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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

ZINC PEROXIDE


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 

peroxides 


Synonyms 

ZINC PEROXIDE (ZN(O2)); ZINC DIOXIDE; ZINC OXIDE (ZNO2); ZINC SUPEROXIDE; ZPO; UN 1516; STCC 4918758; O2Zn









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: powder

Odor:  odorless 

Physical Hazards:  May explode when heated. May ignite combustibles. May react on contact with water. 




Potential Health Effects 
Inhalation 

Short Term:  no information is available 

Long Term:  no information is available 




Skin Contact 

Short Term:  no information is available 

Long Term:  no information is available 




Eye Contact 

Short Term:  no information is available 

Long Term:  no information is available 




Ingestion 

Short Term:  digestive disorders 

Long Term:  no information is available 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
1314-22-3 215-226-7 --ZINC PEROXIDE--100.0




Component Related Regulatory Information 

This product may be regulated, have exposure limits or other information identified as the following: Zinc compounds.









* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. 


Note to Physicians 

For ingestion, consider gastric lavage. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 1 Fire: 0 Reactivity: 3

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 


Extinguishing Media 

water Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with water. Apply water from a protected location or from a safe distance. 


Fire Fighting Measures 

Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Use extinguishing agents appropriate for surrounding fire. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 500 meters (1/3 mile). 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Flood with water. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor odorlessColor white
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition >150 °C
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) 1.571 - 3
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form powder
Molecular Formula Zn-O2Molecular Weight 97.39




Solvent Solubility 
Soluble 

dilute acids, alcohol, acetone 













* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

May react with evolution of heat on contact with water. May explode when heated. 


Conditions to Avoid 

Avoid contact with combustible materials. May ignite or explode on contact with combustible materials. Dangerous gases may accumulate in confined spaces. Containers may rupture or explode if exposed to heat. Avoid friction or contamination. Keep out of water supplies and sewers. 


Incompatible Materials 

metals, combustible materials, reducing agents, 


ZINC PEROXIDE: ALUMINUM: May react violently with burning brilliance. ZINC: May react violently with burning brilliance. OXIDIZERS: COMBUSTIBLE MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. ORGANIC MATERIALS: May increase the burning rate or cause ignition on contact; finely divided materials may result in an explosion. REDUCING MATERIALS: Fire and explosion hazard.

Hazardous Decomposition Products 

oxides of zinc 


Thermal decomposition products: zinc oxide.

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA




Inhalation - Acute Exposure 

ZINC PEROXIDE No data available.


Inhalation - Chronic Exposure 

ZINC PEROXIDE No data available.


Skin Contact - Acute Exposure 

ZINC PEROXIDE No data available.


Skin Contact - Chronic Exposure 

ZINC PEROXIDE No data available.


Eye Contact - Acute Exposure 

ZINC PEROXIDE No data available.


Eye Contact - Chronic Exposure 

ZINC PEROXIDE No data available.


Ingestion - Acute Exposure 

ZINC PEROXIDE Based on similar substances large amounts may produce esophagitis and gastritis.


Ingestion - Chronic Exposure 

ZINC PEROXIDE No data available.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003. Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN/NA #: UN1516

Packing Group: II

Required Label(s): 5.1




TDG Information:

No Classification assigned.




ADR Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN#: UN1516

Packing Group: II

Required Label(s): 5.1

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
ZINC PEROXIDE (1314-22-3)

Restriction(s): E [UN1516] (II)








RID Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN#: UN1516

Packing Group: II

Required Label(s): 5.1




IATA Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN#: UN1516

Packing Group: II

Required Label(s): 5.1




ICAO Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN#: UN1516

Packing Group: II

Required Label(s): 5.1




IMDG Information:

Shipping Name: ZINC PEROXIDE

Hazard Class: 5.1

UN#: UN1516

Packing Group: II

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
ZINC PEROXIDE1314-22-3
SARA 313: 1 % de minimis concentration (related to Zinc compounds)




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: No Chronic Health: No Fire: Yes Pressure: No Reactivity: Yes








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
ZINC PEROXIDE1314-22-3Yes No No Yes Yes 




Not listed under California Proposition 65 




Germany Water Classification 

ZINC PEROXIDE (1314-22-3)

ID Number 430 , hazard class 3 - severe hazard to waters








Symbol(s)

O Oxidizing

Risk Phrases

R8 Contact with combustible material may cause fire.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
ZINC PEROXIDE1314-22-3Yes DSL EIN Yes Yes Yes Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ZINC PEROXIDE (1314-22-3) Approval: 21A3517

Oxidizing Solids Category 2 H272 May intensify fire, oxidizer




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ZINC PEROXIDE (1314-22-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P370+P378 In case of fire: Use appropriate media for extinction

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ZINC PEROXIDE (1314-22-3)

NEMA:Oxidizing Solids Category 2 H272 May intensify fire, oxidizer




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ZINC PEROXIDE (1314-22-3)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H272 May intensify fire, oxidizer

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P370+P378 In case of fire: Use appropriate media for extinction

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC PEROXIDE (1314-22-3)

Taiwan:Oxidizing Solids Category 3 H272 May intensify fire, oxidizer
 Acute toxicity Oral Category 4 H302 Harmful if swallowed
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC PEROXIDE (1314-22-3)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H272 May intensify fire, oxidizer

H302 Harmful if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P270 Do not eat, drink or smoke when using this product

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P332+P313 If skin irritation occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved