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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

URALANE 88844 B


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

metal oxides 









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  off-white 

Change in color: Not available

Physical Form: paste

Odor:  distinct odor 




Potential Health Effects 
Inhalation 

Short Term:  irritation, metal fume fever, difficulty breathing 

Long Term:  irritation, difficulty breathing 




Skin Contact 

Short Term:  irritation 

Long Term:  no information on significant adverse effects 




Eye Contact 

Short Term:  irritation 

Long Term:  no information on significant adverse effects 




Ingestion 

Short Term:  no information on significant adverse effects 

Long Term:  no information on significant adverse effects 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
1344-28-1 215-691-6 --ALUMINUM OXIDE--70.0
7439-97-6 231-106-7 --MERCURYAcute Tox. 2 (Oral) - H300 Acute Tox. 1 (Dermal) - H310 Acute Tox. 2 (Inh.) - H330 Repr. 1B - H360D STOT RE 1 - H372 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H4100.15




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Aluminium compounds, Aluminum insoluble compounds, Aluminium oxides, Aluminum Oxide (135152-65-7), Mercury compounds, Mercury inorganic compounds.









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If a large amount is swallowed, get medical attention. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 1 Fire: 1 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Slight fire hazard. 


Extinguishing Media 

Use extinguishing agents appropriate for surrounding fire. 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Water Release 

Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. 


Occupational spill/release 

Large spills: Collect spilled material in appropriate container for disposal. Avoid generating dust. Clean up residue with a high-efficiency particulate filter vacuum. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ALUMINUM OXIDE1344-28-1
ACGIH: 1 mg/m3 TWA respirable particulate matter (related to Aluminum insoluble compounds)
OSHA (US): 15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction
Mexico: 10 mg/m3 TWA VLE-PPT
MERCURY7439-97-6
ACGIH: 0.025 mg/m3 TWA
 Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH: 0.05 mg/m3 TWA vapor
 0.1 mg/m3 Ceiling
 Potential for dermal absorption
 10 mg/m3 IDLH
Europe: 0.02 mg/m3 TWA
OSHA (US): 0.1 mg/m3 Ceiling
Mexico: 0.05 mg/m3 TWA VLE-PPT
 Skin - potential for cutaneous absorption




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor distinct odorColor off-white
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate <1 (butyl acetate=1)
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point >97.7 °C
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) >1Specific Gravity (water=1) 2.05
Water Solubility (slightly soluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form paste
Volatility <0.5 %  











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. Stable at normal temperatures and pressure. 


Incompatible Materials 

halo carbons, halogens, combustible materials, oxidizing materials 


ALUMINUM OXIDE (ALUMINA) CHLORINATED RUBBER (HOT): Incompatible. CHLORINE TRIFLUORIDE: Violent reaction and possible ignition. ETHYLENE OXIDE: May initiate explosive polymerization. HALOCARBONS: Exothermic reaction above 200 C. HALOCARBONS + METALS: Exothermic reaction at ambient temperatures. OXYGEN DIFLUORIDE: Exothermic reaction. SODIUM NITRATE: May form explosive mixture. VINYL ACETATE: Possible vigorous reaction.

Hazardous Decomposition Products 

miscellaneous decomposition products 


Thermal decomposition products: miscellaneous decomposition products. 

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
ALUMINUM OXIDE (1344-28-1)

Oral LD50 Rat >5000 mg/kg




Component Carcinogenicity

ALUMINUM OXIDE1344-28-1
ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Aluminum insoluble compounds)
DFG: Category 2 (considered to be carcinogenic for man, fibre dust)
MERCURY7439-97-6
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 58 [1993] (Group 3 (not classifiable))
DFG: Category 3B (could be carcinogenic for man)








Medical Conditions Aggravated by Exposure 

respiratory disorders 


Inhalation - Acute Exposure 

METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours.


Inhalation - Chronic Exposure 

METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days.


Inhalation - Other Toxicity Information 

ALUMINUM OXIDE (ALUMINA): Inhalation of high concentrations may cause coughing, shortness of breath, respiratory tract irritation due to mechanical action, unpleasant deposits in the nasal passages, and exacerbation of symptoms in persons with impaired pulmonary function Humans exposed chronically to aluminum oxide, particle size approximately 1.2 microns, did not experience either systemic or respiratory adverse effects Hydrated aluminum oxide, injected intratracheally, produced dense and numerous nodules of advanced fibrosis in rats, a reticulin network with occasional collagen fibers in mice and guinea pigs, and only a slight reticulin network in rabbits A production process in which aluminum oxide (bauxite), iron, coke, and silica are fused at 2000 C poses a threat of Shaver's disease, a rapidly progressive and often fatal interstitial fibrosis of the lungs See information on metal fume fever.


Skin Contact - Acute Exposure 

ALUMINUM OXIDE (ALUMINA) Contact may cause an irritant dermatitis accompanied by pruritis.


Skin Contact - Chronic Exposure 

ALUMINUM OXIDE (ALUMINA) No data available.


Eye Contact - Acute Exposure 

ALUMINUM OXIDE (ALUMINA) Dust may cause mechanical irritation with redness and possibly swelling of the conjunctiva.


Eye Contact - Chronic Exposure 

ALUMINUM OXIDE (ALUMINA) No data available.


Ingestion - Acute Exposure 

ALUMINUM OXIDE (ALUMINA) No data available.


Ingestion - Chronic Exposure 

ALUMINUM OXIDE (ALUMINA) Some aluminum compounds cause constipation.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

MERCURY7439-97-6
Fish: LC50 96 h Cyprinus carpio 0.5 mg/L; LC50 96 h Cyprinus carpio 0.16 mg/L [semi-static]; LC50 96 h Cyprinus carpio 0.18 mg/L [static]; LC50 96 h Oryzias latipes 0.9 mg/L [flow-through]















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

MERCURY7439-97-6
RCRA: waste number U151
 0.2 mg/L regulatory level











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

No Classification assigned.




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
MERCURY (7439-97-6)

Restriction(s): E [UN2809] (III)








RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
ALUMINUM OXIDE1344-28-1
SARA 313: 1 % de minimis concentration (fibrous forms)
MERCURY7439-97-6
SARA 313: 1 % Supplier notification limit
CERCLA: 1 lb final RQ; 0.454 kg final RQ
TSCA 12b: Section 5 , 1 % de minimus concentration




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Fire: No Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
ALUMINUM OXIDE1344-28-1Yes Yes Yes Yes Yes 
MERCURY7439-97-6Yes Yes Yes Yes Yes 




The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): 

WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects




Component Analysis 
MERCURY7439-97-6
Repro/Dev. Tox developmental toxicity , 7/1/1990












Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
ALUMINUM OXIDE1344-28-1
 1 %
MERCURY7439-97-6
 0.1 %








Germany Water Classification 

ALUMINUM OXIDE (1344-28-1)

ID Number 1346 , not considered hazardous to water

MERCURY (7439-97-6)

ID Number 393 , hazard class 3 - severe hazard to waters




REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 
MERCURY (7439-97-6)

Use restricted. See item 18[a]. (certain mercury-containing devices shall not be placed on the EU market after April 10, 2014); Use restricted. See item 30.








Symbol(s)

Xn Harmful

Risk Phrases

R20 Harmful by inhalation.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
ALUMINUM OXIDE1344-28-1Yes DSL EIN Yes Yes Yes Yes Yes Yes 
MERCURY7439-97-6Yes DSL EIN Yes Yes No Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
MERCURY (7439-97-6)

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled

Reproductive Toxicity Category 1B H360D May damage the unborn child

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
MERCURY (7439-97-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H330 Fatal if inhaled

H360D May damage the unborn child

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
MERCURY (7439-97-6)

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled (Minimum classification)

Reproductive Toxicity Category 1B H360D May damage the unborn child (Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development: May damage/Suspected of damaging fertility or the unborn child; According to the criteria, the general hazard statement can be replaced by the hazard statement indicating the specific effect of concern in accordance with section 1.1.2.1.2; When the other differentiation is not mentioned, this is due to evidence proving no such effect, inconclusive data or no data and the obligations in Article 4(3) shall apply for that differentiation)

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (No information to prove exclusion of certain routes of exposure)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
MERCURY (7439-97-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H330 Fatal if inhaled

H360D May damage the unborn child

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ALUMINUM OXIDE (1344-28-1) Approval: 738

Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (lungs)

MERCURY (7439-97-6)

Acute toxicity Inhalation - Vapour Category 1 H330 Fatal if inhaled Approval: 23B5578

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 23B5578

Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 23B5578

Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Approval: 23B5578

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (cardiovascular system,Central Nervous System,kidneys,liver,respiratory system) Approval: 23B5578

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (blood,cardiovascular system,gum,liver,nervous system) Approval: 23B5578

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Approval: 23B5578

Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects Approval: 23B5578




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ALUMINUM OXIDE (1344-28-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H335 May cause respiratory irritation

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P271 Use only outdoors or in a well-ventilated area

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

MERCURY (7439-97-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H330 Fatal if inhaled

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H360 May damage fertility or the unborn child

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P320 Specific treatment is urgent (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ALUMINUM OXIDE (1344-28-1)

MOEL:Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure lungs,respiratory system


MERCURY (7439-97-6)

MOE:Acute toxicity Inhalation Category 2 H330 Fatal if inhaled.

Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child.

Specific target organ toxicity - Repeated exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure.

Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life.

Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects.
MOEL:Skin Sensitization Category 1 H317 May cause allergic skin reaction

Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects

Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child

Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs cardiovascular system,Central Nervous System,digestive system,gum,kidneys,liver,respiratory system

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure cardiovascular system,Central Nervous System,circulatory system,gum,kidneys,liver,Peripheral Nervous System

Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ALUMINUM OXIDE (1344-28-1)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H335 May cause respiratory irritation

H372 Causes damage to organs through prolonged or repeated exposure

Prevention

P271 Use only outdoors or in a well-ventilated area

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H330 Fatal if inhaled

H360 May damage fertility or the unborn child

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Danger

Hazard(s)

H317 May cause allergic skin reaction

H341 Suspected of causing genetic defects

H360 May damage fertility or the unborn child

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H413 May cause long lasting harmful effects to aquatic life

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
MERCURY (7439-97-6) Approval: HSR003014

Corrosive to Metals Category 1 H290 May be corrosive to metals

Acute toxicity Oral Category 2 H300 Fatal if swallowed

Acute toxicity Inhalation Category 2 H330 Fatal if inhaled

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (Nervous System)

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish,other)

Hazardous to the Terrestrial Environment - Soil Category 2 H422 Toxic to the soil environment

Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
MERCURY (7439-97-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H290 May be corrosive to metals

H300 Fatal if swallowed

H330 Fatal if inhaled

H317 May cause allergic skin reaction

H360 May damage fertility or the unborn child

H372 Causes damage to organs through prolonged or repeated exposure

H400 Very toxic to aquatic life

H422 Toxic to the soil environment

H431 Very toxic to terrestrial vertebrates

Prevention

P234 Keep only in original container

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P284 Wear respiratory protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P310 Immediately call a POISON CENTER or doctor/physician

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

P320 Specific treatment is urgent (see label)

P330 Rinse mouth

P390 Absorb spillage to prevent material-damage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P406 Store in corrosive resistant container with a resistant inner liner

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
MERCURY (7439-97-6)

Taiwan:Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
 Skin Corrosion/Irritation Category 1 H314 Causes severe skin burns and eye damage
 Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage
 Skin Sensitization Category 1 H317 May cause allergic skin reaction
 Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
 Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
 Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
MERCURY (7439-97-6)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H331 Toxic if inhaled

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H317 May cause allergic skin reaction

H361 Suspected of damaging fertility or the unborn child

H373 May cause damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

Prevention

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P311 Call a POISON CENTER or doctor/physician

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P310 Immediately call a POISON CENTER or doctor/physician

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

P391 Collect spillage

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved