC ACID: Contact may result in fires or explosion.

oxides of zinc 

Thermal decomposition products: zinc oxide.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

history of alcoholism, blood system disorders, liver disorders, nervous system disorders, respiratory disorders, 

MANGANESE COMPOUNDS No data available.

MANGANESE COMPOUNDS: Repeated or prolonged exposure to manganese compounds may result in systemic poisoning known as "manganism", a Parkinsonian-like syndrome It is characterized initially by anorexia, asthenia, headache, insomnia or somnolence, irritability, restlessness, and spasm or pain in the muscles Manganese psychosis may follow with uncontrollable behavior, unaccountable laughing or crying, visual hallucinations, confusion and euphoria Sexual excitement followed by impotence may occur These symptoms may disappear with the onset of true neurological manifestations of slow, slurred and irregular speech, monotonous tone, double vision, impaired hearing, difficulty with fine motor movements, and disturbances in gait and balance with frequent propulsion or retropulsion Mask-like face, decreased movement of the eyelids and eyes and tremors of the upper extremities and head may also occur Other signs and symptoms may include urinary bladder disturbances, excessive salivation and sweating, hematological changes, vasomotor disorders, decreased pulmonary function, kidney and possibly liver damage Removal from exposure shortly after onset of symptoms usually results in improvement, although there may be residual disturbances in gait and speech Once manganism is well established it becomes irreversible and progressive, but not fatal An increased incidence of bronchitis and pneumonitis has been reported in studies of workers exposed to manganese dust and fume, and although these effects have been confirmed by animal experiments, they may represent an aggravation of a pre-existing condition Allergic diseases of the respiratory tract have also been reported in one study.

ZINC PERMANGANATE See information on manganese compounds.

MANGANESE COMPOUNDS: Some manganese compounds may be irritating to the skin ZINC SALTS: Soluble zinc salts are astringent and corrosive and may be easily absorbed through the skin.

MANGANESE COMPOUNDS: Sensitization has been reported in guinea pigs ZINC SALTS: No data available.

ZINC PERMANGANATE See information on manganese compounds and zinc salts.

MANGANESE COMPOUNDS Direct contact with manganese compounds may cause irritation.

MANGANESE COMPOUNDS No data available.

ZINC PERMANGANATE See information on manganese compounds.

MANGANESE COMPOUNDS: Ingestion of extremely large doses of manganese compounds may cause gastrointestinal irritation, resulting in nausea, vomiting, and diarrhea, making less available for absorption ZINC SALTS: Small doses may cause nausea and vomiting In addition to these symptoms, large doses may cause fever, stomach cramps, diarrhea, and fatal collapse due to serious damage to the buccal and gastroenteric mucous membranes.

MANGANESE COMPOUNDS: Manganese poisoning, as described in chronic inhalation, has been reported in persons drinking manganese-contaminated well water ZINC SALTS: Continued administration of small doses may cause digestive disorders and constipation.

ZINC PERMANGANATE See information on manganese compounds and zinc salts.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Japan GHS Labeling Information 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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