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危险化学品

收录危险化学品目录,并提供相应的化学品安全技术说明书(Material Safety Data Sheet,简称MSDS)。用户可获取化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。为实验室安全提供重要参考。



                


* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 
WHITE FUMING NITRIC ACID



ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.








Chemical Family 
acids, inorganic 



Synonyms 
NITRIC ACID, (WHITE FUMING); NITRIC ACID, A.C.S.REAGENT; NITRIC ACID, FUMING; WFNA; UN 2031; HNO3










* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  colorless to yellow 

Change in color: changes color on exposure to light hygroscopic

Physical Form: fuming liquid

Health Hazards:  respiratory tract burns, skin burns, eye burns, mucous membrane burns 

Physical Hazards:  May ignite combustibles. May react on contact with water. 





Potential Health Effects 
Inhalation 
Short Term:  burns 

Long Term:  burns 





Skin Contact 
Short Term:  burns 

Long Term:  burns 





Eye Contact 
Short Term:  burns 

Long Term:  burns 





Ingestion 
Short Term:  burns 

Long Term:  burns 
















* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration No Component Name Synonyms 1272/2008 (CLP) Percent
52583-42-3 -- -- WHITE FUMING NITRIC ACID -- 100




Contaminants 
MAY CONTAIN TRACES OF ARSENIC, CHLORINE, IRON, HEAVY METALS AND IGNITION RESD. 










* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 



Skin 
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 



Eyes 
Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 



Ingestion 
Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 



Note to Physicians 
For inhalation, consider oxygen. Avoid gastric lavage or emesis. 










* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 
NFPA Ratings: 
Health: 3 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe




Flammable Properties 
Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible materials. 



Extinguishing Media 
regular dry chemical, soda ash, water Large fires: Flood with water. Apply water from a protected location or from a safe distance. 



Fire Fighting Measures 
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Flood with water. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Stay upwind and keep out of low areas. Evacuate if fire gets out of control or containers are directly exposed to fire. Evacuation radius: 800 meters (1/2 mile). 










* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Air Release 
Reduce vapors with water spray. Collect runoff for disposal as potential hazardous waste. 



Soil Release 
Trap spilled material at bottom in deep water pockets, excavated holding areas or within sand bag barriers. Dike for later disposal. Absorb with sand or other non-combustible material. Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda ash). 



Water Release 
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. Neutralize. 



Occupational spill/release 
Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Flood with water. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 










* * * Section 7 - HANDLING AND STORAGE  * * *


Handling Procedures 
Subject to handling regulations: U.S. OSHA 29 CFR 1910.119. 



Storage Procedures 
Store and handle in accordance with all current regulations and standards. Store in a tightly closed container. Refrigerate. Keep in the dark. Vent containers periodically (or when exposed to heat). Open containers carefully. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355 Part B). Keep separated from incompatible substances. 










* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 




Component Analysis 
Biological limit value 
There are no biological limit values for any of this product's components. 




Ventilation 
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 



PERSONAL PROTECTIVE EQUIPMENT 
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 



Protective Clothing 
Wear appropriate chemical resistant clothing. 



Glove Recommendations 
Wear appropriate chemical resistant gloves. 



Respiratory Protection 
The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 25 ppm Any supplied-air respirator operated in a continuous-flow mode. Any air-purifying respirator with a full facepiece and a canister providing protection against this substance. Only non-oxidizable sorbents are allowed (not charcoal). Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted canister providing protection against the compound of concern. Only non-oxidizable sorbents are allowed (not charcoal). Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape - Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted canister providing protection against the compound of concern. Only non-oxidizable sorbents are allowed (not charcoal). Any appropriate escape-type, self-contained breathing apparatus. 










* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance  Not available  Physical State  Liquid
Odor  Not available  Color  colorless to yellow
Odor Threshold  Not available  pH  (acidic)
Melting Point  Not available  Boiling Point  Not available 
Freezing point  Not available  Evaporation Rate  Not available 
Boiling Point Range  Not available  Flammability (solid, gas)  Not available 
Autoignition  Not available  Flash Point  not flammable
Lower Explosive Limit  Not available  Decomposition  Not available 
Upper Explosive Limit  Not available  Vapor Pressure  6.6 mmHg at 20 °C
Vapor Density (air=1)  1.3 Specific Gravity (water=1)  1.49
Water Solubility  Not available  Partition coefficient: n-octanol/water  Not available 
Viscosity  Not available  Solubility (Other)  Not available 
Change in color  changes color on exposure to light, hygroscopic Density  Not available 
Physical Form  fuming liquid Molecular Formula  H-N-O3
Molecular Weight  63.01











* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 
Stable at normal temperatures and pressure. May react with evolution of heat on contact with water. 



Conditions to Avoid 
Avoid contact with combustible materials. Keep dry. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. 



Incompatible Materials 
acids, combustible materials, halo carbons, amines, bases, oxidizing materials, metals, halogens, metal salts, metal oxides, reducing agents, peroxides, metal carbide, cyanides, 



NITRIC ACID: ACETIC ACID: May react explosively. ACETIC ANHYDRIDE: Explosive reaction by friction or impact. ACETONE: May react explosively. ACETONITRILE: Explosive mixture. 4-ACETOXY-3-METHOXYBENZALDEHYDE: Exothermic reaction. ACROLEIN: Temperature and pressure increase in closed container. ACRYLONITRILE: Explosive reaction at 90 C. ACRYLONITRILE-METHACRYLATE COPOLYMER: Incompatible. ALCOHOLS: Possible violent reaction or explosion; formation of explosive compound in the presence of heavy metals. ALKANETHIOLS: Exothermic reaction with possible ignition. 2-ALKOXY-1,3-DITHIA-2-PHOSPHOLANE: Ignition reaction. ALLYL ALCOHOL: Temperature and pressure increase in closed container. ALLYL CHLORIDE: Temperature and pressure increase in closed container. AMINES (ALIPHATIC OR AROMATIC): Possible ignition reaction. 2-AMINOETHANOL: Temperature and pressure increase in closed container. 2-AMINOTHIAZOLE: Explosive reaction. AMMONIA (GAS): Burns in an atmosphere of nitric acid vapor. AMMONIUM HYDROXIDE: Temperature and pressure increase in closed container. AMMONIUM NITRATE: Forms explosive mixture. ANILINE: Ignites on contact. ANILINIUM NITRATE: Forms explosive solution. ANION EXCHANGE RESINS: Possible violent exothermic reaction. ANTIMONY: Violent reaction. ARSINE: Explosive reaction. ARSINE-BORON TRIBROMIDE: Violent oxidation. BASES: Reacts. BENZENE: Explosive reaction. BENZIDINE: Spontaneous ignition. BENZONITRILE: Possible explosion. BENZOTHIOPHENE DERIVATIVES: Formation of possibly explosive compounds. N-BENZYL-N-ETHYLANILINE: Vigorous decomposition. 1,4-BIS(METHOXYMETHYL)2,3,5,6-TETRAMETHYLBENZENE: Gas evolution. BISMUTH: Intense exothermic reaction or explosion. 1,3-BIS(TRIFLUOROMETHYL)BENZENE: Possible explosion. BORON: Violent reaction with incandescence. BORON DECAHYDRIDE: Explosive reaction. BORON PHOSPHIDE: Ignition reaction. BROMINE PENTAFLUORIDE: Ignition reaction. N-BUTYL MERCAPTAN: Ignition reaction. N-BUTYRALDEHYDE: Temperature and pressure increase in closed container. CADMIUM PHOSPHIDE: Explosive reaction. CALCIUM HYPOPHOSPHITE: Ignition reaction. CARBON (PULVERIZED): Violent reaction. CELLULOSE: Forms easily combustible ester. CHLORATES: Reacts. CHLORINE: Incompatible. CHLORINE TRIFLUORIDE: Violent reaction. CHLOROBENZENE: Possible explosion. 4-CHLORO-2-NITROANILINE: Forms explosive compound. CHLOROSULFONIC ACID: Temperature and pressure increase in closed container. COAL: Explosive mixture. COATINGS: Attacks. CRESOL: Temperature and pressure increase in closed container. CROTONALDEHYDE: Violent decomposition with ignition. CUMENE: Temperature and pressure increase in closed container. CUPRIC NITRIDE: Explosive reaction. CUPROUS NITRIDE: Violent reaction. CYANATES: Possible explosive reaction. CYCLOHEXANONE: Violent reaction. CYCLOHEXYLAMINE: Forms explosive compound. CYCLOPENTADIENE: Explosive reaction. 1,2-DIAMINOETHANEBIS(TRIMETHYLGOLD): Explosive reaction. DIBORANE: Spontaneous ignition. DI-2-BUTOXYETHYL ETHER: Violent decomposition reaction. 2,6-DI-T-BUTYL PHENOL: Formation of explosive compound. DICHLOROETHANE: Forms shock and heat sensitive mixture. DICHLOROETHYLENE: Forms explosive compound. DICHLOROMETHANE: Forms explosive solution. DICYCLOPENTADIENE: Spontaneous ignition. DIENES: Ignition reaction. DIETHYLAMINO ETHANOL: Possible explosion. DIETHYL ETHER: Possible explosion. 3,6-DIHYDRO-1,2,2H-OXAZINE: Explosive interaction. DIISOPROPYL ETHER: Temperature and pressure increase in closed container. DIMETHYLAMINOMETHYLFERROCENE: Violent decomposition if heated. DIMETHYL ETHER: Forms explosive compound. DIMETHYL HYDRAZINE: Ignites on contact. DIMETHYL SULFOXIDE + 1,4-DIOXANE: Explosion. DIMETHYL SULFOXIDE + <14% WATER: Explosive reaction. DINITROBENZENE: Explosion hazard. DINITROTOLUENE: Explosive reaction. DIOXANE + PERCHLORIC ACID: Possible explosion. DIPHENYL DISTIBENE: Explosive oxidation. DIPHENYL MERCURY + CARBON DISULFIDE: Violent reaction. DIPHENYL TIN: Ignition reaction. DISODIUM PHENYL ORTHOPHOSPHATE: Violent explosion. DIVINYL ETHER: Possible ignition reaction. EPICHLOROHYDRIN: Temperature and pressure increase in closed container. ETHANESULFONAMIDE: Explosive reaction. ETHOXY-ETHYLENE DITHIOPHOSPHATE: Ignition on contact. M-ETHYL ANILINE: Ignition reaction. ETHYLENE DIAMINE: Temperature and pressure increase in closed container. ETHYLENE GLYCOL: Forms shock and heat sensitive mixture. ETHYLENEIMINE: Temperature and pressure increase in closed container. 5-ETHYL-2-METHYL PYRIDINE: Explosive reaction. ETHYL PHOSPHINE: Ignition reaction. 5-ETHYL-2-PICOLINE: Forms explosive compounds. FERROUS OXIDE (POWDERED): Intense exothermic reaction. FLUORINE: Possible explosive reaction. FORMIC ACID: Exothermic reaction with release of toxic gases. 2-FORMYLAMINO-1-PHENYL-1,3-PROPANEDIOL: Possible explosion. FUEL OIL (BURNING): Explosion. FULMINATES: Reacts. FURFURYLIDENE KETONES: Ignites on contact. GERMANIUM: Violent reaction. GLYCEROL: Possible explosion. GLYOXAL: Temperature and pressure increase in closed container. HEXALITHIUM DISILICIDE: Explosive reaction. HEXAMETHYLBENZENE: Possible explosion. 2,2,4,4,6,6-HEXAMETHYLTRITHIANE: Explosive oxidation. HEXENAL: Explodes on heating. HYDRAZINE: Violent reaction. HYDRAZOIC ACID: Energetic reaction. HYDROGEN IODIDE: Ignition reaction. HYDROGEN PEROXIDE: Forms unstable mixture. HYDROGEN PEROXIDE AND KETONES: Forms explosive products. HYDROGEN PEROXIDE AND MERCURIC OXIDE: Forms explosive compounds. HYDROGEN PEROXIDE AND THIOUREA: Forms explosive compounds. HYDROGEN SELENIDE: Ignition reaction. HYDROGEN SULFIDE: Incandescent reaction. HYDROGEN TELLURIDE: Ignition and possible explosive reaction. INDANE AND SULFURIC ACID: Explosive reaction. ISOPRENE: Temperature and pressure increase in closed container. KETONES (CYCLIC): Violent reaction. LACTIC ACID + HYDROFLUORIC ACID: Explosive reaction. LITHIUM: Ignition reaction. LITHIUM SILICIDE: Incandescent reaction. MAGNESIUM: Explosive reaction. MAGNESIUM + 2-NITROANILINE: May ignite on contact. MAGNESIUM PHOSPHIDE: Incandescent reaction. MAGNESIUM SILICIDE: Violent reaction. MAGNESIUM-TITANIUM ALLOY: Forms shock and heat sensitive mixture. MANGANESE (POWDERED): Incandescence and possible explosion. MESITYL OXIDE: Temperature and pressure increase in closed container. MESITYLENE: Possible explosive reaction. METALS: Violent reaction with explosion or ignition. METAL ACETYLIDES: Violent or explosive reaction. METAL CARBIDES: Violent or explosive reaction. METAL CYANIDES: Explosive reactions. METAL FERRICYANIDE OR FERROCYANIDE: Violent reaction. METAL SALICYLATES: Forms explosive compounds. METAL THIOCYANATES: Possible explosion. 2-METHYLBENZIMIDAZOLE + SULFURIC ACID: Possible explosive reaction. 4-METHYLCYCLOHEXANONE: Explosive reaction. 2-METHYL-5-ETHYLPYRIDINE: Temperature and pressure increase in closed container. METHYL THIOPHENE: Ignition reaction. NEODYMIUM PHOSPHIDE: Violent reaction. NICKEL TETRAPHOSPHIDE: Ignition reaction. NITRO AROMATIC HYDROCARBONS: Forms highly explosive products. NITROBENZENE: Explosive reaction, especially in the presence of water. NITROMETHANE: Explosive reaction. NITRONAPHTHALENE: Explosion hazard. NON-METAL OXIDES: Explosive reaction. OLEUM: Temperature and pressure increase in closed container. ORGANIC MATERIALS: Fire and explosion hazard. ORGANIC SUBSTANCES: Possible explosion. PERCHLORATES: Possible explosion. PHENYL ACETYLENE + 1,1-DIMETHYLHYDRAZINE: Violent reaction. PHENYL ORTHOPHOSPHORIC ACID DISODIUM SALT: Forms explosive products. PHOSPHINE + OXYGEN: Spontaneous ignition. PHOSPHONIUM IODIDE: Ignition reaction. PHOSPHORUS (VAPOR): Ignites when heated. PHOSPHOROUS HALIDES: Ignition reaction. PHOSPHORUS TETRAIODIDE: Vigorous reaction. PHOSPHORUS TRICHLORIDE: Explosive reaction. PHTHALIC ACID: Possible explosive reaction. PHTHALIC ANHYDRIDE: Exothermic reaction and forms explosive products. PICRATES: Reacts. PLASTICS: Attacks. POLYALKENES: Intense reaction. POLYDIBROMOSILANES: Explosive reaction. POLY(ETHYLENE OXIDE) DERIVATIVES: Possible explosion. POLYPROPYLENE: Temperature and pressure increase in a closed container. POLY(SILYLENE): Ignition. POLYURETHANE (FOAM): Vigorous reaction. POTASSIUM HYPOPHOSPHITE: Explosive reaction. POTASSIUM PHOSPHINATE: Explodes on evaporation. B-PROPIOLACTONE: Temperature and pressure increase in closed container. PROPIOPHENONE + SULFURIC ACID: Exothermic reaction above -5 C. PROPYLENE GLYCOL + HYDROFLUORIC ACID + SILVER NITRATE: Explosive mixture. PROPYLENE OXIDE: Temperature and pressure increase in closed container. PYRIDINE: Temperature and pressure increase in closed container. PYROCATECHOL: Ignites on contact. REDUCING AGENTS: Possible explosive or ignition reaction. RESORCINOL: Possible explosion. RUBBER: Vigorous reaction, possible explosion. SELENIUM: Vigorous reaction. SELENIUM HYDRIDE: Ignition or incandescent reaction. SELENIUM IODOPHOSPHIDE: Explosive reaction. SILICON: Violent reaction. SILICONE OIL: Possible explosion. SILVER BUTEN-3-YNIDE: Explosion. SODIUM: Spontaneous ignition. SODIUM AZIDE: Exothermic reaction. SODIUM HYDROXIDE: Temperature and pressure increase in a closed container. STIBINE: Explosive reaction. SUCROSE (SOLID): Vigorous reaction. SULFAMIC ACID: Violent reaction with evolution of toxic nitrous oxide. SULFIDES: Reacts. SULFUR DIOXIDE: Explosive reaction. SULFUR HALIDES: Violent reaction. SULFURIC ACID: Possible explosion. SULFURIC ACID + GLYCERIDES: Explosive reaction. SULFURIC ACID + TEREPHTHALIC ACID: Violent reaction. SURFACTANTS + PHOSPHORIC ACID: Explosion hazard. TERPENES: Spontaneous ignition. TETRABORANE: Explosive reaction. TETRABORANE DECAHYDRIDE: Explosive reaction. TETRAPHOSPHOROUS DIIODOTRISELENIDE: Explosive reaction. TETRAPHOSPHOROUS IODIDE: Ignites on contact. TETRAPHOSPHOROUS TETRAOXIDE TRISULFIDE: Violent reaction. THIOALDEHYDES: Violent reaction. THIOKETONES: Violent reaction. THIOPHENES: Explosive reaction. TITANIUM: Forms shock-sensitive compound. TITANIUM ALLOYS: Possible explosive reaction. TITANIUM-MAGNESIUM ALLOY: Possible explosion on impact. TOLUENE: Violent reaction. TOLUIDENE: Ignition reaction. 1,3,5-TRIACETYLHEXAHYDRO-1,3,5-TRIAZINE + TRIFLUOROACETIC ANHYDRIDE: Explosive reaction. TRIAZINE: Violently explosive reaction. TRICADMIUM DIPHOSPHIDE: Explosive reaction. TRIETHYLGALLIUM MONOETHYL ETHER COMPLEX: Ignition reaction. TRIMETHYLTRIOXANE: Intense reaction. TRIS(IODOMERCURI)PHOSPHINE: Violent decomposition. TRITHIOACETONE: Explosive reaction. TURPENTINE: Explosive mixture. UNSYMMETRICAL DIMETHYL HYDRAZINE: Spontaneous ignition. URANIUM: Explosive reaction. URANIUM ALLOY: Violent reaction. URANIUM DISULFIDE: Violent reaction. URANIUM-NEODYMIUM ALLOYS: Explosive reaction. VINYL ACETATE: Temperature and pressure increase in closed container. VINYLIDENE CHLORIDE: Temperature and pressure increase in closed container. WOOD: Possible ignition. P-XYLENE: Intense reaction in presence of sulfuric acid. ZINC: Incandescent reaction. ZINC ETHOXIDE: Possible explosion. ZIRCONIUM-URANIUM ALLOYS: Explosive reaction.

Hazardous Decomposition Products 
oxides of nitrogen 



Thermal decomposition products: oxides of nitrogen.

Possibility of Hazardous Reactions 
Will not polymerize. 










* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 




Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA





Medical Conditions Aggravated by Exposure 
eye disorders, respiratory disorders, skin disorders and allergies, 



Inhalation - Acute Exposure 
NITRIC ACID: Inhalation of acidic substances may cause severe respiratory irritation with coughing, choking, and possibly yellowish burns of the mucous membranes Other initial symptoms may include dizziness, headache, nausea, and weakness Pulmonary edema may be immediate in the most severe exposures, but more likely will occur after a latent period of 5-72 hours The symptoms may include tightness in the chest, dyspnea, dizziness, frothy sputum, and cyanosis Physical findings may include hypotension, weak, rapid pulse, moist rales, and hemoconcentration In non-fatal cases, complete recovery may occur within a few days or weeks or, convalescence may be prolonged with frequent relapses and continued dyspnea and other signs and symptoms of pulmonary insufficiency In severe exposures, death due to anoxia may occur within a few hours after onset of the symptoms of pulmonary edema or following a relapse.



Inhalation - Chronic Exposure 
NITRIC ACID: Depending on the concentration and duration of exposure, repeated or prolonged exposure to an acidic substance may cause erosion of the teeth, inflammatory and ulcerative changes in the mouth, and possibly jaw necrosis Bronchial irritation with cough and frequent attacks of bronchial pneumonia may occur Gastrointestinal disturbances are also possible.



Skin Contact - Acute Exposure 
NITRIC ACID: Direct contact with liquid or vapor may cause severe pain, burns and possibly yellowish stains Burns may be deep with sharp edges and heal slowly with scar tissue formation Dilute solutions of nitric acid may produce mild irritation and harden the epidermis without destroying it Concentrated acid solutions applied to over 25% of the skin area in rats produced elevated methemoglobin and blood nitrate levels.



Skin Contact - Chronic Exposure 
NITRIC ACID: Effects depend on the concentration and duration of exposure Repeated or prolonged contact with acidic substances may result in dermatitis or effects similar to acute exposure.



Eye Contact - Acute Exposure 
NITRIC ACID: Direct contact with acidic substances may cause pain and lacrimation, photophobia, and burns, possibly severe The degree of injury depends on the concentration and duration of contact In mild burns, the epithelium regenerates rapidly and the eye recovers completely In severe cases, the extent of injury may not be fully apparent for several weeks Ultimately, the whole cornea may become deeply vascularized and opaque resulting in blindness In the worst cases, the eye may be totally destroyed Concentrated nitric acid may impart a yellow color to the eye upon contact.



Eye Contact - Chronic Exposure 
NITRIC ACID: Effects depend on the concentration and duration of exposure Repeated or prolonged exposure to acidic substances may cause conjunctivitis or effects as in acute exposure.



Ingestion - Acute Exposure 
NITRIC ACID: Acidic substances may cause circumoral burns with yellow discoloration and corrosion of the mucous membranes of the mouth, throat and esophagus There may be immediate pain and difficulty or inability to swallow or speak Epiglottal edema may result in respiratory distress and possibly asphyxia Marked thirst, epigastric pain, nausea, vomiting and diarrhea may occur Depending on the degree of espohageal and gastric corrosion, the vomitus may contain fresh or dark precipitated blood and large shreds of mucosa Shock with marked hypotension, weak, rapid pulse, shallow respiration, and clammy skin may occur Circulatory collapse may ensue and if uncorrected, lead to renal failure In severe cases, gastric, and to a lesser degree, esophageal perforation and subsequent peritonitis may occur and be accompanied by fever and abdominal rigidity Esophageal, gastric anc pyloric stricture may occur within a few weeks, but may be delayed for months or even years Death may result within a short time from asphyxia, circulatory collapse or aspiration of even minute amounts Later death may be due to peritonitis, severe nephritis or pneumonia Coma and convulsions sometimes occur terminally.



Ingestion - Chronic Exposure 
NITRIC ACID: Depending on the concentration, repeated ingestion of acidic substances may result in inflammatory and ulcerative changes in the mucous membranes of the mouth and other effects as in acute ingestion Reproductive effects have been reported in animals.










* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 















* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. 



Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 











* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN/NA #: UN2031

Packing Group: II

Required Label(s): 8




TDG Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Required Label(s): 8




ADR Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Required Label(s): 8




RID Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Required Label(s): 8




IATA Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Required Label(s): 8




ICAO Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Required Label(s): 8




IMDG Information:

Shipping Name: NITRIC ACID, (Contains:WHITE FUMING NITRIC ACID)

Hazard Class: 8

UN#: UN2031

Packing Group: II

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 















* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 




SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactivity: No








U.S. State Regulations 
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA 




Not listed under California Proposition 65 





Symbol(s)

O Oxidizing

C Corrosive

Risk Phrases

R8 Contact with combustible material may cause fire.

R34 Causes burns.

Safety Phrases

S2 Keep out of the reach of children.

S20 When using do not eat or drink.

S24 Avoid contact with skin.

S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S27 Take off immediately all contaminated clothing.

S39 Wear eye/face protection.

S46 If swallowed, seek medical advice immediately and show this container or label.




Component Analysis - Inventory 
Component  CAS#  US  CA  EU  AU  PH  JP  KR  CN  NZ 
WHITE FUMING NITRIC ACID 52583-42-3 No  No  No  No  No  No  No  Yes  No 








Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Japan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Korea GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification




Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification












Classification 
No classification assigned. 










* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 



Other Information 
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 
Disclaimer: 
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 







Copyright 
Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved