* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name:
WHITE FUMING NITRIC ACID
ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. |
Chemical Family
acids, inorganic
Synonyms
NITRIC ACID, (WHITE FUMING); NITRIC ACID, A.C.S.REAGENT; NITRIC ACID, FUMING; WFNA; UN 2031; HNO3
* * * Section 2 - HAZARDS IDENTIFICATION * * *
Emergency Overview
Color: colorless to yellow
Change in color: changes color on exposure to light hygroscopic
Physical Form: fuming liquid
Health Hazards: respiratory tract burns, skin burns, eye burns, mucous membrane burns
Physical Hazards: May ignite combustibles. May react on contact with water.
Potential Health Effects
Inhalation
Short Term: burns
Long Term: burns
Skin Contact
Short Term: burns
Long Term: burns
Eye Contact
Short Term: burns
Long Term: burns
Ingestion
Short Term: burns
Long Term: burns
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS EC No Registration No |
Component Name Synonyms |
1272/2008 (CLP) |
Percent |
52583-42-3 -- -- |
WHITE FUMING NITRIC ACID |
-- |
100 |
Contaminants
MAY CONTAIN TRACES OF ARSENIC, CHLORINE, IRON, HEAVY METALS AND IGNITION RESD.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately.
Note to Physicians
For inhalation, consider oxygen. Avoid gastric lavage or emesis.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings:
Health: 3 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials.
Extinguishing Media
regular dry chemical, soda ash, water Large fires: Flood with water. Apply water from a protected location or from a safe distance.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Stay upwind and keep out of low areas. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile).
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Air Release
Reduce vapors with water spray. Collect runoff for disposal as potential hazardous waste.
Soil Release
Trap spilled material at bottom in deep water pockets, excavated holding areas or within sand bag barriers. Dike for later disposal. Absorb with sand or other non-combustible material. Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda ash).
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. Neutralize.
Occupational spill/release
Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Flood with water. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
* * * Section 7 - HANDLING AND STORAGE * * *
Handling Procedures
Subject to handling regulations: U.S. OSHA 29 CFR 1910.119.
Storage Procedures
Store and handle in accordance with all current regulations and standards. Store in a tightly closed container. Refrigerate. Keep in the dark. Vent containers periodically (or when exposed to heat). Open containers carefully. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355 Part B). Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components
Component Analysis
Biological limit value
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 25 ppm Any supplied-air respirator operated in a continuous-flow mode. Any air-purifying respirator with a full facepiece and a canister providing protection against this substance. Only non-oxidizable sorbents are allowed (not charcoal). Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted canister providing protection against the compound of concern. Only non-oxidizable sorbents are allowed (not charcoal). Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted canister providing protection against the compound of concern. Only non-oxidizable sorbents are allowed (not charcoal). Any appropriate escape-type, self-contained breathing apparatus.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Appearance
|
Not available |
Physical State
|
Liquid |
Odor
|
Not available |
Color
|
colorless to yellow |
Odor Threshold
|
Not available |
pH
|
(acidic) |
Melting Point
|
Not available |
Boiling Point
|
Not available |
Freezing point
|
Not available |
Evaporation Rate
|
Not available |
Boiling Point Range
|
Not available |
Flammability (solid, gas)
|
Not available |
Autoignition
|
Not available |
Flash Point
|
not flammable |
Lower Explosive Limit
|
Not available |
Decomposition
|
Not available |
Upper Explosive Limit
|
Not available |
Vapor Pressure
|
6.6 mmHg at 20 °C |
Vapor Density (air=1)
|
1.3 |
Specific Gravity (water=1)
|
1.49 |
Water Solubility
|
Not available |
Partition coefficient: n-octanol/water
|
Not available |
Viscosity
|
Not available |
Solubility (Other)
|
Not available |
Change in color
|
changes color on exposure to light, hygroscopic |
Density
|
Not available |
Physical Form
|
fuming liquid |
Molecular Formula
|
H-N-O3 |
Molecular Weight
|
63.01 |
|
|
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure. May react with evolution of heat on contact with water.
Conditions to Avoid
Avoid contact with combustible materials. Keep dry. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers.
Incompatible Materials
acids, combustible materials, halo carbons, amines, bases, oxidizing materials, metals, halogens, metal salts, metal oxides, reducing agents, peroxides, metal carbide, cyanides,
NITRIC ACID: ACETIC ACID: May react explosively. ACETIC ANHYDRIDE: Explosive reaction by friction or impact. ACETONE: May react explosively. ACETONITRILE: Explosive mixture. 4-ACETOXY-3-METHOXYBENZALDEHYDE: Exothermic reaction. ACROLEIN: Temperature and pressure increase in closed container. ACRYLONITRILE: Explosive reaction at 90 C. ACRYLONITRILE-METHACRYLATE COPOLYMER: Incompatible. ALCOHOLS: Possible violent reaction or explosion; formation of explosive compound in the presence of heavy metals. ALKANETHIOLS: Exothermic reaction with possible ignition. 2-ALKOXY-1,3-DITHIA-2-PHOSPHOLANE: Ignition reaction. ALLYL ALCOHOL: Temperature and pressure increase in closed container. ALLYL CHLORIDE: Temperature and pressure increase in closed container. AMINES (ALIPHATIC OR AROMATIC): Possible ignition reaction. 2-AMINOETHANOL: Temperature and pressure increase in closed container. 2-AMINOTHIAZOLE: Explosive reaction. AMMONIA (GAS): Burns in an atmosphere of nitric acid vapor. AMMONIUM HYDROXIDE: Temperature and pressure increase in closed container. AMMONIUM NITRATE: Forms explosive mixture. ANILINE: Ignites on contact. ANILINIUM NITRATE: Forms explosive solution. ANION EXCHANGE RESINS: Possible violent exothermic reaction. ANTIMONY: Violent reaction. ARSINE: Explosive reaction. ARSINE-BORON TRIBROMIDE: Violent oxidation. BASES: Reacts. BENZENE: Explosive reaction. BENZIDINE: Spontaneous ignition. BENZONITRILE: Possible explosion. BENZOTHIOPHENE DERIVATIVES: Formation of possibly explosive compounds. N-BENZYL-N-ETHYLANILINE: Vigorous decomposition. 1,4-BIS(METHOXYMETHYL)2,3,5,6-TETRAMETHYLBENZENE: Gas evolution. BISMUTH: Intense exothermic reaction or explosion. 1,3-BIS(TRIFLUOROMETHYL)BENZENE: Possible explosion. BORON: Violent reaction with incandescence. BORON DECAHYDRIDE: Explosive reaction. BORON PHOSPHIDE: Ignition reaction. BROMINE PENTAFLUORIDE: Ignition reaction. N-BUTYL MERCAPTAN: Ignition reaction. N-BUTYRALDEHYDE: Temperature and pressure increase in closed container. CADMIUM PHOSPHIDE: Explosive reaction. CALCIUM HYPOPHOSPHITE: Ignition reaction. CARBON (PULVERIZED): Violent reaction. CELLULOSE: Forms easily combustible ester. CHLORATES: Reacts. CHLORINE: Incompatible. CHLORINE TRIFLUORIDE: Violent reaction. CHLOROBENZENE: Possible explosion. 4-CHLORO-2-NITROANILINE: Forms explosive compound. CHLOROSULFONIC ACID: Temperature and pressure increase in closed container. COAL: Explosive mixture. COATINGS: Attacks. CRESOL: Temperature and pressure increase in closed container. CROTONALDEHYDE: Violent decomposition with ignition. CUMENE: Temperature and pressure increase in closed container. CUPRIC NITRIDE: Explosive reaction. CUPROUS NITRIDE: Violent reaction. CYANATES: Possible explosive reaction. CYCLOHEXANONE: Violent reaction. CYCLOHEXYLAMINE: Forms explosive compound. CYCLOPENTADIENE: Explosive reaction. 1,2-DIAMINOETHANEBIS(TRIMETHYLGOLD): Explosive reaction. DIBORANE: Spontaneous ignition. DI-2-BUTOXYETHYL ETHER: Violent decomposition reaction. 2,6-DI-T-BUTYL PHENOL: Formation of explosive compound. DICHLOROETHANE: Forms shock and heat sensitive mixture. DICHLOROETHYLENE: Forms explosive compound. DICHLOROMETHANE: Forms explosive solution. DICYCLOPENTADIENE: Spontaneous ignition. DIENES: Ignition reaction. DIETHYLAMINO ETHANOL: Possible explosion. DIETHYL ETHER: Possible explosion. 3,6-DIHYDRO-1,2,2H-OXAZINE: Explosive interaction. DIISOPROPYL ETHER: Temperature and pressure increase in closed container. DIMETHYLAMINOMETHYLFERROCENE: Violent decomposition if heated. DIMETHYL ETHER: Forms explosive compound. DIMETHYL HYDRAZINE: Ignites on contact. DIMETHYL SULFOXIDE + 1,4-DIOXANE: Explosion. DIMETHYL SULFOXIDE + <14% WATER: Explosive reaction. DINITROBENZENE: Explosion hazard. DINITROTOLUENE: Explosive reaction. DIOXANE + PERCHLORIC ACID: Possible explosion. DIPHENYL DISTIBENE: Explosive oxidation. DIPHENYL MERCURY + CARBON DISULFIDE: Violent reaction. DIPHENYL TIN: Ignition reaction. DISODIUM PHENYL ORTHOPHOSPHATE: Violent explosion. DIVINYL ETHER: Possible ignition reaction. EPICHLOROHYDRIN: Temperature and pressure increase in closed container. ETHANESULFONAMIDE: Explosive reaction. ETHOXY-ETHYLENE DITHIOPHOSPHATE: Ignition on contact. M-ETHYL ANILINE: Ignition reaction. ETHYLENE DIAMINE: Temperature and pressure increase in closed container. ETHYLENE GLYCOL: Forms shock and heat sensitive mixture. ETHYLENEIMINE: Temperature and pressure increase in closed container. 5-ETHYL-2-METHYL PYRIDINE: Explosive reaction. ETHYL PHOSPHINE: Ignition reaction. 5-ETHYL-2-PICOLINE: Forms explosive compounds. FERROUS OXIDE (POWDERED): Intense exothermic reaction. FLUORINE: Possible explosive reaction. FORMIC ACID: Exothermic reaction with release of toxic gases. 2-FORMYLAMINO-1-PHENYL-1,3-PROPANEDIOL: Possible explosion. FUEL OIL (BURNING): Explosion. FULMINATES: Reacts. FURFURYLIDENE KETONES: Ignites on contact. GERMANIUM: Violent reaction. GLYCEROL: Possible explosion. GLYOXAL: Temperature and pressure increase in closed container. HEXALITHIUM DISILICIDE: Explosive reaction. HEXAMETHYLBENZENE: Possible explosion. 2,2,4,4,6,6-HEXAMETHYLTRITHIANE: Explosive oxidation. HEXENAL: Explodes on heating. HYDRAZINE: Violent reaction. HYDRAZOIC ACID: Energetic reaction. HYDROGEN IODIDE: Ignition reaction. HYDROGEN PEROXIDE: Forms unstable mixture. HYDROGEN PEROXIDE AND KETONES: Forms explosive products. HYDROGEN PEROXIDE AND MERCURIC OXIDE: Forms explosive compounds. HYDROGEN PEROXIDE AND THIOUREA: Forms explosive compounds. HYDROGEN SELENIDE: Ignition reaction. HYDROGEN SULFIDE: Incandescent reaction. HYDROGEN TELLURIDE: Ignition and possible explosive reaction. INDANE AND SULFURIC ACID: Explosive reaction. ISOPRENE: Temperature and pressure increase in closed container. KETONES (CYCLIC): Violent reaction. LACTIC ACID + HYDROFLUORIC ACID: Explosive reaction. LITHIUM: Ignition reaction. LITHIUM SILICIDE: Incandescent reaction. MAGNESIUM: Explosive reaction. MAGNESIUM + 2-NITROANILINE: May ignite on contact. MAGNESIUM PHOSPHIDE: Incandescent reaction. MAGNESIUM SILICIDE: Violent reaction. MAGNESIUM-TITANIUM ALLOY: Forms shock and heat sensitive mixture. MANGANESE (POWDERED): Incandescence and possible explosion. MESITYL OXIDE: Temperature and pressure increase in closed container. MESITYLENE: Possible explosive reaction. METALS: Violent reaction with explosion or ignition. METAL ACETYLIDES: Violent or explosive reaction. METAL CARBIDES: Violent or explosive reaction. METAL CYANIDES: Explosive reactions. METAL FERRICYANIDE OR FERROCYANIDE: Violent reaction. METAL SALICYLATES: Forms explosive compounds. METAL THIOCYANATES: Possible explosion. 2-METHYLBENZIMIDAZOLE + SULFURIC ACID: Possible explosive reaction. 4-METHYLCYCLOHEXANONE: Explosive reaction. 2-METHYL-5-ETHYLPYRIDINE: Temperature and pressure increase in closed container. METHYL THIOPHENE: Ignition reaction. NEODYMIUM PHOSPHIDE: Violent reaction. NICKEL TETRAPHOSPHIDE: Ignition reaction. NITRO AROMATIC HYDROCARBONS: Forms highly explosive products. NITROBENZENE: Explosive reaction, especially in the presence of water. NITROMETHANE: Explosive reaction. NITRONAPHTHALENE: Explosion hazard. NON-METAL OXIDES: Explosive reaction. OLEUM: Temperature and pressure increase in closed container. ORGANIC MATERIALS: Fire and explosion hazard. ORGANIC SUBSTANCES: Possible explosion. PERCHLORATES: Possible explosion. PHENYL ACETYLENE + 1,1-DIMETHYLHYDRAZINE: Violent reaction. PHENYL ORTHOPHOSPHORIC ACID DISODIUM SALT: Forms explosive products. PHOSPHINE + OXYGEN: Spontaneous ignition. PHOSPHONIUM IODIDE: Ignition reaction. PHOSPHORUS (VAPOR): Ignites when heated. PHOSPHOROUS HALIDES: Ignition reaction. PHOSPHORUS TETRAIODIDE: Vigorous reaction. PHOSPHORUS TRICHLORIDE: Explosive reaction. PHTHALIC ACID: Possible explosive reaction. PHTHALIC ANHYDRIDE: Exothermic reaction and forms explosive products. PICRATES: Reacts. PLASTICS: Attacks. POLYALKENES: Intense reaction. POLYDIBROMOSILANES: Explosive reaction. POLY(ETHYLENE OXIDE) DERIVATIVES: Possible explosion. POLYPROPYLENE: Temperature and pressure increase in a closed container. POLY(SILYLENE): Ignition. POLYURETHANE (FOAM): Vigorous reaction. POTASSIUM HYPOPHOSPHITE: Explosive reaction. POTASSIUM PHOSPHINATE: Explodes on evaporation. B-PROPIOLACTONE: Temperature and pressure increase in closed container. PROPIOPHENONE + SULFURIC ACID: Exothermic reaction above -5 C. PROPYLENE GLYCOL + HYDROFLUORIC ACID + SILVER NITRATE: Explosive mixture. PROPYLENE OXIDE: Temperature and pressure increase in closed container. PYRIDINE: Temperature and pressure increase in closed container. PYROCATECHOL: Ignites on contact. REDUCING AGENTS: Possible explosive or ignition reaction. RESORCINOL: Possible explosion. RUBBER: Vigorous reaction, possible explosion. SELENIUM: Vigorous reaction. SELENIUM HYDRIDE: Ignition or incandescent reaction. SELENIUM IODOPHOSPHIDE: Explosive reaction. SILICON: Violent reaction. SILICONE OIL: Possible explosion. SILVER BUTEN-3-YNIDE: Explosion. SODIUM: Spontaneous ignition. SODIUM AZIDE: Exothermic reaction. SODIUM HYDROXIDE: Temperature and pressure increase in a closed container. STIBINE: Explosive reaction. SUCROSE (SOLID): Vigorous reaction. SULFAMIC ACID: Violent reaction with evolution of toxic nitrous oxide. SULFIDES: Reacts. SULFUR DIOXIDE: Explosive reaction. SULFUR HALIDES: Violent reaction. SULFURIC ACID: Possible explosion. SULFURIC ACID + GLYCERIDES: Explosive reaction. SULFURIC ACID + TEREPHTHALIC ACID: Violent reaction. SURFACTANTS + PHOSPHORIC ACID: Explosion hazard. TERPENES: Spontaneous ignition. TETRABORANE: Explosive reaction. TETRABORANE DECAHYDRIDE: Explosive reaction. TETRAPHOSPHOROUS DIIODOTRISELENIDE: Explosive reaction. TETRAPHOSPHOROUS IODIDE: Ignites on contact. TETRAPHOSPHOROUS TETRAOXIDE TRISULFIDE: Violent reaction. THIOALDEHYDES: Violent reaction. THIOKETONES: Violent reaction. THIOPHENES: Explosive reaction. TITANIUM: Forms shock-sensitive compound. TITANIUM ALLOYS: Possible explosive reaction. TITANIUM-MAGNESIUM ALLOY: Possible explosion on impact. TOLUENE: Violent reaction. TOLUIDENE: Ignition reaction. 1,3,5-TRIACETYLHEXAHYDRO-1,3,5-TRIAZINE + TRIFLUOROACETIC ANHYDRIDE: Explosive reaction. TRIAZINE: Violently explosive reaction. TRICADMIUM DIPHOSPHIDE: Explosive reaction. TRIETHYLGALLIUM MONOETHYL ETHER COMPLEX: Ignition reaction. TRIMETHYLTRIOXANE: Intense reaction. TRIS(IODOMERCURI)PHOSPHINE: Violent decomposition. TRITHIOACETONE: Explosive reaction. TURPENTINE: Explosive mixture. UNSYMMETRICAL DIMETHYL HYDRAZINE: Spontaneous ignition. URANIUM: Explosive reaction. URANIUM ALLOY: Violent reaction. URANIUM DISULFIDE: Violent reaction. URANIUM-NEODYMIUM ALLOYS: Explosive reaction. VINYL ACETATE: Temperature and pressure increase in closed container. VINYLIDENE CHLORIDE: Temperature and pressure increase in closed container. WOOD: Possible ignition. P-XYLENE: Intense reaction in presence of sulfuric acid. ZINC: Incandescent reaction. ZINC ETHOXIDE: Possible explosion. ZIRCONIUM-URANIUM ALLOYS: Explosive reaction.
Hazardous Decomposition Products
oxides of nitrogen
Thermal decomposition products: oxides of nitrogen.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and no selected endpoints have been identified
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Medical Conditions Aggravated by Exposure
eye disorders, respiratory disorders, skin disorders and allergies,
Inhalation - Acute Exposure
NITRIC ACID: Inhalation of acidic substances may cause severe respiratory irritation with coughing, choking, and possibly yellowish burns of the mucous membranes Other initial symptoms may include dizziness, headache, nausea, and weakness Pulmonary edema may be immediate in the most severe exposures, but more likely will occur after a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, dizziness, frothy sputum, and cyanosis Physical findings may include hypotension, weak, rapid pulse, moist rales, and hemoconcentration In non-fatal cases, complete recovery may occur within a few days or weeks or, convalescence may be prolonged with frequent relapses and continued dyspnea and other signs and symptoms of pulmonary insufficiency In severe exposures, death due to anoxia may occur within a few hours after onset of the symptoms of pulmonary edema or following a relapse.
Inhalation - Chronic Exposure
NITRIC ACID: Depending on the concentration and duration of exposure, repeated or prolonged exposure to an acidic substance may cause erosion of the teeth, inflammatory and ulcerative changes in the mouth, and possibly jaw necrosis Bronchial irritation with cough and frequent attacks of bronchial pneumonia may occur Gastrointestinal disturbances are also possible.
Skin Contact - Acute Exposure
NITRIC ACID: Direct contact with liquid or vapor may cause severe pain, burns and possibly yellowish stains Burns may be deep with sharp edges and heal slowly with scar tissue formation Dilute solutions of nitric acid may produce mild irritation and harden the epidermis without destroying it Concentrated acid solutions applied to over 25% of the skin area in rats produced elevated methemoglobin and blood nitrate levels.
Skin Contact - Chronic Exposure
NITRIC ACID: Effects depend on the concentration and duration of exposure Repeated or prolonged contact with acidic substances may result in dermatitis or effects similar to acute exposure.
Eye Contact - Acute Exposure
NITRIC ACID: Direct contact with acidic substances may cause pain and lacrimation, photophobia, and burns, possibly severe The degree of injury depends on the concentration and duration of contact In mild burns, the epithelium regenerates rapidly and the eye recovers completely In severe cases, the extent of injury may not be fully apparent for several weeks Ultimately, the whole cornea may become deeply vascularized and opaque resulting in blindness In the worst cases, the eye may be totally destroyed Concentrated nitric acid may impart a yellow color to the eye upon contact.
Eye Contact - Chronic Exposure
NITRIC ACID: Effects depend on the concentration and duration of exposure Repeated or prolonged exposure to acidic substances may cause conjunctivitis or effects as in acute exposure.
Ingestion - Acute Exposure
NITRIC ACID: Acidic substances may cause circumoral burns with yellow discoloration and corrosion of the mucous membranes of the mouth, throat and esophagus There may be immediate pain and difficulty or inability to swallow or speak Epiglottal edema may result in respiratory distress and possibly asphyxia Marked thirst, epigastric pain, nausea, vomiting and diarrhea may occur Depending on the degree of espohageal and gastric corrosion, the vomitus may contain fresh or dark precipitated blood and large shreds of mucosa Shock with marked hypotension, weak, rapid pulse, shallow respiration, and clammy skin may occur Circulatory collapse may ensue and if uncorrected, lead to renal failure In severe cases, gastric, and to a lesser degree, esophageal perforation and subsequent peritonitis may occur and be accompanied by fever and abdominal rigidity Esophageal, gastric anc pyloric stricture may occur within a few weeks, but may be delayed for months or even years Death may result within a short time from asphyxia, circulatory collapse or aspiration of even minute amounts Later death may be due to peritonitis, severe nephritis or pneumonia Coma and convulsions sometimes occur terminally.
Ingestion - Chronic Exposure
NITRIC ACID: Depending on the concentration, repeated ingestion of acidic substances may result in inflammatory and ulcerative changes in the mucous membranes of the mouth and other effects as in acute ingestion Reproductive effects have been reported in animals.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN/NA #: UN2031
Packing Group: II
Required Label(s): 8
TDG Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Required Label(s): 8
ADR Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Required Label(s): 8
RID Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Required Label(s): 8
IATA Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Required Label(s): 8
ICAO Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Required Label(s): 8
IMDG Information:
Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)
Hazard Class: 8
UN#: UN2031
Packing Group: II
Component Marine Pollutants (IMDG)
Not regulated as dangerous goods.
* * * Section 15 - REGULATORY INFORMATION * * *
US Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No
U.S. State Regulations
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA
Not listed under California Proposition 65
Symbol(s)
O Oxidizing
C Corrosive
Risk Phrases
R8 Contact with combustible material may cause fire.
R34 Causes burns.
Safety Phrases
S2 Keep out of the reach of children.
S20 When using do not eat or drink.
S24 Avoid contact with skin.
S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 Take off immediately all contaminated clothing.
S39 Wear eye/face protection.
S46 If swallowed, seek medical advice immediately and show this container or label.
Component Analysis - Inventory
Component |
CAS# |
US |
CA |
EU |
AU |
PH |
JP |
KR |
CN |
NZ |
WHITE FUMING NITRIC ACID |
52583-42-3 |
No |
No |
No |
No |
No |
No |
No |
Yes |
No |
Globally Harmonized System of Classification and Labeling (GHS)
The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements
Australia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
European Union GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Indonesia GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Japan GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Korea GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
New Zealand GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
South Africa GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Taiwan GHS Classifications
No published information available
This material may be hazardous according to published criteria for classification
Classification
No classification assigned.
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse.
Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times.
Copyright
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved