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危险化学品

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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 

SUCCINIC ACID PEROXIDE

ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.







Chemical Family 

organic peroxides 

Synonyms 

3,3-(DIOXYDICARBONYL)DIPROPIONIC ACID; ALPHOZONE; BIS(3-CARBOXYPROPIONYL) PEROXIDE; SUCCINIC PEROXIDE; SUCCINYL PEROXIDE; UN 2135; STCC 4919170








* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  white 

Change in color: Not available

Physical Form: powder

Odor:  odorless 

Health Hazards:  eye burns 

Physical Hazards:  May explode if exposed to shock, friction or heating. Flammable solid. Explosive if dry. Dust/air mixtures may ignite or explode. Organic peroxide. May ignite or explode on contact with combustible materials. 



Potential Health Effects 
Inhalation 

Short Term:  irritation, headache 

Long Term:  no information is available 



Skin Contact 

Short Term:  no information is available 

Long Term:  no information on significant adverse effects 



Eye Contact 

Short Term:  burns 

Long Term:  same as effects reported in short term exposure 



Ingestion 

Short Term:  difficulty breathing 

Long Term:  no information is available 














* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
123-23-9 204-611-5 --SUCCINIC ACID PEROXIDE--100










* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 

Skin 

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. 

Eyes 

Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 

Ingestion 

Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. 

Note to Physicians 

For inhalation, consider oxygen. For ingestion, consider gastric lavage. 








* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 

NFPA Ratings: 
Health: 3 Fire: 3 Reactivity: 4

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe



Flammable Properties 

Severe fire hazard. Dust/air mixtures may ignite or explode. Organic peroxide. Flammable. Burns faster as the fire progresses. May ignite or explode on contact with combustible materials. Containers may rupture or explode if exposed to heat. 

Extinguishing Media 

regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. 

Fire Fighting Measures 

Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). 








* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Occupational spill/release 

Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Use non-sparking tools and equipment. Move containers away from spill to a safe area. Large spills: Wet down area with water. Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. 








* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 

Store and handle in accordance with all current regulations and standards. Store in a tightly closed container. Keep in the dark. Keep separated from incompatible substances. 








* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Component Exposure Limits 

ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components 



Component Analysis 

Biological limit value 

There are no biological limit values for any of this product's components. 



Ventilation 

Based on available information, additional ventilation is not required. Ensure compliance with applicable exposure limits. 

PERSONAL PROTECTIVE EQUIPMENT 

Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 

Protective Clothing 

Wear appropriate chemical resistant clothing. 

Glove Recommendations 

Wear appropriate chemical resistant gloves. 

Respiratory Protection 

Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any air-purifying half-mask respirator equipped with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator (gas mask) with a chin-style, front-mounted or back-mounted organic vapor canister having an N100, R100, or P100 filter. Any powered, air-purifying respirator with a tight-fitting facepiece, organic vapor cartridge(s) and high-efficiency particulate filter(s). Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 








* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available Physical State Solid
Odor odorlessColor white
Odor Threshold Not available pH Not available 
Melting Point Not available Boiling Point Not available 
Freezing point Not available Evaporation Rate Not available 
Boiling Point Range Not available Flammability (solid, gas) Not available 
Autoignition Not available Flash Point Not available 
Lower Explosive Limit Not available Decomposition 125 °C
Upper Explosive Limit Not available Vapor Pressure Not available 
Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 
Water Solubility 30 %Partition coefficient: n-octanol/water Not available 
Viscosity Not available Solubility (Other) Not available 
Bioconcentration Factor (BCF) 0.5Density Not available 
KOC 669.88 (estimated from water solubility)Physical Form powder
Taste sour tasteMolecular Formula C8-H10-O8
Molecular Weight 234.18  



Solvent Solubility 
Soluble 

alcohol, acetone 

Slightly Soluble 

ether 

Insoluble 

benzene, chloroform, petroleum solvents 












* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 

Explosive if dry. May explode if exposed to shock, friction or heating. 

Conditions to Avoid 

Avoid heat, flames, sparks and other sources of ignition. Avoid friction or contamination. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. 

Incompatible Materials 

combustible materials, reducing agents, 

SUCCINIC ACID PEROXIDE: ACRYLIC COMPOUNDS: Polymerization may be initiated by organic peroxides. COMBUSTIBLE MATERIALS: May ignite on contact; finely divided materials may result in an explosion. REDUCING AGENTS: Fire and explosion hazard. VINYL COMPOUNDS: Polymerization may be initiated by organic peroxides.

Hazardous Decomposition Products 

miscellaneous decomposition products 

Thermal decomposition products: miscellaneous decomposition products.

Possibility of Hazardous Reactions 

Will not polymerize. 








* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and no selected endpoints have been identified 



Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA



Inhalation - Acute Exposure 

SUCCINIC ACID PEROXIDE: No data available However, organic peroxides may irritate mucous membranes The vapors of some organic peroxides may cause headaches, intoxication similar to alcohol, and lung edema if inhaled in high concentrations.

Inhalation - Chronic Exposure 

SUCCINIC ACID PEROXIDE No data available.

Skin Contact - Acute Exposure 

SUCCINIC ACID PEROXIDE: No data available Organic peroxides are likely to cause skin irritation.

Skin Contact - Chronic Exposure 

SUCCINIC ACID PEROXIDE: No data available However, prolonged or repeated exposure to organic peroxides may lead to sensitization dermatitis.

Eye Contact - Acute Exposure 

CORROSIVE SUBSTANCES: Direct contact may cause severe irritation, pain and burns, possibly severe The degree of injury depends on the concentration and duration of contact The full extent of the injury may not be immediately apparent.

Eye Contact - Chronic Exposure 

CORROSIVE SUBSTANCES: Effects depend on concentration and duration of exposure Repeated or prolonged contact may result in conjunctivitis or effects as in acute exposure.

Eye - Other Toxicity Information 

SUCCINIC ACID PEROXIDE See information on corrosive substances.

Ingestion - Acute Exposure 

SUCCINIC ACID PEROXIDE: No data available Ingestion of organic peroxides may cause decreased pulse and temperature, dyspnea, and stupor.

Ingestion - Chronic Exposure 

SUCCINIC ACID PEROXIDE No data available.








* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

No LOLI ecotoxicity data are available for this product's components 














* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 

Dispose in accordance with all applicable regulations. 

Component Waste Numbers 

The U.S. EPA has not published waste numbers for this product's components 










* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information:

Shipping Name: ORGANIC PEROXIDE TYPE B, SOLID, (Contains:SUCCINIC ACID PEROXIDE)

Hazard Class: 5.2

UN/NA #: UN3102

Required Label(s): 5.2, 1



TDG Information:

No Classification assigned.



ADR Information:

No Classification assigned.



RID Information:

Shipping Name: ORGANIC PEROXIDE TYPE B, SOLID

Hazard Class: 5.2

UN#: UN3102

Required Label(s): 5.2 + 1



IATA Information:

No Classification assigned.



ICAO Information:

No Classification assigned.



IMDG Information:

Shipping Name: ORGANIC PEROXIDE TYPE B, SOLID

Hazard Class: 5.2

UN#: UN3102

Component Marine Pollutants (IMDG) 

Not regulated as dangerous goods. 














* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan 



SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Acute Health: Yes Chronic Health: No Fire: Yes Pressure: Yes Reactivity: Yes







U.S. State Regulations 
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA 



Not listed under California Proposition 65 



Symbol(s)

O Oxidizing

F Highly Flammable

Xi Irritant

Risk Phrases

R2 Risk of explosion by shock, friction, fire or other sources of ignition.

R7 May cause fire.

R11 Highly flammable.

R36 Irritating to eyes.

R41 Risk of serious damage to eyes.

Safety Phrases

S2 Keep out of the reach of children.

S24 Avoid contact with skin.

S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S39 Wear eye/face protection.

S46 If swallowed, seek medical advice immediately and show this container or label.



Component Analysis - Inventory 
Component CAS# US CA EU AU PH JP KR CN NZ 
SUCCINIC ACID PEROXIDE123-23-9Yes NSL EIN No Yes Yes Yes Yes No 







Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification

European Union GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Indonesia GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
SUCCINIC ACID PEROXIDE (123-23-9) Approval: 23A5084

Organic Peroxides Type B H241 Heating may cause a fire or explosion



Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
SUCCINIC ACID PEROXIDE (123-23-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H241 Heating may cause a fire or explosion

Prevention

P234 Keep only in original container

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

Storage

P410 Protect from sunlight

P411+P235 Store at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
SUCCINIC ACID PEROXIDE (123-23-9)

NEMA:Organic Peroxides Type C;Type D H242 Heating may cause a fire



Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
SUCCINIC ACID PEROXIDE (123-23-9)

Symbol(s)

 


Signal Word Danger

Hazard(s)

H242 Heating may cause a fire

Prevention

P234 Keep only in original container

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P220 Keep/Store away from clothing/combustible materials

P280 Wear protective gloves/protective clothing/eye protection/face protection

Storage

P410 Protect from sunlight

P411+P235 Store at temperatures not exceeding manufacturer recommendations

P420 Store away from other materials

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations



New Zealand GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



South Africa GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification



Taiwan GHS Classifications 

No published information available

This material may be hazardous according to published criteria for classification











Classification 

No classification assigned. 








* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 

Other Information 

Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 

Disclaimer: 

Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 





Copyright 

Copyright 1984-2016 ChemADVISOR, Inc "RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved