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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

DURACELL ALKALINE BATTERIES


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Synonyms 

ALKALINE MANGANESE DIOXIDE CELLS; MN1300 (D); MN1400 (C); MN1500 (AA); MN2400 (AAA); MN2500 (AAAA; MN908 (LANTERN 6V); MN918 (LANTERN 4.5V); MN1604 (9V); MN21 (12V); MN9100 (N); DAC100; DAC105; DAC110; DAC116-118; DAC123-124; DAC130; DAC200; DAC610; DAC810; DAC820; DAC918


Product Use 

battery 









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  dark 

Change in color: Not available

Physical Form: battery

Health Hazards:  This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns 




Potential Health Effects 
Inhalation 

Short Term:  This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe) 

Long Term:  same as effects reported in short term exposure 




Skin Contact 

Short Term:  This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe) 

Long Term:  irritation (possibly severe), allergic reactions 




Eye Contact 

Short Term:  This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, irritation (possibly severe), tearing 

Long Term:  irritation (possibly severe) 




Ingestion 

Short Term:  This product is considered to be nonhazardous, however the following effects may occur as a result of damage to the product:, burns 

Long Term:  same as effects reported in short term exposure 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
1313-13-9 215-202-6 --MANGANESE DIOXIDEAcute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H33235 - 40
7440-66-6 231-175-3 --ZINC--10 - 15
1310-58-3 215-181-3 --POTASSIUM HYDROXIDEAcute Tox. 4 (Oral) - H302 Skin Corr. 1A - H3145 - 10
7440-44-0 231-153-3 --CARBON, ACTIVATED--1 - 5
7782-42-5 231-955-3 --GRAPHITE--1 - 5
1314-13-2 215-222-5 --ZINC OXIDEAquatic Acute 1 - H400 Aquatic Chronic 1 - H410<1




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Manganese oxides, Manganese compounds, inorganic, Manganese compounds, n.o.s., Zinc compounds, Graphite, synthetic.









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Get medical attention. 


Skin 

Wash exposed skin with soap and water. 


Eyes 

Flush eyes with plenty of water. 


Ingestion 

If a large amount is swallowed, get medical attention. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. 


Extinguishing Media 

Use extinguishing agents appropriate for surrounding fire. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Water Release 

Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. 


Occupational spill/release 

Small spills of the liquid component: Collect spilled material in appropriate container for disposal. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









* * * Section 7 - HANDLING AND STORAGE  * * *


Handling Procedures 

Use methods to minimize dust. 


Storage Procedures 

Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

MANGANESE DIOXIDE1313-13-9
ACGIH: 0.02 mg/m3 TWA as Mn respirable particulate matter; 0.1 mg/m3 TWA as Mn inhalable particulate matter (related to Manganese inorganic compounds)
NIOSH: 1 mg/m3 TWA as Mn (related to Manganese compounds)
 3 mg/m3 STEL as Mn (related to Manganese compounds)
 500 mg/m3 IDLH as Mn (related to Manganese compounds)
OSHA (US): 5 mg/m3 Ceiling as Mn (related to Manganese compounds)
Mexico: 0.2 mg/m3 TWA VLE-PPT as Mn (related to Manganese inorganic compounds)
POTASSIUM HYDROXIDE1310-58-3
ACGIH: 2 mg/m3 Ceiling
NIOSH: 2 mg/m3 Ceiling
CARBON, ACTIVATED7440-44-0
Mexico: 2 mg/m3 TWA VLE-PPT dust
GRAPHITE7782-42-5
ACGIH: 2 mg/m3 TWA (all forms except graphite fibers) respirable particulate matter
NIOSH: 2.5 mg/m3 TWA (natural) respirable dust
 1250 mg/m3 IDLH
OSHA (US): 15 mg/m3 TWA (synthetic) total dust; 5 mg/m3 TWA (synthetic) respirable fraction
 15 mppcf TWA (natural)
Mexico: 2 mg/m3 TWA VLE-PPT (synthetic and natural)
ZINC OXIDE1314-13-2
ACGIH: 2 mg/m3 TWA respirable particulate matter
 10 mg/m3 STEL respirable particulate matter
NIOSH: 5 mg/m3 TWA dust and fume
 10 mg/m3 STEL fume
 15 mg/m3 Ceiling dust
 500 mg/m3 IDLH
OSHA (US): 5 mg/m3 TWA fume; 15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction
Mexico: 5 mg/m3 TWA VLE-PPT fume; 10 mg/m3 TWA VLE-PPT dust
 10 mg/m3 STEL [PPT-CT] fume




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Based on available information, additional ventilation is not required. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Eye protection not required under normal conditions. 


Protective Clothing 

Protective clothing is not required under normal conditions. 


Glove Recommendations 

Protective gloves are not required under normal conditions. 


Protective Materials 

neoprene, rubber, latex 


Respiratory Protection 

No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor Not available Color dark
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility Not available Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form battery











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Protect from physical damage and heat. Avoid heat, flames, sparks and other sources of ignition. 


Incompatible Materials 

oxidizing materials 


GRAPHITE CHLORINE TRIFLUORIDE: Ignition. FLUORINE: Explosive reaction. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN: Fire and explosion. POTASSIUM (BURNING): Explosion. POTASSIUM PEROXIDE: Fire and explosion hazard. ZINC ACIDS: Evolves hydrogen gas which may be ignited by the heat of the reaction ALKALIES: Evolves hydrogen gas which may be ignited by the heat of the reaction. ALUMINUM (POWDER): Possible ignition. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL: May spark on impact. AMMONIUM NITRATE: Violent reaction or formation of explosive mixture. AMMONIUM SULFIDE: May explode in a closed container. ARSENIC: Incandescent reaction when heated. ARSENIC TRIOXIDE: Explosive reaction on heating. BROMOMETHANE: Forms flammable compounds. CADMIUM: Incandescent reaction. CALCIUM CHLORIDE: Evolves hydrogen gas which may be ignited by the heat of the reaction. CARBON DISULFIDE: Incandescent reaction. CARBON TETRACHLORIDE + METHANOL: Extremely vigorous reaction. CHLORATES: Forms shock-sensitive mixtures. CHLORINATED RUBBER: Violent or explosive reaction at elevated temperatures. CHROMIC ANHYDRIDE: Violent reaction and possible ignition. COBALT HALIDE (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. ETHYL ACETOACETATE + TRIBROMONEOPENTYL ALCOHOL: May react explosively. HALOCARBONS: Possible violent reaction with ignition. HALOGENS: Possible ignition. HYDRAZINE NITRATE: Ignites on warming. HYDROXYLAMINE: May ignite or explode when heated. INTERHALOGENS: Violent reaction and possible ignition. LEAD AZIDE: Increased sensitivity to explosive decomposition. MANGANESE DICHLORIDE: Explosive reaction when heated. METAL OXIDES: Possible ignition or incandescent reaction. NITRIC ACID: Incandescent reaction. 2-NITROANISOLE + SODIUM HYDROXIDE: Exothermic reaction. NITROBENZENE: May form pyrophoric residue. NITRYL FLUORIDE: Incandesces when warmed. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXYFORMIC ACID: Violent explosion on contact. POTASSIUM NITRATE: Explosive reaction on heating. POTASSIUM PEROXIDE: Incandescent reaction. RHODIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. RUTHENIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. SELENIUM: Incandescent reaction. SELENINYL BROMIDE: Ignition. SILVER + ELECTROLYTES (BATTERIES): May spontaneously combust. SODIUM PEROXIDE: Incandescent reaction. SULFUR: Violent reaction. TELLURIUM: Incandescent reaction. ZINC CHLORIDE: May increase flammability. MANGANESE DIOXIDE ALUMINUM: Violent reaction when heated. ANILINIUM PERCHLORATE: Explodes. BARIUM CHLORATE: May explode. CALCIUM CHLORATE: May explode. CALCIUM HYDRIDE: Incandesces when warmed. CHLORATES: May explode. CHLORINE TRIFLUORIDE: Incandescent reaction. COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; contact with finely divided materials may result in an explosion. DIBORON TETRAFLUORIDE: Violent reaction at 15 C. HYDROCHLORIC ACID: Releases chlorine fumes. HYDROGEN PEROXIDE: May explode. HYDROGEN SULFIDE: May ignite. HYDROXYLAMINIUM CHLORIDE (20% SOLN): Vigorous reaction. HYPOPHOSPHITES: Fire and explosion hazard. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. PERMONOSULFURIC ACID (92%): Explosive decomposition. PHOSPHIDES: Fire and explosion hazard. POTASSIUM AZIDE: Violent reaction when heated. REDUCING MATERIALS: Fire and explosion hazard. RUBIDIUM CARBIDE: Incandescent reaction at 350 C. SODIUM PEROXIDE: Violent decomposition. SULFIDES: Fire and explosion hazard. SULFUR: Fire and explosion hazard. CARBON ALKALI METALS: Contact may result in an exothermic reaction with ignition or an explosion. AMMONIUM NITRATE: Possible explosion when heated. AMMONIUM PERCHLORATE: Possible explosion on heating. BROMATES: Contact is likely to result in ignition or an explosion. CALCIUM HYPOCHLORITE: Possible explosion on heating. CHLORATES: Contact is likely to result in ignition or an explosion. CHLORINE MONOXIDE: Explodes. CHROMATES: Incompatible. DICHLORINE OXIDE: Explosion reaction. HALOGENS: Contact of carbon with any halogen is liable to result in ignition or an explosion. INTERHALOGENS: Contact of carbon with any interhalogen is liable to result in ignition or an explosion. IODATES: Contact is likely to result in ignition or an explosion. IODINE PENTOXIDE: Explodes when warmed. METAL NITRATES: Contact is likely to result in ignition or an explosion. NITRIC ACID: Violent reaction. NITROGEN OXIDE: Ignition with incandescence. NITROGEN TRIFLUORIDE: Explosion at reduced temperatures. OILS (UNSATURATED): Fire and explosion hazard. OXIDES: Contact with many oxides is likely to result in ignition or an explosion. OXIDIZERS (STRONG): Fire and explosion hazard. OXOSALTS: Contact is likely to result in ignition or an explosion. OXYGEN: May result in ignition or an explosion. OXYGEN DIFLUORIDE: Possible explosion. OZONE: Fire hazard. PEROXIDES: Contact is likely to result in ignition or an explosion. PEROXYFORMIC ACID: Violent oxidation. PEROXYFUROIC ACID: Explosive decomposition. POTASSIUM PERMANGANATE: Ignition on heating. SODIUM SULFIDE: May undergo spontaneous heating. TRIOXYGEN DIFLUORIDE: Ignition with possible explosion. POTASSIUM HYDROXIDE ACETIC ACID: Reacts violently. ACIDS: Violent reaction. ACROLEIN: Violent polymerization. ACRYLONITRILE: Violent polymerization. ALCOHOLS: Dissolves exothermically. ALUMINUM: Corrosive in the presence of moisture. AMMONIUM HEXACHLOROPLATINATE: Formation of explosive product. AMMONIUM SALTS: Evolution of ammonia gas. BENZOYL CHLORIDE + SODIUM AZIDE: Violent exothermic reaction. P-BIS(1,2-DIBROMOETHYL)BENZENE: Highly exothermic reaction. BROMOFORM: Violent, exothermic reaction. BROMOFORM + CYCLIC POLYETHYLENE OXIDES: Possible explosive reaction. CALCIUM CARBIDE + CHLORINE: Formation of explosive dichloroacetylene. CHLORINE: Explosive reaction. CHLORINE DIOXIDE: Explosion on contact. CHLORINE + HYDROGEN PEROXIDE: Produces red luminescence during reaction. CHLOROFORM + METHANOL: Intense exothermic reaction. CYCLOPENTADIENE: Vigorous exothermic resin formation. 1,2-DICHLOROETHYLENE: Formation of explosive and spontaneously flammable chloroacetylene. GERMANIUM: Incandescent reaction. GLASS: Slowly attacked. HYDROCARBONS (HALOGENATED): Violent reaction. HYPONITROUS ACID: Ignition reaction. LEAD: Corrosive in the presence of moisture. MALEIC ANHYDRIDE: Decomposes exothermically or explosively. METALS: Corrosive reaction with formation of flammable hydrogen gas. N-METHYL-N-NITROSOUREA + METHYLENE CHLORIDE: Explosive reaction. NITRIC TRICHLORIDE: Explosive reaction. NITROALKANES: Formation of explosive salts. NITROBENZENE + METHANOL (TRACE): Violent, exothermic reaction. NITROETHANE: Formation of explosive salt. NITROGEN TRICHLORIDE: Explosive reaction. NITROMETHANE: Formation of explosive salt. O-NITROPHENOL (MOLTEN): Reacts violently. NITROPROPANE: Formation of explosive salt. N-NITROSOMETHYLUREA + N-BUTYL ETHER: Formation of explosive compound. PHOSPHORUS: Evolution of flammable phosphine. POTASSIUM PEROXODISULFATE: Ignition reaction. POTASSIUM PERSULFATE + WATER: Exothermic reaction. SUGARS: Evolve carbon monoxide at or above 84 C. TETRACHLOROETHANE: Formation of flammable chloroacetylene gas. 2,2,3,3-TETRAFLUOROPROPANOL: Exothermic reaction. TETRAHYDROFURAN (PEROXIDISED): Possible explosive reaction. THORIUM DICARBIDE: Incandescent reaction on heating. TIN: Corrosive in the presence of moisture. TRICHLOROETHYLENE: Formation of explosive dichloroacetylene on heating. 2,4,6-TRINITROTOLUENE + METHANOL: Formation of explosive product. ZINC: Corrosive in the presence of moisture.

Hazardous Decomposition Products 

zinc, manganese, hydrogen, potassium compounds, miscellaneous decomposition products 


Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
MANGANESE DIOXIDE (1313-13-9)

Oral LD50 Rat 9000 mg/kg

POTASSIUM HYDROXIDE (1310-58-3)

Oral LD50 Rat 284 mg/kg

CARBON, ACTIVATED (7440-44-0)

Oral LD50 Rat >10000 mg/kg

ZINC OXIDE (1314-13-2)

Oral LD50 Rat >5000 mg/kg




Component Carcinogenicity

MANGANESE DIOXIDE1313-13-9
ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Manganese inorganic compounds)








Medical Conditions Aggravated by Exposure 

respiratory disorders, history of alcoholism, heart or cardiovascular disorders, eye disorders, skin disorders and allergies, blood system disorders, respiratory disorders, skin disorders and allergies, liver disorders, skin disorders, nervous system disorders, respiratory disorders, 


Excessive zinc intake has been associated with a copper-deficiency anemia. 

Inhalation - Acute Exposure 

CARBON, ACTIVATED: Inhalation of dust may cause irritation GRAPHITE: Dust may be mildly irritating to the upper respiratory tract METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours POTASSIUM HYDROXIDE: Inhalation of dust or mist may cause symptoms of respiratory tract irritation possibly including coughing, choking, pain in the nose, mouth, and throat, lesions of the nasal septum, and burns of the mucous membranes If sufficient quantities are inhaled, pulmonary edema may develop, often with a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, frothy sputum, cyanosis, and dizziness Physical findings may include weak, rapid pulse, hypotension, hemoconcentration, and moist rales ZINC: Inhalation of dust may cause irritation with difficulty in breathing and sneezing Neurological and psychiatric symptomology including irritability, upper extremity coarse intention tremor, incoordination, and ataxia have also been reported Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic, or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude, and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but it is quickly lost All symptoms usually subside within 24-36 hours MANGANESE COMPOUNDS: No data available.


Inhalation - Chronic Exposure 

ZINC: Severe gastrointestinal disturbances and hypochromic anemia have been reported, but other chemicals may have contributed to the effects CARBON, ACTIVATED: Repeated or prolonged exposure may cause irritation, weight loss, weakness, pulmonary edema, decreased pulmonary function, and eventual lung damage GRAPHITE: Repeated inhalation of impure graphite for years may cause graphitosis, a progressive and disabling pneumonconiosis It is unclear what role silica impurities play in the occurrence and severity of the disease Exposed persons may be asymptomatic for years and then suddenly become disabled or may develop headache, cough, dyspnea, tightness in the chest, pain, depression, decreased appetite, black sputum, and digital clubbing Pulmonary edema with severe alveolar hypoxia resulting in cor pulmonale with pulmonary hypertension, right ventricular hypertrophy, and venous congestion have been reported following long exposure to graphite dust Histopathological examinations have revealed scarring of the lungs, large cysts filled with black fluid, focal and diffuse fibrogenic changes with perifocal emphysema, fibrotic lesions characterized by interwoven bands of collagen in the lungs and bronchial lymph nodes, and widely scattered particles, spicules, and plates of graphite Hydrothorax, pneumothorax, pleural thickening, and occasionally, pneumonitis may occur METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days POTASSIUM HYDROXIDE: Depending on the concentration and duration of exposure, repeated or prolonged exposure to corrosive substances may cause inflammatory and ulcerative changes in the mouth and possibly bronchial and gastrointestinal disturbances MANGANESE COMPOUNDS: Repeated or prolonged exposure to manganese compounds may result in systemic poisoning known as "manganism", a Parkinsonian-like syndrome It is characterized initially by anorexia, asthenia, headache, insomnia or somnolence, irritability, restlessness, and spasm or pain in the muscles Manganese psychosis may follow with uncontrollable behavior, unaccountable laughing or crying, visual hallucinations, confusion and euphoria Sexual excitement followed by impotence may occur These symptoms may disappear with the onset of true neurological manifestations of slow, slurred and irregular speech, monotonous tone, double vision, impaired hearing, difficulty with fine motor movements, and disturbances in gait and balance with frequent propulsion or retropulsion Mask-like face, decreased movement of the eyelids and eyes and tremors of the upper extremities and head may also occur Other signs and symptoms may include urinary bladder disturbances, excessive salivation and sweating, hematological changes, vasomotor disorders, decreased pulmonary function, kidney and possibly liver damage Removal from exposure shortly after onset of symptoms usually results in improvement, although there may be residual disturbances in gait and speech Once manganism is well established it becomes irreversible and progressive, but not fatal An increased incidence of bronchitis and pneumonitis has been reported in studies of workers exposed to manganese dust and fume, and although these effects have been confirmed by animal experiments, they may represent an aggravation of a pre-existing condition Allergic diseases of the respiratory tract have also been reported in one study.


Inhalation - Other Toxicity Information 

MANGANESE DIOXIDE See information on metal fume fever and manganese compounds.


Skin Contact - Acute Exposure 

ZINC: Dust may cause mechanical irritation and mild dermatitis in intertriginous areas Reaction with moisture on skin may result in serious burns POTASSIUM HYDROXIDE: Direct contact may cause severe pain, burns, and possibly brownish stains The corroded areas are soft, gelatinous and necrotic, and the tissue destruction may be deep GRAPHITE: No data available MANGANESE COMPOUNDS: Some manganese compounds may be irritating to the skin CARBON, ACTIVATED: May cause irritation.


Skin Contact - Chronic Exposure 

GRAPHITE: Graphite has been reported to produce an allergic dermatitis in workers MANGANESE COMPOUNDS: Sensitization has been reported in guinea pigs POTASSIUM HYDROXIDE: Repeated or prolonged contact may cause dermatitis or effects similar to acute exposure Frequent applications of aqueous solutions (3-6 percent) of potassium hydroxide to the skin of mice for 46 weeks produced tumors identical to those from coal tar; warts occurred first and then skin tumors developed ZINC: 300 ug applied to human skin intermittently for 3 days caused mild irritation Allergic reactions are rare, but have been reported CARBON, ACTIVATED: Repeated or prolonged contact may cause mechanical irritation.


Skin Contact - Other Toxicity Information 

MANGANESE DIOXIDE: May cause irritation with redness and pain Repeated or prolonged contact may cause dermatitis See information on manganese compounds.


Eye Contact - Acute Exposure 

GRAPHITE: May cause slight mechanical irritation and discoloration of lids and conjunctiva Large quantities may obstruct aqueous outflow mechanically MANGANESE COMPOUNDS: Direct contact with manganese compounds may cause irritation POTASSIUM HYDROXIDE: Direct contact with solid or solutions may cause pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact There may be edema, destruction of epithelium, corneal opacification, and iritis When damage is less than excessive, these symptoms tend to ameliorate In severe burns, the full extent of the injury may not be immediately apparent Late complications may include persistent edema, vascularization, and scarring of the cornea, permanent opacity, staphyloma, cataract, and symblepharon ZINC: Dust may cause mechanical irritation or injury to the surface of the eye, with discomfort, reddening, and tearing Direct contact may cause serious corneal burns CARBON, ACTIVATED: Contact with dust may cause irritation.


Eye Contact - Chronic Exposure 

POTASSIUM HYDROXIDE: Effects depend on concentration and duration of exposure Repeated or prolonged exposure to vapors and/or fumes may result in conjunctivitis or effects as in acute exposure MANGANESE COMPOUNDS: No data available GRAPHITE: No data available CARBON, ACTIVATED: Repeated or prolonged contact may cause irritation ZINC: No data available.


Eye - Other Toxicity Information 

MANGANESE DIOXIDE: May cause redness, pain, tearing and irritation Repeated or prolonged contact may cause conjunctivitis See information on manganese compounds.


Ingestion - Acute Exposure 

POTASSIUM HYDROXIDE: Ingestion of 273 mg/kg of potassium hydroxide was lethal to rats tested Ingestion of strong alkalies may be followed by severe pain, vomiting, diarrhea, and collapse The vomitus contains blood and desquamated mucosal lining If death does not occur in the first 24 hours, the patient may improve for 2-4 days and then have a sudden onset of severe abdominal pain, boardlike abdominal rigidity, and rapid fall of blood pressure indicating delayed gastric or esophageal perforation Damage to the esophagus and stomach after ingestion may progress for 2-3 weeks Death from peritonitis may occur as late as 1 month after ingestion Even though the patient recovers from the immediate damage, esophageal stricture may occur weeks, months or even years later to make swallowing difficult CARBON, ACTIVATED: Ingestion of large amounts may cause gastrointestinal irritation with nausea, vomiting, and stomach pain ZINC: Large oral doses may cause gastrointestinal distress with stomach cramps, dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting, hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, tightness in the throat, shock, collapse, renal failure, and death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach MANGANESE COMPOUNDS: Ingestion of extremely large doses of manganese compounds may cause gastrointestinal irritation, resulting in nausea, vomiting, and diarrhea, making less available for absorption GRAPHITE: No data available.


Ingestion - Chronic Exposure 

CARBON, ACTIVATED: No data available ZINC: Patients taking zinc in amounts 10 times the RDA for months and years have not shown any adverse reactions Excessive absorption may cause copper-deficiency anemia Ingestion of approximately 85.7 mg/kg/day for 2 days caused lethargy, lightheadedness, staggering, and difficulty in writing clearly 2 people who ingested 40 ppm in drinking water for several months experienced lack of concentration, drowsiness, mental and physical fatigue, pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, nausea, weight loss, and lassitude 90 ppm in the diet for 5 weeks has resulted in a decrease in the HDL cholesterol level Pancreatic abnormalities have also been observed A diet of 0.25% in rats caused no injury; above 0.25% there was breakdown of the homeostatic mechanism, growth retardation, hypochromic anemia, and defective mineralization of the bones Mice fed 500 ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm for 13 weeks caused liver and kidney damage and some deaths Cows fed 2% for 2 days developed severe enteritis, with 7 of 40 dying Severe pulmonary emphysema and changes in the myocardium, kidneys, and liver were observed Pigs fed >1000 ppm had reduced food intake and weight gain; at >2000 ppm, death occurred after 2 weeks Bone changes were observed in foals fed 5400 ppm High dietary levels of zinc have been associated with reduced fetal weights, altered concentrations of fetal iron and copper, and alopecia and reduced growth of offspring in animals POTASSIUM HYDROXIDE: Depending on the concentration, repeated ingestion may cause effects as with acute ingestion GRAPHITE: No data available MANGANESE COMPOUNDS: Manganese poisoning, as described in chronic inhalation, has been reported in persons drinking manganese-contaminated well water.


Ingestion - Other Toxicity Information 

MANGANESE DIOXIDE See information on manganese compounds.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

ZINC7440-66-6
Fish: LC50 96 h Pimephales promelas 2.16 - 3.05 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.211 - 0.269 mg/L [semi-static]; LC50 96 h Pimephales promelas 2.66 mg/L [static]; LC50 96 h Cyprinus carpio 30 mg/L; LC50 96 h Cyprinus carpio 0.45 mg/L [semi-static]; LC50 96 h Cyprinus carpio 7.8 mg/L [static]; LC50 96 h Lepomis macrochirus 3.5 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.59 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 0.41 mg/L [static]
Algae: EC50 96 h Pseudokirchneriella subcapitata 0.11 - 0.271 mg/L [static] EPA; EC50 72 h Pseudokirchneriella subcapitata 0.09 - 0.125 mg/L [static] EPA
Invertebrate: EC50 48 h Daphnia magna 0.139 - 0.908 mg/L [Static] EPA








Bioconcentration Factor 

MANGANESE DIOXIDE1313-13-9
BCF (no bioaccumulation expected)











* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

No Classification assigned.




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
ZINC (7440-66-6)

Restriction(s): E [UN1435] (III, ashes); E [UN1436] (I, dust or powder); D/E [UN1436] (II, dust or powder); E [UN1436] (III, dust or powder)

POTASSIUM HYDROXIDE (1310-58-3)

Restriction(s): E [UN1813] (II, solid); E [UN1814] (II, solution); E [UN1814] (III, solution)

CARBON, ACTIVATED (7440-44-0)

Restriction(s): D/E [UN1361] (II); E [UN1361] (III); E [UN1362] (III)








RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
MANGANESE DIOXIDE1313-13-9
SARA 313: 1 % de minimis concentration (related to Manganese compounds)
ZINC7440-66-6
SARA 313: 1 % de minimis concentration (dust or fume only)
CERCLA: 454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
POTASSIUM HYDROXIDE1310-58-3
CERCLA: 1000 lb final RQ; 454 kg final RQ
ZINC OXIDE1314-13-2
SARA 313: 1 % de minimis concentration (related to Zinc compounds)




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: No Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
MANGANESE DIOXIDE1313-13-9Yes No Yes Yes Yes 
ZINC7440-66-6Yes Yes No Yes Yes 
POTASSIUM HYDROXIDE1310-58-3Yes Yes Yes Yes Yes 
GRAPHITE7782-42-5Yes Yes Yes Yes Yes 
ZINC OXIDE1314-13-2Yes Yes Yes Yes Yes 




Not listed under California Proposition 65 




Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
MANGANESE DIOXIDE1313-13-9
 1 % (related to Manganese compounds)
POTASSIUM HYDROXIDE1310-58-3
 1 %
ZINC OXIDE1314-13-2
 1 %








Germany Water Classification 

MANGANESE DIOXIDE (1313-13-9)

ID Number 7145 , hazard class 1 - low hazard to waters

ZINC (7440-66-6)

ID Number 1349 , not considered hazardous to water (particle size >1mm)

ID Number 7325 , hazard class 2 - hazard to waters (particle size <=1 mm)

POTASSIUM HYDROXIDE (1310-58-3)

ID Number 345 , hazard class 1 - low hazard to waters

CARBON, ACTIVATED (7440-44-0)

ID Number 801 , not considered hazardous to water

GRAPHITE (7782-42-5)

ID Number 801 , not considered hazardous to water

ZINC OXIDE (1314-13-2)

ID Number 2187 , hazard class 2 - hazard to waters




REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process 
GRAPHITE (7782-42-5)

Assigned to Member State Germany (Initial Grounds for Concern: Suspected C, Wide dispersive use, Exposure on environment, Consumer use, Cumulative exposure, Exposure of workers)

ZINC OXIDE (1314-13-2)

Assigned to Member State Germany (Initial Grounds for Concern: Other hazard related to nano form, Wide dispersive use, Consumer use, Exposure of workers, Other exposure)












Symbol(s)

Xn Harmful

C Corrosive

Risk Phrases

R20/22 Harmful by inhalation and if swallowed.

R34 Causes burns.

R41 Risk of serious damage to eyes.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
MANGANESE DIOXIDE1313-13-9Yes DSL EIN Yes Yes Yes Yes Yes Yes 
ZINC7440-66-6Yes DSL EIN Yes Yes No Yes Yes Yes 
POTASSIUM HYDROXIDE1310-58-3Yes DSL EIN Yes Yes Yes Yes Yes Yes 
CARBON, ACTIVATED7440-44-0Yes DSL EIN Yes Yes No Yes Yes Yes 
GRAPHITE7782-42-5Yes DSL EIN Yes Yes No Yes Yes Yes 
ZINC OXIDE1314-13-2Yes DSL EIN Yes Yes Yes Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
MANGANESE DIOXIDE (1313-13-9)

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

ZINC (7440-66-6)

Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (dust and powder; pyrophoric)

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (dust and powder; pyrophoric)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (dust and powder; stabilised)

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (dust and powder, pyrophoric)

POTASSIUM HYDROXIDE (1310-58-3)

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage

ZINC OXIDE (1314-13-2)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H250 Catches fire spontaneously if exposed to air

H260 In contact with water releases flammable gases which may ignite spontaneously

H410 Very toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P222 Do not allow contact with air

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P422 Store contents under appropriate liquid or inert gas as specified

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

POTASSIUM HYDROXIDE (1310-58-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC OXIDE (1314-13-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H410 Very toxic to aquatic life with long lasting effects

Prevention

P273 Avoid release to the environment

Response

P391 Collect spillage

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
MANGANESE DIOXIDE (1313-13-9)

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification)

POTASSIUM HYDROXIDE (1310-58-3)

Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification)

Skin Corrosion/Irritation Category 1A H314 Causes severe skin burns and eye damage

ZINC OXIDE (1314-13-2)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

POTASSIUM HYDROXIDE (1310-58-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC OXIDE (1314-13-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H410 Very toxic to aquatic life with long lasting effects

Prevention

P273 Avoid release to the environment

Response

P391 Collect spillage

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
MANGANESE DIOXIDE (1313-13-9)

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: H26-B-098 / R-044

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 201

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (nervous system,respiratory system) Approval:

Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life Approval: H26-B-098 / R-044

ZINC (7440-66-6)

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 20A2067

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 20A2067

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 20A2067

POTASSIUM HYDROXIDE (1310-58-3)

Acute toxicity Oral Category 3 H301 Toxic if swallowed Approval: 598

Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage Approval: 598

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage Approval: 598

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 598

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways Approval: 598

ZINC OXIDE (1314-13-2)

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 25B0001

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system,systemic toxicity) Approval: 25B0001

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 25B0001




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H341 Suspected of causing genetic defects

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H413 May cause long lasting harmful effects to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H320 Causes eye irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P391 Collect spillage

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

POTASSIUM HYDROXIDE (1310-58-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H370 Causes damage to organs

H304 May be fatal if swallowed and enters airways

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P331 Do NOT induce vomiting

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC OXIDE (1314-13-2)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H361 Suspected of damaging fertility or the unborn child

H370 Causes damage to organs

H410 Very toxic to aquatic life with long lasting effects

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P321 Specific treatment (see label)

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
MANGANESE DIOXIDE (1313-13-9)

MOEL:Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure cardiovascular system,nervous system,respiratory system


ZINC (7440-66-6)

MOEL:Acute toxicity Oral Category 3 H301 Toxic if swallowed

Carcinogenicity Category 1A H350 May cause cancer

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
NEMA:Flammable Solids Category 2 H228 Flammable solid


POTASSIUM HYDROXIDE (1310-58-3)

MOE:Acute toxicity Oral Category 4 H302 Harmful if swallowed.

Skin corrosion/irritation Category 1 H314 Causes severe skin burns and eye damage.
MOEL:Acute toxicity Oral Category 3 H301 Toxic if swallowed

Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory system

Aspiration Hazard Category 1 H304 May be fatal if swallowed and enters airways


GRAPHITE (7782-42-5)

MOEL:Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure circulatory system,liver


ZINC OXIDE (1314-13-2)

MOEL:Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs body,respiratory system

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure lungs

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H350 May cause cancer

H400 Very toxic to aquatic life

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P330 Rinse mouth

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H228 Flammable solid

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H301 Toxic if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H370 Causes damage to organs

H304 May be fatal if swallowed and enters airways

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P331 Do NOT induce vomiting

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H373 May cause damage to organs through prolonged or repeated exposure

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray

Response

P314 Get medical advice/attention if you feel unwell

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P321 Specific treatment (see label)

P391 Collect spillage

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
MANGANESE DIOXIDE (1313-13-9) Approval: HSR003741

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child

Reproductive Toxicity Effects on or via lactation H362 May cause harm to breast-fed children

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (Nervous System)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates

ZINC (7440-66-6) Approval: HSR001301

Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder/dust, PG I)

Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder/dust, PG I)

Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled (powder/dust, PG I)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder/dust, PG I)

POTASSIUM HYDROXIDE (1310-58-3) Approval: HSR001546

Corrosive to Metals Category 1 H290 May be corrosive to metals

Acute toxicity Oral Category 3 H301 Toxic if swallowed

Skin Corrosion/Irritation Category 1B H314 Causes severe skin burns and eye damage

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates

CARBON, ACTIVATED (7440-44-0) Approval: HSR001271

Self-Heating Substances and Mixtures Category 2 H252 Self-heating in large quantities, may catch fire

ZINC OXIDE (1314-13-2) Approval: HSR003104

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (algal,crustacean,fish)

Hazardous to the Terrestrial Environment - Vertebrates Category 3 H433 Harmful to terrestrial vertebrates




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H302 Harmful if swallowed

H330 Fatal if inhaled

H319 Causes serious eye irritation

H361 Suspected of damaging fertility or the unborn child

H362 May cause harm to breast-fed children

H372 Causes damage to organs through prolonged or repeated exposure

H433 Harmful to terrestrial vertebrates

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P263 Avoid contact during pregnancy/while nursing

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H251 Self-heating, may catch fire

H260 In contact with water releases flammable gases which may ignite spontaneously

H333 May be harmful if inhaled

H400 Very toxic to aquatic life

Prevention

P235+P410 Keep cool. Protect from sunlight

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P407 Maintain air gap between stacks/pallets

P413 Store bulk masses at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

POTASSIUM HYDROXIDE (1310-58-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H290 May be corrosive to metals

H301 Toxic if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H402 Harmful to aquatic life

H432 Toxic to terrestrial vertebrates

Prevention

P234 Keep only in original container

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P390 Absorb spillage to prevent material-damage

Storage

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

CARBON, ACTIVATED (7440-44-0)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H252 Self-heating in large quantities, may catch fire

Prevention

P235+P410 Keep cool. Protect from sunlight

P280 Wear protective gloves/protective clothing/eye protection/face protection

Storage

P407 Maintain air gap between stacks/pallets

P413 Store bulk masses at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

ZINC OXIDE (1314-13-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H410 Very toxic to aquatic life with long lasting effects

H433 Harmful to terrestrial vertebrates

Prevention

P273 Avoid release to the environment

Response

P391 Collect spillage

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
ZINC (7440-66-6)

Listing: Present (powder)

POTASSIUM HYDROXIDE (1310-58-3)

Listing: Present (solution >=0.5% and <2% by mass)

Listing: Present (solution >=2% and <25% by mass)

Listing: Present (solution >=25% by mass)

Listing: Present (solid)




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
MANGANESE DIOXIDE (1313-13-9)

Taiwan:Acute toxicity Oral Category 4 H302 Harmful if swallowed
 Acute toxicity Inhalation Category 4 H332 Harmful if inhaled
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation


ZINC (7440-66-6)

Taiwan:Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder)
 Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder)
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation (powder)
 Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (powder)


POTASSIUM HYDROXIDE (1310-58-3)

Taiwan:Corrosive to Metals Category 1 H290 May be corrosive to metals
 Acute toxicity Oral Category 3 H301 Toxic if swallowed
 Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage
 Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage


CARBON, ACTIVATED (7440-44-0)

Taiwan:Self-Heating Substances and Mixtures Category 2 H252 Self-heating in large quantities, may catch fire


ZINC OXIDE (1314-13-2)

Taiwan:Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
 Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
MANGANESE DIOXIDE (1313-13-9)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H302 Harmful if swallowed

H332 Harmful if inhaled

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

ZINC (7440-66-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H250 Catches fire spontaneously if exposed to air

H261 In contact with water releases flammable gases

H316 Causes mild skin irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P222 Do not allow contact with air

P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire

P231+P232 Handle under inert gas. Protect from moisture

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P332+P313 If skin irritation occurs: Get medical advice/attention

P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P402+P404 Store in a dry place. Store in a closed container

P422 Store contents under appropriate liquid or inert gas as specified

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

POTASSIUM HYDROXIDE (1310-58-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H290 May be corrosive to metals

H301 Toxic if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

Prevention

P234 Keep only in original container

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P363 Wash contaminated clothing before reuse

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P321 Specific treatment (see label)

P330 Rinse mouth

P390 Absorb spillage to prevent material-damage

Storage

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

CARBON, ACTIVATED (7440-44-0)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H252 Self-heating in large quantities, may catch fire

Prevention

P235+P410 Keep cool. Protect from sunlight

P280 Wear protective gloves/protective clothing/eye protection/face protection

Storage

P407 Maintain air gap between stacks/pallets

P413 Store bulk masses at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

ZINC OXIDE (1314-13-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H316 Causes mild skin irritation

H320 Causes eye irritation

H335 May cause respiratory irritation

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P273 Avoid release to the environment

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved