VANADIUM SULFATE

inorganic, salt 

VANADYL SULFATE; VANADIC SULFATE; C.I. 77940; VANADIUM OXOOSULFATE; VANADIUM OXYSULFATE; VANADIUM SULFATE DIHYDRATE; STCC 4963384; V-8; VANADIUM, OXO(SULFATO(2-)KAPPAO)-; VANADIUM, OXO(SULFATO(2-)-O)-; VANADIUM OXIDE SULPHATE; VANADIUM OXIDE SULFATE; OXO(SULFATO)VANADIUM; OXOVANADIUM(IV) SULFATE; VANADIUM OXIDE SULFATE (VO(SO4)); VANADIUM OXYSULFATE (VOSO4); VANADIUM SULFATE (VO(SO4)); VANADIUM, OXOSULFATO-; VANADYL MONOSULFATE

Emergency Overview 

Color:  blue 

Change in color: Not available

Physical Form: crystalline powder

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation 

Short Term:  irritation, nausea, difficulty breathing, asthma, headache, dizziness, blindness, lung congestion, lung damage 

Long Term:  wheezing, kidney damage, liver damage 

Short Term:  irritation, itching 

Long Term:  same as effects reported in short term exposure 

Short Term:  irritation, tearing 

Long Term:  no information on significant adverse effects 

Short Term:  metallic taste, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, convulsions 

Long Term:  no information on significant adverse effects 

This product may be regulated, have exposure limits or other information identified as the following: Vanadium compounds.

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Get medical attention immediately. 

For ingestion, consider gastric lavage and catharsis. Consider oxygen. 

calcium disodium edetate/dextrose, intravenous; calcium disodium edetate/procaine, intramuscular. Get medical attention immediately. 

See Section 9 for Flammability Properties 

Negligible fire hazard. 

regular dry chemical, regular foam, water Large fires: Use regular foam or flood with fine water spray. 

Move container from fire area if it can be done without risk. Fight large fires from a protected location or safe distance. Stay away from the ends of tanks. Dike for later disposal. Do not scatter spilled material with high-pressure water streams. 

Dig holding area such as lagoon, pond or pit for containment. Cover with plastic sheet or tarp to minimize spreading and protect from contact with water. 

Add an oxidizing agent. Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda ash). Collect spilled material using mechanical equipment. 

Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Small dry spills: Move containers away from spill to a safe area. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 

Store and handle in accordance with all current regulations and standards. 

Component Exposure Limits 

Biological limit value 

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Wear appropriate chemical resistant clothing. 

Wear appropriate chemical resistant gloves. 

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: Vanadium (V) 0.5 mg/m3 Any air-purifying respirator equipped with an N100, R100, or P100 filter (including N100, R100, and P100 filtering facepieces) except quarter-mask respirators. Any supplied-air respirator. 1.25 mg/m3 Any supplied-air respirator operated in a continuous-flow mode. Any powered, air-purifying respirator with a high-efficiency particulate filter. 2.5 mg/m3 Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 35 mg/m3 Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying, full-facepiece respirator equipped with an N100, R100, or P100 filter. Any appropriate escape-type, self-contained breathing apparatus. 

Stable at normal temperatures and pressure. 

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. 

oxidizing materials 

OXIDIZERS (STRONG): Fire and explosion hazard.

oxides of sulfur 

Thermal decomposition products: oxides of sulfur.

Will not polymerize. 

Component Analysis - LD50/LC50 

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

Vanadium dust and compounds may cause respiratory tract irritation, serous or hemorrhagic rhinitis, sore throat, cough, sneezing, tracheitis, bronchitis, pneumonitis, hemoptysis, and bronchiectasis More severe exposures may result in pulmonary edema and pneumonia which may be fatal If victim survives, there may be persistent asthma-type bronchitis, bouts of dyspnea, paroxysmal cough, or emphysema Pallor, altered taste, green tongue, blackening of the teeth, headache, nausea, insomnia, anorexia, weight loss, nervousness, dizziness, kidney malfunction, tremor of the distal extremeties, psychic disturbances, and blindness are also possible Symptoms may be delayed several days up to a week.

May cause symptoms as with acute inhalation, especially inflammatory action on the tracheobronchial tree, nose and throat irritation, violent coughing, wheezing, bronchitis, bronchial rales, rhinitis, and dyspnea There may also be blood changes, liver and kidney damage, and an increased susceptibility to respiratory changes.

May cause irritation and eczema-like eczema with intense itching, and possibly generalized uticaria.

Repeated or prolonged exposure may cause dermatitis.

May cause irritation, intense lacrimation, a burning sensation of the conjuctiva, and conjuctivitis.

Repeated or prolonged exposure may cause conjuctivitis.

Ingestion may cause metallic taste, hemorrhagic rhinitis, nausea, vomiting, diarrhea, abdominal pain and spasms, tremor, dyspnea, convulsions, and possible damage to the liver, kidneys, lungs, gastrointestinal tract, adrenal cortex, brain, spinal cord, and bone marrow.

Prolonged ingestion may produce the same symptoms as for acute ingestion.

Component Analysis - Aquatic Toxicity 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

ADR Tunnel Code Restrictions 

Component Marine Pollutants (IMDG) 

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Not listed under California Proposition 65 

Canadian WHMIS Ingredient Disclosure List (IDL) 

Germany Water Classification 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

European Union GHS Classifications 

Indonesia GHS Classifications 

Japan GHS Classifications 

Korea GHS Classifications 

Korea GHS Labeling Information 

New Zealand GHS Classifications 

New Zealand GHS Labeling Information 

South Africa GHS Classifications 

Taiwan GHS Classifications 

Taiwan GHS Labeling Information 

No classification assigned. 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 

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