* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
DURACELL ALKALINE BATTERIES
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Synonyms
ALKALINE MANGANESE DIOXIDE CELLS; MN1300 (D); MN1400 (C); MN1500 (AA); MN2400 (AAA); MN2500 (AAAA; MN908 (LANTERN 6V); MN918 (LANTERN 4.5V); MN1604 (9V); MN21 (12V); MN9100 (N); DAC100; DAC105; DAC110; DAC116-118; DAC123-124; DAC130; DAC200; DAC610; DAC810; DAC820; DAC918
Product Use
battery
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: dark
Change in color: Not available
Physical Form: battery
Health Hazards: This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns
Potential Health Effects
Inhalation
Short Term: This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe)
Long Term: same as effects reported in short term exposure
Skin Contact
Short Term: This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe)
Long Term: irritation (possibly severe), allergic reactions
Eye Contact
Short Term: This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe), tearing
Long Term: irritation (possibly severe)
Ingestion
Short Term: This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, burns
Long Term: same as effects reported in short term exposure
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
1313-13-9 215-202-6 -- | MANGANESE DIOXIDE | Acute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332 | 35 - 40 |
7440-66-6 231-175-3 -- | ZINC | -- | 10 - 15 |
1310-58-3 215-181-3 -- | POTASSIUM HYDROXIDE | Acute Tox. 4 (Oral) - H302 Skin Corr. 1A - H314 | 5 - 10 |
7440-44-0 231-153-3 -- | CARBON, ACTIVATED | -- | 1 - 5 |
7782-42-5 231-955-3 -- | GRAPHITE | -- | 1 - 5 |
1314-13-2 215-222-5 -- | ZINC OXIDE | Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 | <1 |
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Manganese oxides, Manganese compounds, inorganic, Manganese compounds, n.o.s., Zinc compounds, Graphite, synthetic.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Get medical attention.
Skin
Wash exposed skin with soap and water.
Eyes
Flush eyes with plenty of water.
Ingestion
If a large amount is swallowed, get medical attention.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Negligible fire hazard.
Extinguishing Media
Use extinguishing agents appropriate for surrounding fire.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.
Occupational spill/release
Small spills of the liquid component: Collect spilled material in appropriate container for disposal. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Handling Procedures
Use methods to minimize dust.
Storage Procedures
Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
MANGANESE DIOXIDE | 1313-13-9 |
ACGIH: | 0.02 mg/m3 TWA as Mn respirable particulate matter; 0.1 mg/m3 TWA as Mn inhalable particulate matter (related to Manganese inorganic compounds) |
NIOSH: | 1 mg/m3 TWA as Mn (related to Manganese compounds) |
| 3 mg/m3 STEL as Mn (related to Manganese compounds) |
| 500 mg/m3 IDLH as Mn (related to Manganese compounds) |
OSHA (US): | 5 mg/m3 Ceiling as Mn (related to Manganese compounds) |
Mexico: | 0.2 mg/m3 TWA VLE-PPT as Mn (related to Manganese inorganic compounds) |
POTASSIUM HYDROXIDE | 1310-58-3 |
ACGIH: | 2 mg/m3 Ceiling |
NIOSH: | 2 mg/m3 Ceiling |
CARBON, ACTIVATED | 7440-44-0 |
Mexico: | 2 mg/m3 TWA VLE-PPT dust |
GRAPHITE | 7782-42-5 |
ACGIH: | 2 mg/m3 TWA (all forms except graphite fibers) respirable particulate matter |
NIOSH: | 2.5 mg/m3 TWA (natural) respirable dust |
| 1250 mg/m3 IDLH |
OSHA (US): | 15 mg/m3 TWA (synthetic) total dust; 5 mg/m3 TWA (synthetic) respirable fraction |
| 15 mppcf TWA (natural) |
Mexico: | 2 mg/m3 TWA VLE-PPT (synthetic and natural) |
ZINC OXIDE | 1314-13-2 |
ACGIH: | 2 mg/m3 TWA respirable particulate matter |
| 10 mg/m3 STEL respirable particulate matter |
NIOSH: | 5 mg/m3 TWA dust and fume |
| 10 mg/m3 STEL fume |
| 15 mg/m3 Ceiling dust |
| 500 mg/m3 IDLH |
OSHA (US): | 5 mg/m3 TWA fume; 15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction |
Mexico: | 5 mg/m3 TWA VLE-PPT fume; 10 mg/m3 TWA VLE-PPT dust |
| 10 mg/m3 STEL [PPT-CT] fume |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Based on available information, additional ventilation is not required. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Eye protection not required under normal conditions.
Protective Clothing
Protective clothing is not required under normal conditions.
Glove Recommendations
Protective gloves are not required under normal conditions.
Protective Materials
neoprene, rubber, latex
Respiratory Protection
No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Solid |
Odor | Not available | Color | dark |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | Not available |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | Not available |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | Not available | Specific Gravity (water=1) | Not available |
Water Solubility | Not available | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | battery |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Protect from physical damage and heat. Avoid heat, flames, sparks and other sources of ignition.
Incompatible Materials
oxidizing materials
GRAPHITE CHLORINE TRIFLUORIDE: Ignition. FLUORINE: Explosive reaction. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN: Fire and explosion. POTASSIUM (BURNING): Explosion. POTASSIUM PEROXIDE: Fire and explosion hazard. ZINC ACIDS: Evolves hydrogen gas which may be ignited by the heat of the reaction ALKALIES: Evolves hydrogen gas which may be ignited by the heat of the reaction. ALUMINUM (POWDER): Possible ignition. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL: May spark on impact. AMMONIUM NITRATE: Violent reaction or formation of explosive mixture. AMMONIUM SULFIDE: May explode in a closed container. ARSENIC: Incandescent reaction when heated. ARSENIC TRIOXIDE: Explosive reaction on heating. BROMOMETHANE: Forms flammable compounds. CADMIUM: Incandescent reaction. CALCIUM CHLORIDE: Evolves hydrogen gas which may be ignited by the heat of the reaction. CARBON DISULFIDE: Incandescent reaction. CARBON TETRACHLORIDE + METHANOL: Extremely vigorous reaction. CHLORATES: Forms shock-sensitive mixtures. CHLORINATED RUBBER: Violent or explosive reaction at elevated temperatures. CHROMIC ANHYDRIDE: Violent reaction and possible ignition. COBALT HALIDE (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. ETHYL ACETOACETATE + TRIBROMONEOPENTYL ALCOHOL: May react explosively. HALOCARBONS: Possible violent reaction with ignition. HALOGENS: Possible ignition. HYDRAZINE NITRATE: Ignites on warming. HYDROXYLAMINE: May ignite or explode when heated. INTERHALOGENS: Violent reaction and possible ignition. LEAD AZIDE: Increased sensitivity to explosive decomposition. MANGANESE DICHLORIDE: Explosive reaction when heated. METAL OXIDES: Possible ignition or incandescent reaction. NITRIC ACID: Incandescent reaction. 2-NITROANISOLE + SODIUM HYDROXIDE: Exothermic reaction. NITROBENZENE: May form pyrophoric residue. NITRYL FLUORIDE: Incandesces when warmed. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXYFORMIC ACID: Violent explosion on contact. POTASSIUM NITRATE: Explosive reaction on heating. POTASSIUM PEROXIDE: Incandescent reaction. RHODIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. RUTHENIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. SELENIUM: Incandescent reaction. SELENINYL BROMIDE: Ignition. SILVER + ELECTROLYTES (BATTERIES): May spontaneously combust. SODIUM PEROXIDE: Incandescent reaction. SULFUR: Violent reaction. TELLURIUM: Incandescent reaction. ZINC CHLORIDE: May increase flammability. MANGANESE DIOXIDE ALUMINUM: Violent reaction when heated. ANILINIUM PERCHLORATE: Explodes. BARIUM CHLORATE: May explode. CALCIUM CHLORATE: May explode. CALCIUM HYDRIDE: Incandesces when warmed. CHLORATES: May explode. CHLORINE TRIFLUORIDE: Incandescent reaction. COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; contact with finely divided materials may result in an explosion. DIBORON TETRAFLUORIDE: Violent reaction at 15 C. HYDROCHLORIC ACID: Releases chlorine fumes. HYDROGEN PEROXIDE: May explode. HYDROGEN SULFIDE: May ignite. HYDROXYLAMINIUM CHLORIDE (20% SOLN): Vigorous reaction. HYPOPHOSPHITES: Fire and explosion hazard. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. PERMONOSULFURIC ACID (92%): Explosive decomposition. PHOSPHIDES: Fire and explosion hazard. POTASSIUM AZIDE: Violent reaction when heated. REDUCING MATERIALS: Fire and explosion hazard. RUBIDIUM CARBIDE: Incandescent reaction at 350 C. SODIUM PEROXIDE: Violent decomposition. SULFIDES: Fire and explosion hazard. SULFUR: Fire and explosion hazard. CARBON ALKALI METALS: Contact may result in an exothermic reaction with ignition or an explosion. AMMONIUM NITRATE: Possible explosion when heated. AMMONIUM PERCHLORATE: Possible explosion on heating. BROMATES: Contact is likely to result in ignition or an explosion. CALCIUM HYPOCHLORITE: Possible explosion on heating. CHLORATES: Contact is likely to result in ignition or an explosion. CHLORINE MONOXIDE: Explodes. CHROMATES: Incompatible. DICHLORINE OXIDE: Explosion reaction. HALOGENS: Contact of carbon with any halogen is liable to result in ignition or an explosion. INTERHALOGENS: Contact of carbon with any interhalogen is liable to result in ignition or an explosion. IODATES: Contact is likely to result in ignition or an explosion. IODINE PENTOXIDE: Explodes when warmed. METAL NITRATES: Contact is likely to result in ignition or an explosion. NITRIC ACID: Violent reaction. NITROGEN OXIDE: Ignition with incandescence. NITROGEN TRIFLUORIDE: Explosion at reduced temperatures. OILS (UNSATURATED): Fire and explosion hazard. OXIDES: Contact with many oxides is likely to result in ignition or an explosion. OXIDIZERS (STRONG): Fire and explosion hazard. OXOSALTS: Contact is likely to result in ignition or an explosion. OXYGEN: May result in ignition or an explosion. OXYGEN DIFLUORIDE: Possible explosion. OZONE: Fire hazard. PEROXIDES: Contact is likely to result in ignition or an explosion. PEROXYFORMIC ACID: Violent oxidation. PEROXYFUROIC ACID: Explosive decomposition. POTASSIUM PERMANGANATE: Ignition on heating. SODIUM SULFIDE: May undergo spontaneous heating. TRIOXYGEN DIFLUORIDE: Ignition with possible explosion. POTASSIUM HYDROXIDE ACETIC ACID: Reacts violently. ACIDS: Violent reaction. ACROLEIN: Violent polymerization. ACRYLONITRILE: Violent polymerization. ALCOHOLS: Dissolves exothermically. ALUMINUM: Corrosive in the presence of moisture. AMMONIUM HEXACHLOROPLATINATE: Formation of explosive product. AMMONIUM SALTS: Evolution of ammonia gas. BENZOYL CHLORIDE + SODIUM AZIDE: Violent exothermic reaction. P-BIS(1,2-DIBROMOETHYL)BENZENE: Highly exothermic reaction. BROMOFORM: Violent, exothermic reaction. BROMOFORM + CYCLIC POLYETHYLENE OXIDES: Possible explosive reaction. CALCIUM CARBIDE + CHLORINE: Formation of explosive dichloroacetylene. CHLORINE: Explosive reaction. CHLORINE DIOXIDE: Explosion on contact. CHLORINE + HYDROGEN PEROXIDE: Produces red luminescence during reaction. CHLOROFORM + METHANOL: Intense exothermic reaction. CYCLOPENTADIENE: Vigorous exothermic resin formation. 1,2-DICHLOROETHYLENE: Formation of explosive and spontaneously flammable chloroacetylene. GERMANIUM: Incandescent reaction. GLASS: Slowly attacked. HYDROCARBONS (HALOGENATED): Violent reaction. HYPONITROUS ACID: Ignition reaction. LEAD: Corrosive in the presence of moisture. MALEIC ANHYDRIDE: Decomposes exothermically or explosively. METALS: Corrosive reaction with formation of flammable hydrogen gas. N-METHYL-N-NITROSOUREA + METHYLENE CHLORIDE: Explosive reaction. NITRIC TRICHLORIDE: Explosive reaction. NITROALKANES: Formation of explosive salts. NITROBENZENE + METHANOL (TRACE): Violent, exothermic reaction. NITROETHANE: Formation of explosive salt. NITROGEN TRICHLORIDE: Explosive reaction. NITROMETHANE: Formation of explosive salt. O-NITROPHENOL (MOLTEN): Reacts violently. NITROPROPANE: Formation of explosive salt. N-NITROSOMETHYLUREA + N-BUTYL ETHER: Formation of explosive compound. PHOSPHORUS: Evolution of flammable phosphine. POTASSIUM PEROXODISULFATE: Ignition reaction. POTASSIUM PERSULFATE + WATER: Exothermic reaction. SUGARS: Evolve carbon monoxide at or above 84 C. TETRACHLOROETHANE: Formation of flammable chloroacetylene gas. 2,2,3,3-TETRAFLUOROPROPANOL: Exothermic reaction. TETRAHYDROFURAN (PEROXIDISED): Possible explosive reaction. THORIUM DICARBIDE: Incandescent reaction on heating. TIN: Corrosive in the presence of moisture. TRICHLOROETHYLENE: Formation of explosive dichloroacetylene on heating. 2,4,6-TRINITROTOLUENE + METHANOL: Formation of explosive product. ZINC: Corrosive in the presence of moisture.
Hazardous Decomposition Products
zinc, manganese, hydrogen, potassium compounds, miscellaneous decomposition products
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
MANGANESE DIOXIDE (1313-13-9)
Oral LD50 Rat 9000 mg/kg
POTASSIUM HYDROXIDE (1310-58-3)
Oral LD50 Rat 284 mg/kg
CARBON, ACTIVATED (7440-44-0)
Oral LD50 Rat >10000 mg/kg
ZINC OXIDE (1314-13-2)
Oral LD50 Rat >5000 mg/kg
Component Carcinogenicity
MANGANESE DIOXIDE | 1313-13-9 |
ACGIH: | A4 - Not Classifiable as a Human Carcinogen (related to Manganese inorganic compounds) |
Medical Conditions Aggravated by Exposure
respiratory disorders, history of alcoholism, heart or cardiovascular disorders, eye disorders, skin disorders and allergies, blood system disorders, respiratory disorders, skin disorders and allergies, liver disorders, skin disorders, nervous system disorders, respiratory disorders,
Excessive zinc intake has been associated with a copper-deficiency anemia.
Inhalation - Acute Exposure
CARBON, ACTIVATED: Inhalation of dust may cause irritation GRAPHITE: Dust may be mildly irritating to the upper respiratory tract METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours POTASSIUM HYDROXIDE: Inhalation of dust or mist may cause symptoms of respiratory tract irritation possibly including coughing, choking, pain in the nose, mouth, and throat, lesions of the nasal septum, and burns of the mucous membranes If sufficient quantities are inhaled, pulmonary edema may develop, often with a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include weak, rapid pulse, hypotension, hemoconcentration, and moist rales ZINC: Inhalation of dust may cause irritation with difficulty in breathing and sneezing Neurological and psychiatric symptomology including irritability, upper extremity coarse intention tremor, incoordination, and ataxia have also been reported Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic, or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude, and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but it is quickly lost All symptoms usually subside within 24-36 hours MANGANESE COMPOUNDS: No data available.
Inhalation - Chronic Exposure
ZINC: Severe gastrointestinal disturbances and hypochromic anemia have been reported, but other chemicals may have contributed to the effects CARBON, ACTIVATED: Repeated or prolonged exposure may cause irritation, weight loss, weakness, pulmonary edema, decreased pulmonary function, and eventual lung damage GRAPHITE: Repeated inhalation of impure graphite for years may cause graphitosis, a progressive and disabling pneumonconiosis It is unclear what role silica impurities play in the occurrence and severity of the disease Exposed persons may be asymptomatic for years and then suddenly become disabled or may develop headache, cough, dyspnea, tightness in the chest, pain, depression, decreased appetite, black sputum, and digital clubbing Pulmonary edema with severe alveolar hypoxia resulting in cor pulmonale with pulmonary hypertension, right ventricular hypertrophy, and venous congestion have been reported following long exposure to graphite dust Histopathological examinations have revealed scarring of the lungs, large cysts filled with black fluid, focal and diffuse fibrogenic changes with perifocal emphysema, fibrotic lesions characterized by interwoven bands of collagen in the lungs and bronchial lymph nodes, and widely scattered particles, spicules, and plates of graphite Hydrothorax, pneumothorax, pleural thickening, and occasionally, pneumonitis may occur METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days POTASSIUM HYDROXIDE: Depending on the concentration and duration of exposure, repeated or prolonged exposure to corrosive substances may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances MANGANESE COMPOUNDS: Repeated or prolonged exposure to manganese compounds may result in systemic poisoning known as "manganism", a Parkinsonian-like syndrome It is characterized initially by anorexia, asthenia, headache, insomnia or somnolence, irritability, restlessness, and spasm or pain in the muscles Manganese psychosis may follow with uncontrollable behavior, unaccountable laughing or crying, visual hallucinations, confusion and euphoria Sexual excitement followed by impotence may occur These symptoms may disappear with the onset of true neurological manifestations of slow, slurred and irregular speech, monotonous tone, double vision, impaired hearing, difficulty with fine motor movements, and disturbances in gait and balance with frequent propulsion or retropulsion Mask-like face, decreased movement of the eyelids and eyes and tremors of the upper extremities and head may also occur Other signs and symptoms may include urinary bladder disturbances, excessive salivation and sweating, hematological changes, vasomotor disorders, decreased pulmonary function, kidney and possibly liver damage Removal from exposure shortly after onset of symptoms usually results in improvement, although there may be residual disturbances in gait and speech Once manganism is well established it becomes irreversible and progressive, but not fatal An increased incidence of bronchitis and pneumonitis has been reported in studies of workers exposed to manganese dust and fume, and although these effects have been confirmed by animal experiments, they may represent an aggravation of a pre-existing condition Allergic diseases of the respiratory tract have also been reported in one study.
Inhalation - Other Toxicity Information
MANGANESE DIOXIDE See information on metal fume fever and manganese compounds.
Skin Contact - Acute Exposure
ZINC: Dust may cause mechanical irritation and mild dermatitis in intertriginous areas Reaction with moisture on skin may result in serious burns POTASSIUM HYDROXIDE: Direct contact may cause severe pain, burns, and possibly brownish stains The corroded areas are soft, gelatinous and necrotic, and the tissue destruction may be deep GRAPHITE: No data available MANGANESE COMPOUNDS: Some manganese compounds may be irritating to the skin CARBON, ACTIVATED: May cause irritation.
Skin Contact - Chronic Exposure
GRAPHITE: Graphite has been reported to produce an allergic dermatitis in workers MANGANESE COMPOUNDS: Sensitization has been reported in guinea pigs POTASSIUM HYDROXIDE: Repeated or prolonged contact may cause dermatitis or effects similar to acute exposure Frequent applications of aqueous solutions (3-6 percent) of potassium hydroxide to the skin of mice for 46 weeks produced tumors identical to those from coal tar; warts occurred first and then skin tumors developed ZINC: 300 ug applied to human skin intermittently for 3 days caused mild irritation Allergic reactions are rare, but have been reported CARBON, ACTIVATED: Repeated or prolonged contact may cause mechanical irritation.
Skin Contact - Other Toxicity Information
MANGANESE DIOXIDE: May cause irritation with redness and pain Repeated or prolonged contact may cause dermatitis See information on manganese compounds.
Eye Contact - Acute Exposure
GRAPHITE: May cause slight mechanical irritation and discoloration of lids and conjunctiva Large quantities may obstruct aqueous outflow mechanically MANGANESE COMPOUNDS: Direct contact with manganese compounds may cause irritation POTASSIUM HYDROXIDE: Direct contact with solid or solutions may cause pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact There may be edema, destruction of epithelium, corneal opacification, and iritis When damage is less than excessive, these symptoms tend to ameliorate In severe burns, the full extent of the injury may not be immediately apparent Late complications may include persistent edema, vascularization, and scarring of the cornea, permanent opacity, staphyloma, cataract, and symblepharon ZINC: Dust may cause mechanical irritation or injury to the surface of the eye, with discomfort, reddening, and tearing Direct contact may cause serious corneal burns CARBON, ACTIVATED: Contact with dust may cause irritation.
Eye Contact - Chronic Exposure
POTASSIUM HYDROXIDE: Effects depend on concentration and duration of exposure Repeated or prolonged exposure to vapors and/or fumes may result in conjunctivitis or effects as in acute exposure MANGANESE COMPOUNDS: No data available GRAPHITE: No data available CARBON, ACTIVATED: Repeated or prolonged contact may cause irritation ZINC: No data available.
Eye - Other Toxicity Information
MANGANESE DIOXIDE: May cause redness, pain, tearing and irritation Repeated or prolonged contact may cause conjunctivitis See information on manganese compounds.
Ingestion - Acute Exposure
POTASSIUM HYDROXIDE: Ingestion of 273 mg/kg of potassium hydroxide was lethal to rats tested Ingestion of strong alkalies may be followed by severe pain, vomiting, diarrhea, and collapse The vomitus contains blood and desquamated mucosal lining If death does not occur in the first 24 hours, the patient may improve for 2-4 days and then have a sudden onset of severe abdominal pain, boardlike abdominal rigidity, and rapid fall of blood pressure indicating delayed gastric or esophageal perforation Damage to the esophagus and stomach after ingestion may progress for 2-3 weeks Death from peritonitis may occur as late as 1 month after ingestion Even though the patient recovers from the immediate damage, esophageal stricture may occur weeks, months or even years later to make swallowing difficult CARBON, ACTIVATED: Ingestion of large amounts may cause gastrointestinal irritation with nausea, vomiting, and stomach pain ZINC: Large oral doses may cause gastrointestinal distress with stomach cramps, dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting, hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, tightness in the throat, shock, collapse, renal failure, and death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach MANGANESE COMPOUNDS: Ingestion of extremely large doses of manganese compounds may cause gastrointestinal irritation, resulting in nausea, vomiting, and diarrhea, making less available for absorption GRAPHITE: No data available.
Ingestion - Chronic Exposure
CARBON, ACTIVATED: No data available ZINC: Patients taking zinc in amounts 10 times the RDA for months and years have not shown any adverse reactions Excessive absorption may cause copper-deficiency anemia Ingestion of approximately 85.7 mg/kg/day for 2 days caused lethargy, lightheadedness, staggering, and difficulty in writing clearly 2 people who ingested 40 ppm in drinking water for several months experienced lack of concentration, drowsiness, mental and physical fatigue, pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, nausea, weight loss, and lassitude 90 ppm in the diet for 5 weeks has resulted in a decrease in the HDL cholesterol level Pancreatic abnormalities have also been observed A diet of 0.25% in rats caused no injury; above 0.25% there was breakdown of the homeostatic mechanism, growth retardation, hypochromic anemia, and defective mineralization of the bones Mice fed 500 ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm for 13 weeks caused liver and kidney damage and some deaths Cows fed 2% for 2 days developed severe enteritis, with 7 of 40 dying Severe pulmonary emphysema and changes in the myocardium, kidneys, and liver were observed Pigs fed >1000 ppm had reduced food intake and weight gain; at >2000 ppm, death occurred after 2 weeks Bone changes were observed in foals fed 5400 ppm High dietary levels of zinc have been associated with reduced fetal weights, altered concentrations of fetal iron and copper, and alopecia and reduced growth of offspring in animals POTASSIUM HYDROXIDE: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion GRAPHITE: No data available MANGANESE COMPOUNDS: Manganese poisoning, as described in chronic inhalation, has been reported in persons drinking manganese-contaminated well water.
Ingestion - Other Toxicity Information
MANGANESE DIOXIDE See information on manganese compounds.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
ZINC | 7440-66-6 |
Fish: | LC50 96 h Pimephales promelas 2.16 - 3.05 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.211 - 0.269 mg/L [semi-static]; LC50 96 h Pimephales promelas 2.66 mg/L [static]; LC50 96 h Cyprinus carpio 30 mg/L; LC50 96 h Cyprinus carpio 0.45 mg/L [semi-static]; LC50 96 h Cyprinus carpio 7.8 mg/L [static]; LC50 96 h Lepomis macrochirus 3.5 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.59 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 0.41 mg/L [static] |
Algae: | EC50 96 h Pseudokirchneriella subcapitata 0.11 - 0.271 mg/L [static] EPA; EC50 72 h Pseudokirchneriella subcapitata 0.09 - 0.125 mg/L [static] EPA |
Invertebrate: | EC50 48 h Daphnia magna 0.139 - 0.908 mg/L [Static] EPA |
Bioconcentration Factor
MANGANESE DIOXIDE | 1313-13-9 |
BCF | (no bioaccumulation expected) |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
TDG Information:
No Classification assigned.
ADR Information:
No Classification assigned.
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
ZINC (7440-66-6)
Restriction(s): E [UN1435] (III, ashes); E [UN1436] (I, dust or powder); D/E [UN1436] (II, dust or powder); E [UN1436] (III, dust or powder)
POTASSIUM HYDROXIDE (1310-58-3)
Restriction(s): E [UN1813] (II, solid); E [UN1814] (II, solution); E [UN1814] (III, solution)
CARBON, ACTIVATED (7440-44-0)
Restriction(s): D/E [UN1361] (II); E [UN1361] (III); E [UN1362] (III)
RID Information:
No Classification assigned.
IATA Information:
No Classification assigned.
ICAO Information:
No Classification assigned.
IMDG Information:
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
MANGANESE DIOXIDE | 1313-13-9 |
SARA 313: | 1 % de minimis concentration (related to Manganese compounds) |
ZINC | 7440-66-6 |
SARA 313: | 1 % de minimis concentration (dust or fume only) |
CERCLA: | 454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm) |
POTASSIUM HYDROXIDE | 1310-58-3 |
CERCLA: | 1000 lb final RQ; 454 kg final RQ |
ZINC OXIDE | 1314-13-2 |
SARA 313: | 1 % de minimis concentration (related to Zinc compounds) |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Fire: No Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
MANGANESE DIOXIDE | 1313-13-9 | Yes | No | Yes | Yes | Yes |
ZINC | 7440-66-6 | Yes | Yes | No | Yes | Yes |
POTASSIUM HYDROXIDE | 1310-58-3 | Yes | Yes | Yes | Yes | Yes |
GRAPHITE | 7782-42-5 | Yes | Yes | Yes | Yes | Yes |
ZINC OXIDE | 1314-13-2 | Yes | Yes | Yes | Yes | Yes |
Not listed under California Proposition 65
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
MANGANESE DIOXIDE | 1313-13-9 |
| 1 % (related to Manganese compounds) |
POTASSIUM HYDROXIDE | 1310-58-3 |
| 1 % |
ZINC OXIDE | 1314-13-2 |
| 1 % |
Germany Water Classification
MANGANESE DIOXIDE (1313-13-9)
ID Number 7145 , hazard class 1 - low hazard to waters
ZINC (7440-66-6)
ID Number 1349 , not considered hazardous to water (particle size >1mm)
ID Number 7325 , hazard class 2 - hazard to waters (particle size <=1 mm)
POTASSIUM HYDROXIDE (1310-58-3)
ID Number 345 , hazard class 1 - low hazard to waters
CARBON, ACTIVATED (7440-44-0)
ID Number 801 , not considered hazardous to water
GRAPHITE (7782-42-5)
ID Number 801 , not considered hazardous to water
ZINC OXIDE (1314-13-2)
ID Number 2187 , hazard class 2 - hazard to waters
REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006
This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process
GRAPHITE (7782-42-5)
Assigned to Member State Germany (Initial Grounds for Concern: Suspected C, Wide dispersive use, Exposure on environment, Consumer use, Cumulative exposure, Exposure of workers)
ZINC OXIDE (1314-13-2)
Assigned to Member State Germany (Initial Grounds for Concern: Other hazard related to nano form, Wide dispersive use, Consumer use, Exposure of workers, Other exposure)
Symbol(s)
Xn Harmful
C Corrosive
Risk Phrases
R20/22 Harmful by inhalation and if swallowed.
R34 Causes burns.
R41 Risk of serious damage to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
MANGANESE DIOXIDE | 1313-13-9 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
ZINC | 7440-66-6 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
POTASSIUM HYDROXIDE | 1310-58-3 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
CARBON, ACTIVATED | 7440-44-0 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
GRAPHITE | 7782-42-5 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
ZINC OXIDE | 1314-13-2 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
MANGANESE DIOXIDE (1313-13-9)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
ZINC (7440-66-6)
Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (dust and powder; pyrophoric)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (dust and powder; pyrophoric)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (dust and powder; stabilised)
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (dust and powder, pyrophoric)
POTASSIUM HYDROXIDE (1310-58-3)
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
ZINC OXIDE (1314-13-2)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H260 In contact with water releases flammable gases which may ignite spontaneously
H410 Very toxic to aquatic life with long lasting effects
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
POTASSIUM HYDROXIDE (1310-58-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC OXIDE (1314-13-2)
Symbol(s)
Signal Word Warning
Hazard(s)
H410 Very toxic to aquatic life with long lasting effects
Prevention
P273 Avoid release to the environment
Response
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
MANGANESE DIOXIDE (1313-13-9)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)
POTASSIUM HYDROXIDE (1310-58-3)
Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)
Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage
ZINC OXIDE (1314-13-2)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
POTASSIUM HYDROXIDE (1310-58-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC OXIDE (1314-13-2)
Symbol(s)
Signal Word Warning
Hazard(s)
H410 Very toxic to aquatic life with long lasting effects
Prevention
P273 Avoid release to the environment
Response
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
MANGANESE DIOXIDE (1313-13-9)
Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: H26-B-098 / R-044
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 201
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (nervous system,respiratory system) Approval:
Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life Approval: H26-B-098 / R-044
ZINC (7440-66-6)
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 20A2067
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 20A2067
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 20A2067
POTASSIUM HYDROXIDE (1310-58-3)
Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 598
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage Approval: 598
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 598
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 598
Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways Approval: 598
ZINC OXIDE (1314-13-2)
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 25B0001
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system,systemic toxicity) Approval: 25B0001
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 25B0001
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H341 Suspected of causing genetic defects
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H413 May cause long lasting harmful effects to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P321 Specific treatment (see label)
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Warning
Hazard(s)
H320 Causes eye irritation
H410 Very toxic to aquatic life with long lasting effects
Prevention
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
POTASSIUM HYDROXIDE (1310-58-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs
H304 May be fatal if swallowed and enters airways
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P331 Do NOT induce vomiting
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC OXIDE (1314-13-2)
Symbol(s)
Signal Word Danger
Hazard(s)
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H410 Very toxic to aquatic life with long lasting effects
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
MANGANESE DIOXIDE (1313-13-9)
MOEL: | Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure cardiovascular system,nervous system,respiratory system |
ZINC (7440-66-6)
MOEL: | Acute toxicity Oral Category 3 H301 Toxic if swallowed Carcinogenicity Category 1A H350 May cause cancer Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life |
NEMA: | Flammable Solids Category 2 H228 Flammable solid |
POTASSIUM HYDROXIDE (1310-58-3)
MOE: | Acute toxicity Oral Category 4 H302 Harmful if swallowed. Skin corrosion/irritation Category 1 H314 Causes severe skin burns and eye damage. |
MOEL: | Acute toxicity Oral Category 3 H301 Toxic if swallowed Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways |
GRAPHITE (7782-42-5)
MOEL: | Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure circulatory system,liver |
ZINC OXIDE (1314-13-2)
MOEL: | Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs body,respiratory system Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure lungs Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P321 Specific treatment (see label)
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H350 May cause cancer
H400 Very toxic to aquatic life
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P330 Rinse mouth
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H228 Flammable solid
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P240 Ground/Bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P370+P378 In case of fire: Use appropriate media for extinction
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs
H304 May be fatal if swallowed and enters airways
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P331 Do NOT induce vomiting
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Warning
Hazard(s)
H373 May cause damage to organs through prolonged or repeated exposure
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray
Response
P314 Get medical advice/attention if you feel unwell
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
MANGANESE DIOXIDE (1313-13-9) Approval: HSR003741
Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 2 H330 Fatal if inhaled
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation
Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Reproductive Toxicity Effects on or via lactation H362 May cause harm to breast-fed children
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (Nervous System)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
ZINC (7440-66-6) Approval: HSR001301
Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder/dust, PG I)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder/dust, PG I)
Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled (powder/dust, PG I)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder/dust, PG I)
POTASSIUM HYDROXIDE (1310-58-3) Approval: HSR001546
Corrosive to Metals Category 1 H290 May be corrosive to metals
Acute toxicity Oral Category 3 H301 Toxic if swallowed
Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage
Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates
CARBON, ACTIVATED (7440-44-0) Approval: HSR001271
Self-Heating Substances and Mixtures Category 2 H252 Self-heating in large quantities, may catch fire
ZINC OXIDE (1314-13-2) Approval: HSR003104
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (algal,crustacean,fish)
Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Danger
Hazard(s)
H302 Harmful if swallowed
H330 Fatal if inhaled
H319 Causes serious eye irritation
H361 Suspected of damaging fertility or the unborn child
H362 May cause harm to breast-fed children
H372 Causes damage to organs through prolonged or repeated exposure
H433 Harmful to terrestrial vertebrates
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P263 Avoid contact during pregnancy/while nursing
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P320 Specific treatment is urgent (see label)
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H251 Self-heating, may catch fire
H260 In contact with water releases flammable gases which may ignite spontaneously
H333 May be harmful if inhaled
H400 Very toxic to aquatic life
Prevention
P235+P410 Keep cool. Protect from sunlight
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P407 Maintain air gap between stacks/pallets
P413 Store bulk masses at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
POTASSIUM HYDROXIDE (1310-58-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H290 May be corrosive to metals
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H402 Harmful to aquatic life
H432 Toxic to terrestrial vertebrates
Prevention
P234 Keep only in original container
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P390 Absorb spillage to prevent material-damage
Storage
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
CARBON, ACTIVATED (7440-44-0)
Symbol(s)
Signal Word Warning
Hazard(s)
H252 Self-heating in large quantities, may catch fire
Prevention
P235+P410 Keep cool. Protect from sunlight
P280 Wear protective gloves/protective clothing/eye protection/face protection
Storage
P407 Maintain air gap between stacks/pallets
P413 Store bulk masses at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
ZINC OXIDE (1314-13-2)
Symbol(s)
Signal Word Warning
Hazard(s)
H410 Very toxic to aquatic life with long lasting effects
H433 Harmful to terrestrial vertebrates
Prevention
P273 Avoid release to the environment
Response
P391 Collect spillage
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website
ZINC (7440-66-6)
Listing: Present (powder)
POTASSIUM HYDROXIDE (1310-58-3)
Listing: Present (solution >=0.5% and <2% by mass)
Listing: Present (solution >=2% and <25% by mass)
Listing: Present (solution >=25% by mass)
Listing: Present (solid)
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
MANGANESE DIOXIDE (1313-13-9)
Taiwan: | Acute toxicity Oral Category 4 H302 Harmful if swallowed |
| Acute toxicity Inhalation Category 4 H332 Harmful if inhaled |
| Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation |
| Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
ZINC (7440-66-6)
Taiwan: | Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder) |
| Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder) |
| Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation (powder) |
| Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (powder) |
POTASSIUM HYDROXIDE (1310-58-3)
Taiwan: | Corrosive to Metals Category 1 H290 May be corrosive to metals |
| Acute toxicity Oral Category 3 H301 Toxic if swallowed |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
CARBON, ACTIVATED (7440-44-0)
Taiwan: | Self-Heating Substances and Mixtures Category 2 H252 Self-heating in large quantities, may catch fire |
ZINC OXIDE (1314-13-2)
Taiwan: | Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation |
| Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation |
| Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation |
| Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
MANGANESE DIOXIDE (1313-13-9)
Symbol(s)
Signal Word Warning
Hazard(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P332+P313 If skin irritation occurs: Get medical advice/attention
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
ZINC (7440-66-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H250 Catches fire spontaneously if exposed to air
H261 In contact with water releases flammable gases
H316 Causes mild skin irritation
H410 Very toxic to aquatic life with long lasting effects
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P231+P232 Handle under inert gas. Protect from moisture
P280 Wear protective gloves/protective clothing/eye protection/face protection
P273 Avoid release to the environment
Response
P332+P313 If skin irritation occurs: Get medical advice/attention
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P370+P378 In case of fire: Use appropriate media for extinction
P391 Collect spillage
Storage
P402+P404 Store in a dry place. Store in a closed container
P422 Store contents under appropriate liquid or inert gas as specified
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
POTASSIUM HYDROXIDE (1310-58-3)
Symbol(s)
Signal Word Danger
Hazard(s)
H290 May be corrosive to metals
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
Prevention
P234 Keep only in original container
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P363 Wash contaminated clothing before reuse
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P321 Specific treatment (see label)
P330 Rinse mouth
P390 Absorb spillage to prevent material-damage
Storage
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
CARBON, ACTIVATED (7440-44-0)
Symbol(s)
Signal Word Warning
Hazard(s)
H252 Self-heating in large quantities, may catch fire
Prevention
P235+P410 Keep cool. Protect from sunlight
P280 Wear protective gloves/protective clothing/eye protection/face protection
Storage
P407 Maintain air gap between stacks/pallets
P413 Store bulk masses at temperatures not exceeding manufacturer recommendations
P420 Store away from other materials
ZINC OXIDE (1314-13-2)
Symbol(s)
Signal Word Warning
Hazard(s)
H316 Causes mild skin irritation
H320 Causes eye irritation
H335 May cause respiratory irritation
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P273 Avoid release to the environment
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P332+P313 If skin irritation occurs: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved