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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

MEKOR VOLATILE CORROSION INHIBITOR


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Product Use 

additives 









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: liquid

Odor:  unpleasant odor 

Health Hazards:  potentially fatal on contact with the skin, skin irritation, eye irritation, allergic reactions 

Physical Hazards:  Flash back hazard. Combustible liquid and vapor. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, drowsiness, blood disorders 

Long Term:  no information on significant adverse effects 




Skin Contact 

Short Term:  potentially fatal on contact with the skin, irritation, allergic reactions 

Long Term:  irritation 




Eye Contact 

Short Term:  irritation (possibly severe) 

Long Term:  irritation 




Ingestion 

Short Term:  irritation, nausea, vomiting, drowsiness, blood disorders 

Long Term:  no information on significant adverse effects 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
96-29-7 202-496-6 --2-BUTANONE OXIMEAcute Tox. 4 (Dermal) - H312 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Carc. 2 - H35185 - 100
7732-18-5 231-791-2 --WATER--<15











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention. 


Note to Physicians 

For inhalation, consider oxygen. For ingestion, consider activated charcoal slurry. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 2 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Moderate fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. 


Extinguishing Media 

alcohol-resistant foam, carbon dioxide, regular dry chemical, water 


Large fires: Use regular foam or flood with fine water spray. 

Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Remove sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Protective Materials 

rubber 


Respiratory Protection 

No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Liquid
Odor unpleasant odorColor colorless
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point 152 °C
Freezing point Not available Evaporation Rate <1 (butyl acetate=1)
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point 63 °C PMCC
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure 10 mmHg at 20 °C
Vapor Density (air=1) 3Specific Gravity (water=1) 0.916 - 0.924
Water Solubility Not available Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form liquid
Volatility >95 %OSHA Flammability Class IIIA











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. 


Incompatible Materials 

bases, acids, oxidizing materials, metals, peroxides 


MEKOR VOLATILE CORROSION INHIBITOR ALKALIES (STRONG): Incompatible. ORGANIC ACIDS (STRONG): Incompatible. OXIDIZING AGENTS (STRONG): Incompatible. 2-BUTANONE OXIME ACIDIC IMPURITIES: Distillation with acidic impurities has caused violent explosions. ACIDS: Decomposition is promoted. ALKALIES: Incompatible. METALS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXIDES: Incompatible. SULFURIC ACID: After hydrolization with aqueous sulfuric acid and the release of 2-Butanone during distillation, the residue, hydroxylammonium sulfate decomposed violently.

Hazardous Decomposition Products 

oxides of carbon, nitrogen, ketones, amides 


Thermal decomposition products: oxides of carbon, nitrogen, methyl ethyl ketone, substituted amides. 

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
2-BUTANONE OXIME (96-29-7)

Oral LD50 Rat 930 mg/kg

Dermal LD50 Rabbit 1000 - 1800 mg/kg

Inhalation LC50 Rat >4800 mg/m3 4 h (no deaths occurred)

WATER (7732-18-5)

Oral LD50 Rat >90 mL/kg




Component Carcinogenicity

2-BUTANONE OXIME96-29-7
DFG: Category 2 (considered to be carcinogenic for man)








May inhibit alcohol metabolism. 

Inhalation - Acute Exposure 

MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): Vapor or mist may cause nose, throat and respiratory tract irritation, central nervous system depression with symptoms that include dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness, respiratory failure, methemoglobinemia (blood abnormality resulting in a bluish tint to the skin or mucous membrane) and coma may also occur 2-BUTANONE OXIME: May cause irritation Animal data shows a narcotic action at high vapor concentrations and at very high concentrations may lead to coma and respiratory failure Methemoglobinemia has also been reported.


Inhalation - Chronic Exposure 

MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available 2-BUTANONE OXIME: In an animal study, the red blood cells were affected and gross histopathologic alterations were observed in the spleen, lung and kidneys.


Skin Contact - Acute Exposure 

MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): Exposure may cause mild irritation with symptoms that include redness, burning, and allergic skin reactions Skin absorption is possible, and may contribute to symptoms of toxicity 2-BUTANONE OXIME: May cause irritation and sensitization An acute dermal animal study with 200 mg/kg caused mild hematologic effects.


Skin Contact - Chronic Exposure 

2-BUTANONE OXIME: Repeated or prolonged exposure to irritants may cause dermatitis MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available.


Eye Contact - Acute Exposure 

2-BUTANONE OXIME: May cause irritation, possibly severe with damage MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): May cause severe irritation Symptoms may include stinging, tearing, redness, swelling and damage.


Eye Contact - Chronic Exposure 

2-BUTANONE OXIME: Repeated or prolonged contact with irritant may cause conjunctivitis MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available.


Ingestion - Acute Exposure 

MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): May be harmful and cause gastrointestinal irritation with nausea, vomiting, diarrhea, methemoglobinemia (blood abnormality resulting in a bluish tint to the skin or mucous membranes) 2-BUTANONE OXIME: May cause irritation to the respiratory system, nausea and vomiting May also cause narcotic effects as in acute inhalation Methemoglobinemia has also been reported.


Ingestion - Chronic Exposure 

MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available 2-BUTANONE OXIME: Studies in rats resulted in hemolytic anemia.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

2-BUTANONE OXIME96-29-7
Fish: LC50 96 h Pimephales promelas 777 - 914 mg/L [flow-through]; LC50 96 h Poecilia reticulata 760 mg/L [static]
Algae: EC50 72 h Desmodesmus subspicatus 83 mg/L IUCLID
Invertebrate: EC50 48 h Daphnia magna 750 mg/L IUCLID








Bioconcentration Factor 

2-BUTANONE OXIME96-29-7
BCF 0.5 - 5.8 BCF method: OECD 305C











* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: COMBUSTIBLE LIQUID, N.O.S., (Contains:2-BUTANONE OXIME)

Hazard Class: 3

UN/NA #: NA1993

Packing Group: III




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.




RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
2-BUTANONE OXIME96-29-7No No Yes No No 




Not listed under California Proposition 65 




Germany Water Classification 

2-BUTANONE OXIME (96-29-7)

ID Number 1558 , hazard class 1 - low hazard to waters




REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process 
2-BUTANONE OXIME (96-29-7)

Assigned to Member State Germany (Initial Grounds for Concern: Human health/CMR, Sensitiser, Exposure/Wide dispersive use, Consumer use, Cumulative exposure, High RCR, Aggregated tonnage)












Symbol(s)

Xn Harmful

Xi Irritant

Risk Phrases

R21 Harmful in contact with skin.

R41 Risk of serious damage to eyes.

R43 May cause sensitization by skin contact.

R40 Limited evidence of a carcinogenic effect.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
2-BUTANONE OXIME96-29-7Yes DSL EIN Yes Yes Yes Yes Yes Yes 
WATER7732-18-5Yes DSL EIN Yes Yes No Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
2-BUTANONE OXIME (96-29-7)

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Carcinogenicity Category 2 H351 Suspected of causing cancer

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
2-BUTANONE OXIME (96-29-7)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H312 Harmful in contact with skin

H318 Causes serious eye damage

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
2-BUTANONE OXIME (96-29-7)

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin (Minimum classification)

Serious Eye Damage/Eye Irritation Category 1 H318 Causes serious eye damage

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Carcinogenicity Category 2 H351 Suspected of causing cancer




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
2-BUTANONE OXIME (96-29-7)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H312 Harmful in contact with skin

H318 Causes serious eye damage

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

Prevention

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P310 Immediately call a POISON CENTER or doctor/physician

P321 Specific treatment (see label)

Storage

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2-BUTANONE OXIME (96-29-7) Approval: 20A2151

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Hematopoietic System)

Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
2-BUTANONE OXIME (96-29-7)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H312 Harmful in contact with skin

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

H372 Causes damage to organs through prolonged or repeated exposure

H402 Harmful to aquatic life

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
2-BUTANONE OXIME (96-29-7) Approval: HSR001191

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 4 H302 Harmful if swallowed

Acute toxicity Dermal Category 4 H312 Harmful in contact with skin

Acute toxicity Inhalation Category 4 H332 Harmful if inhaled

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation

Skin Sensitization Category 1 H317 May cause allergic skin reaction

Carcinogenicity Category 2 H351 Suspected of causing cancer

Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled

Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (blood,Hematopoietic System,liver,spleen)

Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (algal)

Hazardous to the Terrestrial Environment - Soil Category 1 H421 Very toxic to the soil environment

Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
2-BUTANONE OXIME (96-29-7)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

H316 Causes mild skin irritation

H319 Causes serious eye irritation

H317 May cause allergic skin reaction

H351 Suspected of causing cancer

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

H421 Very toxic to the soil environment

H432 Toxic to terrestrial vertebrates

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P272 Contaminated work clothing should not be allowed out of the workplace

P280 Wear protective gloves/protective clothing/eye protection/face protection

P260 Do not breathe dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

P201 Obtain special instructions before use

P202 Do not handle until all safety precautions have been read and understood

P270 Do not eat, drink or smoke when using this product

P273 Avoid release to the environment

Response

P308+P313 IF exposed or concerned: Get medical advice/attention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P362+P364 Take off contaminated clothing and wash it before reuse

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

P321 Specific treatment (see label)

P330 Rinse mouth

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved