Material Name: MEKOR VOLATILE CORROSION INHIBITOR SDS ID: ohsed575 Issue Date: 2016-06-28 Revision: 2.08 |
MEKOR VOLATILE CORROSION INHIBITOR
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additives
Emergency Overview
Color: colorless
Change in color: Not available
Physical Form: liquid
Odor: unpleasant odor
Health Hazards: potentially fatal on contact with the skin, skin irritation, eye irritation, allergic reactions
Physical Hazards: Flash back hazard. Combustible liquid and vapor.
Short Term: irritation, drowsiness, blood disorders
Long Term: no information on significant adverse effects
Short Term: potentially fatal on contact with the skin, irritation, allergic reactions
Long Term: irritation
Short Term: irritation (possibly severe)
Long Term: irritation
Short Term: irritation, nausea, vomiting, drowsiness, blood disorders
Long Term: no information on significant adverse effects
CAS EC No Registration No | Component Name Synonyms | 1272/2008 (CLP) | Percent |
96-29-7 202-496-6 -- | 2-BUTANONE OXIME | Acute Tox. 4 (Dermal) - H312 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Carc. 2 - H351 | 85 - 100 |
7732-18-5 231-791-2 -- | WATER | -- | <15 |
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention.
For inhalation, consider oxygen. For ingestion, consider activated charcoal slurry.
See Section 9 for Flammability Properties
Moderate fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point.
alcohol-resistant foam, carbon dioxide, regular dry chemical, water
Large fires: Use regular foam or flood with fine water spray.
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Avoid heat, flames, sparks and other sources of ignition. Remove sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas.
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances.
Component Exposure Limits
Biological limit value
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Wear appropriate chemical resistant clothing.
Wear appropriate chemical resistant gloves.
rubber
No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Appearance | Not available | Physical State | Liquid |
Odor | unpleasant odor | Color | colorless |
Odor Threshold | Not available | pH | Not available |
Melting Point | Not available | Boiling Point | 152 °C |
Freezing point | Not available | Evaporation Rate | <1 (butyl acetate=1) |
Boiling Point Range | Not available | Flammability (solid, gas) | Not available |
Autoignition | Not available | Flash Point | 63 °C PMCC |
Lower Explosive Limit | Not available | Decomposition | Not available |
Upper Explosive Limit | Not available | Vapor Pressure | 10 mmHg at 20 °C |
Vapor Density (air=1) | 3 | Specific Gravity (water=1) | 0.916 - 0.924 |
Water Solubility | Not available | Partition coefficient: n-octanol/water | Not available |
Viscosity | Not available | Solubility (Other) | Not available |
Density | Not available | Physical Form | liquid |
Volatility | >95 % | OSHA Flammability Class | IIIA |
Stable at normal temperatures and pressure.
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat.
bases, acids, oxidizing materials, metals, peroxides
MEKOR VOLATILE CORROSION INHIBITOR ALKALIES (STRONG): Incompatible. ORGANIC ACIDS (STRONG): Incompatible. OXIDIZING AGENTS (STRONG): Incompatible. 2-BUTANONE OXIME ACIDIC IMPURITIES: Distillation with acidic impurities has caused violent explosions. ACIDS: Decomposition is promoted. ALKALIES: Incompatible. METALS: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXIDES: Incompatible. SULFURIC ACID: After hydrolization with aqueous sulfuric acid and the release of 2-Butanone during distillation, the residue, hydroxylammonium sulfate decomposed violently.
oxides of carbon, nitrogen, ketones, amides
Thermal decomposition products: oxides of carbon, nitrogen, methyl ethyl ketone, substituted amides.
Will not polymerize.
Component Analysis - LD50/LC50
Component Carcinogenicity
2-BUTANONE OXIME | 96-29-7 |
DFG: | Category 2 (considered to be carcinogenic for man) |
May inhibit alcohol metabolism.
MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): Vapor or mist may cause nose, throat and respiratory tract irritation, central nervous system depression with symptoms that include dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness, respiratory failure, methemoglobinemia (blood abnormality resulting in a bluish tint to the skin or mucous membrane) and coma may also occur 2-BUTANONE OXIME: May cause irritation Animal data shows a narcotic action at high vapor concentrations and at very high concentrations may lead to coma and respiratory failure Methemoglobinemia has also been reported.
MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available 2-BUTANONE OXIME: In an animal study, the red blood cells were affected and gross histopathologic alterations were observed in the spleen, lung and kidneys.
MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): Exposure may cause mild irritation with symptoms that include redness, burning, and allergic skin reactions Skin absorption is possible, and may contribute to symptoms of toxicity 2-BUTANONE OXIME: May cause irritation and sensitization An acute dermal animal study with 200 mg/kg caused mild hematologic effects.
2-BUTANONE OXIME: Repeated or prolonged exposure to irritants may cause dermatitis MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available.
2-BUTANONE OXIME: May cause irritation, possibly severe with damage MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): May cause severe irritation Symptoms may include stinging, tearing, redness, swelling and damage.
2-BUTANONE OXIME: Repeated or prolonged contact with irritant may cause conjunctivitis MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available.
MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): May be harmful and cause gastrointestinal irritation with nausea, vomiting, diarrhea, methemoglobinemia (blood abnormality resulting in a bluish tint to the skin or mucous membranes) 2-BUTANONE OXIME: May cause irritation to the respiratory system, nausea and vomiting May also cause narcotic effects as in acute inhalation Methemoglobinemia has also been reported.
MEKOR VOLATILE CORROSION INHIBITOR (Drew Chemical Corporation has reported the following): No data available 2-BUTANONE OXIME: Studies in rats resulted in hemolytic anemia.
Component Analysis - Aquatic Toxicity
2-BUTANONE OXIME | 96-29-7 |
Fish: | LC50 96 h Pimephales promelas 777 - 914 mg/L [flow-through]; LC50 96 h Poecilia reticulata 760 mg/L [static] |
Algae: | EC50 72 h Desmodesmus subspicatus 83 mg/L IUCLID |
Invertebrate: | EC50 48 h Daphnia magna 750 mg/L IUCLID |
Bioconcentration Factor
2-BUTANONE OXIME | 96-29-7 |
BCF | 0.5 - 5.8 BCF method: OECD 305C |
Dispose in accordance with all applicable regulations.
Component Waste Numbers
Component Marine Pollutants (IMDG)
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Component | CAS | CA | MA | MN | NJ | PA |
2-BUTANONE OXIME | 96-29-7 | No | No | Yes | No | No |
Not listed under California Proposition 65
Germany Water Classification
REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006
Component | CAS# | US | CA | EU | AU | PH | JP | KR | CN | NZ |
2-BUTANONE OXIME | 96-29-7 | Yes | DSL | EIN | Yes | Yes | Yes | Yes | Yes | Yes |
WATER | 7732-18-5 | Yes | DSL | EIN | Yes | Yes | No | Yes | Yes | Yes |
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
Australia GHS Labeling Information
European Union GHS Classifications
European Union GHS Labeling Information
Indonesia GHS Classifications
Japan GHS Classifications
Japan GHS Labeling Information
Korea GHS Classifications
New Zealand GHS Classifications
New Zealand GHS Labeling Information
South Africa GHS Classifications
Taiwan GHS Classifications
No classification assigned.
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
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