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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。

  



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

VERICLEAN SOLVENT WITH OS-120, MCC-DC1


ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Synonyms 

VERICLEAN(TM)


Product Use 

detergent/soap 









* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless 

Change in color: Not available

Physical Form: aerosol

Odor:  sweet odor 

Health Hazards:  respiratory tract irritation, skin irritation, eye irritation, central nervous system depression 

Physical Hazards:  Containers may rupture or explode if exposed to heat. 




Potential Health Effects 
Inhalation 

Short Term:  irritation, drowsiness 

Long Term:  same as effects reported in short term exposure 




Skin Contact 

Short Term:  irritation 

Long Term:  same as effects reported in short term exposure 




Eye Contact 

Short Term:  irritation (possibly severe), tearing, eye damage 

Long Term:  same as effects reported in short term exposure 




Ingestion 

Short Term:  ingestion of a gas is unlikely 

Long Term:  no information on significant adverse effects 















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
107-46-0 203-492-7 --BIS(TRIMETHYLSILYL) OXIDE--80.1
811-97-2 212-377-0 --1,1,1,2-TETRAFLUOROETHANE--10.0
107-98-2 203-539-1 --PROPYLENE GLYCOL MONOMETHYL ETHERFlam. Liq. 3 - H226 STOT SE 3 - H3369.9











* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. 


Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 


Eyes 

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 


Ingestion 

If a large amount is swallowed, get medical attention. 









* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 1 Fire: 4 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 

Severe fire hazard. Vapor/air mixtures are explosive. Containers may rupture or explode if exposed to heat. 


Extinguishing Media 

carbon dioxide, regular dry chemical 


Fire Fighting Measures 

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. 









* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Small spills of the liquid component: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Spills with a large number of canisters: Reduce vapors with water spray. Remove sources of ignition. 









* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. See original container for storage recommendations. Keep separated from incompatible substances. 









* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2
ACGIH: 50 ppm TWA
 100 ppm STEL
NIOSH: 100 ppm TWA; 360 mg/m3 TWA
 150 ppm STEL; 540 mg/m3 STEL
Europe: 100 ppm TWA; 375 mg/m3 TWA
 Possibility of significant uptake through the skin
 150 ppm STEL; 568 mg/m3 STEL




Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 




Ventilation 

Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. 


PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 


Protective Clothing 

Wear appropriate chemical resistant clothing. 


Glove Recommendations 

Wear appropriate chemical resistant gloves. 


Protective Materials 

neoprene 


Respiratory Protection 

No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed. 









* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance clearPhysical State Aerosol
Odor sweet odorColor colorless
Odor Threshold Not available pH (neutral)
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point -4 °C TCC
Lower Explosive Limit Not available Decomposition Not available 
Upper Explosive Limit Not available Vapor Pressure 44.6 mmHg at 25 °C
Vapor Density (air=1) Not available Specific Gravity (water=1) 0.77
Water Solubility (insoluble)Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Density Not available Physical Form aerosol
Volatility 100 %  











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Stable at normal temperatures and pressure. 


Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Containers may rupture or explode if exposed to heat. 


Incompatible Materials 

halo carbons, combustible materials, halogens, oxidizing materials, acids, metals 


VERICLEAN SOLVENT WITH OS-120, MCC-DC1 ACETYL CHLORIDE: Incompatible. ALDEHYDES: Incompatible. HALOGENS: Incompatible. HALOGEN COMPOUNDS: Incompatible. NITRIC ACID (CONCENTRATED): Incompatible. OXIDIZERS (STRONG): Incompatible. SULFURIC ACID (CONCENTRATED): Incompatible. PROPYLENE GLYCOL MONOMETHYL ETHER OXIDIZERS (STRONG): Fire and explosion hazard. 1,1,1,2-TETRAFLUOROETHANE ALKALI OR ALKALINE EARTH METALS: Incompatible. ALUMINUM (ABRADED SURFACE): May cause strong exothermic reaction. ALUMINUM (POWDER): Incompatible. CALCIUM: Incompatible. MAGNESIUM: Incompatible. OXIDIZERS (STRONG): Fire and explosion hazard. POTASSIUM: Incompatible. ZINC: Incompatible. BIS(TRIMETHYLSILYL) OXIDE ACIDS: Incompatible. BASES: Incompatible. STRONG OXIDIZERS: Fire and explosion hazard.

Hazardous Decomposition Products 

oxides of carbon, oxides of silicon, carbon compounds, aldehydes 


Thermal decomposition products: oxides of carbon, silicon dioxide, carbon compounds, formaldehyde. 

Possibility of Hazardous Reactions 

Will not polymerize. 









* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Oral LD50 Rat >5000 mg/kg

Inhalation LC50 Rat 15956 ppm 4 h

1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Inhalation LC50 Rat 1500 g/m3 4 h

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Oral LD50 Rat 5000 mg/kg

Dermal LD50 Rabbit 13 g/kg

Inhalation LC50 Rat >7559 ppm 6 h (no deaths occurred)




Component Carcinogenicity

PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2
ACGIH: A4 - Not Classifiable as a Human Carcinogen








Medical Conditions Aggravated by Exposure 

heart or cardiovascular disorders, immune system disorders or allergies, respiratory disorders, skin disorders, central nervous system disorders, blood system disorders, 


Additional Data 

Stimulants such as epinephrine may induce ventricular fibrillation. 


Inhalation - Acute Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Due to the low vapor pressure of silicone fluids, the acute toxicity is generally low Animal experiments indicate that silicone oils are eliminated very slowly from the lungs, but their presence is not expected to cause any adverse reactions Animal inhalation of very high concentrations of silicone oil has resulted in fatal narcosis, although animals that survived the narcosis recovered completely PROPYLENE GLYCOL MONOMETHYL ETHER: Exposure to 100 ppm may cause irritation and the odor may be objectionable; 1000 ppm may cause central nervous system depression with headache, nausea, lightheadedness, drowsiness, incoordination, and possibly unconsciousness Death from central nervous system depression occurred in rats exposed to 10,000 ppm for 5-6 hours 1,1,1,2-TETRAFLUOROETHANE: No toxic effects were observed in test animals exposed to concentrations up to 81000 ppm Lethargy and rapid respiration were noted at concentrations of 205000 ppm and pulmonary congestion, edema, and central nervous system effects including dyspnea occured at concentrations of 750000 ppm May also cause heart irregularities, unconsciousness or death Liquid contact can cause frostbite.


Inhalation - Chronic Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Animals inhaling 4400 ppm of bis(trimethylsilyl) oxide for 19-26 days showed signs of slight depression An increase in liver and kidney weights was noted in rats PROPYLENE GLYCOL MONOMETHYL ETHER: Repeated exposure of animals produced slight growth depression and very slight liver and lung effects Central nervous system depression was noticed initially, but tolerance soon developed Slight fetotoxicity in the form of delayed sternebral ossification was observed in rats The dose was also maternally toxic 1,1,1,2-TETRAFLUOROETHANE: Overexposure may cause dizziness and loss of concentration At higher levels, central nervous system depression and cardiac arrhythmia may occur.


Skin Contact - Acute Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Direct contact may result in mild irritation PROPYLENE GLYCOL MONOMETHYL ETHER: May cause mild irritation 1,1,1,2-TETRAFLUOROETHANE: Some fluorocarbon liquids remove natural oils from the skin causing drying and irritation Sensitization develops rarely Direct contact with liquid fluorocarbons may cause freezing injury and possibly frostbite.


Skin Contact - Chronic Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Prolonged or repeated exposure may cause dermatitis PROPYLENE GLYCOL MONOMETHYL ETHER: Repeated application to animal skin produced mild irritation, slight increase in kidney weight, mild narcosis, and some deaths 1,1,1,2-TETRAFLUOROETHANE: No data available.


Eye Contact - Acute Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Silicone oils may irritate the ocular mucosa causing redness, pain and lacrimation A silicone fluid injected into rabbit eyes resulted in transient irritation with complete clearing after 48 hours PROPYLENE GLYCOL MONOMETHYL ETHER: Application produced a score of 3-4 out of 10 in rabbit eyes Vapors around 100 ppm may cause irritation; 250 ppm may cause lacrimation 1,1,1,2-TETRAFLUOROETHANE: Splashes of some liquid fluorocarbons may cause frostbite, with effects from temporary irritation to severe damage.


Eye Contact - Chronic Exposure 

BIS(TRIMETHYLSILYL) OXIDE: May cause irritation and conjunctivitis Silicone oils injected into various parts of the rabbit eyes have effects ranging from no immediate damage to edema, vascularization, scarring of the cornea and cataracts after 2 to 3 months PROPYLENE GLYCOL MONOMETHYL ETHER: Prolonged or repeated exposure to irritants may cause conjunctivitis 1,1,1,2-TETRAFLUOROETHANE: No data available.


Ingestion - Acute Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Ingestion of large doses of bis(trimethylsilyl) oxide may cause inebriation and transient central nervous system depression PROPYLENE GLYCOL MONOMETHYL ETHER: Single doses administered to animals produced dyspnea, somnolence, ataxia, and death from anesthesia 1,1,1,2-TETRAFLUOROETHANE: May cause irritation of the digestive tract.


Ingestion - Chronic Exposure 

BIS(TRIMETHYLSILYL) OXIDE: Chronic feeding of bis(trimethylsilyl) oxide to rats resulted in widespread systemic irritation PROPYLENE GLYCOL MONOMETHYL ETHER: Repeated administration of 3 gm/kg to animals produced minor changes in the liver and kidneys 1,1,1,2-TETRAFLUOROETHANE: No data available.









* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

BIS(TRIMETHYLSILYL) OXIDE107-46-0
Fish: LC50 96 h Oncorhynchus mykiss 3.02 mg/L [flow-through]
PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2
Fish: LC50 96 h Pimephales promelas 20.8 g/L [static]
Invertebrate: EC50 48 h Daphnia magna 23300 mg/L IUCLID








Bioconcentration Factor 

BIS(TRIMETHYLSILYL) OXIDE107-46-0
BCF 1300 species: fish
PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2
BCF <2











* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 


Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

No Classification assigned.




TDG Information:

No Classification assigned.




ADR Information:

No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Restriction(s): C/E [UN3159]

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Restriction(s): D/E [UN3092] (III)








RID Information:

No Classification assigned.




IATA Information:

No Classification assigned.




ICAO Information:

No Classification assigned.




IMDG Information:

No Classification assigned.

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: Yes Pressure: Yes Reactivity: No








U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component CAS CA MA MN NJ PA 
1,1,1,2-TETRAFLUOROETHANE811-97-2No No Yes No No 
PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2Yes Yes Yes Yes Yes 




Not listed under California Proposition 65 




Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2
 1 %








Germany Water Classification 

BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

ID Number 542 , hazard class 1 - low hazard to waters (footnote 13)

ID Number 9235 , hazard class 2 - hazard to waters

1,1,1,2-TETRAFLUOROETHANE (811-97-2)

ID Number 2350 , hazard class 1 - low hazard to waters

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

ID Number 1597 , hazard class 1 - low hazard to waters




REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Assigned to Member State United Kingdom (Initial Grounds for Concern: Human health/Suspected CMR, Exposure/Use in personal care products, aggregated tonnage)












Symbol(s)

F Highly Flammable

Xi Irritant

Risk Phrases

R11 Highly flammable.

R36/38 Irritating to eyes and skin.




Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
BIS(TRIMETHYLSILYL) OXIDE107-46-0Yes DSL EIN Yes Yes Yes Yes Yes Yes 
1,1,1,2-TETRAFLUOROETHANE811-97-2Yes DSL EIN Yes Yes Yes Yes Yes Yes 
PROPYLENE GLYCOL MONOMETHYL ETHER107-98-2Yes DSL EIN Yes Yes Yes Yes Yes Yes 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H336 May cause drowsiness or dizziness

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness




European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H336 May cause drowsiness or dizziness

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0) Approval: 23A5018

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Gases Under Pressure Liquefied gas H280 Contains gas under pressure, may explode when heated Approval: 21A3509

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 21A3509

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Flammable Liquids Category 3 H226 Flammable liquid and vapour Approval: 25B0008

Acute toxicity Inhalation - Vapour Category 4 H332 Harmful if inhaled Approval: 25B0008

Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 25B0008

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness Approval: 25B0008




Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H280 Contains gas under pressure, may explode when heated

H336 May cause drowsiness or dizziness

Prevention

P271 Use only outdoors or in a well-ventilated area

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P405 Store locked up

P410+P403 Protect from sunlight. Store in a well-ventilated place

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H332 Harmful if inhaled

H320 Causes eye irritation

H336 May cause drowsiness or dizziness

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

NEMA:Flammable Liquids Category 2 H225 Highly flammable liquid and vapour


PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

MOEL:Flammable Liquids Category 3 H226 Flammable liquid and vapour

Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation

Specific Target Organ Toxicity - Single Exposure Category 3 H336 May cause drowsiness or dizziness
NEMA:Flammable Liquids Category 3 H226 Flammable liquid and vapour




Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H319 Causes serious eye irritation

H336 May cause drowsiness or dizziness

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P271 Use only outdoors or in a well-ventilated area

P280 Wear protective gloves/protective clothing/eye protection/face protection

P261 Avoid breathing dust/fume/gas/mist/vapours/spray

P264 Wash thoroughly after handling

Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed

P403+P235 Store in a well-ventilated place. Keep cool

P405 Store locked up

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0) Approval: HSR006733

Flammable Liquids Category 2 H225 Highly flammable liquid and vapour

Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (fish)

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2) Approval: HSR001187

Flammable Liquids Category 3 H226 Flammable liquid and vapour

Acute toxicity Oral Category 5 H303 May be harmful if swallowed

Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation

Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation




New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H400 Very toxic to aquatic life

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P273 Avoid release to the environment

Response

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

P391 Collect spillage

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H303 May be harmful if swallowed

H316 Causes mild skin irritation

H319 Causes serious eye irritation

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P332+P313 If skin irritation occurs: Get medical advice/attention

P312 Call a POISON CENTER or doctor/physician if you feel unwell

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations




South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Listing: Present




Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Taiwan:Flammable Liquids Category 2 H225 Highly flammable liquid and vapour
 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation


1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Taiwan:Gases Under Pressure Compressed gas H280 Contains gas under pressure, may explode when heated (classified in accordance to European Union CLP Regulation, classification obtained from joint registration or through majority of the enterprises)


PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Taiwan:Flammable Liquids Category 3 H226 Flammable liquid and vapour
 Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation




Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
BIS(TRIMETHYLSILYL) OXIDE (107-46-0)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H225 Highly flammable liquid and vapour

H316 Causes mild skin irritation

H320 Causes eye irritation

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P332+P313 If skin irritation occurs: Get medical advice/attention

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations

1,1,1,2-TETRAFLUOROETHANE (811-97-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H280 Contains gas under pressure, may explode when heated

Storage

P410+P403 Protect from sunlight. Store in a well-ventilated place

PROPYLENE GLYCOL MONOMETHYL ETHER (107-98-2)

Symbol(s)

 


Signal Word Warning

Hazard(s)

H226 Flammable liquid and vapour

H319 Causes serious eye irritation

Prevention

P233 Keep container tightly closed

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 Ground/Bond container and receiving equipment

P241 Use explosion-proof electrical/ventilating/lighting equipment

P242 Use only non-sparking tools

P243 Take precautionary measures against static discharge

P280 Wear protective gloves/protective clothing/eye protection/face protection

P264 Wash thoroughly after handling

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337+P313 If eye irritation persists: Get medical advice/attention

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower

P370+P378 In case of fire: Use appropriate media for extinction

Storage

P403+P235 Store in a well-ventilated place. Keep cool

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations












Classification 

No classification assigned. 









* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 


Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 






Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved