Material Name: 1,3-CYCLOHEXADIENE SDS ID: ohs26740 Issue Date: 2016-06-23 Revision: 2.05 |
1,3-CYCLOHEXADIENE
ChemADVISOR, Inc.Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
hydrocarbons, alicyclic
1,2-DIHYDRO BENZENE; C6H8
Emergency Overview
Color: colorless
Change in color: Not available
Physical Form: liquid
Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire.
Short Term: symptoms of drunkenness
Long Term: same as effects reported in other routes of exposure
Short Term: irritation
Long Term: same as effects reported in short term exposure
Short Term: irritation
Long Term: no information is available
Short Term: diarrhea
Long Term: no information is available
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
592-57-4 209-764-1 -- | 1,3-CYCLOHEXADIENE | -- | 100.0 |
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If a large amount is swallowed, get medical attention.
See Section 9 for Flammability Properties
Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point.
regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray.
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Store in a cool, dry place. Store in a tightly closed container. Refrigerate. Keep separated from incompatible substances.
Component Exposure Limits
Biological limit value
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Appearance | Not available | Physical State | Liquid |
Odor | Not available | Color | colorless |
Odor Threshold | Not available | pH | Not available |
Melting Point | -89 °C | Boiling Point | 80 - 81 °C |
Freezing point | Not available | Evaporation Rate | Not available |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | 26 °C SCC |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | Not available |
Vapor Density (air=1) | Not available | Specific Gravity (water=1) | 0.8405 |
Water Solubility | (insoluble) | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Molecular Formula | C6-H8 | Molecular Weight | 80.13 |
OSHA Flammability Class | IC |
alcohol, ether, benzene, chloroform
Stable at normal temperatures and pressure.
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers.
oxidizing materials, halogens, acids,
1,3-CYCLOHEXADIENE: OXIDIZERS (STRONG): Fire and explosion hazard. ALKENES: FLUORINE: Spontaneous ignition. NITROGEN OXIDES: Ignition. PEROXYFORMIC ACID: Violent reaction.
oxides of carbon
Thermal decomposition products: oxides of carbon.
Will not polymerize.
Component Analysis - LD50/LC50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
1,3-CYCLOHEXADIENE: No specific data available High concentration of some alicyclic hydrocarbons may cause central nervous system depression.
1,3-CYCLOHEXADIENE Repeated or prolonged exposure to alicyclic hydrocarbons may cause effects as detailed in acute exposure.
1,3-CYCLOHEXADIENE: May cause irritation Skin absorption may occur.
1,3-CYCLOHEXADIENE: No specific data available Repeated or prolonged contact with alicyclic hydrocarbons may cause defatting of the skin and a dry scaly, fissured dermatitis.
1,3-CYCLOHEXADIENE: May cause irritation Mild conjunctivitis has been reported following vapor exposure to alicyclic hydrocarbons.
1,3-CYCLOHEXADIENE No data available.
1,3-CYCLOHEXADIENE: No specific data available Severe diarrhea and vascular collapse leading to heart, lung, liver and brain effects due to alicyclic hydrocarbons have been reported in animals.
1,3-CYCLOHEXADIENE No data available.
Component Analysis - Aquatic Toxicity
Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in accordance with all applicable regulations.
Component Waste Numbers
Component Marine Pollutants (IMDG)
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Not listed under California Proposition 65
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
1,3-CYCLOHEXADIENE | 592-57-4 | Yes | NSL | EIN | Yes | No | Yes | Yes | No | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
European Union GHS Classifications
Indonesia GHS Classifications
Japan GHS Classifications
Korea GHS Classifications
NEMA: | Flammable Liquids Category 2 H225 Highly flammable liquid and vapour |
Korea GHS Labeling Information
New Zealand GHS Classifications
New Zealand GHS Labeling Information
South Africa GHS Classifications
Taiwan GHS Classifications
No classification assigned.
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
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Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
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