* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
URALANE 88844 B
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Chemical Family
metal oxides
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: off-white
Change in color: Not available
Physical Form: paste
Odor: distinct odor
Potential Health Effects
Inhalation
Short Term: irritation, metal fume fever, difficulty breathing
Long Term: irritation, difficulty breathing
Skin Contact
Short Term: irritation
Long Term: no information on significant adverse effects
Eye Contact
Short Term: irritation
Long Term: no information on significant adverse effects
Ingestion
Short Term: no information on significant adverse effects
Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
1344-28-1 215-691-6 -- | ALUMINUM OXIDE | -- | 70.0 |
7439-97-6 231-106-7 -- | MERCURY | Acute Tox. 2 (Oral) - H300 Acute Tox. 1 (Dermal) - H310 Acute Tox. 2 (Inh.) - H330 Repr. 1B - H360D STOT RE 1 - H372 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 | 0.15 |
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Aluminium compounds, Aluminum insoluble compounds, Aluminium oxides, Aluminum Oxide (135152-65-7), Mercury compounds, Mercury inorganic compounds.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
If a large amount is swallowed, get medical attention.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 1 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Slight fire hazard.
Extinguishing Media
Use extinguishing agents appropriate for surrounding fire.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.
Occupational spill/release
Large spills: Collect spilled material in appropriate container for disposal. Avoid generating dust. Clean up residue with a high-efficiency particulate filter vacuum. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ALUMINUM OXIDE | 1344-28-1 |
ACGIH: | 1 mg/m3 TWA respirable particulate matter (related to Aluminum insoluble compounds) |
OSHA (US): | 15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction |
Mexico: | 10 mg/m3 TWA VLE-PPT |
MERCURY | 7439-97-6 |
ACGIH: | 0.025 mg/m3 TWA |
| Skin - potential significant contribution to overall exposure by the cutaneous route |
NIOSH: | 0.05 mg/m3 TWA vapor |
| 0.1 mg/m3 Ceiling |
| Potential for dermal absorption |
| 10 mg/m3 IDLH |
Europe: | 0.02 mg/m3 TWA |
OSHA (US): | 0.1 mg/m3 Ceiling |
Mexico: | 0.05 mg/m3 TWA VLE-PPT |
| Skin - potential for cutaneous absorption |
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance | Not available | Physical State | Solid |
Odor | distinct odor | Color | off-white |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | Not available |
Freezing point | Not available | Evaporation Rate | <1 (butyl acetate=1) |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | >97.7 °C |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | >1 | Specific Gravity (water=1) | 2.05 |
Water Solubility | (slightly soluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | paste |
Volatility | <0.5 % | | |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure. Stable at normal temperatures and pressure.
Incompatible Materials
halo carbons, halogens, combustible materials, oxidizing materials
ALUMINUM OXIDE (ALUMINA) CHLORINATED RUBBER (HOT): Incompatible. CHLORINE TRIFLUORIDE: Violent reaction and possible ignition. ETHYLENE OXIDE: May initiate explosive polymerization. HALOCARBONS: Exothermic reaction above 200 C. HALOCARBONS + METALS: Exothermic reaction at ambient temperatures. OXYGEN DIFLUORIDE: Exothermic reaction. SODIUM NITRATE: May form explosive mixture. VINYL ACETATE: Possible vigorous reaction.
Hazardous Decomposition Products
miscellaneous decomposition products
Thermal decomposition products: miscellaneous decomposition products.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
ALUMINUM OXIDE (1344-28-1)
Oral LD50 Rat >5000 mg/kg
Component Carcinogenicity
ALUMINUM OXIDE | 1344-28-1 |
ACGIH: | A4 - Not Classifiable as a Human Carcinogen (related to Aluminum insoluble compounds) |
DFG: | Category 2 (considered to be carcinogenic for man, fibre dust) |
MERCURY | 7439-97-6 |
ACGIH: | A4 - Not Classifiable as a Human Carcinogen |
IARC: | Monograph 58 [1993] (Group 3 (not classifiable)) |
DFG: | Category 3B (could be carcinogenic for man) |
Medical Conditions Aggravated by Exposure
respiratory disorders
Inhalation - Acute Exposure
METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours.
Inhalation - Chronic Exposure
METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days.
Inhalation - Other Toxicity Information
ALUMINUM OXIDE (ALUMINA): Inhalation of high concentrations may cause coughing, shortness of breath, respiratory tract irritation due to mechanical action, unpleasant deposits in the nasal passages, and exacerbation of symptoms in persons with impaired pulmonary function Humans exposed chronically to aluminum oxide, particle size approximately 1.2 microns, did not experience either systemic or respiratory adverse effects Hydrated aluminum oxide, injected intratracheally, produced dense and numerous nodules of advanced fibrosis in rats, a reticulin network with occasional collagen fibers in mice and guinea pigs, and only a slight reticulin network in rabbits A production process in which aluminum oxide (bauxite), iron, coke, and silica are fused at 2000 C poses a threat of Shaver's disease, a rapidly progressive and often fatal interstitial fibrosis of the lungs See information on metal fume fever.
Skin Contact - Acute Exposure
ALUMINUM OXIDE (ALUMINA) Contact may cause an irritant dermatitis accompanied by pruritis.
Skin Contact - Chronic Exposure
ALUMINUM OXIDE (ALUMINA) No data available.
Eye Contact - Acute Exposure
ALUMINUM OXIDE (ALUMINA) Dust may cause mechanical irritation with redness and possibly swelling of the conjunctiva.
Eye Contact - Chronic Exposure
ALUMINUM OXIDE (ALUMINA) No data available.
Ingestion - Acute Exposure
ALUMINUM OXIDE (ALUMINA) No data available.
Ingestion - Chronic Exposure
ALUMINUM OXIDE (ALUMINA) Some aluminum compounds cause constipation.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
MERCURY | 7439-97-6 |
Fish: | LC50 96 h Cyprinus carpio 0.5 mg/L; LC50 96 h Cyprinus carpio 0.16 mg/L [semi-static]; LC50 96 h Cyprinus carpio 0.18 mg/L [static]; LC50 96 h Oryzias latipes 0.9 mg/L [flow-through] |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
MERCURY | 7439-97-6 |
RCRA: | waste number U151 |
| 0.2 mg/L regulatory level |
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
No Classification assigned.
TDG Information:
No Classification assigned.
ADR Information:
No Classification assigned.
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations
MERCURY (7439-97-6)
Restriction(s): E [UN2809] (III)
RID Information:
No Classification assigned.
IATA Information:
No Classification assigned.
ICAO Information:
No Classification assigned.
IMDG Information:
No Classification assigned.
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan
ALUMINUM OXIDE | 1344-28-1 |
SARA 313: | 1 % de minimis concentration (fibrous forms) |
MERCURY | 7439-97-6 |
SARA 313: | 1 % Supplier notification limit |
CERCLA: | 1 lb final RQ; 0.454 kg final RQ |
TSCA 12b: | Section 5 , 1 % de minimus concentration |
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Acute Health: Yes Fire: No Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component | CAS | CA | MA | MN | NJ | PA |
ALUMINUM OXIDE | 1344-28-1 | Yes | Yes | Yes | Yes | Yes |
MERCURY | 7439-97-6 | Yes | Yes | Yes | Yes | Yes |
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects
Component Analysis
MERCURY | 7439-97-6 |
Repro/Dev. Tox | developmental toxicity , 7/1/1990 |
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
ALUMINUM OXIDE | 1344-28-1 |
| 1 % |
MERCURY | 7439-97-6 |
| 0.1 % |
Germany Water Classification
ALUMINUM OXIDE (1344-28-1)
ID Number 1346 , not considered hazardous to water
MERCURY (7439-97-6)
ID Number 393 , hazard class 3 - severe hazard to waters
REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006
This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
MERCURY (7439-97-6)
Use restricted. See item 18[a]. (certain mercury-containing devices shall not be placed on the EU market after April 10, 2014); Use restricted. See item 30.
Symbol(s)
Xn Harmful
Risk Phrases
R20 Harmful by inhalation.
Component Analysis - Inventory
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
ALUMINUM OXIDE | 1344-28-1 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
MERCURY | 7439-97-6 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
MERCURY (7439-97-6)
Acute toxicity Inhalation Category 2 H330 Fatal if inhaled
Reproductive Toxicity Category 1B H360D May damage the unborn child
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
Australia GHS Labeling Information
Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC)
MERCURY (7439-97-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H330 Fatal if inhaled
H360D May damage the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
European Union GHS Classifications
Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
MERCURY (7439-97-6)
Acute toxicity Inhalation Category 2 H330 Fatal if inhaled (Minimum classification)
Reproductive Toxicity Category 1B H360D May damage the unborn child (Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development: May damage/Suspected of damaging fertility or the unborn child; According to the criteria, the general hazard statement can be replaced by the hazard statement indicating the specific effect of concern in accordance with section 1.1.2.1.2; When the other differentiation is not mentioned, this is due to evidence proving no such effect, inconclusive data or no data and the obligations in Article 4(3) shall apply for that differentiation)
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (No information to prove exclusion of certain routes of exposure)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects
European Union GHS Labeling Information
Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP)
MERCURY (7439-97-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H330 Fatal if inhaled
H360D May damage the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
ALUMINUM OXIDE (1344-28-1) Approval: 738
Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (lungs)
MERCURY (7439-97-6)
Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled Approval: 23B5578
Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 23B5578
Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 23B5578
Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Approval: 23B5578
Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (cardiovascular system,Central Nervous System,kidneys,liver,respiratory system) Approval: 23B5578
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (blood,cardiovascular system,gum,liver,nervous system) Approval: 23B5578
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 23B5578
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 23B5578
Japan GHS Labeling Information
Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
ALUMINUM OXIDE (1344-28-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P271 Use only outdoors or in a well-ventilated area
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
MERCURY (7439-97-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H330 Fatal if inhaled
H319 Causes serious eye irritation
H317 May cause allergic skin reaction
H360 May damage fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P320 Specific treatment is urgent (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Korea GHS Classifications
Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
ALUMINUM OXIDE (1344-28-1)
MOEL: | Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure lungs,respiratory system |
MERCURY (7439-97-6)
MOE: | Acute toxicity Inhalation Category 2 H330 Fatal if inhaled. Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child. Specific target organ toxicity - Repeated exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure. Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life. Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects. |
MOEL: | Skin Sensitization Category 1 H317 May cause allergic skin reaction Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs cardiovascular system,Central Nervous System,digestive system,gum,kidneys,liver,respiratory system Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure cardiovascular system,Central Nervous System,circulatory system,gum,kidneys,liver,Peripheral Nervous System Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life |
Korea GHS Labeling Information
Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only)
ALUMINUM OXIDE (1344-28-1)
Symbol(s)
Signal Word Danger
Hazard(s)
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
Prevention
P271 Use only outdoors or in a well-ventilated area
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
Response
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H330 Fatal if inhaled
H360 May damage fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Symbol(s)
Signal Word Danger
Hazard(s)
H317 May cause allergic skin reaction
H341 Suspected of causing genetic defects
H360 May damage fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H413 May cause long lasting harmful effects to aquatic life
Prevention
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P321 Specific treatment (see label)
Storage
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
New Zealand GHS Classifications
Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
MERCURY (7439-97-6) Approval: HSR003014
Corrosive to Metals Category 1 H290 May be corrosive to metals
Acute toxicity Oral Category 2 H300 Fatal if swallowed
Acute toxicity Inhalation Category 2 H330 Fatal if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (Nervous System)
Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish,other)
Hazardous to the Terrestrial Environment - Soil Category 2 H422 Toxic to the soil environment
Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates
New Zealand GHS Labeling Information
Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html
MERCURY (7439-97-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H290 May be corrosive to metals
H300 Fatal if swallowed
H330 Fatal if inhaled
H317 May cause allergic skin reaction
H360 May damage fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H422 Toxic to the soil environment
H431 Very toxic to terrestrial vertebrates
Prevention
P234 Keep only in original container
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P310 Immediately call a POISON CENTER or doctor/physician
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P320 Specific treatment is urgent (see label)
P330 Rinse mouth
P390 Absorb spillage to prevent material-damage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P406 Store in corrosive resistant container with a resistant inner liner
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
South Africa GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
MERCURY (7439-97-6)
Taiwan: | Acute toxicity Inhalation Category 3 H331 Toxic if inhaled |
| Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage |
| Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage |
| Skin Sensitization Category 1 H317 May cause allergic skin reaction |
| Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child |
| Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure |
| Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects |
Taiwan GHS Labeling Information
Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS
MERCURY (7439-97-6)
Symbol(s)
Signal Word Danger
Hazard(s)
H331 Toxic if inhaled
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause allergic skin reaction
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Prevention
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P264 Wash thoroughly after handling
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P273 Avoid release to the environment
Response
P308+P313 IF exposed or concerned: Get medical advice/attention
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 Call a POISON CENTER or doctor/physician
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P310 Immediately call a POISON CENTER or doctor/physician
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P362+P364 Take off contaminated clothing and wash it before reuse
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P310 Immediately call a POISON CENTER or doctor/physician
P321 Specific treatment (see label)
P391 Collect spillage
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved